CN107118452A - A kind of sole for being applied to run and preparation method thereof - Google Patents
A kind of sole for being applied to run and preparation method thereof Download PDFInfo
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- CN107118452A CN107118452A CN201710441280.3A CN201710441280A CN107118452A CN 107118452 A CN107118452 A CN 107118452A CN 201710441280 A CN201710441280 A CN 201710441280A CN 107118452 A CN107118452 A CN 107118452A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention provides a kind of sole for being applied to run and preparation method thereof, is related to sole technical field, it is adaptable to which the sole of running includes the raw material of following parts by weight：15 19 parts of nitrile rubber, 50 60 parts of brombutyl, 10 20 parts of nano silicon, 15 parts of haloflex, 13 parts of Tissuemat E, 0.2 0.8 parts of magnesia, 14 parts of nano zine oxide, 0.6 1.4 parts of sulphur, 6 18 parts of quartz glass fibre, 6 10 parts of vinylon, 9 15 parts of boron fibre, 7 13 parts of Fypro, 0.6 1.6 parts of vulcanization accelerator, 48 parts of plasticiser, 0.6 1.8 parts of antioxidant, 24 parts of white smoke active agent, 12 parts of coupling agent, 0.5 0.9 parts of softening agent, 0.2 0.8 parts of 0.2 0.4 parts of light stabilizer and heat stabilizer.Preparation method comprises the following steps：（1）Weigh raw material,（2）Addition banbury,（3）Addition two-roll mill,（4）Sulfidization molding.The problem of present invention has these performances of high anti-skidding, compression strength, rupture strength, good toughness and light weight when solving still different in existing sole.
Description
Technical field
The invention belongs to sole technical field, and in particular to a kind of sole for being applied to run and preparation method thereof.
Background technology
With the economic development and improvement of people's living standards, health is increasingly paid attention to, wherein motion is exactly to obtain
The important way of health, protection instrument when sport footwear is moved as people often occurs footwear after a bit of time is worn
The phenomenon of sole fracture.Sole, as the important component of footwear, is the most direct position that footwear are contacted with ground, tough for its
The quality of property concerns the quality of whole footwear.
This outsole must also be provided simultaneously with other performances in addition to this good basic performance of skid resistance, for example：Pressure resistance
Degree height and light weight.
But have when still different in existing sole high anti-skidding, compression strength, High anti bending strength, good toughness and light weight these
Performance.
The content of the invention
In order to which there is high anti-skidding, compression strength, High anti bending strength, good toughness and matter when solving still different in existing sole
It is the problem of these light performances, obtained suitable it is an object of the invention to provide a kind of sole for being applied to run and preparation method thereof
Sole for running has the advantages that high anti-skidding, compression strength, High anti bending strength, good toughness and light weight.
The invention provides following technical scheme：
A kind of sole for being applied to run, includes the raw material of following parts by weight：15-19 parts of nitrile rubber, brombutyl 50-
60 parts, 10-20 parts of nano silicon, 1-5 parts of haloflex, 1-3 parts of Tissuemat E, 0.2-0.8 parts of magnesia, nano oxygen
Change 1-4 parts of zinc, 0.6-1.4 parts of sulphur, 6-18 parts of quartz glass fibre, 6-10 parts of vinylon, boron fibre 9-
15 parts, 7-13 parts of Fypro, 0.6-1.6 parts of vulcanization accelerator, 4-8 parts of plasticiser, 0.6-1.8 parts of antioxidant, white cigarette
0.2-0.8 parts of 2-4 parts of activating agent, 1-2 parts of coupling agent, 0.5-0.9 parts of softening agent, 0.2-0.4 parts of light stabilizer and heat stabilizer.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
With the addition of vinylon in raw material, vinylon have high intensity, good toughness and
The characteristics of acid and alkali-resistance.
With the addition of boron fibre in raw material, boron fibre have high temperature resistant, light weight and it is elastic good the characteristics of.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Preferably, the raw material of following parts by weight is included：17 parts of nitrile rubber, 55 parts of brombutyl, nanometer titanium dioxide
15 parts of silicon, 3 parts of haloflex, 2 parts of Tissuemat E, 0.5 part of magnesia, 2.5 parts of nano zine oxide, 1 part of sulphur, quartz glass
12 parts of fiber, 8 parts of vinylon, 12 parts of boron fibre, 10 parts of Fypro, 1.1 parts of vulcanization accelerator, plasticising
6 parts of agent, 1.2 parts of antioxidant, 3 parts of white smoke active agent, 1.5 parts of coupling agent, 0.7 part of softening agent, 0.3 part of light stabilizer and heat are steady
Determine 0.5 part of agent.
Preferably, the vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time,
Curing temperature is reduced, vulcanizing agent consumption is reduced and improves the physical and mechanical properties of rubber, also with age inhibiting effect；Certain 2-
Thiol benzothiazole is intended only as the optimal selection of vulcanization accelerator herein, and other vulcanization accelerators can still be selected
With.
Preferably, the softening agent is fatty oils softening agent, and softening agent is used to improve the processing characteristics of sole and used
Performance, improves the plasticity of micelle, reduces temperature when viscosity and the mixing of micelle, improves the tensile strength and wearability of sole；
Certain fatty oils softening agent is intended only as the optimal selection of softening agent herein, and other softening agents can still be selected.
Preferably, the plasticizer is fatty acid butyl ester, it is possible to increase suitable for the toughness of the sole of running, be easy to be applicable
Processed in the sole of running；Certain fatty acid butyl ester is intended only as the optimal selection of plasticizer herein, other plasticizer according to
It can so select.
Preferably, the coupling agent is silane coupler, can promote the bonding between raw material, improves the rheology of composite
Property；Certain silane coupler is intended only as the optimal selection of coupling agent herein, and other coupling agents can still be selected.
Preferably, the light stabilizer is carbon black, can cover or reflect the material of ultraviolet, prevent light from penetrating sole
It is internal；Certain carbon black is intended only as the optimal selection of light stabilizer herein, and other light stabilizers can still be selected.
Preferably, the heat stabilizer is barium stearate, improves the heat endurance of the sole suitable for running；Certainly it is stearic
Sour barium is intended only as the optimal selection of heat stabilizer herein, and other heat stabilizers can still be selected.
A kind of preparation method for the sole for being applied to run, comprises the following steps：
（1）Parts by weight according to the sole raw material suitable for running weigh raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 125-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
The beneficial effects of the invention are as follows：
1st, have when the present invention solves in existing sole still different high anti-skidding, compression strength, High anti bending strength, good toughness and
The problem of these performances of light weight.
2nd, quartz glass fibre is with the addition of in raw material of the invention, quartz glass fibre has intensity height, high temperature resistant, corrosion resistant
Erosion, heat-insulated and chemical stability are good.
3rd, vinylon is with the addition of in raw material of the invention, vinylon has intensity
The characteristics of high, good toughness and acid and alkali-resistance.
4th, with the addition of boron fibre in raw material of the invention, boron fibre have high temperature resistant, light weight and it is elastic good the characteristics of.
5th, with the addition of Fypro in raw material of the invention, Fypro have nontoxic, light weight, high mechanical strength,
The characteristics of wearability is good and elastic good.
6th, heretofore described vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, when shortening vulcanization
Between, curing temperature is reduced, vulcanizing agent consumption is reduced and improves the physical and mechanical properties of rubber, also with age inhibiting effect；When
Right 2- thiol benzothiazoles are intended only as the optimal selection of vulcanization accelerator herein, and other vulcanization accelerators still can be with
From.
7th, heretofore described softening agent is fatty oils softening agent, and softening agent is used to improve the processing characteristics of sole and made
With performance, the plasticity of micelle is improved, temperature when viscosity and the mixing of micelle is reduced, the tensile strength of sole is improved and wear-resisting
Property；Certain fatty oils softening agent is intended only as the optimal selection of softening agent herein, and other softening agents can still be selected.
8th, heretofore described plasticizer is fatty acid butyl ester, it is possible to increase suitable for the toughness of the sole of running, be easy to
Suitable for the sole processing of running；Certain fatty acid butyl ester is intended only as the optimal selection of plasticizer, others plasticising herein
Agent can still be selected.
9th, heretofore described coupling agent is silane coupler, can promote the bonding between raw material, improves composite
Rheological characteristic；Certain silane coupler is intended only as the optimal selection of coupling agent herein, and other coupling agents can still be selected.
10th, heretofore described light stabilizer is carbon black, can cover or reflect the material of ultraviolet, prevent light from penetrating
Inside sole；Certain carbon black is intended only as the optimal selection of light stabilizer herein, and other light stabilizers can still be selected.
11st, heretofore described heat stabilizer is barium stearate, improves the heat endurance of the sole suitable for running；Certainly
Barium stearate is intended only as the optimal selection of heat stabilizer herein, and other heat stabilizers can still be selected.
Embodiment
Embodiment 1
A kind of sole for being applied to run, includes the raw material of following parts by weight：17 parts of nitrile rubber, 55 parts of brombutyl,
15 parts of nano silicon, 3 parts of haloflex, 2 parts of Tissuemat E, 0.5 part of magnesia, 2.5 parts of nano zine oxide, sulphur 1
Part, 12 parts of quartz glass fibre, 8 parts of vinylon, 12 parts of boron fibre, 10 parts of Fypro, vulcanization promote
1.1 parts of agent, 6 parts of plasticizer, 1.2 parts of antioxidant, 3 parts of white smoke active agent, 1.5 parts of coupling agent, 0.7 part of softening agent, light are stable
0.5 part of 0.3 part of agent and heat stabilizer.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
With the addition of vinylon in raw material, vinylon have high intensity, good toughness and
The characteristics of acid and alkali-resistance.
With the addition of boron fibre in raw material, boron fibre have high temperature resistant, light weight and it is elastic good the characteristics of.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect；Certain 2- mercaptos benzene a pair of horses going side by side
Thiazole is intended only as the optimal selection of vulcanization accelerator herein, and other vulcanization accelerators can still be selected.
Softening agent is fatty oils softening agent, and softening agent is used to improve the processing characteristics and performance of sole, improves glue
The plasticity of grain, reduces temperature when viscosity and the mixing of micelle, improves the tensile strength and wearability of sole；Certain fatty oils
Softening agent is intended only as the optimal selection of softening agent herein, and other softening agents can still be selected.
Plasticizer is fatty acid butyl ester, it is possible to increase suitable for the toughness of the sole of running, be easy to the footwear suitable for running
Bottom is processed；Certain fatty acid butyl ester is intended only as the optimal selection of plasticizer herein, and other plasticizer can still be selected.
Coupling agent is silane coupler, can promote the bonding between raw material, improves the rheological characteristic of composite；Certain silane
Coupling agent is intended only as the optimal selection of coupling agent herein, and other coupling agents can still be selected.
Light stabilizer is carbon black, can cover or reflect the material of ultraviolet, prevents light from penetrating inside sole；Certain carbon
The black optimal selection for being intended only as light stabilizer herein, other light stabilizers can still be selected.
Heat stabilizer is barium stearate, improves the heat endurance of the sole suitable for running；Certain barium stearate is herein
The optimal selection of heat stabilizer is intended only as, other heat stabilizers can still be selected.
A kind of preparation method for the sole for being applied to run, comprises the following steps：
（1）Parts by weight according to the sole raw material suitable for running weigh raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 125-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Embodiment 2
A kind of sole for being applied to run, includes the raw material of following parts by weight：15 parts of nitrile rubber, 50 parts of brombutyl,
10 parts of nano silicon, 1 part of haloflex, 1 part of Tissuemat E, 0.2 part of magnesia, 1 part of nano zine oxide, sulphur 0.6
Part, 6 parts of quartz glass fibre, 6 parts of vinylon, 9 parts of boron fibre, 7 parts of Fypro, vulcanization accelerator
0.6 part, 4 parts of plasticiser, 0.6 part of antioxidant, 2 parts of white smoke active agent, 1 part of coupling agent, 0.5 part of softening agent, light stabilizer 0.2
0.2 part of part and heat stabilizer.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
With the addition of vinylon in raw material, vinylon have high intensity, good toughness and
The characteristics of acid and alkali-resistance.
With the addition of boron fibre in raw material, boron fibre have high temperature resistant, light weight and it is elastic good the characteristics of.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect；Certain 2- mercaptos benzene a pair of horses going side by side
Thiazole is intended only as the optimal selection of vulcanization accelerator herein, and other vulcanization accelerators can still be selected.
Softening agent is fatty oils softening agent, and softening agent is used to improve the processing characteristics and performance of sole, improves glue
The plasticity of grain, reduces temperature when viscosity and the mixing of micelle, improves the tensile strength and wearability of sole；Certain fatty oils
Softening agent is intended only as the optimal selection of softening agent herein, and other softening agents can still be selected.
Plasticizer is fatty acid butyl ester, it is possible to increase suitable for the toughness of the sole of running, be easy to the footwear suitable for running
Bottom is processed；Certain fatty acid butyl ester is intended only as the optimal selection of plasticizer herein, and other plasticizer can still be selected.
Coupling agent is silane coupler, can promote the bonding between raw material, improves the rheological characteristic of composite；Certain silane
Coupling agent is intended only as the optimal selection of coupling agent herein, and other coupling agents can still be selected.
Light stabilizer is carbon black, can cover or reflect the material of ultraviolet, prevents light from penetrating inside sole；Certain carbon
The black optimal selection for being intended only as light stabilizer herein, other light stabilizers can still be selected.
Heat stabilizer is barium stearate, improves the heat endurance of the sole suitable for running；Certain barium stearate is herein
The optimal selection of heat stabilizer is intended only as, other heat stabilizers can still be selected.
A kind of preparation method for the sole for being applied to run, comprises the following steps：
（1）Parts by weight according to the sole raw material suitable for running weigh raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 125-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Embodiment 3
A kind of sole for being applied to run, includes the raw material of following parts by weight：19 parts of nitrile rubber, 60 parts of brombutyl,
20 parts of nano silicon, 5 parts of haloflex, 3 parts of Tissuemat E, 0.8 part of magnesia, 4 parts of nano zine oxide, sulphur 1.4
Part, 18 parts of quartz glass fibre, 10 parts of vinylon, 15 parts of boron fibre, 13 parts of Fypro, vulcanization promote
1.6 parts of agent, 8 parts of plasticiser, 1.8 parts of antioxidant, 4 parts of white smoke active agent, 2 parts of coupling agent, 0.9 part of softening agent, light stabilizer
0.4 part and 0.8 part of heat stabilizer.
With the addition of quartz glass fibre in raw material, quartz glass fibre have intensity height, high temperature resistant, it is corrosion-resistant, heat-insulated and
Chemical stability is good.
With the addition of vinylon in raw material, vinylon have high intensity, good toughness and
The characteristics of acid and alkali-resistance.
With the addition of boron fibre in raw material, boron fibre have high temperature resistant, light weight and it is elastic good the characteristics of.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Vulcanization accelerator is 2- thiol benzothiazoles, can promote sulfurization, shortens cure time, reduction vulcanization temperature
Degree, reduces vulcanizing agent consumption and improves the physical and mechanical properties of rubber, also with age inhibiting effect；Certain 2- mercaptos benzene a pair of horses going side by side
Thiazole is intended only as the optimal selection of vulcanization accelerator herein, and other vulcanization accelerators can still be selected.
Softening agent is fatty oils softening agent, and softening agent is used to improve the processing characteristics and performance of sole, improves glue
The plasticity of grain, reduces temperature when viscosity and the mixing of micelle, improves the tensile strength and wearability of sole；Certain fatty oils
Softening agent is intended only as the optimal selection of softening agent herein, and other softening agents can still be selected.
Plasticizer is fatty acid butyl ester, it is possible to increase suitable for the toughness of the sole of running, be easy to the footwear suitable for running
Bottom is processed；Certain fatty acid butyl ester is intended only as the optimal selection of plasticizer herein, and other plasticizer can still be selected.
Coupling agent is silane coupler, can promote the bonding between raw material, improves the rheological characteristic of composite；Certain silane
Coupling agent is intended only as the optimal selection of coupling agent herein, and other coupling agents can still be selected.
Light stabilizer is carbon black, can cover or reflect the material of ultraviolet, prevents light from penetrating inside sole；Certain carbon
The black optimal selection for being intended only as light stabilizer herein, other light stabilizers can still be selected.
Heat stabilizer is barium stearate, improves the heat endurance of the sole suitable for running；Certain barium stearate is herein
The optimal selection of heat stabilizer is intended only as, other heat stabilizers can still be selected.
A kind of preparation method for the sole for being applied to run, comprises the following steps：
（1）Parts by weight according to the sole raw material suitable for running weigh raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 125-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Comparative example 1
A kind of sole, includes the raw material of following parts by weight：15 parts of nitrile rubber, 60 parts of brombutyl, nano silicon
17 parts, 2 parts of haloflex, 2.5 parts of Tissuemat E, 0.6 part of magnesia, 2.5 parts of nano zine oxide, 1.3 parts of sulphur, vulcanization promote
Enter 2 parts of 1.3 parts of agent, 6 parts of plasticiser, 3 parts of white smoke active agent and coupling agent.
A kind of preparation method of sole, comprises the following steps：
（1）Raw material is weighed according to the parts by weight of sole raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 120-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
The sole and comparative example 1 that embodiment 1, embodiment 2 and embodiment 3 are made suitable for running are made sole and carry out performance survey
Examination, obtains following test result, as shown in table 1：
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Density（g/cm3） | 1.008 | 1.116 | 1.228 | 1.354 |
| Compression strength（Mpa） | 31.6 | 25.7 | 22.2 | 18.3 |
| Tensile strength（Mpa） | 18.6 | 15.4 | 12.9 | 9.5 |
| Rupture strength（Mpa） | 34.1 | 26.9 | 23.6 | 16.5 |
| Static on-slip coefficient（High oil） | 0.67 | 0.65 | 0.62 | 0.57 |
| Static on-slip coefficient（High oil adds water） | 0.67 | 0.63 | 0.60 | 0.54 |
| Dynamic on-slip coefficient（Heel） | 0.65 | 0.62 | 0.59 | 0.52 |
| Dynamic on-slip coefficient（Smoothly） | 0.64 | 0.63 | 0.60 | 0.53 |
From the data of table 1 compare as can be seen that it is an advantage of the invention that：
1st, a kind of sole for being applied to run and preparation method thereof, from the density measured as can be seen that embodiment 1-3 density is equal
Less than comparative example 1, illustrate that the present invention is applied to the sole light weight run.
2nd, a kind of sole for being applied to run and preparation method thereof, from the compression strength measured as can be seen that embodiment 1-3
Compression strength be above comparative example 1, illustrate that the compression strength of sole that the present invention is applied to run is high.
3rd, a kind of sole for being applied to run and preparation method thereof, tensile strength is according to ISO 37：2005 tests, from survey
The tensile strength that the tensile strength obtained can be seen that embodiment 1-3 is above comparative example 1, illustrates that the present invention is applied to what is run
The good toughness of sole.
4th, a kind of sole for being applied to run and preparation method thereof, from the rupture strength measured as can be seen that embodiment 1-3
Rupture strength be above comparative example 1, illustrate the present invention be applied to run sole High anti bending strength.
5th, a kind of sole for being applied to run and preparation method thereof, static on-slip coefficient is according to F1677：2005 tests, are moved
State on-slip coefficient is according to ISO13287：2012 test SRA patterns (cleaning solution pollution interface), from the static on-slip coefficient measured
（High oil）, static on-slip coefficient（High oil adds water）, dynamic on-slip coefficient（Heel）With dynamic on-slip coefficient（Smoothly）As can be seen that
Embodiment 1-3 static on-slip coefficient（High oil）, static on-slip coefficient（High oil adds water）, dynamic on-slip coefficient（Heel）And dynamic
On-slip coefficient（Smoothly）Comparative example 1 is above, illustrates that the present invention is applied to the good antiskid effect of the sole of running.
6th, a kind of sole for being applied to run and preparation method thereof, reality is can be seen that from the data of each index measured
Apply example 1 and be superior to embodiment 2, embodiment 3 and comparative example 1, illustrate that the present invention is applied to the composition of raw materials and system of the sole of running
The reasonability of Preparation Method.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or equivalent substitution, all essences in the present invention are carried out to which part technical characteristic
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (9)
1. a kind of sole for being applied to run, it is characterised in that include the raw material of following parts by weight：15-19 parts of nitrile rubber, bromine
Change 50-60 parts of butyl rubber, 10-20 parts of nano silicon, 1-5 parts of haloflex, 1-3 parts of Tissuemat E, magnesia
0.2-0.8 parts, 1-4 parts of nano zine oxide, 0.6-1.4 parts of sulphur, 6-18 parts of quartz glass fibre, vinylon
6-10 parts, 9-15 parts of boron fibre, 7-13 parts of Fypro, 0.6-1.6 parts of vulcanization accelerator, 4-8 parts of plasticiser, antioxidant
0.6-1.8 parts, 2-4 parts of white smoke active agent, 1-2 parts of coupling agent, 0.5-0.9 parts of softening agent, 0.2-0.4 parts of light stabilizer and heat are steady
Determine 0.2-0.8 parts of agent.
2. the sole according to claim 1 for being applied to run, it is characterised in that include the raw material of following parts by weight：Fourth
17 parts of nitrile rubber, 55 parts of brombutyl, 15 parts of nano silicon, 3 parts of haloflex, 2 parts of Tissuemat E, magnesia
0.5 part, 2.5 parts of nano zine oxide, 1 part of sulphur, 12 parts of quartz glass fibre, 8 parts of vinylon, boron fibre 12
Part, 10 parts of Fypro, 1.1 parts of vulcanization accelerator, 6 parts of plasticizer, 1.2 parts of antioxidant, 3 parts of white smoke active agent, coupling
0.5 part of 1.5 parts of agent, 0.7 part of softening agent, 0.3 part of light stabilizer and heat stabilizer.
3. the sole according to claim 1 for being applied to run, it is characterised in that：The vulcanization accelerator is 2- mercaptos
Benzothiazole.
4. the sole according to claim 1 for being applied to run, it is characterised in that：The softening agent softens for fatty oils
Agent.
5. the sole according to claim 1 for being applied to run, it is characterised in that：The plasticizer is fatty acid butyl ester.
6. the sole according to claim 1 for being applied to run, it is characterised in that：The coupling agent is silane coupler.
7. the sole according to claim 1 for being applied to run, it is characterised in that：The light stabilizer is carbon black.
8. the sole according to claim 1 for being applied to run, it is characterised in that：The heat stabilizer is barium stearate.
9. a kind of preparation method of sole for being applied to run as described in claim 1-8 any one, it is characterised in that
Comprise the following steps：
（1）Parts by weight according to the sole raw material suitable for running weigh raw material；
（2）Raw material in addition to nano zine oxide, sulphur, vulcanization accelerator is put into banburying in banbury, existed in temperature control
Dumping under the conditions of 125-130 DEG C, room temperature places 24h, produces standing material；
（3）By step（2）In standing material, nano zine oxide, sulphur and vulcanization accelerator add in two-roll mill and knead, mix
After refining is uniform, sheet material is produced；
（4）By step（3）In sheet material be cut into sole shape and be put into sulfidization molding in rubber boots mould.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710441280.3A CN107118452A (en) | 2017-06-13 | 2017-06-13 | A kind of sole for being applied to run and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710441280.3A CN107118452A (en) | 2017-06-13 | 2017-06-13 | A kind of sole for being applied to run and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107118452A true CN107118452A (en) | 2017-09-01 |
Family
ID=59729927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710441280.3A Withdrawn CN107118452A (en) | 2017-06-13 | 2017-06-13 | A kind of sole for being applied to run and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107118452A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
-
2017
- 2017-06-13 CN CN201710441280.3A patent/CN107118452A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277344A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Chef shoe sole and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 中华人民共和国铁道部制订: "《铁路物资技术保管规程》", 30 June 1979, 人民铁道出版社 * |
| 王玉芬等: "《石英玻璃》", 31 January 2007, 化学工业出版社 * |
| 胡晓熙等: "《无机材料性质及其发展研究》", 30 April 2015, 中国水利水电出版社 * |
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