CN102871291A - Anti-skid sole and preparation method thereof - Google Patents
Anti-skid sole and preparation method thereof Download PDFInfo
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- CN102871291A CN102871291A CN201210390399XA CN201210390399A CN102871291A CN 102871291 A CN102871291 A CN 102871291A CN 201210390399X A CN201210390399X A CN 201210390399XA CN 201210390399 A CN201210390399 A CN 201210390399A CN 102871291 A CN102871291 A CN 102871291A
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Abstract
The invention discloses a sole and a manufacturing method for the sole, and aims to provide a sole with high abrasion resistance and anti-skid property. According to the technical scheme, the sole consists of the following components in part by mass: 45 to 55 parts of nitrile rubber, 18 to 22 parts of brombutyl rubber, 21 to 25 parts of butadiene rubber, 6 to 8 parts of natural rubber, 28 to 32 parts of nano silicon dioxide, 18 to 22 parts of glass fiber, 3.5 to 4.5 parts of nylon fiber, 0.8 to 1.2 parts of polyethylene glycol 4000 (PEG 4000), 1.8 to 2.2 parts of rubber white smoke active agent, 1.4 to 1.6 parts of stearic acid, 3.5 to 4.5 parts of ZnCO3, 0.8 to 1.2 parts of antioxidant, 1.8 to 2.2 parts of coupling agent, 4.5 to 5.5 parts of anti-skid agent, 0.5 part of microcrystalline wax, 1.5 to 2.0 parts of sulfur, and 2.0 to 2.5 parts of vulcanization accelerator. The invention belongs to the technical field of making of shoes.
Description
Technical field
The present invention relates to a kind of sole, specifically, is Antiskid sole, and the present invention also discloses the preparation method of this sole, belongs to the footwear manufacture technology field.
Technical background
Comfortableness and security when the antiskid property of sole directly affects footwear and wears.A lot of countries and regions have been listed the antiskid property of sole in and have been produced and imported and exported one of essential items for inspection of footwear quality testing.The improvement of shoe soles slip stopping can further improve the quality of footwear.Guarantee the security of consumer's dress, be conducive to the status that China breaks through the weight trade barrier continuation maintenance footwear big export country of footwear importer, win the reputation of high-quality footwear exported country.
China is footwear manufacturing and big export country the biggest in the world, footwear output accounts for 53% of world's output aggregate, outlet accounts for more than 60% of problem of world's outlet, and the shoe industry in Guangdong ranks first in the country, the exploitation of on-slip glue material and commercial application, not only filled up the technological gap of China on these series of products, make the footwear material manufacturing of China immediately following the paces in the world, reach international like product advanced level, and will promote the manufacturing quality level of China's footwear material, make the footwear material of China have more international competitiveness.
In the prior art, originally the part sole has under the decorative pattern condition non-skid property good, but sole abrasion is fast, the very fast decline of non-skid property.For ice slip energy and profit non-skid property, prior art can not be brought into play desired high non-skid property.
Summary of the invention
For the problems referred to above, the present invention discloses good sole of a kind of wearability and antiskid property and preparation method thereof.
Last technical scheme of the present invention is: this sole comprises the component of following mass parts: described sole is comprised of the component of following mass parts: nitrile rubber 45-55 part, brombutyl rubber 18-22 part, butadiene rubber 21-25 part, natural rubber 6-8 part, nano silicon 28-32 part, glass fibre 18-22 part, nylon fiber 3.5-4.5 part, PEG4000 0.8-1.2 part, white smoke active agent HC650 1.8-2.2 part, stearic acid 1.4-1.6 part, ZnCO
33.5-4.5 part, antioxidant 0.8-1.2 part, coupling agent 1.8-2.2 part, on-slip agent 4.5-5.5 part, 0.5 part of microwax, sulphur 1.5-2.0 part, vulcanization accelerator 2.0-2.5 part.
Further, above-mentioned a kind of Antiskid sole is characterized in that, described sole is comprised of the component of following mass parts: nitrile rubber 48-52 part, brombutyl rubber 19-20 part, butadiene rubber 22-24 part, natural rubber 6.5-7.5 part, nano silicon 29-31 part, glass fibre 19-21 part, nylon fiber 3.5-4.5 part, 1 part of PEG40000,2 parts of white smoke active agent HC650,1.5 parts of stearic acid ST/A, ZnCO
34 parts, 1 part of antioxidant, 2 parts of coupling agents, 4 parts of on-slip agent, 0.5 part of microwax, 1.8 parts in sulphur, vulcanization accelerator 2.1-2.4 part.
A technical scheme is after of the present invention: the preparation method of the sole of this wearability and antiskid property: according to above-mentioned sole mass parts prescription, prepare various materials, its error range is controlled at ± 0.1 g scope in; The various materials of preparation are mixed incorporation time 8 minutes, 130 ° of C of mixing temperature in banbury; According to different sole thickness demands, mill compressing tablet, cutting machine stamping-out sizing material; The sizing material of stamping-out is vulcanized in mould, and temperature is controlled at 160-170 ° of C, molding time 300-400 second; Sulfuration is finished, and carries out rear operation behind the taking-up sole and processes, and flow process finishes.
Antiskid sole provided by the present invention, prior art is compared, and has following advantage:
1, the present invention by rubber as matrix material, with polar rubber and modified rubber thereof as composite, with inorganic nano material as the enhancement Nano filling, simultaneously by the interface modification technology between fibrous material and the rubber matrix, the direction uniformity that has guaranteed fiber is arranged, and the cross section, and section is to ground plane, greatly strengthen gripping power and skid resistance on the ice and snow face, make prepared sole have good profit wet skid and can and ice the face non-skid property;
2, the brombutyl that adds has good airtight and watertightness, guarantees the wet and slippery property of good waterproof;
3, added coupling agent and on-slip agent, made the rubber can tight polymerization with adding material, the good attraction of adhering to, gripping power has improved the on-slip agent.
Specific embodiments
For the present invention is described better, below the present invention is described in further detail, but do not consist of any limitation of the invention.
Embodiment 1
A kind of sole of the present invention is comprised of the component of following mass parts: 55 parts of nitrile rubbers, 22 parts of brombutyl rubber, 21 parts of butadiene rubbers, 8 parts of natural rubbers, 28 parts of nano silicons, 22 parts in glass fibre, its length 3mm, 3.5 parts of nylon fibers, 1.2 parts of PEG4000,2.2 parts of white smoke active agent HC650,1.6 parts of stearic acid ST/A, ZnCO
34.5 part, 1.2 parts of antioxidant BHTs, 2.2 parts of silane coupling agents, 5.5 parts of on-slip agent, 0.5 part of microwax, 2.0 parts in sulphur, vulcanization accelerator TBBS2.5 part.
Embodiment 2
Another kind of sole of the present invention is comprised of the component of following mass parts: 45 parts of nitrile rubbers, 18 parts of brombutyl rubber, 25 parts of butadiene rubbers, 6 parts of natural rubbers, 32 parts of nano silicons, 18 parts in glass fibre, its length 4mm, 3.5 parts of nylon fibers, 1.2 parts of PEG-4000,1.8 parts of white smoke active agent HC650,1.4 parts of stearic acid ST/A, ZnCO
33.5 part, 0.8 part of antioxidant BHT, 2.2 parts of silane coupling agents, 5.5 parts of on-slip agent, 0.5 part of microwax, 1.5 parts in sulphur, 2.0 parts of vulcanization accelerator TBBS.
Embodiment 3
Of the present invention also have a kind of sole to be comprised of the component of following mass parts: 50 parts of nitrile rubbers, 20 parts of brombutyl rubber, 23 parts of butadiene rubbers, 7 parts of natural rubbers, 30 parts of nano silicons, 20 parts in glass fibre, 4 parts of its length 3.5mm nylon fibers, 1 part of PEG4000,2 parts of white smoke active agent HC650,1.5 parts of stearic acid ST/A, ZnCO
34 parts, 1 part of antioxidant BHT, 2 parts of silane coupling agents, 5 parts of on-slip agent, 0.5 part of microwax, 1.7 parts in sulphur, 2.5 parts of vulcanization accelerator TBBS.
Embodiment 4
Of the present invention also have a kind of sole to be comprised of the component of following mass parts: 49 parts of nitrile rubbers, 20 parts of brombutyl rubber, 23 parts of butadiene rubbers, 7 parts of natural rubbers, 30 parts of nano silicons, 20 parts in glass fibre, 4 parts of its length 4mm nylon fibers, 1 part of PEG4000,2 parts of white smoke active agent HC650,1.5 parts of stearic acid ST/A, ZnCO
34 parts, 1 part of antioxidant BHT, 2 parts of silane coupling agents, 4 parts of on-slip agent, 0.5 part of microwax, 1.8 parts in sulphur, 2.1 parts of vulcanization accelerator TBBS.
Performance validation tests
By the Antiskid sole of above preparation method gained, carry out performance validation tests.
Test condition: load 400N; Test environment: 20 ℃, 65 ° ± 5 ° % of relative humidity, ice-patch surface: 0 ℃
Method of testing 1:SATRA PM144:1999
Test result: confficient of static friction 0.42; The coefficient of kinetic friction 0.11;
Method of testing 2:ASTM-F609
Test result: do wet anti-skid factor 1.22; Wet type anti-skid factor 0.85.
Method of testing 3:ISO4649
Test result: DIN85mm3;
Method of testing 4:ASTM D471; Test result: 8.5%.
Result of the test shows, Antiskid sole of the present invention, and every test data obviously is better than international physical property measurement standard.
(1) SATRA pm144 testing standard: Jing Mo wipes Xi Shuo＞=0.1; Dynamic friction Xi Shuo＞=0.05;
(2) ASTM-F609 testing standard: dry type ﹥ 0.8; Wet type ﹥ 0.4;
(3) ISO4649 testing standard: DIN＜=250mm
3
(4) ASTM D471 testing standard:＜=15%.
Claims (7)
1. an Antiskid sole is characterized in that, described sole is comprised of the component of following mass parts: nitrile rubber 45-55 part, brombutyl rubber 18-22 part, butadiene rubber 21-25 part, natural rubber 6-8 part, nano silicon 28-32 part, glass fibre 18-22 part, nylon fiber 3.5-4.5 part, PEG4000 0.8-1.2 part, rubber white smoke active agent 1.8-2.2 part, stearic acid 1.4-1.6 part, ZnCO
33.5-4.5 part, antioxidant 0.8-1.2 part, coupling agent 1.8-2.2 part, on-slip agent 4.5-5.5 part, 0.5 part of microwax, sulphur 1.5-2.0 part, vulcanization accelerator 2.0-2.5 part.
2. a kind of Antiskid sole according to claim 1 is characterized in that, described sole is comprised of the component of following mass parts: nitrile rubber 48-52 part, brombutyl rubber 19-20 part, butadiene rubber 22-24 part, natural rubber 6.5-7.5 part, nano silicon 29-31 part, glass fibre 19-21 part, nylon fiber 3.5-4.5 part, 1 part of PEG4000,2 parts of white smoke active agent HC650,1.5 parts of stearic acid ST/A, ZnCO
34 parts, 1 part of antioxidant, 2 parts of coupling agents, 4 parts of on-slip agent, 0.5 part of microwax, 1.8 parts in sulphur, vulcanization accelerator 2.1-2.4 part.
3. a kind of Antiskid sole according to claim 1 is characterized in that, described antioxidant is antioxidant BHT.
4. a kind of Antiskid sole according to claim 1 is characterized in that, described coupling agent is silane coupling agent.
5. a kind of Antiskid sole according to claim 1 is characterized in that, described vulcanization accelerator is TBBS.
6. a kind of Antiskid sole according to claim 1 is characterized in that, the length of described glass fibre is 3-4mm.
7. the preparation method of Antiskid sole claimed in claim 1 is: according to above-mentioned sole mass parts prescription, prepare various materials, its error range is controlled at ± 0.1 g scope in; The various materials of preparation are mixed incorporation time 8 minutes, 130 ° of C of mixing temperature in banbury; According to different sole thickness demands, mill compressing tablet, cutting machine stamping-out sizing material; The sizing material of stamping-out is vulcanized in mould, and temperature is controlled at 160-170 ° of C, molding time 300-400 second; Sulfuration is finished, and carries out rear operation behind the taking-up sole and processes, and flow process finishes.
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| CN201210390399.XA CN102871291B (en) | 2012-10-15 | 2012-10-15 | Anti-skid sole and preparation method thereof |
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| CN103589016A (en) * | 2013-10-18 | 2014-02-19 | 青岛科技大学 | Composite material for anti-slip soles and preparation method of composite material |
| CN103589000A (en) * | 2013-10-18 | 2014-02-19 | 青岛科技大学 | High-elasticity damping wear-resistant antiskid shoe sole composite material and preparation method thereof |
| CN103772763A (en) * | 2013-12-25 | 2014-05-07 | 泉州鑫泰鞋材有限公司 | Rubber composite and preparation process thereof |
| CN104004235A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN104004237A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
| CN104277409A (en) * | 2014-09-27 | 2015-01-14 | 赵东奇 | Puncture-resistant material and preparation method thereof |
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104479177A (en) * | 2014-11-28 | 2015-04-01 | 刘中华 | Fishing shoe rubber, anti-skid fishing shoes and preparation method of fishing shoe rubber |
| CN105086422A (en) * | 2015-08-31 | 2015-11-25 | 贵州省材料产业技术研究院 | Long glass fiber reinforced TPU non-slip soles and preparation method thereof |
| CN105694149A (en) * | 2016-04-19 | 2016-06-22 | 莆田市协顺鞋业有限公司 | Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material |
| CN105733162A (en) * | 2016-04-19 | 2016-07-06 | 莆田市协顺鞋业有限公司 | Light oil-proof sole material and preparation method thereof |
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN105968686A (en) * | 2016-07-06 | 2016-09-28 | 江文宏 | Ice surface and greasy ground antiskid rubber plastic synthetic material and preparation method thereof |
| CN104744736B (en) * | 2013-12-26 | 2016-12-07 | 青岛蓝农谷农产品研究开发有限公司 | Material for sole of shoe and preparation method thereof |
| CN107033474A (en) * | 2017-05-23 | 2017-08-11 | 林玉萍 | A kind of preparation method of rubber soles |
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| CN103588999A (en) * | 2013-10-18 | 2014-02-19 | 青岛科技大学 | Wear-resistant sole composite material and preparation method thereof |
| CN103589016A (en) * | 2013-10-18 | 2014-02-19 | 青岛科技大学 | Composite material for anti-slip soles and preparation method of composite material |
| CN103589000A (en) * | 2013-10-18 | 2014-02-19 | 青岛科技大学 | High-elasticity damping wear-resistant antiskid shoe sole composite material and preparation method thereof |
| CN103588999B (en) * | 2013-10-18 | 2016-01-20 | 青岛科技大学 | A kind of Wear-resistant sole composite material and preparation method thereof |
| CN103589016B (en) * | 2013-10-18 | 2016-05-11 | 青岛科技大学 | A kind of Antiskid sole composite and preparation method thereof |
| CN103589000B (en) * | 2013-10-18 | 2015-10-21 | 青岛科技大学 | A kind of high-elastic damping, wear-resisting antiskid shoe sole composite material and preparation method thereof |
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| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
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| CN105694149B (en) * | 2016-04-19 | 2018-01-23 | 莆田市协顺鞋业有限公司 | A kind of sole oil resistant low-temperature resistance material and preparation method thereof |
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN105968686A (en) * | 2016-07-06 | 2016-09-28 | 江文宏 | Ice surface and greasy ground antiskid rubber plastic synthetic material and preparation method thereof |
| CN107033474A (en) * | 2017-05-23 | 2017-08-11 | 林玉萍 | A kind of preparation method of rubber soles |
| CN107099066A (en) * | 2017-06-14 | 2017-08-29 | 合肥博创机械制造有限公司 | A kind of athletic shoe sole and preparation method thereof |
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| CN109942919A (en) * | 2019-04-02 | 2019-06-28 | 晋江市鑫铭鞋材科技有限公司 | A kind of ice face Anti-skidding rubber sole formula and its manufacture craft |
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| CN112375268A (en) * | 2020-09-09 | 2021-02-19 | 福建省华昂体育用品有限公司 | Anti-slip sole and preparation method thereof |
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