CN104817802B - A kind of high grip rubber soles and preparation method thereof - Google Patents
A kind of high grip rubber soles and preparation method thereof Download PDFInfo
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- CN104817802B CN104817802B CN201510166165.0A CN201510166165A CN104817802B CN 104817802 B CN104817802 B CN 104817802B CN 201510166165 A CN201510166165 A CN 201510166165A CN 104817802 B CN104817802 B CN 104817802B
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005864 Sulphur Substances 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004073 vulcanization Methods 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002480 mineral oil Substances 0.000 claims abstract description 9
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000077 silane Inorganic materials 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 5
- 229920001194 natural rubber Polymers 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims 1
- 238000004513 sizing Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000636 poly(norbornene) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention relates to a kind of sole, a kind of rubber soles with high grip and preparation method thereof are provided, the composition of the high grip rubber soles includes natural rubber, poly-norbornene rubber, brombutyl, mineral oil, white carbon, age resistor, polyethylene glycol, silane coupler, Tissuemat E, zinc oxide, sulphur, vulcanization accelerator, above component material is removed into sulphur, sizing material beyond vulcanization accelerator is put into banburying in banbury, 115 120 degree of dumpings, room temperature is placed 24 hours, then kneaded in two-roll mill, and add the sulphur of precise, vulcanization accelerator, after mixing is uniform, with uniform sheet slice, material is finally cut into sole shape and is put into sulfidization molding in rubber boots mould, obtain high grip rubber soles.
Description
Technical field
The invention belongs to organic high molecular compound technical field, more particularly to a kind of high grip rubber soles and its system
Preparation Method.
Background technology
Poly-norbornene rubber, maintains and is all interfixed between twin nuclei, each two adjacent carbon atom, construction unit
In carbon atom activity it is difficult, therefore with higher glass transition temperature and heat decomposition temperature.Poly-norbornene rubber
Molecular structure is mutually tangled between the macromolecular that some segments rely on chemical bond linkage to get up, macromolecular chain, the presence of side chain
Exacerbate mutual entanglement.Certain deformation is produced under external periodic force effect, causes high polymer due to being tangled between strand
During stretching-retraction circulation needs to overcome the frictional resistance between a part of strand, this deformation to lag behind stress,
The form that mechanical energy is changed into heat energy is dissipated, and is further presented as with high coefficient of friction, i.e. high grip.
The content of the invention
It is an object of the invention to provide it is a kind of with earth-grasping force is good, high mechanical strength the features such as high grip rubber boots
Bottom, and prepare the preparation method of foregoing high grip rubber soles.
To achieve the above object, the present invention is adopted the following technical scheme that：A kind of high grip rubber soles, by component material
By natural rubber, poly-norbornene rubber, brombutyl, white carbon, mineral oil, zinc oxide, age resistor, polyethylene glycol,
Silane coupler, Tissuemat E, sulphur, vulcanization accelerator are prepared from.
Wherein：A kind of each component material of high grip rubber soles is expressed as by weight：
Further, the parts by weight of each component material are preferably：
Wherein, the poly-norbornene rubber is poly-norbornene rubber of the molecular weight in 2,000,000-500 ten thousand dalton.
Wherein, the brominated amount of the brombutyl is more than 1.5%.
A kind of preparation method for preparing foregoing high grip rubber soles, natural rubber, poly- drop are weighed according to formula rate
Norbornene rubber, brombutyl, white carbon, mineral oil, zinc oxide, age resistor, polyethylene glycol, silane coupler, poly- second
Alkene wax, sulphur, vulcanization accelerator, banburying in banbury is put into by sizing material of the component material in addition to sulphur, vulcanization accelerator,
110-120 degree dumpings, room temperature is placed 24 hours, is then kneaded in two-roll mill, and adds the sulphur of precise, vulcanization
Accelerator, after mixing is uniform, with uniform sheet slice, is finally cut into sole shape by material and is put into rubber boots mould and be sulfided into
Type, that is, obtain high grip rubber soles.
By taking preceding solution, the present invention has the advantages that：
1, significantly, it is superior to be embodied in anti-skid property of soles for the effects of high grip rubber soles of the present invention, dry type, wet
The on-slip coefficient of formula is up to 1.17,0.70 respectively, hence it is evident that better than the Antiskid sole of prior art.Because polynorbornene rubber
The distribution of trans base forms the high resistance of intermolecular movement in plastic structure, with high coefficient of friction.
2. the material of main part of high-damping expanded material of the present invention is poly-norbornene rubber, with surface porosity, extremely strong
The features such as absorption affinity and hydrocarbon have high affinity, can add substantial amounts of filling oil without influenceing other physical property, carry
High process operation performance, and reduce production cost.
Embodiment
In conjunction with specific embodiment, the present invention is further described.
Embodiment 1：
In the present embodiment, a kind of high grip rubber soles are made up of by weight following components：
Sizing material of the component material in addition to sulphur, vulcanization accelerator is put into banburying in banbury, 119 degree of dumpings, room temperature
Place 24 hours, then kneaded in two-roll mill, and add the sulphur of precise, vulcanization accelerator, after mixing is uniform,
With uniform sheet slice, material is finally cut into sole shape and is put into sulfidization molding in rubber boots mould, that is, obtains high grip rubber
Rubber sole.
A kind of above-mentioned high grip rubber soles prepared, density 1.08g/cm3, hardness A 62, DIN is wear-resisting
143mm3, tensile strength 18.2MPa, tearing strength 75N/mm, the half sole 1.01 smooth 1.17 of on-slip coefficient dry type heel 1.04, only
The sliding half sole 0.66 smooth 0.70 of coefficient wet type heel 0.66, the wet ice face of on-slip coefficient smooth 0.30.
Embodiment 2：
In the present embodiment, a kind of preparation method of high grip rubber soles substantially with the preparation method phase in embodiment 1
Together, except that：
55 parts of poly-norbornene rubber, 8 parts of brombutyl, 25 parts of white carbon, 25 parts of mineral oil, 2 parts of polyethylene glycol,
2 parts of silane coupler.
A kind of above-mentioned high grip rubber soles prepared, density 1.06g/cm3, hardness A 59, DIN is wear-resisting
167mm3, tensile strength 19.3MPa, tearing strength 79N/mm, the half sole 1.02 smooth 1.06 of on-slip coefficient dry type heel 1.02, only
The sliding half sole 0.62 smooth 0.65 of coefficient wet type heel 0.63, the wet ice face of on-slip coefficient smooth 0.24.
Embodiment 3：
In the present embodiment, a kind of preparation method of high grip rubber soles substantially with the preparation method phase in embodiment 1
Together, except that：
45 parts of poly-norbornene rubber, 12 parts of brombutyl, 35 parts of white carbon, 35 parts of mineral oil, polyethylene glycol 4
Part, 3 parts of silane coupler；Control is in 120 degree of dumpings.
A kind of above-mentioned high grip rubber soles prepared, density 1.16g/cm3, hardness A 69, DIN is wear-resisting
231mm3, tensile strength 15.8MPa, tearing strength 57N/mm, the half sole 0.91 smooth 0.96 of on-slip coefficient dry type heel 0.96, only
The sliding half sole 0.48 smooth 0.52 of coefficient wet type heel 0.49, the wet ice face of on-slip coefficient smooth 0.16.
Embodiment 4：
In the present embodiment, a kind of preparation method of high grip rubber soles substantially with the preparation method phase in embodiment 1
Together, except that：
40 parts of poly-norbornene rubber, 15 parts of brombutyl, 35 parts of white carbon, 25 parts of mineral oil.
A kind of above-mentioned high grip rubber soles prepared, density 1.19g/cm3, hardness A 65, DIN is wear-resisting
287mm3, tensile strength 14MPa, tearing strength 49N/mm, the half sole 0.84 smooth 0.88 of on-slip coefficient dry type heel 0.83, on-slip
The half sole 0.48 smooth 0.49 of coefficient wet type heel 0.47, the wet ice face of on-slip coefficient smooth 0.11.
After the data preparation of above-described embodiment 1~4, obtain such as table 1 below (note：Hardness is measured using GS-706G hardness
Examination, DIN it is wear-resisting according to GB/T 9867-2008 test, tensile strength according to GB/T 528-2009 test, tearing strength according to
GB/T 529-2008 test right-angle tearing test piece, and on-slip coefficient is according to TM144：2011 tests)：
The performance parameter table of comparisons of high grip rubber soles prepared by table 1, embodiment 1~4
In summary, according to high grip rubber soles made from the preparation method of the high grip rubber soles of the present invention
With earth-grasping force is good, high mechanical strength the features such as, be particularly suitable for applying in terms of sole.
Described above, only using the embodiment of this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (5)
1. a kind of high grip rubber soles, it is characterised in that be made up of following raw materials according：
15 parts of natural rubber
40-55 parts of poly-norbornene rubber
8-15 parts of brombutyl
25-35 parts of white carbon
25-35 parts of mineral oil
1-3 part of zinc oxide
1-2 part of age resistor
2-4 parts of polyethylene glycol
2-3 parts of silane coupler
2-3 parts of Tissuemat E
2-3 parts of sulphur
2-3 parts of vulcanization accelerator.
2. high grip rubber soles according to claim 1, it is characterised in that the parts by weight of each raw material are：
15 parts of natural rubber
50 parts of poly-norbornene rubber
10 parts of brombutyl
30 parts of white carbon
30 parts of mineral oil
1 part of zinc oxide
1.5 parts of age resistor
3 parts of polyethylene glycol
3 parts of silane coupler
2 parts of Tissuemat E
2 parts of sulphur
2.2 parts of vulcanization accelerator.
3. high grip rubber soles according to claim 1, it is characterised in that：Poly-norbornene rubber is that molecular weight exists
The poly-norbornene rubber of 2000000-500 ten thousand dalton.
4. high grip rubber soles according to claim 1, it is characterised in that：The brominated amount of the brombutyl is big
In 1.5%.
5. a kind of preparation method for preparing any high grip rubber soles of claim 1-4, it is characterised in that：First by day
Right rubber, poly-norbornene rubber, brombutyl, white carbon, mineral oil, zinc oxide, age resistor, polyethylene glycol, silane
Coupling agent, Tissuemat E are put into banburying in banbury, and 115-120 degree dumpings, room temperature is placed 24 hours, then in two-roll mill
Upper mixing, and the sulphur of precise, vulcanization accelerator are added, after mixing is uniform, with uniform sheet slice, finally material is cut out
Sulfidization molding in rubber boots mould is put into sole shape, that is, obtains high grip rubber soles.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510166165.0A CN104817802B (en) | 2015-04-09 | 2015-04-09 | A kind of high grip rubber soles and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510166165.0A CN104817802B (en) | 2015-04-09 | 2015-04-09 | A kind of high grip rubber soles and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104817802A CN104817802A (en) | 2015-08-05 |
| CN104817802B true CN104817802B (en) | 2017-09-12 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153488A (en) * | 2015-10-09 | 2015-12-16 | 际华三五三七制鞋有限责任公司 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
| CN105801948B (en) * | 2016-04-26 | 2017-11-24 | 茂泰(福建)鞋材有限公司 | A kind of ice face anti-slip rubber composition and its production method |
| CN106065098B (en) * | 2016-06-02 | 2018-01-30 | 泉州市晋科技术检测有限公司 | A kind of ski-proof snow land boots |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101885865B (en) * | 2010-08-09 | 2011-11-02 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102061017B (en) * | 2010-12-06 | 2012-10-10 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| CN104163946A (en) * | 2014-07-16 | 2014-11-26 | 宁国中辰密封件有限公司 | Automobile shock absorber bushing |
| CN104277274B (en) * | 2014-08-07 | 2016-07-20 | 福建登泰科技有限公司 | A kind of oil-proof anti-skid rubber soles and preparation method thereof |
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Inventor after: Ding Sibo Inventor after: Zheng Rongda Inventor after: Lu Xin Inventor after: Luo Xianfa Inventor after: Liao Yibin Inventor after: Guo Cailian Inventor after: Wang Yuling Inventor after: Zhou Xiaolan Inventor after: Lin Jiang Inventor after: Jin Xiaohong Inventor before: Lu Xin Inventor before: Zheng Rongda Inventor before: Ding Sibo Inventor before: Luo Xianfa Inventor before: Liao Yibin Inventor before: Guo Cailian Inventor before: Zhou Xiaolan Inventor before: Lin Hexiang Inventor before: Lin Jiang Inventor before: Jin Xiaohong |
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Effective date of registration: 20160706 Address after: 362200 Jinjiang City, Quanzhou Province, the first industrial zone of the village of the village of Fujian Applicant after: FUJIAN DENGTAI SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: Chen Dai Zhen Jiang tou Cun 362000 Fujian city of Quanzhou province Jinjiang City Applicant before: Maotai(Fujian) Soles Co.,Ltd. |
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Inventor after: Lu Xin Inventor after: Luo Xianfa Inventor after: Ding Sibo Inventor after: Liao Yibin Inventor after: Guo Cailian Inventor after: Lin Hexiang Inventor after: Lin Chouzhi Inventor after: Jin Xiaohong Inventor after: Zheng Rongda Inventor before: Ding Sibo Inventor before: Zheng Rongda Inventor before: Lu Xin Inventor before: Luo Xianfa Inventor before: Liao Yibin Inventor before: Guo Cailian Inventor before: Wang Yuling Inventor before: Zhou Xiaolan Inventor before: Lin Jiang Inventor before: Jin Xiaohong |
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Effective date of registration: 20161025 Address after: 362200 Jinjiang Province, Quanzhou City, the first village of the town of Applicant after: Maotai(Fujian) Soles Co.,Ltd. Address before: 362200 Jinjiang City, Quanzhou Province, the first industrial zone of the village of the village of Fujian Applicant before: FUJIAN DENGTAI SCIENCE AND TECHNOLOGY Co.,Ltd. |
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Address after: No. 588, Jinxin Road, Jiangtou Village, Chendai Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Maotai (Fujian) New Material Technology Co.,Ltd. Address before: 362200 Chen Dai Jiang tou Cun, Jinjiang City, Quanzhou City, Fujian Province Patentee before: Maotai(Fujian) Soles Co.,Ltd. |
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