CN107118453A - A kind of sole and preparation method thereof - Google Patents
A kind of sole and preparation method thereof Download PDFInfo
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- CN107118453A CN107118453A CN201710441291.1A CN201710441291A CN107118453A CN 107118453 A CN107118453 A CN 107118453A CN 201710441291 A CN201710441291 A CN 201710441291A CN 107118453 A CN107118453 A CN 107118453A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention provides a kind of sole and preparation method thereof, is related to footwear technical field, sole includes the raw material of following parts by weight：13 17 parts of nitrile rubber, 50 70 parts of brombutyl, 10 24 parts of nano silicon, 13 parts of haloflex, 14 parts of Tissuemat E, 0.2 1 parts of magnesia, 14 parts of nano zine oxide, 0.6 2 parts of sulphur, 6 10 parts of nano-calcium carbonate, 59 parts of bentonite, 7 13 parts of bamboo charcoal, 9 15 parts of quartz glass fibre, 7 13 parts of polypropylene fibre, 0.6 2 parts of vulcanization accelerator, 48 parts of plasticiser, 0.6 2 parts of antioxidant, 24 parts of white smoke active agent, 13 parts of coupling agent, 0.2 0.6 parts of 0.2 0.4 parts of lubricant and heat stabilizer；Preparation method comprises the following steps：（1）Weigh raw material,（2）Addition banbury,（3）Addition two-roll mill,（4）Sulfidization molding.The present invention has high anti-skidding, antibacterial, compression strength, good toughness and these performances of light weight when solving still different in existing sole the problem of.
Description
Technical field
The invention belongs to footwear technical field, and in particular to a kind of sole and preparation method thereof.
Background technology
Because sole is the most direct position that footwear are contacted with ground, people avoid not in the different places that come in and go out, sole
Can adhesion it is various dirty, if infrequently cleared up, be easy to grow harmful bacteria, harmful to human in life or office space
Health.
This outsole must also be provided simultaneously with other performances in addition to this good basic performance of skid resistance, for example：Pressure resistance
Degree height, good toughness and light weight.
But there are high anti-skidding, antibacterial, compression strength, good toughness and light weight these performances when still different in existing sole.
The content of the invention
In order to have when solving in existing sole still different high anti-skidding, antibacterial, compression strength, good toughness and light weight these
The problem of performance, it is an object of the invention to provide a kind of sole and preparation method thereof, obtained sole has anti-skidding, antibacterial, resisted
The advantage of Compressive Strength height, good toughness and light weight.
The invention provides following technical scheme：
A kind of sole, includes the raw material of following parts by weight：13-17 parts of nitrile rubber, 50-70 parts of brombutyl, nanometer two
10-24 parts of silica, 1-3 parts of haloflex, 1-4 parts of Tissuemat E, 0.2-1 parts of magnesia, 1-4 parts of nano zine oxide, sulphur
0.6-2 parts of sulphur, 6-10 parts of nano-calcium carbonate, 5-9 parts of bentonite, 7-13 parts of bamboo charcoal, 9-15 parts of quartz glass fibre, polypropylene are fine
7-13 parts of dimension, 0.6-2 parts of vulcanization accelerator, 4-8 parts of plasticiser, 0.6-2 parts of antioxidant, 2-4 parts of white smoke active agent, coupling agent
0.2-0.6 parts of 1-3 parts, 0.2-0.4 parts of lubricant and heat stabilizer.
Nano-calcium carbonate is with the addition of in raw material, nano-calcium carbonate is as the filler of sole, the stream with improvement sole raw material
Denaturation, improves its mouldability, toughness and intensity.
Bentonite is with the addition of in raw material, bentonite is to gas, liquid and the certain adsorption capacity of organic substance.
Bamboo charcoal is with the addition of in raw material, bamboo charcoal is loose and porous structure, and its molecule is fine and closely woven porous, and quality is hard, with very strong
Adsorption capacity, can purify air, eliminate peculiar smell, antibacterial expelling parasite and breathing damping.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
It with the addition of polypropylene fibre in raw material, polypropylene fibre has that light weight, intensity are high, elasticity is good, wear-resisting, corrosion-resistant,
The characteristics of electric insulation and insulation.
Preferably, the raw material of following parts by weight is included：15 parts of nitrile rubber, 60 parts of brombutyl, nanometer titanium dioxide
17 parts of silicon, 2 parts of haloflex, 2.5 parts of Tissuemat E, 0.6 part of magnesia, 2.5 parts of nano zine oxide, sulphur 1.3 part, nanometer
8 parts of calcium carbonate, 7 parts of bentonite, 10 parts of bamboo charcoal, 12 parts of quartz glass fibre, 10 parts of polypropylene fibre, 1.3 parts of vulcanization accelerator,
0.4 part of 6 parts of plasticiser, 1.3 parts of antioxidant, 3 parts of white smoke active agent, 2 parts of coupling agent, 0.3 part of lubricant and heat stabilizer.
Preferably, the vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time,
Curing temperature is reduced, vulcanizing agent consumption is reduced and improves the physical and mechanical properties of rubber, also with age inhibiting effect.
Preferably, the plasticiser is phthalate plasticiser, it is possible to increase the toughness of sole, is easy to sole to add
Work.
Preferably, the antioxidant is dilauryl thiodipropionate, can prevent or delay sole to aoxidize.
Preferably, the coupling agent is zirconium class coupling agent, can promote the bonding between raw material, improves the rheology of composite
Property.
Preferably, the lubricant is fatty acid amide series lubricant agent, and reduction polymer can be played in polymeric inner
The effect of intermolecular cohesion, so as to improve the interior frictional heat and mobility of sole raw material.
Preferably, the heat stabilizer is aluminum stearate, improves the heat endurance of sole.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
The beneficial effects of the invention are as follows：
1st, have when the present invention solves in existing sole still different high anti-skidding, antibacterial, compression strength, good toughness and light weight this
The problem of a little performances.
2nd, with the addition of nano-calcium carbonate in raw material of the invention, nano-calcium carbonate as sole filler, with improving footwear
The rheological characteristic of bottom raw material, improves its mouldability, toughness and intensity.
3rd, bentonite is with the addition of in raw material of the invention, bentonite is to gas, liquid and the certain energy of adsorption of organic substance
Power.
4th, bamboo charcoal is with the addition of in raw material of the invention, bamboo charcoal is loose and porous structure, and its molecule is fine and closely woven porous, quality is hard
Firmly, with very strong adsorption capacity, air can be purified, peculiar smell, antibacterial expelling parasite and breathing damping is eliminated.
5th, quartz glass fibre is with the addition of in raw material of the invention, quartz glass fibre has intensity height, high temperature resistant, corrosion resistant
Erosion, heat-insulated and chemical stability are good.
6th, polypropylene fibre is with the addition of in raw material of the invention, polypropylene fibre has light weight, intensity high, elastic good, resistance to
The characteristics of mill, corrosion-resistant, electric insulation and insulation.
7th, heretofore described vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, when shortening vulcanization
Between, curing temperature is reduced, vulcanizing agent consumption is reduced and improves the physical and mechanical properties of rubber, also with age inhibiting effect.
8th, heretofore described plasticiser is phthalate plasticiser, it is possible to increase the toughness of sole, is easy to footwear
Bottom is processed.
9th, heretofore described antioxidant is dilauryl thiodipropionate, can prevent or delay sole to aoxidize.
10th, heretofore described coupling agent is zirconium class coupling agent, can promote the bonding between raw material, improves composite
Rheological characteristic.
11st, heretofore described lubricant is fatty acid amide series lubricant agent, reduction can be played in polymeric inner poly-
The effect of cohesive force between adduct molecule, so as to improve the interior frictional heat and mobility of sole raw material.
12nd, heretofore described heat stabilizer is aluminum stearate, improves the heat endurance of sole.
Embodiment
Embodiment 1
A kind of sole, includes the raw material of following parts by weight：15 parts of nitrile rubber, 60 parts of brombutyl, nano silicon
17 parts, 2 parts of haloflex, 2.5 parts of Tissuemat E, 0.6 part of magnesia, 2.5 parts of nano zine oxide, 1.3 parts of sulphur, nano-sized carbon
Sour 8 parts of calcium, 7 parts of bentonite, 10 parts of bamboo charcoal, 12 parts of quartz glass fibre, 10 parts of polypropylene fibre, 1.3 parts of vulcanization accelerator, modeling
0.4 part of 6 parts of agent, 1.3 parts of antioxidant, 3 parts of white smoke active agent, 2 parts of coupling agent, 0.3 part of lubricant and heat stabilizer.
Nano-calcium carbonate is with the addition of in raw material, nano-calcium carbonate is as the filler of sole, the stream with improvement sole raw material
Denaturation, improves its mouldability, toughness and intensity.
Bentonite is with the addition of in raw material, bentonite is to gas, liquid and the certain adsorption capacity of organic substance.
Bamboo charcoal is with the addition of in raw material, bamboo charcoal is loose and porous structure, and its molecule is fine and closely woven porous, and quality is hard, with very strong
Adsorption capacity, can purify air, eliminate peculiar smell, antibacterial expelling parasite and breathing damping.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
It with the addition of polypropylene fibre in raw material, polypropylene fibre has that light weight, intensity are high, elasticity is good, wear-resisting, corrosion-resistant,
The characteristics of electric insulation and insulation.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect.
Plasticiser is phthalate plasticiser, it is possible to increase the toughness of sole, is easy to sole to process.
Antioxidant is dilauryl thiodipropionate, can prevent or delay sole to aoxidize.
Coupling agent is zirconium class coupling agent, can promote the bonding between raw material, improves the rheological characteristic of composite.
Lubricant be fatty acid amide series lubricant agent, can polymeric inner play reduction polymer molecule between cohesive force
Effect, so as to improve the interior frictional heat and mobility of sole raw material.
Heat stabilizer is aluminum stearate, improves the heat endurance of sole.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Embodiment 2
A kind of sole, includes the raw material of following parts by weight：13 parts of nitrile rubber, 50 parts of brombutyl, nano silicon
10 parts, 1 part of haloflex, 1 part of Tissuemat E, 0.2 part of magnesia, 1 part of nano zine oxide, 0.6 part of sulphur, nano-calcium carbonate
6 parts, 5 parts of bentonite, 7 parts of bamboo charcoal, 9 parts of quartz glass fibre, 7 parts of polypropylene fibre, 0.6 part of vulcanization accelerator, plasticiser 4
Part, 0.6 part of antioxidant, 2 parts of white smoke active agent, 1 part of coupling agent, 0.2 part of lubricant and 0.2 part of heat stabilizer.
Nano-calcium carbonate is with the addition of in raw material, nano-calcium carbonate is as the filler of sole, the stream with improvement sole raw material
Denaturation, improves its mouldability, toughness and intensity.
Bentonite is with the addition of in raw material, bentonite is to gas, liquid and the certain adsorption capacity of organic substance.
Bamboo charcoal is with the addition of in raw material, bamboo charcoal is loose and porous structure, and its molecule is fine and closely woven porous, and quality is hard, with very strong
Adsorption capacity, can purify air, eliminate peculiar smell, antibacterial expelling parasite and breathing damping.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
It with the addition of polypropylene fibre in raw material, polypropylene fibre has that light weight, intensity are high, elasticity is good, wear-resisting, corrosion-resistant,
The characteristics of electric insulation and insulation.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect.
Plasticiser is phthalate plasticiser, it is possible to increase the toughness of sole, is easy to sole to process.
Antioxidant is dilauryl thiodipropionate, can prevent or delay sole to aoxidize.
Coupling agent is zirconium class coupling agent, can promote the bonding between raw material, improves the rheological characteristic of composite.
Lubricant be fatty acid amide series lubricant agent, can polymeric inner play reduction polymer molecule between cohesive force
Effect, so as to improve the interior frictional heat and mobility of sole raw material.
Heat stabilizer is aluminum stearate, improves the heat endurance of sole.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Embodiment 3
A kind of sole, includes the raw material of following parts by weight：17 parts of nitrile rubber, 70 parts of brombutyl, nano silicon
24 parts, 3 parts of haloflex, 4 parts of Tissuemat E, 1 part of magnesia, 4 parts of nano zine oxide, 2 parts of sulphur, nano-calcium carbonate 10
Part, 9 parts of bentonite, 13 parts of bamboo charcoal, 15 parts of quartz glass fibre, 13 parts of polypropylene fibre, 2 parts of vulcanization accelerator, plasticiser 8
Part, 2 parts of antioxidant, 4 parts of white smoke active agent, 3 parts of coupling agent, 0.4 part of lubricant and 0.6 part of heat stabilizer.
Nano-calcium carbonate is with the addition of in raw material, nano-calcium carbonate is as the filler of sole, the stream with improvement sole raw material
Denaturation, improves its mouldability, toughness and intensity.
Bentonite is with the addition of in raw material, bentonite is to gas, liquid and the certain adsorption capacity of organic substance.
Bamboo charcoal is with the addition of in raw material, bamboo charcoal is loose and porous structure, and its molecule is fine and closely woven porous, and quality is hard, with very strong
Adsorption capacity, can purify air, eliminate peculiar smell, antibacterial expelling parasite and breathing damping.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
It with the addition of polypropylene fibre in raw material, polypropylene fibre has that light weight, intensity are high, elasticity is good, wear-resisting, corrosion-resistant,
The characteristics of electric insulation and insulation.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect.
Plasticiser is phthalate plasticiser, it is possible to increase the toughness of sole, is easy to sole to process.
Antioxidant is dilauryl thiodipropionate, can prevent or delay sole to aoxidize.
Coupling agent is zirconium class coupling agent, can promote the bonding between raw material, improves the rheological characteristic of composite.
Lubricant be fatty acid amide series lubricant agent, can polymeric inner play reduction polymer molecule between cohesive force
Effect, so as to improve the interior frictional heat and mobility of sole raw material.
Heat stabilizer is aluminum stearate, improves the heat endurance of sole.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Comparative example 1
A kind of sole, includes the raw material of following parts by weight：15 parts of nitrile rubber, 60 parts of brombutyl, nano silicon
17 parts, 2 parts of haloflex, 2.5 parts of Tissuemat E, 0.6 part of magnesia, 2.5 parts of nano zine oxide, 1.3 parts of sulphur, vulcanization promote
Enter 2 parts of 1.3 parts of agent, 6 parts of plasticiser, 3 parts of white smoke active agent and coupling agent.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Sole is made in embodiment 1, embodiment 2, embodiment 3 and comparative example and carries out performance test, is obtained such as following table test result,
As shown in table 1：
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Density（g/cm3） | 1.012 | 1.098 | 1.196 | 1.354 |
| Compression strength（Mpa） | 33.2 | 26.2 | 22.2 | 18.3 |
| Tensile strength（Mpa） | 15.2 | 13.6 | 11.8 | 9.5 |
| Anti-microbial property（%） | 79 | 72 | 64 | 0 |
| Static on-slip coefficient（High oil） | 0.67 | 0.65 | 0.63 | 0.59 |
| Static on-slip coefficient（High oil adds water） | 0.66 | 0.64 | 0.62 | 0.56 |
| Dynamic on-slip coefficient（Heel） | 0.63 | 0.62 | 0.60 | 0.54 |
| Dynamic on-slip coefficient（Smoothly） | 0.64 | 0.63 | 0.61 | 0.55 |
From the data of table 1 compare as can be seen that it is an advantage of the invention that：
1st, a kind of sole and preparation method thereof, from the density measured as can be seen that embodiment 1-3 density is below comparative example 1,
Illustrate sole light weight of the present invention.
2nd, a kind of sole and preparation method thereof, from the compression strength measured as can be seen that embodiment 1-3 compression strength is equal
Higher than comparative example 1, illustrate that the compression strength of sole of the present invention is high.
3rd, a kind of sole and preparation method thereof, tensile strength is according to ISO 37：2005 tests, from the tensile strength measured
As can be seen that embodiment 1-3 tensile strength is above comparative example 1, illustrate the good toughness of sole of the present invention.
4th, a kind of sole and preparation method thereof, from the anti-microbial property measured as can be seen that embodiment 1-3 anti-microbial property is equal
Better than comparative example 1, illustrate the good anti-bacterial effect of sole of the present invention.
5th, a kind of sole and preparation method thereof, static on-slip coefficient is according to F1677：2005 tests, dynamic on-slip coefficient is pressed
According to ISO13287：2012 test SRA patterns (cleaning solution pollution interface), from the static on-slip coefficient measured（High oil）, static state stops
Sliding coefficient（High oil adds water）, dynamic on-slip coefficient（Heel）With dynamic on-slip coefficient（Smoothly）As can be seen that embodiment 1-3's is quiet
State on-slip coefficient（High oil）, static on-slip coefficient（High oil adds water）, dynamic on-slip coefficient（Heel）With dynamic on-slip coefficient（It is flat
It is sliding）Comparative example 1 is above, illustrates the good antiskid effect of sole of the present invention.
6th, a kind of sole and preparation method thereof, from the data of each index measured as can be seen that embodiment 1 is superior to reality
Example 2, embodiment 3 and comparative example 1 are applied, illustrates the composition of raw materials of sole of the present invention and the reasonability of preparation method.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or equivalent substitution, all essences in the present invention are carried out to which part technical characteristic
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (9)
1. a kind of sole, it is characterised in that include the raw material of following parts by weight：13-17 parts of nitrile rubber, brombutyl
50-70 parts, 10-24 parts of nano silicon, 1-3 parts of haloflex, 1-4 parts of Tissuemat E, 0.2-1 parts of magnesia, nanometer
1-4 parts of zinc oxide, 0.6-2 parts of sulphur, 6-10 parts of nano-calcium carbonate, 5-9 parts of bentonite, 7-13 parts of bamboo charcoal, quartz glass fibre
9-15 parts, 7-13 parts of polypropylene fibre, 0.6-2 parts of vulcanization accelerator, 4-8 parts of plasticiser, 0.6-2 parts of antioxidant, white cigarette live
Property 0.2-0.6 parts of 2-4 parts of agent, 1-3 parts of coupling agent, 0.2-0.4 parts of lubricant and heat stabilizer.
2. sole according to claim 1, it is characterised in that include the raw material of following parts by weight：15 parts of nitrile rubber, bromine
Change 60 parts of butyl rubber, 17 parts of nano silicon, 2 parts of haloflex, 2.5 parts of Tissuemat E, magnesia 0.6 part, nanometer
2.5 parts of zinc oxide, 1.3 parts of sulphur, 8 parts of nano-calcium carbonate, 7 parts of bentonite, 10 parts of bamboo charcoal, 12 parts of quartz glass fibre, poly- third
10 parts of alkene fiber, 1.3 parts of vulcanization accelerator, 6 parts of plasticiser, 1.3 parts of antioxidant, 3 parts of white smoke active agent, 2 parts of coupling agent, profit
0.4 part of 0.3 part of lubrication prescription and heat stabilizer.
3. sole according to claim 1, it is characterised in that：The vulcanization accelerator is 2- thiol benzothiazoles.
4. sole according to claim 1, it is characterised in that：The plasticiser is phthalate plasticiser.
5. sole according to claim 1, it is characterised in that：The antioxidant is dilauryl thiodipropionate.
6. sole according to claim 1, it is characterised in that：The coupling agent is zirconium class coupling agent.
7. sole according to claim 1, it is characterised in that：The lubricant is fatty acid amide series lubricant agent.
8. sole according to claim 1, it is characterised in that：The heat stabilizer is aluminum stearate.
9. the preparation method of a kind of sole as described in claim 1-8 any one, it is characterised in that comprise the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710441291.1A CN107118453A (en) | 2017-06-13 | 2017-06-13 | A kind of sole and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710441291.1A CN107118453A (en) | 2017-06-13 | 2017-06-13 | A kind of sole and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107118453A true CN107118453A (en) | 2017-09-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710441291.1A Withdrawn CN107118453A (en) | 2017-06-13 | 2017-06-13 | A kind of sole and preparation method thereof |
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| CN (1) | CN107118453A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109463843A (en) * | 2018-12-13 | 2019-03-15 | 盐城市吉成鞋业有限公司 | A kind of ski-proof snow land boots that heat-preservation ventilating effect is good |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
-
2017
- 2017-06-13 CN CN201710441291.1A patent/CN107118453A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王玉芬等: "《新型纺织材料及应用（第二版）》", 31 October 2011, 化学工业出版社 * |
| 肖长发等: "《化学纤维概论（第3版）》", 30 June 2015, 中国纺织出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109463843A (en) * | 2018-12-13 | 2019-03-15 | 盐城市吉成鞋业有限公司 | A kind of ski-proof snow land boots that heat-preservation ventilating effect is good |
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