CN107216506A - A kind of oil resistant synthetic rubber - Google Patents
A kind of oil resistant synthetic rubber Download PDFInfo
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- CN107216506A CN107216506A CN201710401882.6A CN201710401882A CN107216506A CN 107216506 A CN107216506 A CN 107216506A CN 201710401882 A CN201710401882 A CN 201710401882A CN 107216506 A CN107216506 A CN 107216506A
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- synthetic rubber
- oil resistant
- resistant synthetic
- rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of oil resistant synthetic rubber, in parts by mass, including following material:32 40 parts of haloflex, 52 60 parts of nitrile rubber, 8 parts of brombutyl, 8 parts of magnesia, 10 parts of white carbon, 23 parts of 01 reinforcing agents of XJ, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks, 25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester, 6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, 2.3 parts of age resistor, 0.4 part of cTp antiscorching agent, modified 7.5 parts of coumarone resin, 1.9 parts of accelerator, 3.1 parts of sulphur.The oil resistant synthetic rubber of the present invention is made by conventional mixing, the characteristics of with high temperature resistant, oil resistivity, resistance to ozone, good air-tightness, and its compatibility, pliability, flexible resistance energy and oil resistance reach professional standard, and meeting production needs and user's needs.
Description
Technical field
The present invention relates to a kind of synthetic rubber, more particularly to a kind of oil resistant synthetic rubber.
Background technology
Rubber is divided into two kinds of natural rubber and synthetic rubber, for the characteristic of cost-effective raising rubber, in 20 generation
Record just starts produce synthetic rubber, developed rapidly after the forties, because its have high resiliency, insulating properties, air-tightness, oil resistant,
The performance such as high temperature resistant or low temperature, is widely used in industrial or agricultural, national defence, traffic and daily life.
The content of the invention
The present invention provides a kind of oil resistant synthetic rubber, and synthetic rubber has compatibility, pliability, flexible resistance energy, oil resistant
Professional standard can be reached with ageing-resistant performance.
To reach above-mentioned purpose, realized by following scheme：A kind of oil resistant synthetic rubber, it is characterised in that：Oil resistant is synthesized
Rubber is by mass parts：32-40 parts of haloflex, 52-60 parts of nitrile rubber, 8 parts of brombutyl, 8 parts of magnesia, in vain
10 parts of carbon black, 23 parts of XJ-01 reinforcing agents, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks, 25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester, oxidation
6 parts of zinc, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, 2.3 parts of age resistor, 0.4 part of cTp antiscorching agent is modified ancient
7.5 parts of the grand resin of horse, 1.9 parts of accelerator, 3.1 parts of sulphur.
It is preferred that, it is by mass parts：32 parts of haloflex, 60 parts of nitrile rubber, 8 parts of brombutyl, magnesia 8
Part, 10 parts of white carbon, 23 parts of XJ-01 reinforcing agents, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks, 25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester,
6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, 2.3 parts of age resistor, 0.4 part of cTp antiscorching agent changes
7.5 parts of property coumarone resin, 1.9 parts of accelerator, 3.1 parts of sulphur.
It is preferred that, it is by mass parts：40 parts of haloflex, 52 parts of nitrile rubber, 8 parts of brombutyl, magnesia 8
Part, 10 parts of white carbon, 23 parts of XJ-01 reinforcing agents, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks, 25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester,
6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, 2.3 parts of age resistor, 0.4 part of cTp antiscorching agent is modified
7.5 parts of coumarone resin, 1.9 parts of accelerator, 3.1 parts of sulphur.
The haloflex is haloflex 135A.
The nitrile rubber is nitrile rubber 3305.
The brombutyl is brombutyl 2039.
The age resistor is anti-aging agent RD, either antioxidant 4010NA or the combination of the two；Wherein：What the two was combined
Match as 1.1 parts of RD age resistor, 1.2 parts of 4010NA age resistor.
The accelerator is the combination of altax, either accelerant CZ or NA-22 vulcanization accelerators, or three；
Wherein：The proportioning of triplicity is 0.7 part of DM accelerator, 0.5 part of CZ accelerator, 0.7 part of NA-22 vulcanization accelerators.
The oil resistant synthetic rubber, is made by conventional compounding process.
Beneficial effect：
The oil resistant synthetic rubber of the present invention is kneaded by conventional method and is made, with high temperature resistant, oil resistivity, resistance to ozone, air-tightness
Good the characteristics of, compared with prior art oil resistant rubber, primary raw material is changed, by haloflex CPE, nitrile rubber
NBR, tri- kinds of primary raw materials of brombutyl BIIR composition, the synthetic rubber compatibility being made, pliability, flexible resistance energy,
Oil resistant and ageing-resistant performance can reach professional standard, and meeting production needs and user's needs, therefore, makees under oiliness environment
Oil-resisting rubber hose is used.
Embodiment
Embodiment 1:
A kind of oil resistant synthetic rubber, in parts by mass, including following components:32 parts of haloflex, 60 parts of nitrile rubber, bromination
8 parts of butyl rubber, 8 parts of magnesia, 10 parts of white carbon, 23 parts of XJ-01 reinforcing agents, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks,
25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester, 6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, age resistor 2.3
Part, 0.4 part of cTp antiscorching agent, modified 7.5 parts of coumarone resin, 1.9 parts of accelerator, 3.1 parts of sulphur.
This kind of oil resistant synthetic rubber, routinely mixing is produced.
This kind of oil resistant synthetic rubber, oil resistance is good.
This kind of oil resistant synthetic rubber performance such as following table:
。
Embodiment 2:
A kind of oil resistant synthetic rubber, in parts by mass, including following components:40 parts of haloflex, 52 parts of nitrile rubber, bromination
8 parts of butyl rubber, 8 parts of magnesia, 10 parts of white carbon, 23 parts of XJ-01 reinforcing agents, 60 parts of N550 carbon blacks, 40 parts of N660 carbon blacks,
25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester, 6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin, 3.2 parts of barium stearate, age resistor 2.3
Part, 0.4 part of cTp antiscorching agent, modified 7.5 parts of coumarone resin, 1.9 parts of accelerator, 3.1 parts of sulphur.
This kind of oil resistant synthetic rubber, routinely mixing is produced.
This kind of oil resistant synthetic rubber, oil resistance is good.
This kind of oil resistant synthetic rubber performance such as following table:
。
Invention can be further appreciated that by the embodiment of the present invention given above, above example is only the several of the present invention
Specific embodiment, but the present invention design be not limited thereto, it is all using this design to the present invention progress unsubstantiality change,
The behavior for invading the scope of the present invention all should be belonged to.
Claims (8)
1. a kind of oil resistant synthetic rubber, it is characterised in that in parts by mass, including following components：32-40 parts of haloflex,
52-60 parts of nitrile rubber, 8 parts of brombutyl, 8 parts of magnesia, 10 parts of white carbon, 23 parts of XJ-01 reinforcing agents, N550 charcoals
Black 60 parts, 40 parts of N660 carbon blacks, 25 parts of fine particle calcium carbonate, 40 parts of dioctyl ester, 6 parts of zinc oxide, 1,801 3 parts of stearic acid, 1 part of paraffin is stearic
Sour 3.2 parts of barium, 2.3 parts of age resistor, 0.4 part of cTp antiscorching agent, modified 7.5 parts of coumarone resin, 1.9 parts of accelerator, sulphur 3.1
Part；Oil resistant synthetic rubber is made by conventional mixing in above-mentioned formula.
2. oil resistant synthetic rubber according to claim 1, it is characterised in that in parts by mass, including following components：Chlorination
32 parts of polyethylene, 60 parts of nitrile rubber.
3. oil resistant synthetic rubber according to claim 1, it is characterised in that in parts by mass, including following components：Chlorination
40 parts of polyethylene, 52 parts of nitrile rubber.
4. according to any described oil resistant synthetic rubber of claims 1 to 3, it is characterised in that the haloflex is chlorination
Polyethylene 135A.
5. according to any described oil resistant synthetic rubber of claims 1 to 3, it is characterised in that the nitrile rubber is butyronitrile rubber
Glue 3305.
6. oil resistant synthetic rubber according to claim 1, it is characterised in that the brombutyl is butyl rubber bromide
Glue 2039.
7. oil resistant synthetic rubber according to claim 1, it is characterised in that the age resistor is anti-aging agent RD or anti-
Old agent 4010NA or the combination of the two；Wherein the two proportioning combined is 1.1 parts of RD age resistor, 1.2 parts of 4010NA age resistor.
8. oil resistant synthetic rubber according to claim 1, it is characterised in that the accelerator is altax, or is promoted
Enter agent CZ, either the combination of NA-22 vulcanization accelerators or three；Wherein the proportioning of triplicity is 0.7 part of DM accelerator,
0.5 part of CZ accelerator, 0.7 part of NA-22 vulcanization accelerators.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710401882.6A CN107216506A (en) | 2017-06-01 | 2017-06-01 | A kind of oil resistant synthetic rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710401882.6A CN107216506A (en) | 2017-06-01 | 2017-06-01 | A kind of oil resistant synthetic rubber |
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| Publication Number | Publication Date |
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| CN107216506A true CN107216506A (en) | 2017-09-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710401882.6A Pending CN107216506A (en) | 2017-06-01 | 2017-06-01 | A kind of oil resistant synthetic rubber |
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| CN (1) | CN107216506A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117088A (en) * | 2019-12-31 | 2020-05-08 | 芜湖融汇化工有限公司 | Chlorinated polyethylene regenerated rubber |
Citations (6)
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|---|---|---|---|---|
| CN103540042A (en) * | 2012-07-12 | 2014-01-29 | 上海起帆电线电缆有限公司 | Rubber composition for travelling crane cable sheath |
| CN103951857A (en) * | 2014-04-02 | 2014-07-30 | 山东美晨科技股份有限公司 | NBR/PVC preparation raw material with excellent performance |
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
| CN104788760A (en) * | 2015-04-21 | 2015-07-22 | 无锡宝通带业股份有限公司 | Cover rubber simultaneously using chemigum and chlorinated polyethylene for oil-proof flame-retardant conveyer belt |
| CN105694149A (en) * | 2016-04-19 | 2016-06-22 | 莆田市协顺鞋业有限公司 | Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material |
| CN105860169A (en) * | 2016-04-29 | 2016-08-17 | 安徽华宇电缆集团有限公司 | High-flame-retardant cable special for oil platform |
-
2017
- 2017-06-01 CN CN201710401882.6A patent/CN107216506A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540042A (en) * | 2012-07-12 | 2014-01-29 | 上海起帆电线电缆有限公司 | Rubber composition for travelling crane cable sheath |
| CN103951857A (en) * | 2014-04-02 | 2014-07-30 | 山东美晨科技股份有限公司 | NBR/PVC preparation raw material with excellent performance |
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
| CN104788760A (en) * | 2015-04-21 | 2015-07-22 | 无锡宝通带业股份有限公司 | Cover rubber simultaneously using chemigum and chlorinated polyethylene for oil-proof flame-retardant conveyer belt |
| CN105694149A (en) * | 2016-04-19 | 2016-06-22 | 莆田市协顺鞋业有限公司 | Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material |
| CN105860169A (en) * | 2016-04-29 | 2016-08-17 | 安徽华宇电缆集团有限公司 | High-flame-retardant cable special for oil platform |
Non-Patent Citations (1)
| Title |
|---|
| 阮桂海编: "《丁基橡胶应用工艺》", 31 July 1980 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117088A (en) * | 2019-12-31 | 2020-05-08 | 芜湖融汇化工有限公司 | Chlorinated polyethylene regenerated rubber |
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