CN104277344B - A kind of shoes for kitchener sole and preparation method thereof - Google Patents
A kind of shoes for kitchener sole and preparation method thereof Download PDFInfo
- Publication number
- CN104277344B CN104277344B CN201410387233.1A CN201410387233A CN104277344B CN 104277344 B CN104277344 B CN 104277344B CN 201410387233 A CN201410387233 A CN 201410387233A CN 104277344 B CN104277344 B CN 104277344B
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- Prior art keywords
- sole
- kitchener
- shoes
- parts
- nitrile rubber
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- 238000002360 preparation method Methods 0.000 title abstract description 16
- 239000003921 oil Substances 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004014 plasticizer Substances 0.000 claims abstract description 16
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 14
- 238000004073 vulcanization Methods 0.000 claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011593 sulfur Substances 0.000 claims abstract description 11
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 11
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 239000000779 smoke Substances 0.000 claims abstract description 9
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000013543 active substance Substances 0.000 claims abstract description 8
- 229910000077 silane Inorganic materials 0.000 claims abstract description 8
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 7
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 7
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 6
- 229920005557 bromobutyl Polymers 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims 2
- 229920001971 elastomer Polymers 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- -1 Tissuemat E Substances 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000003068 static effect Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 101100387915 Caenorhabditis elegans dop-4 gene Proteins 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 235000021152 breakfast Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical group C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention relates to a kind of sole, disclosing a kind of shoes for kitchener sole and preparation method thereof, described shoes for kitchener sole composition includes: nitrile rubber, brombutyl, nano silicon, plasticiser, age resistor, white smoke active agent, silane coupler, chlorinated polyethylene, Tissuemat E, magnesium oxide, zinc oxide, sulfur, vulcanization accelerator；Employing brominated rubber is base rubber, nitrile rubber in conjunction with oil resistant, obtaining a kind of anti-skidding, comfortable shoes for kitchener sole, this shoes for kitchener is that the personnel of operation provide reliable, favourable and safety guarantee under kitchen environment, defines footwear indispensable in work, life.
Description
Technical field
The present invention relates to a kind of sole, particularly to the preparation method of a kind of shoes for kitchener sole.
Background technology
State's Putting common first, bread is the staff of life, and anyone be unable to do without the plain tea and simple food of one day breakfast, lunch and dinner, but the few go to close
The cook that note is chronically in oil smoke surroundings is wearing any footwear.Hotel, dining room kitchen the most disorderly and the most unsystematic, and ground
Having water, cleaning mixture, oil stain on face, cook wears conventional shoe and is easy to slide into, and causes unnecessary injury, and seldom has on market
For the custom-designed shoes of cook.Foot's stress time that needs when cook works to stand for a long time is the longest, adds the relative of kitchen
Moist environment, therefore the design of shoes for kitchener is worthy of careful study very much, especially sole, will have intensive anti-skid design (such as triangle
Shape), pollute at cleaning mixture and must possess good non-skid property on interface, to take into account dress softness, comfortable foot feeling, gently simultaneously
The most convenient etc..
Summary of the invention
In order to make up the deficiency of existing patented technology, it is an object of the invention to provide a kind of anti-skidding, comfortable shoes for kitchener
Sole and preparation method thereof.
For achieving the above object, the solution of the present invention is: a kind of shoes for kitchener sole, composition includes: nitrile rubber, bromine
Change butyl rubber, nano silicon, plasticiser, age resistor, white smoke active agent, silane coupler, chlorinated polyethylene, polyethylene
Wax, magnesium oxide, zinc oxide, sulfur, vulcanization accelerator, and be expressed as by weight:
Nitrile rubber 15 parts
Brombutyl 50-75 part
Nano silicon 10-25 part
Plasticiser 4-10 part
Age resistor 0.5-2 part
White smoke active agent 2-5 part
Silane coupler 1-3 part
Chlorinated polyethylene 1-3 part
Tissuemat E 1-4 part
Magnesium oxide 0.2-1 part
Zinc oxide 1-4 part
Sulfur 0.5-2 part
Vulcanization accelerator 0.5-2 part
Further: described shoes for kitchener sole is preferably prepared from by the raw material of following weight portion by following components:
Nitrile rubber 15 parts
Brombutyl 65-70 part
Nano silicon 15-20 part
Plasticiser 5-7 part
Age resistor 0.5-1 part
White smoke active agent 3 3.5 parts
Silane coupler 1.5-2 part
Chlorinated polyethylene 2.5-3 part
Tissuemat E 2-3 part
Magnesium oxide 0.2 0.6 parts
Zinc oxide 1.5-3 part
Sulfur 0.5-1.0 part
Vulcanization accelerator 0.8-1.5 part
Wherein, described nitrile rubber be acrylonitrile content be the nitrile rubber of the high oil resistant high Mooney viscosity of 41%.
Wherein, described brombutyl is the BIIR 2030 or BIIR X2 of Lanxess Corporation of Germany.
Wherein, described plasticiser at least includes dioctyl phthalate (DOP), dioctyl adipate (DOA), acetyl
One in base tributyl citrate (ATBC).
Wherein, described age resistor is 1010；Described white smoke active agent is PEG 4000；Described silane coupler is
Si-69；Described vulcanization accelerator is MBTS.
A kind of preparation method preparing aforementioned shoes for kitchener sole, weighs all components according to formula proportion, by deoxygenation
Banburying in banbury put into by sizing material beyond zinc, sulfur, vulcanization accelerator, 120-130 degree binder removal, and room temperature places 24 hours, so
After mixing in two-roll mill, and add the zinc oxide of precise, sulfur, vulcanization accelerator, mixing uniformly after, with uniformly
Lamellar slice, is finally cut into material sole shape and puts into sulfidization molding in rubber boots mould, i.e. obtain oil-proof anti-skid rubber soles.
By use aforesaid technical scheme, the invention has the beneficial effects as follows: employing brombutyl be base rubber,
Nitrile rubber in conjunction with oil resistant, it is thus achieved that a kind of anti-skidding, comfortable shoes for kitchener sole, on the ceramic tile ground having water, cleaning mixture, oil stain
Having good non-skid property on face, protection cook is difficult to slip, and dress is soft, comfortable foot feeling, meets under kitchen environment
Particular/special requirement, contrast prior art, the present invention has the advantage that
1, the brombutyl that present invention selection has wider vulcanization characteristics, air-tightness is fine, curingprocess rate is fast is
Main rubber, reduces the hardness of sole, also improves production efficiency while keeping preferable mechanical property.
2, the sole that the present invention obtains, improves comprehensively and pollutes ground static state and dynamic on-slip system in analog kitchen
Number, is the shoes for kitchener sole of a excellent performance.
3, the present invention reduces the usage amount of inorganic filler nano silicon, adds environment-friendlyplasticizer plasticizer, weakens polymerization
The stress of thing molecule interchain, reduces the processing temperature of material, adds the pliability of material simultaneously, improve the comfortable of sole
Property.
Detailed description of the invention
In conjunction with specific embodiment, the present invention is further described.
Embodiment 1:
In the present embodiment, a kind of shoes for kitchener sole is made up of by weight following components:
Nitrile rubber NBR 1,041 15 parts, brombutyl X2 68 parts, nano silicon 17 parts, plasticiser DOP
7 parts, 1,010 0.8 parts of age resistor, white smoke active agent PEG-4000 3 parts, silane coupler Si 69 1.5 parts, chlorinated polyethylene
2.5 parts, Tissuemat E 3 parts, magnesium oxide 0.4 part, zinc oxide 2 parts, 0.8 part of sulfur, accelerator M BTS 1.2 parts.
Sizing material in addition to zinc oxide, sulfur, vulcanization accelerator is put into banburying in banbury, and 115 degree of binder removals, room temperature is put
Put 24 hours, then mixing in two-roll mill, and add the zinc oxide of precise, sulfur, vulcanization accelerator, mixing all
After even, with uniform sheet slice, finally material is cut into sole shape and puts into sulfidization molding in rubber boots mould, only i.e. obtain oil resistant
Sliding rubber soles.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.108 g/cm3, shore hardness 50, DIN wear-resisting 146
cm3, folding 60,000 flawless, hot strength 11.1 MPa, static on-slip coefficient height oil 0.56 oil add water 0.57, dynamic on-slip system
Number SRA heel 0.51 smooths 0.59.
Embodiment 2:
In the present embodiment, the preparation method of a kind of shoes for kitchener sole is the most identical with the preparation method in embodiment 1, institute
Except for the difference that:
Brombutyl X2 50 parts, plasticiser DOP 4 parts.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.113 g/cm3, shore hardness 52, DIN wear-resisting 166
cm3, folding 60,000 flawless, hot strength 10.2 MPa, static on-slip coefficient height oil 0.52 oil add water 0.51, dynamic on-slip system
Number SRA heel 0.49 smooths 0.52.
Embodiment 3:
In the present embodiment, the preparation method of a kind of shoes for kitchener sole is the most identical with the preparation method in embodiment 1, institute
Except for the difference that:
Brombutyl 2,030 75 parts, plasticiser DOP 5 parts, plasticiser DOA 5 parts；Control at 110 degree of binder removals.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.102 g/cm3, shore hardness 48, DIN wear-resisting 148
cm3, folding 60,000 flawless, hot strength 10.8 MPa, static on-slip coefficient height oil 0.58 oil add water 0.58, dynamic on-slip system
Number SRA heel 0.54 smooths 0.60.
Embodiment 4:
In the present embodiment, the preparation method of a kind of shoes for kitchener sole is the most identical with the preparation method in embodiment 1, institute
Except for the difference that:
Nano silicon 25 parts, plasticiser ATBC 10 parts, chlorinated polyethylene 1 part；Control at 120 degree of binder removals.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.117 g/cm3, shore hardness 51, DIN wear-resisting 139
cm3, folding 60,000 flawless, hot strength 10.3 MPa, static on-slip coefficient height oil 0.50 oil add water 0.51, dynamic on-slip system
Number SRA heel 0.48 smooths 0.50.
Embodiment 5:
In the present embodiment, the preparation method of a kind of shoes for kitchener sole is the most identical with the preparation method in embodiment 1, institute
Except for the difference that:
Nano silicon 10 parts, plasticiser DOP 5 parts, plasticiser DOA 5 parts.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.102 g/cm3, shore hardness 49, DIN wear-resisting 145
cm3, folding 60,000 flawless, hot strength 9.5 MPa, static on-slip coefficient height oil 0.61 oil add water 0.61, dynamic on-slip coefficient
SRA heel 0.57 smooths 0.61.
After the data compilation of above-described embodiment 1～5, obtain such as following table 1(note: shore hardness A is according to ISO 7619:
1997 tests, DIN is wear-resisting to be tested according to TM 174:1994, and folding test is tested according to GB/T 15107-2013, hot strength
Testing according to ISO 37:2005, static on-slip coefficient is tested according to F1677:2005, and dynamic on-slip coefficient is according to ISO
13287:2012 test SRA pattern (cleaning mixture pollution interface)):
| Embodiment | 1 | 2 | 3 | 4 | 5 |
| Density (g/cm3) | 1.108 | 1.113 | 1.102 | 1.117 | 1.102 |
| Shore hardness A | 50 | 52 | 48 | 51 | 49 |
| Wear-resisting (the cm of DIN3) | 146 | 166 | 148 | 139 | 145 |
| Folding 60,000 | Flawless | Flawless | Flawless | Flawless | Flawless |
| Hot strength (MPa) | 11.1 | 10.2 | 10.8 | 10.3 | 9.5 |
| Static on-slip coefficient (high oil) | 0.56 | 0.52 | 0.58 | 0.50 | 0.61 |
| Static on-slip coefficient (high oil adds water) | 0.57 | 0.51 | 0.58 | 0.51 | 0.61 |
| Dynamically on-slip coefficient (heel) | 0.51 | 0.49 | 0.54 | 0.48 | 0.57 |
| Dynamically on-slip coefficient (smoothing) | 0.59 | 0.52 | 0.60 | 0.50 | 0.61 |
Table 1: the performance parameter synopsis at the bottom of on-slip EVA shoe of embodiment 1～5 preparation.
In sum, according to the preparation method of shoes for kitchener sole of the present invention, it is possible to prepare a kind of anti-skidding, comfortable cook
Footwear sole, has good non-skid property on the tile floor having water, cleaning mixture, oil stain, and protection is long-time at kitchen work
Cook be difficult to fall down, and dress is soft, comfortable foot feeling, meets the particular/special requirement under kitchen environment.And manufacturing process letter
Single, easy industrialized production.
Described above, only utilize the embodiment of this origination techniques content, any those skilled in the art to use this wound
Make modification, the change done, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (5)
1. a shoes for kitchener sole, it is characterised in that: each component is expressed as by weight:
Nitrile rubber 15 parts
Brombutyl 50-75 part
Nano silicon 10-25 part
Plasticiser 4-10 part
Age resistor 0.5-2 part
White smoke active agent 2-5 part
Silane coupler 1-3 part
Chlorinated polyethylene 1-3 part
Tissuemat E 1-4 part
Magnesium oxide 0.2-1 part
Zinc oxide 1-4 part
Sulfur 0.5-2 part
Vulcanization accelerator 0.5-2 part.
Shoes for kitchener sole the most according to claim 1, it is characterised in that: the parts by weight of each component are:
Nitrile rubber 15 parts
Brombutyl 65-70 part
Nano silicon 15-20 part
Plasticiser 5-7 part
Age resistor 0.5-1 part
White smoke active agent 3 3.5 parts
Silane coupler 1.5-2 part
Chlorinated polyethylene 2.5-3 part
Tissuemat E 2-3 part
Magnesium oxide 0.2-0.6 part
Zinc oxide 1.5-3 part
Sulfur 0.5-1.0 part
Vulcanization accelerator 0.8-1.5 part.
Shoes for kitchener sole the most according to claim 1 and 2, it is characterised in that: nitrile rubber be acrylonitrile content be 41%
The nitrile rubber of high oil resistant high Mooney viscosity.
Shoes for kitchener sole the most according to claim 1 and 2, it is characterised in that: brombutyl is Lanxess Corporation of Germany
BIIR 2030 or BIIR X2.
Shoes for kitchener sole the most according to claim 1 and 2, it is characterised in that: described plasticiser at least includes O-phthalic
One in dioctyl phthalate (DOP), dioctyl adipate (DOA), citroflex A-4 (ATBC).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410387233.1A CN104277344B (en) | 2014-08-07 | 2014-08-07 | A kind of shoes for kitchener sole and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410387233.1A CN104277344B (en) | 2014-08-07 | 2014-08-07 | A kind of shoes for kitchener sole and preparation method thereof |
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| CN104277344A CN104277344A (en) | 2015-01-14 |
| CN104277344B true CN104277344B (en) | 2016-11-02 |
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| CN104693564B (en) * | 2015-04-01 | 2017-03-22 | 中国皮革和制鞋工业研究院 | Light damping and slipping preventing rubber and plastic foamed sole material and preparing method thereof |
| CN105733162B (en) * | 2016-04-19 | 2018-01-23 | 莆田市协顺鞋业有限公司 | A kind of lightweight Oil resistant sole material and preparation method thereof |
| CN105694149B (en) * | 2016-04-19 | 2018-01-23 | 莆田市协顺鞋业有限公司 | A kind of sole oil resistant low-temperature resistance material and preparation method thereof |
| CN106589491B (en) * | 2016-11-29 | 2019-02-26 | 茂泰(福建)鞋材有限公司 | A kind of anti-slip rubber outsole and its manufacture craft |
| CN108570189A (en) * | 2017-04-11 | 2018-09-25 | 李怡嫱 | A kind of grease proofing material for sole of shoe and preparation method thereof |
| CN107216506A (en) * | 2017-06-01 | 2017-09-29 | 十堰银森工贸有限公司 | A kind of oil resistant synthetic rubber |
| CN107118453A (en) * | 2017-06-13 | 2017-09-01 | 合肥远科服装设计有限公司 | A kind of sole and preparation method thereof |
| CN107118452A (en) * | 2017-06-13 | 2017-09-01 | 合肥远科服装设计有限公司 | A kind of sole for being applied to run and preparation method thereof |
| CN107345010A (en) * | 2017-07-29 | 2017-11-14 | 合肥梵清电子商务有限公司 | One kind energy-conservation sole and preparation method thereof |
| CN107746514A (en) * | 2017-11-21 | 2018-03-02 | 王长程 | A kind of shoes for kitchener sole and preparation method thereof |
| CN108384076B (en) * | 2018-02-08 | 2021-02-12 | 浙江中瑞橡胶高分子材料股份有限公司 | Outsole formula with high oil resistance, antistatic property and slip resistance and preparation method thereof |
| CN108485086A (en) * | 2018-04-11 | 2018-09-04 | 东莞市福斯特橡塑科技有限公司 | A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl |
| CN108997625A (en) * | 2018-05-03 | 2018-12-14 | 林扬发 | A kind of new-type Antiskid rubber and preparation method thereof |
| CN109851873B (en) * | 2019-01-27 | 2021-04-13 | 浙江奥康鞋业股份有限公司 | Formula and production process of oil-water type anti-slip material |
| CN109957157A (en) * | 2019-04-02 | 2019-07-02 | 晋江市鑫铭鞋材科技有限公司 | The formula and its technique of a kind of oil ground Anti-skidding rubber sole |
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|---|---|---|---|---|
| CN101899176B (en) * | 2010-08-20 | 2011-10-05 | 温州市海滨秀龙鞋材有限公司 | Material for sole |
| CN102871291B (en) * | 2012-10-15 | 2015-04-08 | 广州市邦尔福鞋材有限公司 | Anti-skid sole and preparation method thereof |
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2014
- 2014-08-07 CN CN201410387233.1A patent/CN104277344B/en active Active
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