CN104357946A - Radiation-proof flame-retardant cotton fiber and preparation method thereof - Google Patents
Radiation-proof flame-retardant cotton fiber and preparation method thereof Download PDFInfo
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Abstract
The invention discloses radiation-proof flame-retardant cotton fiber. The radiation-proof flame-retardant cotton fiber is characterized by being prepared by raw materials in parts by weight as follows: 20-25 parts of the cotton fiber, 2-5 parts of polyester, 4.6-7.3 parts of nano-silver fiber, 12-14 parts of pinus massoniana fiber, 10-12 parts of water soluble polyurethane resin, 12-14 parts of polyethylene glycol oleate, 2.1-3.2 parts of isopropanolamine, 2-4 parts of maca, 1-3 parts of forsythia suspense, 2-5 parts of dandelion, 1.1-2.5 parts of zinc stearate, 3-5 parts of nano organically modified montmorillonite, 5-7 parts of jojoba oil, 105-110 parts of 1-butyl-3-ethylimidazolium dibutyl phosphate, 90-100 parts of 1-butyl-3-methylimidazole acetate, 4-6 parts of an auxiliary and appropriate amount of water. Through synergistic flame retardant function of the nano organically modified montmorillonite, the nano-silver fiber, the polyester and the like, the flame retardant effect and the radiation-proof function of the cotton fiber are improved, and the cotton fiber can be widely applied to the field of radiation-proof textile weaving.
Description
Technical field
The present invention relates to textile material technical field, be specifically related to a kind of radiation proof flame retardant type cotton fiber and preparation method thereof.
Background technology
Cotton fiber is fiber coating on the seed of Malvaceae cotton, and also known as cotton, being called for short cotton, is the main raw material of China's textile industry.The moisture absorption of cotton fiber goods and good permeability, wear-resisting washable, soft and warming, wear warmth retention property winter good, dress in summer is ventilative nice and cool, is widely used in the field such as garment material, drapery.
But cotton fiber makes it apply to be restricted because it exists many defects in the prior art.Such as cotton fiber goods are subject to microbial action, are easily corroded by bacterium, mould, and antibacterial and mouldproof effect is not remarkable; The anti-uv-ray of cotton fiber own is poor, makes it make summer clothes and skin chromogenesis precipitation can be caused even to cause cutaneum carcinoma; Cotton fiber flame retardant effect is poor, and the disaster hidden-trouble caused thus is in rising trend.For overcoming the deficiencies in the prior art, be necessary natural cotton fiber in addition modification, thus be obtainedly applicable to the cotton fiber with functions such as cost low, function diversification, fire-retardant, intensity high, sterilization uvioresistant, radiation proofs of modern for the different demands of cotton fiber goods.
Summary of the invention
Object of the present invention is just to provide a kind of radiation proof flame retardant type cotton fiber and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of radiation proof flame retardant type cotton fiber, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 20-25, polyester fiber 2-5, nano silver fibre 4.6-7.3, Pinus Massoniana Fibers 12-14, water soluble polyurethane resin 10-12, Polyethylene Glycol Oleate 12-14, isopropanolamine 2.1-3.2, agate card 2-4, capsule of weeping forsythia 1-3, dandelion 2-5, zinc stearate 1.1-2.5, nanometer organic modification montmonrillonite 3-5, SIMMONDSIA CHINENSIS SEED OIL 5-7,1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester 105-110,1-butyl-3-N-Methylimidazoleacetic salt 90-100, auxiliary agent 4-6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: diethylenetriamine 1-2, epoxychloropropane 3-6, glyoxal 7-9, ethylene glycol 12-14, polyhexamethylene guanide 0.4-0.7, Foral 1.2-2.5, natrium citricum 2.1-2.6, alkyl phosphate 5-7, fatty alcohol-polyoxyethylene ether 6-8, nano silicon 2-3, its preparation method is by swelling for nano silicon room temperature in distilled water 23 hours, form suspension, then diethylenetriamine, epoxychloropropane, glyoxal, ethylene glycol, alkyl phosphate, fatty alcohol-polyoxyethylene ether mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
The preparation method of described a kind of radiation proof flame retardant type cotton fiber, is characterized in that comprising the following steps:
(1) get agate card and break into that juice adds the capsule of weeping forsythia, dandelion boiling 4-6 hour is filtered, toward filtrate in, add cotton fiber, polyester fiber, nano silver fibre, Pinus Massoniana Fibers immersion 7-10 hour, grind after filtering drying;
(2) above-mentioned Chinese medicine filter residue and nanometer organic modification montmonrillonite are put into high-temperature process 30-40 minute, add water soluble polyurethane resin grinding 10-20 minute spraying dry, add Polyethylene Glycol Oleate, isopropanolamine stirs and evenly mixs, be warming up to 130-150 DEG C, keep temperature to stir 2-3 hour;
(3) step (1) product is placed in step (2) and soaks 15-20 minute, roll compacting 10-15 minute, steam treatment 5-10 minute, clean and dry and add 1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester, 1-butyl-3-N-Methylimidazoleacetic salt stirring 20-40 minute, be heated to 100-119 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
The present invention has following beneficial effect: the present invention, by nanometer organic modification montmonrillonite and the effect of the cooperative flame retardant such as nano silver fibre, polyester fiber, improves the flame retardant effect to cotton fiber and radiation proof function, can be widely used in radiation proof textile weaving field.
Detailed description of the invention
Described a kind of radiation proof flame retardant type cotton fiber, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 22, polyester fiber 2, nano silver fibre 5.6, Pinus Massoniana Fibers 12, water soluble polyurethane resin 11, Polyethylene Glycol Oleate 12, isopropanolamine 2.8, agate card 4, the capsule of weeping forsythia 1, dandelion 2, zinc stearate 1.6, nanometer organic modification montmonrillonite 3, SIMMONDSIA CHINENSIS SEED OIL 5,1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester 105,1-butyl-3-N-Methylimidazoleacetic salt 90, auxiliary agent 6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: diethylenetriamine 1, epoxychloropropane 5, glyoxal 8, ethylene glycol 13, polyhexamethylene guanide 0.5, Foral 1.6, natrium citricum 2.5, alkyl phosphate 6, fatty alcohol-polyoxyethylene ether 8, nano silicon 3, its preparation method is by swelling for nano silicon room temperature in distilled water 23 hours, form suspension, then diethylenetriamine, epoxychloropropane, glyoxal, ethylene glycol, alkyl phosphate, fatty alcohol-polyoxyethylene ether mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
Preparation method comprises the following steps:
(1) get agate card and break into that juice adds the capsule of weeping forsythia, dandelion boiling 4-6 hour is filtered, toward filtrate in, add cotton fiber, polyester fiber, nano silver fibre, Pinus Massoniana Fibers immersion 7-10 hour, grind after filtering drying;
(2) above-mentioned Chinese medicine filter residue and nanometer organic modification montmonrillonite are put into high-temperature process 30-40 minute, add water soluble polyurethane resin grinding 10-20 minute spraying dry, add Polyethylene Glycol Oleate, isopropanolamine stirs and evenly mixs, be warming up to 130-150 DEG C, keep temperature to stir 2-3 hour;
(3) step (1) product is placed in step (2) and soaks 15-20 minute, roll compacting 10-15 minute, steam treatment 5-10 minute, clean and dry and add 1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester, 1-butyl-3-N-Methylimidazoleacetic salt stirring 20-40 minute, be heated to 100-119 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
The technical parameter index of the cotton fiber using the present invention to produce is as follows:
(1) pliability is fluffy smooth flexible, and intensity is high, flame retardant effect is excellent;
(2) bacteriostasis rate of finished product to Escherichia coli, staphylococcus aureus, Candida albicans is all greater than 99.1%;
(3) after 30 washings, antibiotic rate still reaches 95.2%.
Claims (2)
1. a radiation proof flame retardant type cotton fiber, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 20-25, polyester fiber 2-5, nano silver fibre 4.6-7.3, Pinus Massoniana Fibers 12-14, water soluble polyurethane resin 10-12, Polyethylene Glycol Oleate 12-14, isopropanolamine 2.1-3.2, agate card 2-4, capsule of weeping forsythia 1-3, dandelion 2-5, zinc stearate 1.1-2.5, nanometer organic modification montmonrillonite 3-5, SIMMONDSIA CHINENSIS SEED OIL 5-7, 1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester 105-110, 1-butyl-3-N-Methylimidazoleacetic salt 90-100, auxiliary agent 4-6, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: diethylenetriamine 1-2, epoxychloropropane 3-6, glyoxal 7-9, ethylene glycol 12-14, polyhexamethylene guanide 0.4-0.7, Foral 1.2-2.5, natrium citricum 2.1-2.6, alkyl phosphate 5-7, fatty alcohol-polyoxyethylene ether 6-8, nano silicon 2-3, its preparation method is by swelling for nano silicon room temperature in distilled water 23 hours, form suspension, then diethylenetriamine, epoxychloropropane, glyoxal, ethylene glycol, alkyl phosphate, fatty alcohol-polyoxyethylene ether mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
2. the preparation method of a kind of radiation proof flame retardant type cotton fiber according to claim 1, is characterized in that comprising the following steps:
(1) get agate card and break into that juice adds the capsule of weeping forsythia, dandelion boiling 4-6 hour is filtered, toward filtrate in, add cotton fiber, polyester fiber, nano silver fibre, Pinus Massoniana Fibers immersion 7-10 hour, grind after filtering drying;
(2) above-mentioned Chinese medicine filter residue and nanometer organic modification montmonrillonite are put into high-temperature process 30-40 minute, add water soluble polyurethane resin grinding 10-20 minute spraying dry, add Polyethylene Glycol Oleate, isopropanolamine stirs and evenly mixs, be warming up to 130-150 DEG C, keep temperature to stir 2-3 hour;
(3) step (1) product is placed in step (2) and soaks 15-20 minute, roll compacting 10-15 minute, steam treatment 5-10 minute, clean and dry and add 1-butyl-3-ethyl imidazol(e) dibutylphosphoric acid ester, 1-butyl-3-N-Methylimidazoleacetic salt stirring 20-40 minute, be heated to 100-119 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104928795A (en) * | 2015-06-26 | 2015-09-23 | 安徽皖翎羽绒制品有限公司 | Down composite fiber with self-cleaning function |
| CN109267349A (en) * | 2018-09-06 | 2019-01-25 | 江苏阳光股份有限公司 | A kind of fire retardant treatment process of over coating overcoat fabric |
| CN111560774A (en) * | 2020-05-20 | 2020-08-21 | 范数学 | High-flame-retardant antistatic fabric and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225552A (en) * | 2008-02-04 | 2008-07-23 | 东华大学 | Method for dissolving and processing wood/cotton bamboo hemp fibre by employing ionic liquid |
| CN103194839A (en) * | 2013-04-22 | 2013-07-10 | 重庆市黔江区澳特尔服装皮具有限责任公司 | Tujia brocade wall hanging |
| CN103696142A (en) * | 2013-12-10 | 2014-04-02 | 马鞍山湖滨无纺布科技有限公司 | Mould-proof mothproof non-woven fabric and preparation method thereof |
| CN103710775A (en) * | 2013-12-18 | 2014-04-09 | 中国科学院过程工程研究所 | Preparation method of ionic liquid keratin spinning solutions |
-
2014
- 2014-10-15 CN CN201410542275.8A patent/CN104357946A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225552A (en) * | 2008-02-04 | 2008-07-23 | 东华大学 | Method for dissolving and processing wood/cotton bamboo hemp fibre by employing ionic liquid |
| CN103194839A (en) * | 2013-04-22 | 2013-07-10 | 重庆市黔江区澳特尔服装皮具有限责任公司 | Tujia brocade wall hanging |
| CN103696142A (en) * | 2013-12-10 | 2014-04-02 | 马鞍山湖滨无纺布科技有限公司 | Mould-proof mothproof non-woven fabric and preparation method thereof |
| CN103710775A (en) * | 2013-12-18 | 2014-04-09 | 中国科学院过程工程研究所 | Preparation method of ionic liquid keratin spinning solutions |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104928795A (en) * | 2015-06-26 | 2015-09-23 | 安徽皖翎羽绒制品有限公司 | Down composite fiber with self-cleaning function |
| CN109267349A (en) * | 2018-09-06 | 2019-01-25 | 江苏阳光股份有限公司 | A kind of fire retardant treatment process of over coating overcoat fabric |
| CN111560774A (en) * | 2020-05-20 | 2020-08-21 | 范数学 | High-flame-retardant antistatic fabric and preparation method thereof |
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