CN105131365A - Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof - Google Patents
Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof Download PDFInfo
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- CN105131365A CN105131365A CN201510647700.4A CN201510647700A CN105131365A CN 105131365 A CN105131365 A CN 105131365A CN 201510647700 A CN201510647700 A CN 201510647700A CN 105131365 A CN105131365 A CN 105131365A
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Abstract
The invention discloses black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and a preparation method and application thereof. Gum formulas are optimized and screened, so that the formula with specific components and specific dosage is selected; through the formula, the good processing property and mechanical property of the product can be achieved, the bonding performance is improved obviously, and the low-odor performance of the product is guaranteed; besides, both abrasive resistance and tensile resistance are well guaranteed. Stripes of the prepared product are clear, the inside of vulcanized shoe sole rubber can be coated with shoe surrounding bars, and thus the service life is long. The method is simple and easy to implement, cost is low and the using effect of the product is good.
Description
Technical field
The present invention relates to rubber processing, particularly a kind of tasteless wear-resistant type post cure shoe rubber black shoes primer and preparation method thereof and application.
Background technology
Especially roll in end laminating method rubber overshoes manufacturing processed in shoemaking work, due to the calendering formation adhesive function of rubber will be realized, heavy dose ofly in formula must use the Rubber Softener such as machine oil, and the tenderizers such as machine oil, rubber can not take into account the unity meeting sole bonding performance, odor properties.Rubber adhesion performance to be realized on the one hand, just must expand tenderizer machine oil consumption, cause rubber smell to increase so thereupon, and in order to reduce sizing material smell, then must reduce machine oil consumption, the quality problems of rubber adhesion difference can be caused again.
On the other hand, the low taste that good bond properties ensures product again be realized, then to sacrifice rubber overshoes wear resisting property and tensile property for cost, must can make significantly reduce again the work-ing life of rubber overshoes like this, the user demand of user can not be met.Along with social development, human consumer proposes requirements at the higher level to the low smell of rubber overshoes and wearing quality.There are special needs to end bound edge product simultaneously.
For this reason, at the bottom of the low smell of technique simple high adherence energy, the invention of bound edge sole rubber has realistic meaning.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of tasteless wear-resistant type post cure shoe rubber black shoes primer and preparation method thereof and application, it has good mechanical property, processing performance and bond properties, and bag Foxing strip for rubber shoes in shoe soles by using vulcanizing rubber can be realized, and smell is low, to overcome the deficiencies in the prior art.
Of the present inventionly be achieved in that tasteless wear-resistant type post cure shoe rubber black shoes primer, mark calculates by weight, comprise 60 ~ 65 parts of standard rubbers, 35 ~ 40 parts of cis-butadiene cements, 1.8 ~ 2.2 parts of sulphur, 1.8 ~ 2.2 parts of vulcanization accelerators, 7.5 ~ 8.5 portions of promoting agents, 20 ~ 25 parts of spindle oil, 48 ~ 52 parts of carbon blacks
, 1.0 ~ 2.0 parts of anti-aging agent and 2.5~
agent DS-40 is torn in 3.5 parts of homogenizes.
Preferred scheme is, mark calculates by weight, and comprise 65 parts of standard rubbers, 35 parts of cis-butadiene cements, 2 parts of sulphur, 2.0 parts of vulcanization accelerators, 8.0 portions of promoting agents, 23 parts of spindle oil, 50 parts of carbon blacks, agent DS-40 is torn in 1.5 parts of anti-aging agent and 3.0 parts of homogenizes.
Described vulcanization accelerator is, every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S.
Described standard rubber is 1# standard rubber, and carbon black is N220 carbon black.
Described promoting agent is, every 8.0 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides.
Described anti-aging agent is anti-aging agent KY-405L.
The preparation method of tasteless wear-resistant type post cure shoe rubber black shoes primer, gets each component by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure 4 ~ 5 minutes in the Banbury mixer of 80 ~ 120 DEG C in temperature by standard rubber, then on opening rubber mixing machine, make sheet reel, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.40 ~ 0.45, 2) mixing: by broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, promoting agent and anti-aging agent together drop in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into carbon black again and agent DS-40 is torn in homogenize, pressure refining 5 ~ 6 minutes, then spindle oil is added, refine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, obtain tasteless wear-resistant type post cure shoe rubber black shoes primer.
The application of tasteless wear-resistant type post cure shoe rubber black shoes primer, this tasteless wear-resistant type post cure shoe rubber black shoes primer bag roller refining glue on opening rubber mixing machine is beaten sheet to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required thickness, this film stamping machine is cut into the glue embryo sheet of die for shoe-sole requirement shape; Again in 150 ~ 155 DEG C of condition bed dies sulfuration 4 ' ~ 4 ' 50 ", prepare at the bottom of tasteless wear-resistant type post cure shoe rubber black shoes.
In order to verify effect of the present invention further, carry out following experiment:
Rubber proportioning Selection experiment
The making of selection to master batch of rubber plays a key effect.Test-results is as shown in table 1, table 2:
According to table 1 test-results, natural rubber and cis-1,4-polybutadiene rubber is selected to carry out collocation use-testing, to obtain optimised process performance.
Table 1 obtains, and 2 parts of sulphur, 50 parts of white carbon blacks, 23 parts of spindle oil are optimum amount.
Table 2 obtains, 2.0 parts of vulcanization accelerators, 8.0 portions of promoting agents, and 1.5 parts of anti-aging agent are optimum amount.
Drawn by table 3,65 parts of standard rubbers, 35 parts of cis-butadiene cements, it is optimum amount that agent DS-40 is torn in 3.0 parts of homogenizes.
In addition: draw through overtesting: every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S; Every 8 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides; Anti-aging agent is anti-aging agent KY-405L, could realize optimum anti-aging effect and tasteless requirement according to the program.
And prove through test, the basic insipidness of this sole, Akron wear volume is less than 0.35cm
3.
Owing to have employed technique scheme, compared with prior art, the present invention is optimized screening to sizing compound formula, selects the formula of specific components, specific consumption, and such formula makes product have good processing performance and mechanical property, bond properties significantly improves, do the low taste ensureing product, and wear resistance and stretch-resistance all obtain good guarantee, prepared product decorative pattern is clear, bag Foxing strip for rubber shoes in shoe soles by using vulcanizing rubber can be realized, long service life.The present invention is simple, with low cost, and the result of use of product is good.
Embodiment
Embodiments of the invention 1: tasteless wear-resistant type post cure shoe rubber black shoes primer, mark calculates by weight, comprise 65 parts of standard rubbers, 35 parts of cis-butadiene cements, 2 parts of sulphur, 2.0 parts of vulcanization accelerators, 8.0 portions of promoting agents, 23 parts of spindle oil, 50 parts of carbon blacks, agent DS-40 is torn in 1.5 parts of anti-aging agent and 3.0 parts of homogenizes; Described vulcanization accelerator is, every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber, and carbon black is N220 carbon black; Described promoting agent is, every 8.0 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides; Described anti-aging agent is anti-aging agent KY-405L.
The preparation method of tasteless wear-resistant type post cure shoe rubber black shoes primer, gets each component by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure 4 ~ 5 minutes in the Banbury mixer of 80 ~ 120 DEG C in temperature by standard rubber, then on opening rubber mixing machine, make sheet reel, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.40 ~ 0.45, 2) mixing: by broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, promoting agent and anti-aging agent together drop in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into carbon black again and agent DS-40 is torn in homogenize, pressure refining 5 ~ 6 minutes, then spindle oil is added, refine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, obtain tasteless wear-resistant type post cure shoe rubber black shoes primer.
The application of tasteless wear-resistant type post cure shoe rubber black shoes primer, this tasteless wear-resistant type post cure shoe rubber black shoes primer bag roller refining glue on opening rubber mixing machine is beaten sheet to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required thickness, this film stamping machine is cut into the glue embryo sheet of die for shoe-sole requirement shape; Again in 150 ~ 155 DEG C of condition bed dies sulfuration 4 ' ~ 4 ' 50 ", prepare at the bottom of tasteless wear-resistant type post cure shoe rubber black shoes.
Embodiments of the invention 2: tasteless wear-resistant type post cure shoe rubber black shoes primer, mark calculates by weight, comprise 60 parts of standard rubbers, 35 parts of cis-butadiene cements, 1.8 parts of sulphur, 1.8 parts of vulcanization accelerators, 7.5 portions of promoting agents, 20 parts of spindle oil, 48 parts of carbon blacks, agent DS-40 is torn in 1 part of anti-aging agent and 2.5 parts of homogenizes; Described vulcanization accelerator is, every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber, and carbon black is N220 carbon black; Described promoting agent is, every 8.0 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides; Described anti-aging agent is anti-aging agent KY-405L.
Preparation method and application are with embodiment 1.
Embodiments of the invention 3: tasteless wear-resistant type post cure shoe rubber black shoes primer, mark calculates by weight, comprise 65 parts of standard rubbers, 40 parts of cis-butadiene cements, 1.8 parts of sulphur, 1.8 parts of vulcanization accelerators, 7.5 portions of promoting agents, 20 parts of spindle oil, 48 parts of carbon blacks, agent DS-40 is torn in 1 part of anti-aging agent and 2.5 parts of homogenizes; Described vulcanization accelerator is, every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S; Described standard rubber is 1# standard rubber, and carbon black is N220 carbon black; Described promoting agent is, every 8.0 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides; Described anti-aging agent is anti-aging agent KY-405L.
Preparation method and application are with embodiment 1.
Claims (8)
1. a tasteless wear-resistant type post cure shoe rubber black shoes primer, it is characterized in that: mark calculates by weight, comprise 60 ~ 65 parts of standard rubbers, 35 ~ 40 parts of cis-butadiene cements, 1.8 ~ 2.2 parts of sulphur, 1.8 ~ 2.2 parts of vulcanization accelerators, 7.5 ~ 8.5 portions of promoting agents, 20 ~ 25 parts of spindle oil, 48 ~ 52 parts of carbon blacks
, 1.0 ~ 2.0 parts of anti-aging agent and 2.5~
agent DS-40 is torn in 3.5 parts of homogenizes.
2. tasteless wear-resistant type post cure shoe rubber black shoes primer according to claim 1, it is characterized in that: mark calculates by weight, comprise 65 parts of standard rubbers, 35 parts of cis-butadiene cements, 2 parts of sulphur, 2.0 parts of vulcanization accelerators, 8.0 portions of promoting agents, 23 parts of spindle oil, 50 parts of carbon blacks, agent DS-40 is torn in 1.5 parts of anti-aging agent and 3.0 parts of homogenizes.
3. tasteless wear-resistant type post cure shoe rubber black shoes primer according to claim 1 and 2, it is characterized in that: described vulcanization accelerator is, every 2.0 parts of vulcanization accelerators are made up of 0.4 part of altax, 1.2 parts of accelerant CZs and 0.4 part of vulkacit D S.
4. tasteless wear-resistant type post cure shoe rubber black shoes primer according to claim 1 and 2, it is characterized in that: described standard rubber is 1# standard rubber, carbon black is N220 carbon black.
5. tasteless wear-resistant type post cure shoe rubber black shoes primer according to claim 1 and 2, it is characterized in that: described promoting agent is, every 8.0 portions of promoting agents are made up of 2.5 parts of stearic acid and 5.5 parts of nano zine oxides.
6. tasteless wear-resistant type post cure shoe rubber black shoes primer according to claim 1 and 2, is characterized in that: described anti-aging agent is anti-aging agent KY-405L.
7. a preparation method for tasteless wear-resistant type post cure shoe rubber black shoes primer as claimed in claim 1, is characterized in that: get each component by above-mentioned parts by weight, 1) broken-(down)rubber is prepared: be refine pressure 4 ~ 5 minutes in the Banbury mixer of 80 ~ 120 DEG C in temperature by standard rubber, then on opening rubber mixing machine, make sheet reel, obtain the broken-(down)rubber that Wei Shi plasticity number is 0.40 ~ 0.45, 2) mixing: by broken-(down)rubber, cis-butadiene cement, vulcanization accelerator, promoting agent and anti-aging agent together drop in Banbury mixer, temperature is 80 ~ 120 DEG C, pressure refining is after 1 minute, drop into carbon black again and agent DS-40 is torn in homogenize, pressure refining 5 ~ 6 minutes, then spindle oil is added, refine the load of Banbury mixer is raised to when vertex declines again by 0, by rubber unvulcanizate discharge in opening rubber mixing machine, the rubber unvulcanizate of input opening rubber mixing machine is crossed machine and is drawn logical 8 ~ 10 times under 4 ~ 5mm roll spacing, rubber unvulcanizate temperature is made to be reduced to less than 80 DEG C, adding sulphur turns refining evenly, slice water cooling, obtain tasteless wear-resistant type post cure shoe rubber black shoes primer.
8. the application of a tasteless wear-resistant type post cure shoe rubber black shoes primer as claimed in claim 1, it is characterized in that: this tasteless wear-resistant type post cure shoe rubber black shoes primer bag roller refining glue on opening rubber mixing machine is beaten sheet to sizing material smooth surface, by rolling press, sizing material is pressed into the film of required thickness, this film stamping machine is cut into the glue embryo sheet of die for shoe-sole requirement shape; Again in 150 ~ 155 DEG C of condition bed dies sulfuration 4 ' ~ 4 ' 50 ", prepare at the bottom of tasteless wear-resistant type post cure shoe rubber black shoes.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510647700.4A CN105131365A (en) | 2015-10-09 | 2015-10-09 | Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510647700.4A CN105131365A (en) | 2015-10-09 | 2015-10-09 | Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof |
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| CN105131365A true CN105131365A (en) | 2015-12-09 |
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|---|---|---|---|
| CN201510647700.4A Pending CN105131365A (en) | 2015-10-09 | 2015-10-09 | Black rubber shoe sole gum for odorless wear-resisting type bi-vulcanized shoes and preparation method and application thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317493A (en) * | 2016-08-29 | 2017-01-11 | 樊之雄 | Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof |
| CN107722412A (en) * | 2017-10-30 | 2018-02-23 | 际华三五三七制鞋有限责任公司 | Wear-resisting type anti-slip rubber sole and preparation method thereof |
| CN109337137A (en) * | 2018-10-31 | 2019-02-15 | 际华三五三七制鞋有限责任公司 | Tasteless sole rubber of wear-resistant conductive and preparation method and application |
| CN110240747A (en) * | 2019-07-25 | 2019-09-17 | 两者时尚商业(江苏)有限公司 | A kind of abrasive rubber foaming and preparation method thereof |
| CN110628103A (en) * | 2019-09-27 | 2019-12-31 | 际华三五三七有限责任公司 | Rubber sole for kitchen use, preparation method and secondary vulcanization process thereof |
| CN114933745A (en) * | 2022-06-08 | 2022-08-23 | 际华三五三七有限责任公司 | Common black rubber for sole edges of molded shoes and preparation method and application thereof |
| CN114989502A (en) * | 2022-05-18 | 2022-09-02 | 际华三五三七有限责任公司 | High-strength anti-skid odorless sole rubber and preparation method thereof |
-
2015
- 2015-10-09 CN CN201510647700.4A patent/CN105131365A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317493A (en) * | 2016-08-29 | 2017-01-11 | 樊之雄 | Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof |
| CN107722412A (en) * | 2017-10-30 | 2018-02-23 | 际华三五三七制鞋有限责任公司 | Wear-resisting type anti-slip rubber sole and preparation method thereof |
| CN109337137A (en) * | 2018-10-31 | 2019-02-15 | 际华三五三七制鞋有限责任公司 | Tasteless sole rubber of wear-resistant conductive and preparation method and application |
| CN110240747A (en) * | 2019-07-25 | 2019-09-17 | 两者时尚商业(江苏)有限公司 | A kind of abrasive rubber foaming and preparation method thereof |
| CN110628103A (en) * | 2019-09-27 | 2019-12-31 | 际华三五三七有限责任公司 | Rubber sole for kitchen use, preparation method and secondary vulcanization process thereof |
| CN114989502A (en) * | 2022-05-18 | 2022-09-02 | 际华三五三七有限责任公司 | High-strength anti-skid odorless sole rubber and preparation method thereof |
| CN114989502B (en) * | 2022-05-18 | 2024-06-25 | 际华制鞋工业有限公司 | High-strength stretch anti-slip odorless sole rubber and preparation method thereof |
| CN114933745A (en) * | 2022-06-08 | 2022-08-23 | 际华三五三七有限责任公司 | Common black rubber for sole edges of molded shoes and preparation method and application thereof |
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Application publication date: 20151209 |
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