CN110037381B - Production process of anti-slip sole and anti-slip mat - Google Patents

Production process of anti-slip sole and anti-slip mat Download PDF

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Publication number
CN110037381B
CN110037381B CN201910295855.4A CN201910295855A CN110037381B CN 110037381 B CN110037381 B CN 110037381B CN 201910295855 A CN201910295855 A CN 201910295855A CN 110037381 B CN110037381 B CN 110037381B
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parts
slip
sole
rubber
slip mat
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CN110037381A (en
Inventor
章勤华
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Zhejiang Hengcheng Shoes Co ltd
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Zhejiang Hengcheng Shoes Co ltd
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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/14Soles; Sole-and-heel integral units characterised by the constructive form
    • A43B13/22Soles made slip-preventing or wear-resisting, e.g. by impregnation or spreading a wear-resisting layer
    • A43B13/223Profiled soles
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/28Soles; Sole-and-heel integral units characterised by their attachment, also attachment of combined soles and heels
    • A43B13/36Easily-exchangeable soles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/0054Producing footwear by compression moulding, vulcanising or the like; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/12Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a production process of an anti-slip sole and an anti-slip mat. The anti-slip sole comprises a sole base body and an anti-slip pad arranged at the bottom of the sole base body, wherein the sole base body is divided into a front palm part, a foot arch part and a heel part, anti-slip grooves are formed in the front palm part and the heel part, and the anti-slip pad is connected with clamping strips clamped into the anti-slip grooves; the non-slip mat comprises the following components in parts by weight: 30-35 parts of silicon rubber; 35-40 parts of nitrile rubber; 20-25 parts of brominated butyl rubber; 4-6 parts of a compatilizer; 30-40 parts of a filler; 2-3 parts of polyethylene glycol; 2-3 parts of active zinc oxide; 0.4-0.6 part of stearic acid; 0.8-1.2 parts of rosin; 1.6-2 parts of a vulcanizing agent; 1-2 parts of an accelerator; 0.3-0.6 part of anti-aging agent. When the shoes enter and exit the environment needing antiskid, the antiskid pads are taken off or put on the shoes, so that the trouble of replacing the whole pair of shoes is avoided; meanwhile, the non-slip mat has excellent non-slip performance on oil-slippery ground and water-slippery ground.

Description

Production process of anti-slip sole and anti-slip mat
Technical Field
The invention relates to a sole, in particular to an anti-skidding sole and a production process of an anti-skidding mat.
Background
The existing shoes are of various kinds and have various functions according to different purposes and applicable ground, such as: warm keeping, ventilation, wear resistance, skid resistance, portability and the like. The basic requirement of taking the antiskid as the sole is particularly important, and the antiskid shoe can effectively protect a user from falling and skidding. Especially for the working environment with more damp and greasy dirt such as ship body decks and kitchens, the excellent anti-skid performance is the safety guarantee of users.
However, the anti-skid performance and the wear-resistant performance are in conflict, and the sole with good wear-resistant performance is hard, low in friction coefficient and poor in anti-skid performance; the sole with good anti-skid performance is softer, the friction coefficient is high, and the anti-skid performance is good. Therefore, when the shoe enterprises are produced, the balance among the performances of skid resistance, wear resistance, shock absorption and the like can be sought, or special antiskid soles can be produced.
People need to wear anti-skid shoes before entering into environments such as ships, kitchens and the like, and change comfortable shoes after leaving, and frequent shoe changing is time-consuming and labor-consuming and needs to be improved.
Disclosure of Invention
In view of the technical defects, the invention aims to provide an anti-skidding sole, which avoids the trouble of replacing the whole pair of shoes when the shoes enter or exit from the environment needing anti-skidding.
In order to achieve the purpose, the invention provides the following technical scheme:
an anti-slip sole comprises a sole base body and an anti-slip pad arranged at the bottom of the sole base body, wherein the sole base body is divided into a front palm part, a foot arch part and a heel part, anti-slip grooves are formed in the front palm part and the heel part, and the anti-slip pad is connected with clamping strips clamped into the anti-slip grooves;
the non-slip mat comprises the following components in parts by weight:
30-35 parts of silicon rubber
35-40 parts of nitrile rubber
20-25 parts of brominated butyl rubber
4-6 parts of compatilizer
30-40 parts of filler
2-3 parts of polyethylene glycol
2-3 parts of active zinc oxide
0.4 to 0.6 portion of stearic acid
0.8 to 1.2 portions of rosin
1.6-2 parts of vulcanizing agent
1-2 parts of accelerator
0.3-0.6 part of anti-aging agent.
Through adopting above-mentioned technical scheme, slipmat and sole base member separable and dismouting is convenient fast, therefore the slipmat adopts the excellent material of anti-skidding performance to make, and the sole base member adopts excellent performance materials such as wear-resisting, bradyseism to make, and then exerts the biggest with the advantage of two kinds of materials. When the anti-skid pad is sleeved at the bottom of the sole base body, the anti-skid performance of the sole is excellent, and the anti-skid pad is suitable for being used in humid environments such as ship bodies, kitchens and the like; after the non-slip mat is detached, the comfort of wearing the sole is better. The non-slip mat is convenient to disassemble and assemble, and further the trouble of replacing the whole pair of shoes when entering and exiting the environment needing non-slip is avoided. When the anti-skid pad is seriously worn, only a new anti-skid pad needs to be replaced, and the whole shoe does not need to be replaced.
The non-slip mat is formed by mixing silicon rubber, nitrile rubber and brominated butyl rubber, meets the performance requirements of basic wear resistance, tear strength and the like, maximizes the non-slip performance, and is particularly prominent in non-slip surfaces of oily ground and wet ground compared with rubber soles on the market. The rubber macromolecules introduce cyanogen groups and halogen atoms with strong polarity, so that the interaction force among chains is increased, and the skid resistance and the wear resistance of the antiskid mat are ensured; the silicon rubber endows the surface of the anti-skid pad with low surface energy, and the anti-skid pad is not easy to be stained with water and oil, so that the anti-skid pad has better anti-skid property on water and oil ground.
The invention is further configured to: the antiskid grooves are latticed, and the antiskid pad is connected with an arch part tightly attached to the arch part.
By adopting the technical scheme, on one hand, the matched clamping strips are in a grid shape, the stress stability is better, and the process of sleeving the anti-skid mat on the sole base body is smoother; on the other hand, compared with the strip-shaped anti-skidding groove, the anti-skidding performance of the sole base body is better. The non-slip mat is completely attached to the bottom of the sole base body without a gap, so that the non-slip mat cannot slip away towards the gaps of the non-slip mat and the sole base body when a person steps on the protruding object, and the fixing stability of the non-slip mat is further ensured.
The invention is further configured to: the anti-slip mat is connected with the bound edge tightly attached to the side edge of the sole base body, the inner side of the bound edge is connected with a plurality of clamping blocks, and the side edge of the sole base body is provided with clamping grooves for the clamping blocks to be clamped in.
By adopting the technical scheme, the firmness of connection between the non-slip mat and the sole base body is greatly improved.
The invention is further configured to: the side that the slipmat deviates from the sole base member is provided with a plurality of antislip strips along its length direction, the antislip strip is divided into a plurality of antiskid pieces along its width direction, the antiskid piece is equilateral triangle, the antiskid piece includes the non slipping spur that three circumference distributes, and is adjacent have the clearance between the non slipping spur.
Through adopting above-mentioned technical scheme, the non-slip properties of slipmat is excellent, can stand the power of exerting oneself of people's foot toward all directions.
The invention is further configured to: the filler is transparent white carbon black, the vulcanizing agent is compounded by sulfur and DCP, and the accelerator is compounded by accelerator DM, accelerator H and accelerator PX.
Through adopting above-mentioned technical scheme, the slipmat has good transparency, and people can direct observation which department of slipmat does not cooperate the joint with the sole base member, and then the slipmat cover of being convenient for is on the sole base member.
The invention is further configured to: the preparation process of the compatilizer is as follows: according to the weight portion, 20-26 portions of butyl rubber and 0.6-0.8 portion of BPO are mixed, heated to 50-55 ℃, mixed for 12-20min, then 0.4-0.6 portion of KH570 is added, mixed for 8-12min, then heated to 80-85 ℃, mixed for 8-12min, heated to 100-105 ℃, mixed for 8-12min, and finally discharged.
By adopting the technical scheme, the blending compatibility of the silicone rubber, the nitrile rubber and the brominated butyl rubber is improved, and further the mechanical property of the non-slip mat is improved.
The invention is further configured to: the anti-skid pad also comprises 4-6 parts of hydroxyl silicone oil and 0.4-0.8 part of diphenyl silanediol.
By adopting the technical scheme, on one hand, the infiltration and dispersion effects between the filler and the rubber material are enhanced, and the mechanical property of the non-slip mat is further improved; and on the other hand, the water and oil repellency of the non-slip mat is enhanced.
The invention also aims to provide a production process of the non-slip mat.
A production process of a non-slip mat comprises the following steps:
step 1: mixing 30-35 parts by weight of silicone rubber, 35-40 parts by weight of nitrile rubber, 20-25 parts by weight of brominated butyl rubber and 4-6 parts by weight of compatilizer, heating to 50-60 ℃, and mixing for 15-20min to obtain master batch;
step 2: putting the master batch, 30-40 parts of filler, 2-3 parts of polyethylene glycol, 4-6 parts of hydroxyl silicone oil, 0.4-0.8 part of diphenyl silanediol, 2-3 parts of active zinc oxide, 0.4-0.6 part of stearic acid, 0.8-1.2 parts of rosin and 0.3-0.6 part of antioxidant into an internal mixer, carrying out internal mixing for 10-12min at the temperature of 100-120 ℃, and discharging to obtain rubber compound;
and step 3: putting the rubber compound, 1.6-2 parts of vulcanizing agent and 1-2 parts of accelerator into an open mill, and discharging at 40-45 ℃ to obtain rubber sheets;
and 4, step 4: putting the rubber sheet into a vulcanizing machine, vulcanizing at 160-180 ℃ for 8-10min to obtain a vulcanized rubber material;
and 5: and (3) carrying out compression molding on the vulcanized rubber material to obtain the non-slip mat.
In conclusion, the invention has the following beneficial effects:
1. the sole is divided into a sole base body and an anti-slip pad which are detachably mounted, the anti-slip pad is sleeved on a special place needing anti-slip, the anti-slip pad is not required to be taken off from the place needing anti-slip, time and labor are saved compared with a mode of replacing shoes, excessive abrasion of the anti-slip pad is avoided, and the anti-slip pad can be pursued to have excellent anti-slip performance only by meeting basic mechanical performance of manufacturing materials of the anti-slip pad;
2. the non-slip mat is formed by mixing silicon rubber, nitrile rubber and brominated butyl rubber with the help of a compatilizer, and has excellent non-slip performance on oil-slippery ground and water-slippery ground.
Drawings
FIG. 1 is a schematic structural diagram of the first embodiment;
FIG. 2 is an exploded view of the first embodiment;
FIG. 3 is a schematic view showing the structure of a sole base according to a first embodiment;
FIG. 4 is a schematic view of a non-slip mat according to an embodiment;
fig. 5 is an enlarged schematic view of the region a in fig. 4.
Description of reference numerals: 1. a sole base; 11. a front palm portion; 12. an arch portion; 13. a heel portion; 14. a card slot; 2. a non-slip mat; 21. clamping the strip; 22. edge covering; 221. a clamping block; 23. An arching portion; 24. anti-slip strips; 241. an anti-skid block; 2411. anti-skid blocks; 3. and (4) an anti-slip groove.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
The first embodiment is as follows:
an anti-skid sole, as shown in figure 1, comprises a sole base body 1 and an anti-skid pad 2 which is detachably arranged at the bottom of the sole base body 1. The sole base body 1 is made of materials with good performances such as ventilation, shock absorption, wear resistance and the like, and the non-slip mat 2 is made of materials with good non-slip performance. The anti-slip mat 2 can have a better anti-slip effect when being arranged at the bottom of the sole base body 1, so that the danger that a user falls down in an easily-slipping environment is avoided; the wearing comfort of the user is improved after the non-slip mat 2 is detached, and the trouble that the non-slip mat 2 is worn too fast is avoided.
As shown in fig. 2 and 3, the sole base 1 is sequentially divided into a palm portion 11, an arch portion 12 and a heel portion 13 along the length direction thereof, and the palm portion 11 and the heel portion 13 are provided with the grid-shaped anti-slip grooves 3, so that the anti-slip performance of the sole base 1 is improved. One side of the non-slip mat 2 facing the sole base body 1 is fixedly connected with a clamping strip 21 clamped into the non-slip groove 3 and an arch part 23 closely attached to the arch part 12. The clamping strip 21 is matched with the anti-skid groove 3, so that the clamping strip 21 is clamped in the anti-skid groove 3 and has larger resistance with the inner wall of the anti-skid groove, and the fixing effect of the anti-skid pad 2 is further ensured. The matched clamping strips 21 are in a grid shape, so that the stress stability is better, and the process of sleeving the non-slip mat 2 on the sole base body 1 is smoother. The bottom of the non-slip mat 2 and the bottom of the sole base body 1 are completely attached without gaps, so that the non-slip mat 2 cannot slip away towards the gaps of the non-slip mat 2 and the sole base body 1 when a person steps on the protruding object, and the fixing stability of the non-slip mat 2 is further ensured.
As shown in fig. 2 and 3, a hem 22 tightly attached to the side edge of the sole base 1 is integrally connected to one side edge of the non-slip mat 2 facing the sole base 1, four fastening blocks 221 are fixed to the inner side of the hem 22, and a fastening groove 14 for fastening the fastening blocks 221 is formed in the side edge of the sole base 1. The four clamping grooves 14 are respectively arranged on two opposite sides of the front palm part 11 and the arch part 12 in pairs, so that the firmness of connection between the non-slip mat 2 and the sole base body 1 is greatly improved. The clamping block 221 is in a right triangle shape, and the bevel edge deviates from the anti-slip pad 2, so that the sole base body 1 can be clamped conveniently.
As shown in fig. 4 and 5, the side of the non-slip mat 2 away from the sole base body 1 is flat and fixedly connected with a plurality of non-slip strips 24 along the length direction, a gap is formed between every two adjacent non-slip strips 24, and the adjacent non-slip strips 24 are symmetrical with respect to the gap. The anti-slip strips 24 are divided into a plurality of anti-slip blocks 241 along the width direction of the sole base body 1, the anti-slip blocks 241 are equilateral triangles, and gaps are formed between adjacent anti-slip blocks 241 and form a parallelogram together. The anti-skid block 241 comprises three anti-skid blocks 2411 distributed circumferentially around the center of the anti-skid block 241, the anti-skid blocks 2411 are in an obtuse isosceles triangle shape, and a gap is formed between every two adjacent anti-skid blocks 2411. The non-slip mat 2 is excellent in non-slip property and can withstand the force of the human foot in all directions.
The installation process comprises the following steps:
when the shoe sole enters a wet and slippery environment, the anti-skid pad 2 is sleeved on the sole base body 1, the clamping blocks 221 are clamped into the clamping grooves 14, and the clamping strips 21 are clamped into the anti-skid grooves 3.
Example two:
the non-slip mat in the first embodiment comprises the following components in parts by weight:
30 parts of methyl vinyl silicone rubber;
35 parts of nitrile rubber;
20 parts of brominated butyl rubber;
4 parts of a compatilizer;
30 parts of transparent white carbon black;
polyethylene glycol-40002 parts;
2 parts of active zinc oxide;
0.4 part of stearic acid;
0.8 part of rosin;
1.6 parts of vulcanizing agent, wherein the vulcanizing agent is prepared by compounding sulfur and DCP in equal mass ratio;
1 part of accelerator, wherein the accelerator is compounded by accelerator DM, accelerator H and accelerator PX in equal mass ratio;
0.3 part of anti-aging agent, wherein the anti-aging agent is prepared by compounding anti-aging agent 264 and anti-aging agent RD in equal mass ratio;
4 parts of hydroxyl silicone oil;
0.4 part of diphenyl silanediol.
The preparation process of the compatilizer is as follows: according to the weight portion, 20 portions of butyl rubber and 0.6 portion of BPO are mixed, heated to 50 ℃, mixed for 12min, then 0.4 portion of KH570 is added, mixed for 8min, heated to 80 ℃, mixed for 8min, heated to 100 ℃, mixed for 8min, and finally discharged.
A production process of a non-slip mat comprises the following steps:
step 1: according to the weight parts, 30 parts of silicone rubber, 35 parts of nitrile rubber, 20 parts of brominated butyl rubber and 4 parts of compatilizer are put into an internal mixer for mixing, the mixture is heated to 50 ℃, and the mixture is mixed for 15min to obtain master batch;
step 2: putting the master batch, 30 parts of filler, 2 parts of polyethylene glycol, 4 parts of hydroxy silicone oil, 0.4 part of diphenyl silanediol, 2 parts of active zinc oxide, 0.4 part of stearic acid, 0.8 part of rosin and 0.3 part of antioxidant into an internal mixer, carrying out internal mixing for 10min at the temperature of 100 ℃, and discharging to obtain rubber compound;
and step 3: putting the rubber compound, 1.6 parts of vulcanizing agent and 1 part of accelerator into an open mill, and discharging at the temperature of 40 ℃ to obtain a rubber sheet;
and 4, step 4: putting the rubber sheet into a vulcanizing machine, vulcanizing at 160 ℃ for 8min to obtain a vulcanized rubber material;
and 5: and (3) carrying out compression molding on the vulcanized rubber material to obtain the non-slip mat.
Example three:
the non-slip mat in the first embodiment comprises the following components in parts by weight:
35 parts of methyl vinyl silicone rubber;
40 parts of nitrile rubber;
25 parts of brominated butyl rubber;
6 parts of a compatilizer;
40 parts of transparent white carbon black;
polyethylene glycol-40003 parts;
3 parts of active zinc oxide;
0.6 part of stearic acid;
1.2 parts of rosin;
2 parts of vulcanizing agent, wherein the vulcanizing agent is prepared by compounding sulfur and DCP in equal mass ratio;
2 parts of an accelerant, wherein the accelerant is compounded by an accelerant DM, an accelerant H and an accelerant PX in equal mass ratio;
0.6 part of anti-aging agent, wherein the anti-aging agent is prepared by compounding anti-aging agent 264 and anti-aging agent RD in equal mass ratio;
6 parts of hydroxyl silicone oil;
0.8 part of diphenyl silanediol.
The preparation process of the compatilizer is as follows: according to the weight portion, 26 portions of butyl rubber and 0.8 portion of BPO are mixed, heated to 55 ℃, mixed for 20min, then 0.6 portion of KH570 is added, mixed for 12min, then heated to 85 ℃, mixed for 12min, then heated to 105 ℃, mixed for 12min, and finally discharged.
A production process of a non-slip mat comprises the following steps:
step 1: putting 35 parts by weight of silicone rubber, 40 parts by weight of nitrile rubber, 25 parts by weight of brominated butyl rubber and 6 parts by weight of compatilizer into an internal mixer for mixing, heating to 60 ℃, and mixing for 20min to obtain master batch;
step 2: putting the master batch, 40 parts of filler, 3 parts of polyethylene glycol, 6 parts of hydroxy silicone oil, 0.8 part of diphenyl silanediol, 3 parts of active zinc oxide, 0.6 part of stearic acid, 1.2 parts of rosin and 0.6 part of antioxidant into an internal mixer, carrying out internal mixing for 12min at the temperature of 120 ℃, and discharging to obtain a rubber compound;
and step 3: putting the rubber compound, 2 parts of vulcanizing agent and 2 parts of accelerator into an open mill, and discharging at the temperature of 45 ℃ to obtain rubber sheets;
and 4, step 4: putting the rubber sheet into a vulcanizing machine, vulcanizing at 180 ℃ for 10min to obtain a vulcanized rubber material;
and 5: and (3) carrying out compression molding on the vulcanized rubber material to obtain the non-slip mat.
Example four:
the non-slip mat in the first embodiment comprises the following components in parts by weight:
32 parts of methyl vinyl silicone rubber;
38 parts of nitrile rubber;
23 parts of brominated butyl rubber;
5 parts of a compatilizer;
35 parts of transparent white carbon black;
40002.5 parts of polyethylene glycol;
2.5 parts of active zinc oxide;
0.5 part of stearic acid;
1 part of rosin;
1.8 parts of vulcanizing agent, wherein the vulcanizing agent is prepared by compounding sulfur and DCP in equal mass ratio;
1.5 parts of an accelerant which is compounded by an accelerant DM, an accelerant H and an accelerant PX in equal mass ratio;
0.4 part of anti-aging agent, wherein the anti-aging agent is prepared by compounding anti-aging agent 264 and anti-aging agent RD in equal mass ratio;
5 parts of hydroxyl silicone oil;
0.6 part of diphenyl silanediol.
The preparation process of the compatilizer is as follows: according to the weight portion, 23 portions of butyl rubber and 0.7 portion of BPO are mixed, heated to 52 ℃, mixed for 16min, then 0.5 portion of KH570 is added, mixed for 10min, heated to 82 ℃, mixed for 10min, heated to 102 ℃, mixed for 10min, and finally discharged.
A production process of a non-slip mat comprises the following steps:
step 1: putting 32 parts by weight of silicone rubber, 38 parts by weight of nitrile rubber, 23 parts by weight of brominated butyl rubber and 5 parts by weight of compatilizer into an internal mixer for mixing, heating to 55 ℃, and mixing for 18min to obtain master batch;
step 2: putting the master batch, 35 parts of filler, 2.5 parts of polyethylene glycol, 5 parts of hydroxy silicone oil, 0.6 part of diphenyl silanediol, 2.5 parts of active zinc oxide, 0.5 part of stearic acid, 1 part of rosin and 0.4 part of antioxidant into an internal mixer, carrying out internal mixing for 11min at the temperature of 110 ℃, and discharging to obtain a rubber compound;
and step 3: putting the rubber compound, 1.8 parts of vulcanizing agent and 1.5 parts of accelerator into an open mill, and discharging at 42 ℃ to obtain rubber sheets;
and 4, step 4: putting the rubber sheet into a vulcanizing machine, vulcanizing at the temperature of 170 ℃ for 9min to obtain a vulcanized rubber material;
and 5: and (3) carrying out compression molding on the vulcanized rubber material to obtain the non-slip mat.
Example five:
the difference from the fourth embodiment is that the non-slip mat does not comprise diphenyl silanediol and hydroxyl silicone oil.
Comparative example one:
the difference from example four is that the non-slip mat does not comprise a compatibilising agent.
Comparative example two:
the difference from the fourth embodiment is that the non-slip mat does not comprise silicone rubber. A
And (3) testing the performance of the non-slip mat:
first, according to the method recorded in HG/T3082-2010 rubber sole, the mechanical properties of the non-slip mat are tested, and the wear loss of the non-slip mat of the second to fourth examples is less than 250mm3The tensile strength is more than 9MPa, and no crack is produced after 5 ten thousand flexions;
secondly, according to the method recorded in GB/T3903.6-2017 'method for testing the anti-skid performance of the whole shoes of shoes', the friction coefficient of the anti-skid pad is tested, the sample interface is a ceramic tile interface, a glycerol aqueous solution and tertiary water are respectively used as testing media during testing of a wet interface, the testing mode is a horizontal testing mode, and the results are recorded in Table 1.
TABLE 1 test results of coefficient of friction of non-slip mat for each example and comparative example
Coefficient of friction (dry) Coefficient of friction (water) Coefficient of friction (oil)
Example two 1.47 1.36 1.28
EXAMPLE III 1.48 1.36 1.31
Example four 1.50 1.39 1.33
EXAMPLE five 1.48 1.28 1.19
Comparative example 1 1.04 0.81 0.62
Comparative example No. two 1.21 0.93 0.77
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.

Claims (6)

1. An antiskid sole which is characterized in that: the sole comprises a sole base body (1) and a non-slip mat (2) arranged at the bottom of the sole base body (1), wherein the sole base body (1) is divided into a front palm part (11), an arch part (12) and a heel part (13), the front palm part (11) and the heel part (13) are provided with non-slip grooves (3), and the non-slip mat (2) is connected with clamping strips (21) clamped into the non-slip grooves (3);
the non-slip mat (2) comprises the following components in parts by weight:
30-35 parts of silicon rubber;
35-40 parts of nitrile rubber;
20-25 parts of brominated butyl rubber;
4-6 parts of a compatilizer;
30-40 parts of a filler;
2-3 parts of polyethylene glycol;
2-3 parts of active zinc oxide;
0.4-0.6 part of stearic acid;
0.8-1.2 parts of rosin;
1.6-2 parts of a vulcanizing agent;
1-2 parts of an accelerator;
0.3-0.6 part of anti-aging agent;
4-6 parts of hydroxyl silicone oil;
0.4-0.8 part of diphenyl silanediol;
the preparation process of the compatilizer is as follows: according to the weight portion, 20-26 portions of butyl rubber and 0.6-0.8 portion of BPO are mixed, heated to 50-55 ℃, mixed for 12-20min, then 0.4-0.6 portion of KH570 is added, mixed for 8-12min, then heated to 80-85 ℃, mixed for 8-12min, heated to 100-105 ℃, mixed for 8-12min, and finally discharged.
2. The anti-slip shoe sole according to claim 1, wherein: the antiskid grooves (3) are in a grid shape, and the antiskid pad (2) is connected with an arch part (23) which is tightly attached to the arch part (12).
3. The anti-slip shoe sole according to claim 1, wherein: the anti-slip mat (2) is connected with a bound edge (22) which is tightly attached to the side edge of the sole base body (1), the inner side of the bound edge (22) is connected with a plurality of clamping blocks (221), and the side edge of the sole base body (1) is provided with a clamping groove (14) for clamping the clamping blocks (221).
4. The anti-slip shoe sole according to claim 1, wherein: the side that slipmat (2) deviates from sole base member (1) is provided with a plurality of antislip strips (24) along its length direction, antislip strip (24) divide into a plurality of antiskid piece (241) along its width direction, antiskid piece (241) are equilateral triangle, antiskid piece (241) include three non slipping spur (2411) that circumference distributes, and are adjacent have the clearance between non slipping spur (2411).
5. The anti-slip shoe sole according to claim 1, wherein: the filler is transparent white carbon black, the vulcanizing agent is compounded by sulfur and DCP, and the accelerator is compounded by accelerator DM, accelerator H and accelerator PX.
6. A production process of a non-slip mat, which is applied to the non-slip sole of claim 1, characterized by comprising the following steps:
step 1: mixing 30-35 parts by weight of silicone rubber, 35-40 parts by weight of nitrile rubber, 20-25 parts by weight of brominated butyl rubber and 4-6 parts by weight of compatilizer, heating to 50-60 ℃, and mixing for 15-20min to obtain master batch;
step 2: putting the master batch, 30-40 parts of filler, 2-3 parts of polyethylene glycol, 4-6 parts of hydroxyl silicone oil, 0.4-0.8 part of diphenyl silanediol, 2-3 parts of active zinc oxide, 0.4-0.6 part of stearic acid, 0.8-1.2 parts of rosin and 0.3-0.6 part of antioxidant into an internal mixer, carrying out internal mixing for 10-12min at the temperature of 100-120 ℃, and discharging to obtain rubber compound;
and step 3: putting the rubber compound, 1.6-2 parts of vulcanizing agent and 1-2 parts of accelerator into an open mill, and discharging at 40-45 ℃ to obtain rubber sheets;
and 4, step 4: putting the rubber sheet into a vulcanizing machine, vulcanizing at 160-180 ℃ for 8-10min to obtain a vulcanized rubber material;
and 5: and (3) carrying out compression molding on the vulcanized rubber material to obtain the non-slip mat (2).
CN201910295855.4A 2019-04-12 2019-04-12 Production process of anti-slip sole and anti-slip mat Active CN110037381B (en)

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CN111171393A (en) * 2020-01-20 2020-05-19 温州市润邦鞋业有限公司 Tear-resistant sole material and manufacturing method thereof
CN112143230A (en) * 2020-10-12 2020-12-29 江西赛狮实业有限公司 Production process of anti-slip sole and anti-slip mat
CN114847588A (en) * 2022-03-18 2022-08-05 南通奥斯特鞋业有限公司 Antiskid rubber outsole on ice and production process

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Denomination of invention: A production process for anti slip sole and anti slip pad

Effective date of registration: 20230724

Granted publication date: 20210115

Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Wenzhou Lucheng microenterprise franchise sub branch

Pledgor: ZHEJIANG HENGCHENG SHOES Co.,Ltd.

Registration number: Y2023330001546