CN104277344A - Chef shoe sole and preparation method thereof - Google Patents

Chef shoe sole and preparation method thereof Download PDF

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Publication number
CN104277344A
CN104277344A CN201410387233.1A CN201410387233A CN104277344A CN 104277344 A CN104277344 A CN 104277344A CN 201410387233 A CN201410387233 A CN 201410387233A CN 104277344 A CN104277344 A CN 104277344A
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China
Prior art keywords
parts
sole
shoes
kitchener
sulphur
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Granted
Application number
CN201410387233.1A
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Chinese (zh)
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CN104277344B (en
Inventor
卢鑫
丁思博
罗显发
曾建伟
郭彩莲
林荷香
金校红
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Maotai Fujian New Material Technology Co ltd
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Maotai Fujian Shoes Material Co Ltd
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Priority to CN201410387233.1A priority Critical patent/CN104277344B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283Halogenated homo- or copolymers of iso-olefins
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention relates to a sole and discloses a chef shoe sole and a preparation method thereof. The chef shoe sole comprises the following components: nitrile-butadiene rubber, brominated butyl rubber, nanosilicon dioxide, a plasticizer, an anti-aging agent, a white smoke activator, a silane coupling agent, chlorinated polyethylene, polyethylene wax, magnesium oxide, zinc oxide, sulphur and a vulcanization accelerator. The brominated rubber is used as matrix rubber and is combined with the oil-resistant nitrile-butadiene rubber to obtain the antiskid and comfortable chef shoe sole, the chef shoe adopting the sole can provide a reliable, favorable and safe guarantee for personnel operating in a kitchen environment, and shoe products which are indispensable in work and life are formed.

Description

A kind of shoes for kitchener sole and preparation method thereof
Technical field
The present invention relates to a kind of sole, particularly a kind of preparation method of shoes for kitchener sole.
Background technology
State's Putting common first, bread is the staff of life, and anyone be unable to do without the plain tea and simple food of one day breakfast, lunch and dinner, but the few go to pay close attention to the cook be in for a long time in oil smoke surroundings is wearing for what footwear.The kitchen in hotel, dining room is general all more disorderly and more unsystematic, and ground has water, washings, oil stain, and cook wears conventional shoe and is easy to slide into, and causes unnecessary injury, and the custom-designed shoes of little promising cook on market.The foot that needs when cook works to stand for a long time is stressed chronic, add the environment of the relative humidity in kitchen, therefore the design of shoes for kitchener is worthy of careful study very much, especially sole, there is intensive anti-skid design (as triangular shape), pollute on interface at washings and must possess good non-skid property, dress softness, comfortable foot feeling, light and handy convenience etc. will be taken into account simultaneously.
Summary of the invention
In order to make up the deficiency of existing patented technology, the object of the present invention is to provide a kind of anti-skidding, comfortable shoes for kitchener sole and preparation method thereof.
For achieving the above object, solution of the present invention is: a kind of shoes for kitchener sole, composition comprises: paracril, brominated butyl rubber, nano silicon, fluidizer, anti-aging agent, white smoke active agent, silane coupling agent, chlorinatedpolyethylene, polyethylene wax, magnesium oxide, zinc oxide, sulphur, vulcanization accelerator, and is expressed as by weight:
Paracril 15 parts
Brominated butyl rubber 50-75 parts
Nano silicon 10-25 parts
Fluidizer 4-10 parts
0.5-2 part, anti-aging agent
White smoke active agent 2-5 parts
Silane coupling agent 1-3 part
Chlorinatedpolyethylene 1-3 part
Polyethylene wax 1-4 part
0.2-1 part, magnesium oxide
1-4 part, zinc oxide
0.5-2 part, sulphur
Vulcanization accelerator 0.5-2 parts
Further: the raw material that described shoes for kitchener sole preferably presses row weight part by following component is prepared from:
Paracril 15 parts
Brominated butyl rubber 65-70 parts
Nano silicon 15-20 parts
Fluidizer 5-7 parts
0.5-1 part, anti-aging agent
White smoke active agent 3 – 3.5 parts
Silane coupling agent 1.5-2 parts
Chlorinatedpolyethylene 2.5-3 parts
Polyethylene wax 2-3 parts
Magnesium oxide 0.2 – 0.6 part
1.5-3 parts, zinc oxide
Sulphur 0.5-1.0 parts
Vulcanization accelerator 0.8-1.5 parts
Wherein, the paracril of described paracril to be acrylonitrile content the be high oil resistant high Mooney viscosity of 41%.
Wherein, described brominated butyl rubber is BIIR 2030 or the BIIR X2 of German Lanxess Corporation.
Wherein, described fluidizer at least comprises the one in dioctyl phthalate (DOP) (DOP), Octyl adipate (DOA), Tributyl O-acetylcitrate (ATBC).
Wherein, described anti-aging agent is 1010; Described white smoke active agent is PEG 4000; Described silane coupling agent is Si-69; Described vulcanization accelerator is MBTS.
A kind of preparation method preparing aforementioned shoes for kitchener sole, all components is weighed according to formula rate, sizing material except zinc oxide, sulphur, vulcanization accelerator is put into Banbury mixer banburying, 120-130 degree binder removal, room temperature places 24 hours, then mixing in two roller mill, and add zinc oxide, sulphur, the vulcanization accelerator of precise, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely obtain oil-proof anti-skid rubber soles.
By adopting aforesaid technical scheme; the invention has the beneficial effects as follows: employing brominated butyl rubber is base rubber, paracril in conjunction with oil resistant; obtain a kind of anti-skidding, comfortable shoes for kitchener sole; the tile floor having water, washings, oil stain has good non-skid property; protection cook not easily slips, and dress is soft, comfortable foot feeling, meets the particular requirement under kitchen environment; contrast prior art, the present invention has following advantage:
1, the present invention selects to have wider vulcanization characteristics, air-tightness is fine, vulcanization rate is fast brominated butyl rubber is main rubber, reduces the hardness of sole, also improve production efficiency while keeping better mechanical property.
2, the sole of the present invention's acquisition, improve comprehensively and pollute ground Static and dynamic on-slip coefficient in analog kitchen, is the shoes for kitchener sole of a excellent performance.
3, the present invention reduces usage quantity, the interpolation environment-friendlyplasticizer plasticizer of mineral filler nano silicon, weakens the stress of polymer molecule interchain, reduces the processing temperature of material, add the snappiness of material simultaneously, improve the comfortableness of sole.
Embodiment
Now the present invention is further described in conjunction with specific embodiments.
Embodiment 1:
In the present embodiment, a kind of shoes for kitchener sole is made up of by weight following component:
Paracril NBR 1,041 15 parts, brominated butyl rubber X2 68 parts, nano silicon 17 parts, fluidizer DOP 7 parts, 1,010 0.8 parts, anti-aging agent, white smoke active agent PEG-4000 3 parts, silane coupling agent Si 69 1.5 parts, chlorinatedpolyethylene 2.5 parts, polyethylene wax 3 parts, 0.4 part, magnesium oxide, 2 parts, zinc oxide, 0.8 part, sulphur, accelerator M BTS 1.2 parts.
Sizing material except zinc oxide, sulphur, vulcanization accelerator is put into Banbury mixer banburying, 115 degree of binder removals, room temperature places 24 hours, then mixing in two roller mill, and add zinc oxide, sulphur, the vulcanization accelerator of precise, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely obtain oil-proof anti-skid rubber soles.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.108 g/cm 3, shore hardness 50, wear-resisting 146 cm of DIN 3, folding 60,000 flawless, tensile strength 11.1 MPa, high oily 0.56 oil of static on-slip coefficient adds water 0.57, dynamic on-slip coefficient S RA heel 0.51 level and smooth 0.59.
Embodiment 2:
In the present embodiment, a kind of preparation method of shoes for kitchener sole is basic identical with the preparation method in embodiment 1, and difference is:
Brominated butyl rubber X2 50 parts, fluidizer DOP 4 parts.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.113 g/cm 3, shore hardness 52, wear-resisting 166 cm of DIN 3, folding 60,000 flawless, tensile strength 10.2 MPa, high oily 0.52 oil of static on-slip coefficient adds water 0.51, dynamic on-slip coefficient S RA heel 0.49 level and smooth 0.52.
Embodiment 3:
In the present embodiment, a kind of preparation method of shoes for kitchener sole is basic identical with the preparation method in embodiment 1, and difference is:
Brominated butyl rubber 2,030 75 parts, fluidizer DOP 5 parts, fluidizer DOA 5 parts; Control at 110 degree of binder removals.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.102 g/cm 3, shore hardness 48, wear-resisting 148 cm of DIN 3, folding 60,000 flawless, tensile strength 10.8 MPa, high oily 0.58 oil of static on-slip coefficient adds water 0.58, dynamic on-slip coefficient S RA heel 0.54 level and smooth 0.60.
Embodiment 4:
In the present embodiment, a kind of preparation method of shoes for kitchener sole is basic identical with the preparation method in embodiment 1, and difference is:
Nano silicon 25 parts, fluidizer ATBC 10 parts, chlorinatedpolyethylene 1 part; Control at 120 degree of binder removals.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.117 g/cm 3, shore hardness 51, wear-resisting 139 cm of DIN 3, folding 60,000 flawless, tensile strength 10.3 MPa, high oily 0.50 oil of static on-slip coefficient adds water 0.51, dynamic on-slip coefficient S RA heel 0.48 level and smooth 0.50.
Embodiment 5:
In the present embodiment, a kind of preparation method of shoes for kitchener sole is basic identical with the preparation method in embodiment 1, and difference is:
Nano silicon 10 parts, fluidizer DOP 5 parts, fluidizer DOA 5 parts.
The above-mentioned a kind of shoes for kitchener sole prepared, density 1.102 g/cm 3, shore hardness 49, wear-resisting 145 cm of DIN 3, folding 60,000 flawless, tensile strength 9.5 MPa, high oily 0.61 oil of static on-slip coefficient adds water 0.61, dynamic on-slip coefficient S RA heel 0.57 level and smooth 0.61.
After the data preparation of above-described embodiment 1 ~ 5, obtain as following table 1(note: shore hardness A tests according to ISO 7619:1997, DIN is wear-resisting to be tested according to TM 174:1994, folding test is tested according to GB/T 15107-2013, tensile strength is tested according to ISO 37:2005, static on-slip coefficient is tested according to F1677:2005, and dynamic on-slip coefficient tests SRA pattern (washings pollution interface) according to ISO 13287:2012):
Embodiment 1 2 3 4 5
Density (g/cm 3) 1.108 1.113 1.102 1.117 1.102
Shore hardness A 50 52 48 51 49
Wear-resisting (the cm of DIN 3) 146 166 148 139 145
Folding 60,000 Flawless Flawless Flawless Flawless Flawless
Tensile strength (MPa) 11.1 10.2 10.8 10.3 9.5
Static on-slip coefficient (high oil) 0.56 0.52 0.58 0.50 0.61
Static on-slip coefficient (high oil adds water) 0.57 0.51 0.58 0.51 0.61
Dynamic on-slip coefficient (heel) 0.51 0.49 0.54 0.48 0.57
Dynamic on-slip coefficient (smoothly) 0.59 0.52 0.60 0.50 0.61
Table 1: the performance perameter synopsis at the bottom of on-slip EVA shoe prepared by embodiment 1 ~ 5.
In sum; according to the preparation method of shoes for kitchener sole of the present invention; a kind of anti-skidding, comfortable shoes for kitchener sole can be obtained; the tile floor having water, washings, oil stain has good non-skid property; protection is not easily fallen down the cook of kitchen work for a long time; and dress is soft, comfortable foot feeling, meets the particular requirement under kitchen environment.And production process is simple, easy suitability for industrialized production.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.

Claims (7)

1. a shoes for kitchener sole, is characterized in that: composition of the present invention comprises: paracril, brominated butyl rubber, nano silicon, fluidizer, anti-aging agent, white smoke active agent, silane coupling agent, chlorinatedpolyethylene, polyethylene wax, magnesium oxide, zinc oxide, sulphur, vulcanization accelerator.
2. shoes for kitchener sole according to claim 1, is characterized in that: each component is expressed as by weight:
Paracril 15 parts
Brominated butyl rubber 50-75 parts
Nano silicon 10-25 parts
Fluidizer 4-10 parts
0.5-2 part, anti-aging agent
White smoke active agent 2-5 parts
Silane coupling agent 1-3 part
Chlorinatedpolyethylene 1-3 part
Polyethylene wax 1-4 part
0.2-1 part, magnesium oxide
1-4 part, zinc oxide
0.5-2 part, sulphur
Vulcanization accelerator 0.5-2 parts.
3. shoes for kitchener sole according to claim 1 and 2, is characterized in that: the parts by weight of each component are:
Paracril 15 parts
Brominated butyl rubber 65-70 parts
Nano silicon 15-20 parts
Fluidizer 5-7 parts
0.5-1 part, anti-aging agent
White smoke active agent 3 – 3.5 parts
Silane coupling agent 1.5-2 parts
Chlorinatedpolyethylene 2.5-3 parts
Polyethylene wax 2-3 parts
0.2-0.6 part, magnesium oxide
1.5-3 parts, zinc oxide
Sulphur 0.5-1.0 parts
Vulcanization accelerator 0.8-1.5 parts.
4. shoes for kitchener sole according to claim 1 and 2, is characterized in that: the paracril of paracril to be acrylonitrile content the be high oil resistant high Mooney viscosity of 41%.
5. shoes for kitchener sole according to claim 1 and 2, is characterized in that: brominated butyl rubber is BIIR 2030 or the BIIR X2 of German Lanxess Corporation.
6. shoes for kitchener sole according to claim 1 and 2, is characterized in that: described fluidizer at least comprises the one in dioctyl phthalate (DOP) (DOP), Octyl adipate (DOA), Tributyl O-acetylcitrate (ATBC).
7. prepare the preparation method of the arbitrary described shoes for kitchener sole of claim 1 to 6 for one kind, it is characterized in that: weigh paracril according to formula rate, epoxidezed rubber, brominated butyl rubber, nano silicon, fluidizer, anti-aging agent, white smoke active agent, silane coupling agent, polyethylene wax, zinc oxide, sulphur, vulcanization accelerator, will except zinc oxide, sulphur, Banbury mixer banburying put into by sizing material beyond vulcanization accelerator, 120-130 degree binder removal, room temperature places 24 hours, then mixing in two roller mill, and add the zinc oxide of precise, sulphur, vulcanization accelerator, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely oil-proof anti-skid rubber soles is obtained.
CN201410387233.1A 2014-08-07 2014-08-07 A kind of shoes for kitchener sole and preparation method thereof Active CN104277344B (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104693564A (en) * 2015-04-01 2015-06-10 中国皮革和制鞋工业研究院 Light damping and slipping preventing rubber and plastic foamed sole material and preparing method thereof
CN105694149A (en) * 2016-04-19 2016-06-22 莆田市协顺鞋业有限公司 Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material
CN105733162A (en) * 2016-04-19 2016-07-06 莆田市协顺鞋业有限公司 Light oil-proof sole material and preparation method thereof
CN106589491A (en) * 2016-11-29 2017-04-26 茂泰(福建)鞋材有限公司 Antiskid rubber outsole and manufacturing method of same
CN107118452A (en) * 2017-06-13 2017-09-01 合肥远科服装设计有限公司 A kind of sole for being applied to run and preparation method thereof
CN107118453A (en) * 2017-06-13 2017-09-01 合肥远科服装设计有限公司 A kind of sole and preparation method thereof
CN107216506A (en) * 2017-06-01 2017-09-29 十堰银森工贸有限公司 A kind of oil resistant synthetic rubber
CN107345010A (en) * 2017-07-29 2017-11-14 合肥梵清电子商务有限公司 One kind energy-conservation sole and preparation method thereof
CN107746514A (en) * 2017-11-21 2018-03-02 王长程 A kind of shoes for kitchener sole and preparation method thereof
CN108384076A (en) * 2018-02-08 2018-08-10 浙江中瑞橡胶高分子材料股份有限公司 A kind of big-sole formula and preparation method thereof with high oil-resisting antistatic high slip preventing function
CN108485086A (en) * 2018-04-11 2018-09-04 东莞市福斯特橡塑科技有限公司 A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl
CN108570189A (en) * 2017-04-11 2018-09-25 李怡嫱 A kind of grease proofing material for sole of shoe and preparation method thereof
CN108997625A (en) * 2018-05-03 2018-12-14 林扬发 A kind of new-type Antiskid rubber and preparation method thereof
CN109851873A (en) * 2019-01-27 2019-06-07 浙江奥康鞋业股份有限公司 A kind of formula and its production technology of grease formula on-slip material
CN109957157A (en) * 2019-04-02 2019-07-02 晋江市鑫铭鞋材科技有限公司 The formula and its technique of a kind of oil ground Anti-skidding rubber sole

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CN101899176A (en) * 2010-08-20 2010-12-01 温州市海滨秀龙鞋材有限公司 Material for sole
CN102871291A (en) * 2012-10-15 2013-01-16 广州市邦尔福鞋材有限公司 Anti-skid sole and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899176A (en) * 2010-08-20 2010-12-01 温州市海滨秀龙鞋材有限公司 Material for sole
CN102871291A (en) * 2012-10-15 2013-01-16 广州市邦尔福鞋材有限公司 Anti-skid sole and preparation method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104693564A (en) * 2015-04-01 2015-06-10 中国皮革和制鞋工业研究院 Light damping and slipping preventing rubber and plastic foamed sole material and preparing method thereof
CN105694149B (en) * 2016-04-19 2018-01-23 莆田市协顺鞋业有限公司 A kind of sole oil resistant low-temperature resistance material and preparation method thereof
CN105694149A (en) * 2016-04-19 2016-06-22 莆田市协顺鞋业有限公司 Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material
CN105733162A (en) * 2016-04-19 2016-07-06 莆田市协顺鞋业有限公司 Light oil-proof sole material and preparation method thereof
CN106589491A (en) * 2016-11-29 2017-04-26 茂泰(福建)鞋材有限公司 Antiskid rubber outsole and manufacturing method of same
CN106589491B (en) * 2016-11-29 2019-02-26 茂泰(福建)鞋材有限公司 A kind of anti-slip rubber outsole and its manufacture craft
CN108570189A (en) * 2017-04-11 2018-09-25 李怡嫱 A kind of grease proofing material for sole of shoe and preparation method thereof
CN107216506A (en) * 2017-06-01 2017-09-29 十堰银森工贸有限公司 A kind of oil resistant synthetic rubber
CN107118453A (en) * 2017-06-13 2017-09-01 合肥远科服装设计有限公司 A kind of sole and preparation method thereof
CN107118452A (en) * 2017-06-13 2017-09-01 合肥远科服装设计有限公司 A kind of sole for being applied to run and preparation method thereof
CN107345010A (en) * 2017-07-29 2017-11-14 合肥梵清电子商务有限公司 One kind energy-conservation sole and preparation method thereof
CN107746514A (en) * 2017-11-21 2018-03-02 王长程 A kind of shoes for kitchener sole and preparation method thereof
CN108384076A (en) * 2018-02-08 2018-08-10 浙江中瑞橡胶高分子材料股份有限公司 A kind of big-sole formula and preparation method thereof with high oil-resisting antistatic high slip preventing function
CN108485086A (en) * 2018-04-11 2018-09-04 东莞市福斯特橡塑科技有限公司 A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl
CN108997625A (en) * 2018-05-03 2018-12-14 林扬发 A kind of new-type Antiskid rubber and preparation method thereof
CN109851873A (en) * 2019-01-27 2019-06-07 浙江奥康鞋业股份有限公司 A kind of formula and its production technology of grease formula on-slip material
CN109851873B (en) * 2019-01-27 2021-04-13 浙江奥康鞋业股份有限公司 Formula and production process of oil-water type anti-slip material
CN109957157A (en) * 2019-04-02 2019-07-02 晋江市鑫铭鞋材科技有限公司 The formula and its technique of a kind of oil ground Anti-skidding rubber sole

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