CN110317375A - A kind of ice face oil-proof anti-skid footwear material and preparation method thereof - Google Patents
A kind of ice face oil-proof anti-skid footwear material and preparation method thereof Download PDFInfo
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- CN110317375A CN110317375A CN201910673041.XA CN201910673041A CN110317375A CN 110317375 A CN110317375 A CN 110317375A CN 201910673041 A CN201910673041 A CN 201910673041A CN 110317375 A CN110317375 A CN 110317375A
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of ice face oil-proof anti-skid footwear materials and preparation method thereof, are related to footwear material technical field, and raw material includes butyl rubber；Butadiene rubber；Nitrile rubber；Solution polymerized butadiene styrene rubber；White cigarette；Zinc oxide；Anti-aging agent part；Plasticizer；Silane coupling agent；Vulcanization accelerator.Footwear material made from this formula cooperates the specific decorative pattern of outsole, is integrally formed or is pasted in outsole, the sole of acquisition has many advantages, such as oil-proof anti-skid, satisfactory mechanical property and do not return mist.Non-skid property is excellent, can be suitble to use on ice and snow ground.
Description
Technical field
The present invention relates to footwear material technical fields, more specifically, it relates to a kind of ice face oil-proof anti-skid footwear material and its preparation
Method.
Background technique
In the environment for having thin ice, snowfield, ice water, interface of frozen stratum, sole and moist smooth earth or attachment ice sheet
When ground face contact, ice water will be attached to sole surface and form moisture film, so that pedestrian be easy to cause tumble injury of slipping in the process of walking.Cause
This non-skid property of sole is required under ice face, humidity and oil pollution environment it is higher, improve non-skid property be also safety and
Comfortably it is able to ensure key factor.
Based on traditional sole is mainly made with natural rubber and partially synthetic rubber processing at present, although rubber can be reached
Outsole basic wear-resisting, antiskid effect, but can not meet the performance of particular interface on-slip, therefore, it is necessary to by sizing material
Formula and the optimization improvement for being kneaded vulcanisation step increase the coefficient of sliding friction of rubber composition, obtain being more suitable for oil-proof anti-skid shoes
The top-quality rubber at bottom.
Notification number is that the Chinese patent of CN101643562B discloses a kind of Sports shoe sole high slip preventing rubber, the high slip preventing
Rubber is made of the material of following mass parts: 19 parts of butyl rubber；13 parts of butadiene rubber；6 parts of nitrile rubber；White carbon black 23
Part；3 parts of paraffin oil；0.3 part of magnesia；2.3 parts of activating agent；0.6 part of stearic acid；0.5 part of plasticizer；3 parts of calcene；Antifoggant
0.2 part；0.75 part of vulcanizing agent；0.85 part of promotor.
Above-mentioned technical proposal mainly uses the butyl rubber of high-damping, nitrile rubber to improve shoe soles slip stopping effect, still
Butyl rubber is under non-chlorination or brominated situation, it is difficult to and it is compatible with other blend rubbers such as butyronitrile, and then lead to whole machinery
Performance is poor, has much room for improvement.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of ice face oil-proof anti-skid footwear material, have
The characteristics of anti-slip effect, good mechanical performance.
To achieve the above object, the present invention provides the following technical scheme that
A kind of oil-proof anti-skid footwear material, according to parts by weight, raw material includes following components,
By using above-mentioned technical proposal, butyl rubber is synthesized by isobutene and a small amount of isoprene, is generally used to manufacture
The inner tube of a tyre of automobile, airplane wheel has good chemical stability and thermal stability, and most outstanding is air-tightness and watertightness.
After butadiene rubber vulcanization, cold resistance, wearability and elasticity are especially excellent, and ageing-resistant effect is good, are easily used in combination with nitrile rubber, main
It wants the disadvantage is that anti-slippery is poor, tearing is strong and tensile strength is low, it is necessary to and other glue kinds are used in combination.Nitrile rubber mainly uses low temperature
Emulsion polymerization production, oil resistivity is fabulous, and wearability is higher, and heat resistance is preferable, and bonding force is strong.Its shortcoming is that cold resistance, resistance to
Ozone sex-intergrade, elasticity are slightly lower.
Above-mentioned three classes rubber mutually shares, and can accomplish complementation in performance, has wear-resisting, the high performance, low temperature resistant of grasp
Performance, and effectively improve the damped coefficient and antiskid effect of whole system.
Solution polymerized butadiene styrene rubber is with wear-resisting, cold-resistant, heat is low, shrinkage is low, color is good, ash content is few and curingprocess rate is fast
The advantages that, have both the advantages that rolling resistance is small, and wet-sliding resistant performance is excellent.Solution polymerized butadiene styrene rubber all has good with above-mentioned three classes rubber
Good compatibility, and medium can be used as, be conducive to it is whole can homogeneous blend processing, to reach good Physical Mechanical
Can, it can be sufficiently complementary in performance, reach good oil-proof anti-skid performance.
The addition of white cigarette and zinc oxide can be improved the resistance to tearing and wearability of rubbery system.Zinc oxide removes reinforcing agent
Outside, it is alternatively arranged as activator and vulcanization accelerator, the vulcanization, activation and anti-aging of rubber is promoted to act on.Silane coupling agent then can
It is enough so effective that be combined various fillers in rubbery system, thus the mechanical property of the processing performance of rubber product and footwear material
Energy.
Further, the anti-aging agent uses anti-aging agent RD.
By using above-mentioned technical proposal, anti-aging agent RD is also known as 2,2,4- trimethyl -1,2- dihyaroquinolines, is suitable for
The synthetic rubber such as natural rubber and butyronitrile, butylbenzene, it is preferable to aging protection effect caused by heat and oxygen.
Further, the vulcanization accelerator includes 2-2.5 parts and 1-1.5 parts of captax BS of diphenylguanidine TDM.
By using above-mentioned technical proposal, diphenylguanidine TDM is also known as 4,4 '-dithio morpholines, can be used as synthetic rubber
Vulcanizing agent and promotor.Captax BS is also known as 2-[4-morpholinodithio base-N- morpholinyl thioether, is aftereffect vulcanization accelerator,
Putting off property is larger, and vulcanization time is short, is suitable for natural rubber and rubber polymer.The curingprocess rate of diphenylguanidine TDM is slow and promotor
MBS, which is shared, can be improved curingprocess rate, have synergistic function between the two, vulcanize the product of acquisition with more excellent resistance to
The performances such as mill property and intensity.
A kind of chain breaking type anti-aging agent of anti-aging agent RD has reactive N-H functional group in molecular structure, is inhibiting oxidation process
In by with polymer fight for the normal free radical R and RO of chain2To interrupt chain reaction, but in Hydrogen transfer to peroxidating freedom
When on base, at least one molecule hydroperoxides is generated in reaction, and captax BS can react with this hydroperoxides, shape
At non-free radical stable compound, oxidation rate is further decreased.Collaboration is capable of forming between anti-aging agent RD and captax BS to increase
The effect of effect improves age inhibiting effect.
Further, according to parts by weight, raw material includes 10-25 parts of glass fibre.
By using above-mentioned technical proposal, glass fibre is a kind of inorganic non-metallic material haveing excellent performance, and has insulation
Property it is good, heat resistance is strong, corrosion resistance is good, the features such as high mechanical strength, adding glass fibre in rubbery system then can be effective
Improve the wearability and tensile strength of rubbery system.The compatibility of glass fibre and rubbery system is poor, by silane coupled
Agent carries out surface to glass fibre and is modified, then the compatibility between glass fibre and rubber can be effectively improved, so that the two is steady
Consolidation is closed, to improve the comprehensive performance of system.
Further, according to parts by weight, raw material includes 5-7 parts of nine resin of carbon.
By using above-mentioned technical proposal, nine resin of carbon and rubbery system have good compatibility, can be as softening
Agent reduces the Mooney viscosity of rubbery system, and the mixing for being easy to rubbery system is uniform.In addition, nine resin of carbon is added, additionally it is possible to improve
The tan δ value of 0 DEG C of footwear material material, wet-sliding resistant performance are enhanced.
Further, according to parts by weight, raw material includes 5-7 parts of laurane.
By using above-mentioned technical proposal, laurane also known as dodecane are used as organic solvent, in improvement system in system
The dispersing uniformity of each component improves molecule lubricity between rubber molecule, improves processing performance.
Further, according to parts by weight, raw material includes 0.1-0.2 parts of carbon disulfide.
By using above-mentioned technical proposal, anti-aging agent RD is slightly soluble in laurane, so that anti-aging agent RD can not be equal with laurane
It is even to be distributed in rubbery system.At low ambient temperatures, anti-aging agent RD will be precipitated in the part of saturation from rubbery system, be formed
Atomization.Anti-aging agent RD is soluble in carbon disulfide, and can dissolve each other between carbon disulfide and laurane, enable carbon disulfide at
For the medium linked up between laurane and anti-aging agent RD, to increase solubility of the anti-aging agent RD in laurane, to avoid
Form atomization.
Further, according to parts by weight, raw material includes 5-10 parts of PEG-4000.
By using above-mentioned technical proposal, PEG-4000 can change as processing aid with good lubricating action
Kind release property, so that footwear material surface-brightening, the discharge of moisture when additionally aiding vulcanization；It can also be used as vulcanizing activator, it can be right
Captax BS plays activation, improves curingprocess rate and crosslinking degree；It can also can reduce or disappear as activation dispersing agent
Influence except filler to vulcanization makes various auxiliary agents be uniformly dispersed and extends time of scorch, improves the physical mechanical property of footwear material.This
Outside, the alcoholic extract hydroxyl group of PEG-4000 can form hydrogen bond between the N-H of anti-aging agent RD, increase anti-aging agent RD in PEG-4000
Solubility, since PEG-4000 is miscible with laurane, PEG-4000 equally improve anti-aging agent RD in system point
Dissipate property.So that footwear material has stable anti-oxidant, aging action, and atomizating phenomenon will not be generated.
Another object of the present invention is to provide a kind of preparation methods of ice face oil-proof anti-skid footwear material, comprising the following steps:
Step 1, glass fibre is uniformly mixed with the solution that silane coupling agent configures, is dried under the conditions of 100-120 DEG C
It is spare to obtain modified glass-fiber by 3-4h；
Step 2, laurane, anti-aging agent RD, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly,
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 5-10min, adds white cigarette and continues to mix mixing 3-5min, temperature is led when reaching 120-125 DEG C
Rubber master batches are obtained out；
Step 4, rubber master batches, modified glass-fiber, compounding agent and plasticizer and zinc oxide is uniform in rubber mixing machine
Mixing obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 15-20 times, adjustment roller spacing to required thickness goes out
Piece obtains film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Further, step 1, step 2 and step 3 in no particular order sequence, can arbitrarily be adjusted according to working condition.
In conclusion the invention has the following advantages:
It 1. butyl rubber, butadiene rubber and nitrile rubber three classes rubber are mutually mixed, can accomplish complementation in performance, have
Have it is wear-resisting, high grasp performance, resistance to low temperature, and effectively improve the damped coefficient and antiskid effect of whole system.Contain intermingle with fourth
Benzene rubber has many advantages, such as that wear-resisting, cold-resistant, heat is low, shrinkage is low, color is good, ash content is few and curingprocess rate is fast, has both rolling
The advantages that dynamic resistance is small, and wet-sliding resistant performance is excellent.Solution polymerized butadiene styrene rubber and above-mentioned three classes rubber all have good compatibility, and
Medium can be used as, be conducive to it is whole can homogeneous blend processing, can in performance to reach good physical mechanical property
It is sufficiently complementary, reach good oil-proof anti-skid performance；
2. diphenylguanidine TDM is also known as 4,4 '-dithio morpholines, it can be used as the vulcanizing agent and promotor of synthetic rubber.Promote
It is also known as 2-[4-morpholinodithio base-N- morpholinyl thioether into agent MBS, is aftereffect vulcanization accelerator, putting off property is larger, vulcanization time
It is short, it is suitable for natural rubber and rubber polymer.The curingprocess rate of diphenylguanidine TDM is slow and captax BS is shared and be can be improved vulcanization
Speed has synergistic function between the two, and the product for vulcanizing acquisition has the performances such as more excellent wearability and intensity；
3. a kind of chain breaking type anti-aging agent of anti-aging agent RD, there is reactive N-H functional group in molecular structure, is inhibiting to aoxidize
By fighting for the normal free radical R and RO of chain with polymer in journey2To interrupt chain reaction, but Hydrogen transfer to peroxidating from
When by base, at least one molecule hydroperoxides is generated in reaction, and captax BS can react with this hydroperoxides,
Non-free radical stable compound is formed, oxidation rate is further decreased.Collaboration is capable of forming between anti-aging agent RD and captax BS
The effect of synergy improves age inhibiting effect；
4. nine resin of carbon and rubbery system have good compatibility, the Mooney of rubbery system can be reduced as softening agent
Viscosity, the mixing for being easy to rubbery system are uniform.In addition, nine resin of carbon is added, additionally it is possible to improve 0 DEG C of tan δ of footwear material material
Value, wet-sliding resistant performance are enhanced；
5. anti-aging agent RD is slightly soluble in laurane, so that anti-aging agent RD can not be uniformly distributed in rubbery system with laurane.
At low ambient temperatures, anti-aging agent RD will be precipitated in the part of saturation from rubbery system, form atomization.Anti-aging agent RD is soluble in
Carbon disulfide, and can dissolve each other between carbon disulfide and laurane, carbon disulfide is become and links up laurane and prevents old
Medium between agent RD, to increase solubility of the anti-aging agent RD in laurane, to avoid the formation of atomization；
6.PEG-4000 can be used as processing aid, with good lubricating action, improve release property, so that footwear material table
Face is bright, the discharge of moisture when additionally aiding vulcanization；It can also be used as vulcanizing activator, activation can be played to captax BS and is made
With raising curingprocess rate and crosslinking degree；Influence of the filler to vulcanization can also can be reduced or eliminated as activation dispersing agent,
So that various auxiliary agents is uniformly dispersed and extend time of scorch, improves the physical mechanical property of footwear material.In addition, the alcoholic extract hydroxyl group of PEG-4000
Hydrogen bond can be formed between the N-H of anti-aging agent RD, solubility of the anti-aging agent RD in PEG-4000 is increased, due to PEG-
4000 is miscible with laurane, therefore PEG-4000 equally improves dispersibility of the anti-aging agent RD in system.So that footwear material has
Stable anti-oxidant, aging action, and atomizating phenomenon will not be generated.
Detailed description of the invention
Fig. 1 is the flow chart of method provided by the invention.
Specific embodiment
Below in conjunction with attached drawing 1 and embodiment, invention is further described in detail.
Embodiment
Embodiment 1
A kind of ice face oil-proof anti-skid footwear material, according to parts by weight, raw material components are as shown in table 1.Anti-aging agent uses anti-aging agent
RD, accelerant A use diphenylguanidine TDM, and accelerant B uses captax BS.The preparation method of the oil-proof anti-skid footwear material include with
Lower step:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 100 DEG C
It is spare to obtain modified glass-fiber by 3h；
Step 2, by laurane, anti-aging agent, vulcanization accelerator (i.e. accelerant A+accelerant B), carbon disulfide and REG-
4000 are mixed evenly, and it is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 5min, adds white cigarette and continuess to mix mixing 3min, export obtains rubber when temperature reaches 120 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 15 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Wherein, step 1, step 2 and step 3 in no particular order sequence, can arbitrarily be adjusted according to working condition.
Embodiment 2
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.The preparation of oil-proof anti-skid footwear material
Method the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 120 DEG C
It is spare to obtain modified glass-fiber by 4h；
Step 2, laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 10min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 125 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 20 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 3
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.The preparation of oil-proof anti-skid footwear material
Method the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 110 DEG C
It is spare to obtain modified glass-fiber by 3.5h；
Step 2, laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 8min, adds white cigarette and continuess to mix mixing 4min, export obtains rubber when temperature reaches 120 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 18 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 4
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.Wherein, anti-aging agent is using anti-
Old agent NBC.
The preparation method of oil-proof anti-skid footwear material the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 100 DEG C
It is spare to obtain modified glass-fiber by 4h；
Step 2, laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 5min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 125 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 17 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 5
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.Wherein, accelerant A uses one
Vulcanize tetra methylthiuram.
The preparation method of oil-proof anti-skid footwear material the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 110 DEG C
It is spare to obtain modified glass-fiber by 4h；
Step 2, laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 7min, adds white cigarette and continuess to mix mixing 4min, export obtains rubber when temperature reaches 125 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 17 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 6
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.Wherein, accelerant B uses one
Vulcanize tetra methylthiuram.
The preparation method of oil-proof anti-skid footwear material the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 120 DEG C
It is spare to obtain modified glass-fiber by 4h；
Step 2, laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
It is spare to obtain compounding agent；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 5min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 120 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 15 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 7
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.The preparation of oil-proof anti-skid footwear material
Method the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 120 DEG C
It is spare to obtain modified glass-fiber by 3h；
Step 2, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, obtain compounding agent
It is spare；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 10min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 120 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 15 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 8
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.The preparation of oil-proof anti-skid footwear material
Method the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 120 DEG C
It is spare to obtain modified glass-fiber by 3h；
Step 2, laurane, anti-aging agent, vulcanization accelerator and REG-4000 are mixed evenly, it is standby obtains compounding agent
With；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 10min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 120 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 20 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Embodiment 9
The difference from embodiment 1 is that according to parts by weight, raw material components are as shown in table 1.The preparation of oil-proof anti-skid footwear material
Method the following steps are included:
Step 1, glass fibre is uniformly mixed with the silane coupling agent SI-69 solution configured, is dried under the conditions of 120 DEG C
It is spare to obtain modified glass-fiber by 3h；
Step 2, laurane, anti-aging agent, vulcanization accelerator and carbon disulfide are mixed evenly, it is standby obtains compounding agent
With；
Step 3, the mixing of butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon is put into close
Mixing in mill mixes mixing 10min, adds white cigarette and continuess to mix mixing 5min, export obtains rubber when temperature reaches 125 DEG C
Glue masterbatch；
Step 4, rubber master batches, modified glass-fiber, compounding agent and dioctyl phthalate and zinc oxide are being refined
It is uniformly mixed in glue machine, obtains rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 17 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, will
Shoes piece, which is put into matched mold, obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
Performance detection test
Tensile strength (MPa) test is carried out to sample referring to GB/T 528-92, test result is as shown in table 2；
Carry out the on-slip coefficient test of dry type and wet type, test result such as 2 institute of table respectively to sample referring to TM144:2011
Show；
It referring to the heat aging performance of GB/T 3512-2001 measurement sample, is embodied by tensile strength variation (MPa), test
The results are shown in Table 2；
Referring to A method in DIN (Deutsche Industrie Norm) 75201, haze value (%) is carried out to sample and is surveyed
Examination, testing result are as shown in table 2.
Table 1
Table 1- is continuous
Table 2
According to the data of Tables 1 and 2, embodiment 1-9 is compared, and the tensile strength variation of embodiment 4 and embodiment 6 is bright
It is aobvious to increase, illustrate that there is synergistic function between anti-aging agent RD and captax BS, can be improved anti-aging effect.
The tensile strength of embodiment 5 and embodiment 6 is remarkably decreased, and illustrating can between diphenylguanidine TDM and captax BS
Mutually collaboration vulcanization effect, to improve the tensile strength of product.
7 properties of embodiment are declined, and illustrate that laurane can improve the mixing of system as primary solvent
Degree, to improve the comprehensive performance of product.
Haze value significantly improves in embodiment 8, illustrates that carbon disulfide can increase the dispersibility of whole system, in system
Component will not be precipitated because of hypersaturated state, and surface will not be atomized.
Haze value is equally promoted in embodiment 9, illustrates that PEG-4000 can be conducive to improve anti-aging agent RD in system
In dispersibility.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (10)
1. a kind of ice face oil-proof anti-skid footwear material, it is characterised in that: according to parts by weight, raw material includes following components,
5-10 parts of butyl rubber；
15-25 parts of butadiene rubber；
40-60 parts of nitrile rubber；
10-15 parts of solution polymerized butadiene styrene rubber；
10-15 parts of white cigarette；
4-7 parts of zinc oxide；
1.5-2.5 parts of anti-aging agent；
1-5 parts of plasticizer；
2-3 parts of silane coupling agent；
3-4 parts of vulcanization accelerator.
2. a kind of ice face oil-proof anti-skid footwear material according to claim 1, it is characterised in that: the anti-aging agent uses anti-aging agent
RD。
3. a kind of ice face oil-proof anti-skid footwear material according to claim 2, it is characterised in that: the vulcanization accelerator includes promoting
Into 2-2.5 parts and 1-1.5 parts of captax BS of agent DTDM.
4. a kind of ice face oil-proof anti-skid footwear material according to claim 1, it is characterised in that: according to parts by weight, raw material packet
Include 10-25 parts of glass fibre.
5. a kind of ice face oil-proof anti-skid footwear material according to claim 1, it is characterised in that: according to parts by weight, raw material packet
Include 5-7 parts of nine resin of carbon.
6. a kind of ice face oil-proof anti-skid footwear material according to claim 1, it is characterised in that: according to parts by weight, raw material packet
Include 5-7 parts of laurane.
7. a kind of ice face oil-proof anti-skid footwear material according to claim 6, it is characterised in that: according to parts by weight, raw material packet
Include 0.1-0.2 parts of carbon disulfide.
8. a kind of ice face oil-proof anti-skid footwear material according to claim 7, it is characterised in that: according to parts by weight, raw material packet
Include 5-10 parts of PEG-4000.
9. the preparation method of -8 any a kind of ice face oil-proof anti-skid footwear materials according to claim 1, it is characterised in that: including
Following steps,
Step 1, glass fibre is uniformly mixed with the solution that silane coupling agent configures, dries 3-4h under the conditions of 100-120 DEG C,
It is spare to obtain modified glass-fiber；
Step 2, laurane, anti-aging agent RD, vulcanization accelerator, carbon disulfide and REG-4000 are mixed evenly, are obtained
Compounding agent is spare；
Step 3, butyl rubber, butadiene rubber, nitrile rubber, solution polymerized butadiene styrene rubber and nine resin of carbon are mixed and is put into mixer
Middle mixing mixes mixing 5-10min, adds white cigarette and continues to mix mixing 3-5min, and export obtains when temperature reaches 120-125 DEG C
Obtain rubber master batches；
Step 4, rubber master batches, modified glass-fiber, compounding agent and plasticizer and zinc oxide are uniformly mixed in rubber mixing machine,
Obtain rubber compound；
Step 5, rubber compound is kneaded on the double roll mill, is kneaded 15-20 times, adjusted roller spacing to required thickness slice, obtain
Obtain film；
Step 6, film is punched out shoes piece of different shapes, the shape of shoes piece is designed according to different shoe sole prints, by shoes piece
It is put into matched mold and obtains ice face oil-proof anti-skid footwear material in 155-165 DEG C of sulfidization molding.
10. a kind of preparation method of ice face oil-proof anti-skid footwear material according to claim 9, it is characterised in that: step 1, step
Rapid 2 and step 3 in no particular order sequence, can arbitrarily be adjusted according to working condition.
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| CN110698733A (en) * | 2019-10-14 | 2020-01-17 | 福建五持恒科技发展有限公司 | Graphene natural rubber polymer ice top-slip mixed foam material and preparation method thereof |
| CN111154170A (en) * | 2019-12-21 | 2020-05-15 | 温州市龙湾天龙鞋业有限公司 | EVA sole and preparation method thereof |
| CN111253668A (en) * | 2019-12-21 | 2020-06-09 | 温州市龙湾天龙鞋业有限公司 | Anti-slip sole and preparation method thereof |
| CN112831104A (en) * | 2020-12-31 | 2021-05-25 | 浙江中瑞橡胶高分子材料股份有限公司 | Novel modified rubber |
| CN113388172A (en) * | 2021-07-02 | 2021-09-14 | 江南大学 | Rubber sheet capable of stopping slipping on ice and preparation method thereof |
| CN115028909A (en) * | 2022-06-22 | 2022-09-09 | 佛山市俊亿鞋业有限公司 | Ice surface antiskid rubber and preparation method thereof |
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