CN105153488A - Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof - Google Patents
Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN105153488A CN105153488A CN201510647717.XA CN201510647717A CN105153488A CN 105153488 A CN105153488 A CN 105153488A CN 201510647717 A CN201510647717 A CN 201510647717A CN 105153488 A CN105153488 A CN 105153488A
- Authority
- CN
- China
- Prior art keywords
- rubber
- parts
- khaki color
- primer
- calendering type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as a preparation method and application thereof. Through optimization and screening of rubber material compositions, a formula with specific components and specific usage is selected for preparation of the rubber, so that the prepared rubber can be high in technological property and mechanical property, much higher in adhesion property, clear in pattern, good in color effect, and basically odorless; moreover, a rubber shoe edge strip can be wrapped in the rubber, so that the service lives of rubber shoes made of the rubber are long. The preparation method is simple, feasible and low in cost, and the using effect of the rubber is good.
Description
Technical field
The present invention relates to rubber processing, particularly outer bonding rubber boots primer of vapour sulfuration calendering type khaki color and preparation method thereof and application between one.
Background technology
Especially roll in end laminating method rubber overshoes manufacturing processed in shoemaking work, due to the calendering formation adhesive function of rubber will be realized, heavy dose ofly in formula must use the Rubber Softener such as machine oil, and the tenderizers such as machine oil, rubber can not take into account the unity meeting sole bonding performance, odor properties.Rubber adhesion performance to be realized on the one hand, just must expand tenderizer machine oil consumption, cause rubber smell to increase so thereupon, and in order to reduce sizing material smell, then must reduce machine oil consumption, the quality problems of rubber adhesion difference can be caused again.
On the other hand, the low taste that good bond properties ensures product again be realized, then to sacrifice rubber overshoes wear resisting property and tensile property for cost, the work-ing life of rubber overshoes significantly must be reduced again, the user demand of user can not be met.Along with social development, human consumer is to the low smell of rubber overshoes, beautiful in colour and wearing quality proposition requirements at the higher level.There are special needs to end bound edge product simultaneously.
For this reason, at the bottom of the low smell of technique simple high adherence energy, the invention of bound edge sole rubber has realistic meaning.
Summary of the invention
Technical problem to be solved by this invention is: provide outer bonding rubber boots primer of vapour sulfuration calendering type khaki color between one and preparation method thereof and application, it has good bond properties and processing performance, bag Foxing strip for rubber shoes in shoe soles by using vulcanizing rubber can be realized, and smell is low, color effect is good, long service life, to overcome the deficiencies in the prior art.
Of the present inventionly be achieved in that the outer bonding rubber boots primer of a vapour sulfuration calendering type khaki color, mark calculates by weight, comprise 75 ~ 80 parts of standard rubbers, 20 ~ 25 parts of cis-butadiene cements, 1.8 ~ 2.2 parts of sulphur, 0.15 ~ 0.20 part of peptizer DS-T-1,2.2 ~ 2.6 parts of vulcanization accelerators, 2.5 ~ 3.5 parts of stearic acid, 2.5 ~ 3.5 parts of nano zine oxides, 20 ~ 25 parts of 7# machinery oil
45 ~ 50 parts of white carbon blacks, 4.0~
4.5 parts of polyoxyethylene glycol, 10~
15 parts of light calcium carbonates, 2.0 ~ 3.0 parts of anti-aging agent, 8 ~ 10 parts of indenes resin, 0.2 ~ 0.4 part of Whitfield's ointment and 1.4 ~ 1.6 parts of khaki color tinting materials.
Preferred scheme is, mark calculates by weight, comprises 80 parts of standard rubbers, 20 parts of cis-butadiene cements, 2 parts of sulphur, 0.2 part of peptizer DS-T-1,2.4 parts of vulcanization accelerators, 3 parts of stearic acid, 3 parts of nano zine oxides, 23 parts of 7# machinery oil, 50 parts of white carbon blacks, 4.5 parts of polyoxyethylene glycol
10 parts of light calcium carbonates, 2.5 parts of anti-aging agent, 9 parts of indenes resins, 0.3 part of Whitfield's ointment and 1.5 parts of khaki color tinting materials.
Described vulcanization accelerator is, every 2.4 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.6 parts of altaxs and 0.4 part of vulkacit D S.
Described standard rubber is 1# standard rubber; Polyoxyethylene glycol specification is PEG-4000.
Described khaki color tinting material is, khaki color tinting material is made up of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch, and the mass ratio of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch is 11:0.8:8.5:0.1.
Described anti-aging agent is, every 2.5 parts of anti-aging agent are made up of 0.3 part of antioxidant MB, 1 part of anti-aging agent KY-405L and 1.2 part of antioxidant SP-C.
Between the preparation method of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, each component is got by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure in the Banbury mixer of 80 ~ 120 DEG C 6 ~ 8 minutes by standard rubber and peptizer DS-T-1 in temperature, on opening rubber mixing machine, make sheet reel again, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.45 ~ 0.50, 2) mixing: by broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, stearic acid, nano zine oxide, anti-aging agent, khaki color tinting material, Whitfield's ointment, indenes resin drops in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into white carbon black, polyoxyethylene glycol, light calcium carbonate presses refining 5 ~ 6 minutes again, then 7# machinery oil is added, refine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color between obtaining.
Between the application of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, between inciting somebody to action, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color bag roller on opening rubber mixing machine refines glue to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required decorative pattern and thickness again, this film stamping machine is cut into the removing from mould glue embryo sheet of die for shoe-sole requirement shape; Removing from mould glue embryo sheet is adopted to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber soles.
Described employing removing from mould glue embryo sheet to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber solesbe removing from mould glue embryo sheet is fitted in swabbing footwear on the surface, wraps in Foxing strip for rubber shoes surface, after pressing is pasted, produce rubber overshoes by heat of compression air heating sulfuration sizing.
In order to verify effect of the present invention further, carry out following experiment:
Rubber proportioning Selection experiment
The making of selection to master batch of rubber plays a key effect.Test-results is as shown in table 1, table 2:
According to table 1 test-results, natural rubber and cis-1,4-polybutadiene rubber is selected to carry out collocation use-testing, to obtain optimised process performance.
Table 2 obtains, and 2 parts of sulphur, 50 parts of white carbon blacks, 20 parts of light calcium carbonates are optimum amount.
Table 3 obtains, 2.4 parts of vulcanization accelerators, 3 parts of stearic acid, 3 parts of nano zine oxides, and 2.5 parts of anti-aging agent are optimum amount.
Drawn by table 4,4.5 parts of polyoxyethylene glycol, 23 parts of 7# machinery oil, 0.3 part of Whitfield's ointment is optimum amount.
Sizing material color test, 1.5 parts of described khaki color tinting material proportionings are that every 20.4 parts of tinting materials are made up of 11 parts of anatase thpe white powders, 0.8 part of red rubber master batch R-8818 and 8.5 part of yellow rubber master batch Y-8804 and 0.1 part black rubber master batch.
Logical rolled-to-death rubber efficiency test proves, uses 0.1 part of peptizer DS-T-1 that natural rubber can be made to plasticate time shorten half, performance the best.And peptizer DS-T-1 consumption rubber unvulcanizate physicals and processing performance 0.05 ~ 0.15 part time are not affected.
To sum up test-results: preferably optimum formula consumption is: 80 parts of standard rubbers, 20 parts of cis-butadiene cements, 2 parts of sulphur, 0.1 part of peptizer DS-T-1,2.4 parts of vulcanization accelerators, 3 parts of stearic acid, 3 parts of nano zine oxides, 23 parts of 7# machinery oil, 50 parts of white carbon blacks, polyoxyethylene glycol,
10 parts of light calcium carbonates, 2.5 parts of anti-aging agent, 9 parts of indenes resins, 0.3 part of Whitfield's ointment, 1.5 parts of khaki color tinting materials.
Owing to have employed technique scheme, compared with prior art, the present invention is optimized screening to sizing compound formula, select the formula of specific components, specific consumption, such formula makes product have good processing performance and mechanical property, and bond properties significantly improves, prepared product decorative pattern is clear, color effect good, substantially realize tasteless, bag Foxing strip for rubber shoes in shoe soles by using vulcanizing rubber can be realized, long service life.The present invention is simple, with low cost, and the result of use of product is good.
Embodiment
Embodiments of the invention 1: the outer bonding rubber boots primer of a vapour sulfuration calendering type khaki color, mark calculates by weight, comprises 80 parts of standard rubbers, 20 parts of cis-butadiene cements, 2 parts of sulphur, 0.2 part of peptizer DS-T-1,2.4 parts of vulcanization accelerators, 3 parts of stearic acid, 3 parts of nano zine oxides, 23 parts of 7# machinery oil, 50 parts of white carbon blacks, 4.5 parts of polyoxyethylene glycol
10 parts of light calcium carbonates, 2.5 parts of anti-aging agent, 9 parts of indenes resins, 0.3 part of Whitfield's ointment and 1.5 parts of khaki color tinting materials; Described vulcanization accelerator is, every 2.4 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.6 parts of altaxs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber; Polyoxyethylene glycol specification is PEG-4000; Described khaki color tinting material is, khaki color tinting material is made up of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch, and the mass ratio of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch is 11:0.8:8.5:0.1; Described anti-aging agent is, every 2.5 parts of anti-aging agent are made up of 0.3 part of antioxidant MB, 1 part of anti-aging agent KY-405L and 1.2 part of antioxidant SP-C.
Between the preparation method of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, each component is got by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure in the Banbury mixer of 80 ~ 120 DEG C 6 ~ 8 minutes by standard rubber and peptizer DS-T-1 in temperature, on opening rubber mixing machine, make sheet reel again, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.45 ~ 0.50, 2) mixing: by broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, stearic acid, nano zine oxide, anti-aging agent, khaki color tinting material, Whitfield's ointment, indenes resin drops in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into white carbon black, polyoxyethylene glycol, light calcium carbonate presses refining 5 ~ 6 minutes again, then 7# machinery oil is added, refine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color between obtaining.
Between the application of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, between inciting somebody to action, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color bag roller on opening rubber mixing machine refines glue to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required decorative pattern and thickness again, this film stamping machine is cut into the removing from mould glue embryo sheet of die for shoe-sole requirement shape; Removing from mould glue embryo sheet is adopted to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber soles.
Described employing removing from mould glue embryo sheet to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber solesbe removing from mould glue embryo sheet is fitted in swabbing footwear on the surface, wraps in Foxing strip for rubber shoes surface, after pressing is pasted, produce rubber overshoes by heat of compression air heating sulfuration sizing.
Embodiments of the invention 2: the outer bonding rubber boots primer of a vapour sulfuration calendering type khaki color, mark calculates by weight, comprises 75 parts of standard rubbers, 25 parts of cis-butadiene cements, 1.8 parts of sulphur, 0.15 part of peptizer DS-T-1,2.2 parts of vulcanization accelerators, 3.5 parts of stearic acid, 3.5 parts of nano zine oxides, 20 parts of 7# machinery oil, 48 parts of white carbon blacks, 4.0 parts of polyoxyethylene glycol
15 parts of light calcium carbonates, 1 part of anti-aging agent, 8 parts of indenes resins, 0.4 part of Whitfield's ointment and 1.4 parts of khaki color tinting materials; Described vulcanization accelerator is, every 2.4 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.6 parts of altaxs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber; Polyoxyethylene glycol specification is PEG-4000; Described khaki color tinting material is, khaki color tinting material is made up of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch, and the mass ratio of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch is 11:0.8:8.5:0.1; Described anti-aging agent is, every 2.5 parts of anti-aging agent are made up of 0.3 part of antioxidant MB, 1 part of anti-aging agent KY-405L and 1.2 part of antioxidant SP-C.
Preparation method and application are with embodiment 1.
Embodiments of the invention 3: the outer bonding rubber boots primer of a vapour sulfuration calendering type khaki color, mark calculates by weight, comprises 78 parts of standard rubbers, 22 parts of cis-butadiene cements, 2.2 parts of sulphur, 0.17 part of peptizer DS-T-1,2.6 parts of vulcanization accelerators, 2.5 parts of stearic acid, 2.5 parts of nano zine oxides, 25 parts of 7# machinery oil, 45 parts of white carbon blacks, 4.3 parts of polyoxyethylene glycol
13 parts of light calcium carbonates, 2 parts of anti-aging agent, 10 parts of indenes resins, 0.2 part of Whitfield's ointment and 1.6 parts of khaki color tinting materials; Described vulcanization accelerator is, every 2.4 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.6 parts of altaxs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber; Polyoxyethylene glycol specification is PEG-4000; Described khaki color tinting material is, khaki color tinting material is made up of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch, and the mass ratio of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch is 11:0.8:8.5:0.1; Described anti-aging agent is, every 2.5 parts of anti-aging agent are made up of 0.3 part of antioxidant MB, 1 part of anti-aging agent KY-405L and 1.2 part of antioxidant SP-C.
Preparation method and application are with embodiment 1.
Claims (9)
1. the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color between a kind, it is characterized in that: mark calculates by weight, comprise 75 ~ 80 parts of standard rubbers, 20 ~ 25 parts of cis-butadiene cements, 1.8 ~ 2.2 parts of sulphur, 0.15 ~ 0.20 part of peptizer DS-T-1,2.2 ~ 2.6 parts of vulcanization accelerators, 2.5 ~ 3.5 parts of stearic acid, 2.5 ~ 3.5 parts of nano zine oxides, 20 ~ 25 parts of 7# machinery oil
45 ~ 50 parts of white carbon blacks, 4.0~
4.5 parts of polyoxyethylene glycol, 10~
15 parts of light calcium carbonates, 2.0 ~ 3.0 parts of anti-aging agent, 8 ~ 10 parts of indenes resin, 0.2 ~ 0.4 part of Whitfield's ointment and 1.4 ~ 1.6 parts of khaki color tinting materials.
2. according to claim 1 the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, is characterized in that: mark calculates by weight, comprises 80 parts of standard rubbers, 20 parts of cis-butadiene cements, 2 parts of sulphur, 0.2 part of peptizer DS-T-1,2.4 parts of vulcanization accelerators, 3 parts of stearic acid, 3 parts of nano zine oxides, 23 parts of 7# machinery oil, 50 parts of white carbon blacks, 4.5 parts of polyoxyethylene glycol
10 parts of light calcium carbonates, 2.5 parts of anti-aging agent, 9 parts of indenes resins, 0.3 part of Whitfield's ointment and 1.5 parts of khaki color tinting materials.
3. according to claim 1 and 2 the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, it is characterized in that: described vulcanization accelerator is, every 2.4 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.6 parts of altaxs and 0.4 part of vulkacit D S.
4. according to claim 1 and 2 the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, is characterized in that: described standard rubber is 1# standard rubber; Polyoxyethylene glycol specification is PEG-4000.
5. according to claim 1 and 2 the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, it is characterized in that: described khaki color tinting material is, khaki color tinting material is made up of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch, and the mass ratio of anatase thpe white powder, red rubber master batch R-8818, yellow rubber master batch Y-8804 and black rubber master batch is 11:0.8:8.5:0.1.
6. according to claim 1 and 2 the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, it is characterized in that: described anti-aging agent is, every 2.5 parts of anti-aging agent are made up of 0.3 part of antioxidant MB, 1 part of anti-aging agent KY-405L and 1.2 part of antioxidant SP-C.
7. one kind as claimed in claim 1 between the preparation method of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, it is characterized in that: get each component by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure in the Banbury mixer of 80 ~ 120 DEG C 6 ~ 8 minutes by standard rubber and peptizer DS-T-1 in temperature, on opening rubber mixing machine, make sheet reel again, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.45 ~ 0.50; 2) mixing: broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, stearic acid, nano zine oxide, anti-aging agent, khaki color tinting material, Whitfield's ointment, indenes resin are dropped in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into white carbon black, polyoxyethylene glycol, light calcium carbonate presses refining 5 ~ 6 minutes again, then adds 7#
machinery oilrefine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color between obtaining.
8. one kind as claimed in claim 1 between the application of the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color, it is characterized in that: between inciting somebody to action, the outer bonding rubber boots primer of vapour sulfuration calendering type khaki color bag roller on opening rubber mixing machine refines glue to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required decorative pattern and thickness again, this film stamping machine is cut into the removing from mould glue embryo sheet of die for shoe-sole requirement shape; Removing from mould glue embryo sheet is adopted to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber soles.
9. the application of the outer bonding rubber boots primer of according to claim 8 vapour sulfuration calendering type khaki color, is characterized in that: described employing removing from mould glue embryo sheet to prepare between non-mould molding the tasteless sole of bonding pink in vapour sulfuration calendering type
rubber solesbe removing from mould glue embryo sheet is fitted in swabbing footwear on the surface, wraps in Foxing strip for rubber shoes surface, after pressing is pasted, produce rubber overshoes by heat of compression air heating sulfuration sizing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510647717.XA CN105153488A (en) | 2015-10-09 | 2015-10-09 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510647717.XA CN105153488A (en) | 2015-10-09 | 2015-10-09 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105153488A true CN105153488A (en) | 2015-12-16 |
Family
ID=54794559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510647717.XA Pending CN105153488A (en) | 2015-10-09 | 2015-10-09 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105153488A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04126101A (en) * | 1990-09-18 | 1992-04-27 | Noguchi Rubber Kogyo Kk | Production of rubber shoe sole |
| CN103275361A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Wear-resistant and anti-static sole rubber, as well as preparation method and application thereof |
| CN103275360A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Wear-resistant and anti-static flavorless sole rubber, as well as preparation method and application thereof |
| CN104817802A (en) * | 2015-04-09 | 2015-08-05 | 茂泰(福建)鞋材有限公司 | High-traction rubber sole and preparation method thereof |
-
2015
- 2015-10-09 CN CN201510647717.XA patent/CN105153488A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04126101A (en) * | 1990-09-18 | 1992-04-27 | Noguchi Rubber Kogyo Kk | Production of rubber shoe sole |
| CN103275361A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Wear-resistant and anti-static sole rubber, as well as preparation method and application thereof |
| CN103275360A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Wear-resistant and anti-static flavorless sole rubber, as well as preparation method and application thereof |
| CN104817802A (en) * | 2015-04-09 | 2015-08-05 | 茂泰(福建)鞋材有限公司 | High-traction rubber sole and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105131365A (en) | Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof | |
| CN103275361B (en) | Wear-resisting Antistatic sole rubber and preparation method thereof and application | |
| CN103275360B (en) | Tasteless sole rubber of wear-resisting anti-electrostatic and preparation method thereof and application | |
| CN102161786B (en) | High-mutual viscosity lustered yellowing-resistance bleached sole rubber and preparation method thereof | |
| CN101225194A (en) | Ultra-low-temperature fast-curing reinforcing glue for rubber shoes and preparation method thereof | |
| CN103159999A (en) | Wear-resistant sole material and preparation method thereof | |
| CN104829892A (en) | High-wear-resistance rubber material for shoe soles and preparation method thereof | |
| CN102181083A (en) | Oil-resistant anti-slip rubber for soles and preparation method thereof | |
| CN103554561A (en) | High-hardness and extremely-cold-resistant sole material and preparation method thereof | |
| CN104311900A (en) | Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof | |
| CN109836630A (en) | A kind of high-weatherability white rubber sole and preparation method thereof | |
| CN106589478A (en) | Wear-resistant shoe sole material and preparation method thereof | |
| CN105385383B (en) | A kind of all rubber shoes Gasoline rubber paste and its preparation method and application | |
| CN105131367A (en) | Inter-steam vulcanization rolling type internal bonding type pink odorless sole rubber and preparation method and application thereof | |
| CN105153486A (en) | Intermittent steam vulcanization calendered and internally bonded light green odorless shoe sole rubber as well as preparation method and application thereof | |
| CN104371151A (en) | Calendered black rubber surround bar for flexing endurable liberation shoes as well as preparation method and application of calendered black rubber surround bar | |
| CN105131362A (en) | Wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber for shoes and preparation method and application of wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber | |
| CN105367855B (en) | A kind of two-layer compound sole and preparation method thereof | |
| CN103665451A (en) | Molded rubber outsole without exhaust hole and preparation method of molded rubber outsole | |
| CN105153488A (en) | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof | |
| CN111004432A (en) | Preparation method of high-performance composite sole with hollow design | |
| CN104371149A (en) | Rolled type black rubber surrounding bar rubber for wear-resisting liberation shoes as well as preparation method and application thereof | |
| CN105131361A (en) | Inter-steam vulcanization rolling type peak green external binding method rubber sole glue and preparation method and application thereof | |
| CN104311899A (en) | Calendering grass green surrounding bar adhesive for liberation shoes as well as preparation method and application thereof | |
| CN106380650A (en) | Synthetic material for outsole of footwear |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |
|
| RJ01 | Rejection of invention patent application after publication |