CN1042700A - Base metal, alkene earth metals replacement of gold in golden water and preparation method - Google Patents
Base metal, alkene earth metals replacement of gold in golden water and preparation method Download PDFInfo
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- CN1042700A CN1042700A CN 85105006 CN85105006A CN1042700A CN 1042700 A CN1042700 A CN 1042700A CN 85105006 CN85105006 CN 85105006 CN 85105006 A CN85105006 A CN 85105006A CN 1042700 A CN1042700 A CN 1042700A
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- rare earth
- earth metal
- base metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/27—Mixtures of metals, alloys
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention is base metal, rare earth metal replacement of gold in golden water and preparation method, does not promptly have Jinsui River.Belong to the liquid decorative material that porcelain, fine pottery, glass and the enamelware colored drawing of silicate product are used.Mainly be that resinate with base metal and rare earth metal mixes mutually with rhodium sulfides and organic solvent, become the Jinsui River that does not contain gold, this Jinsui River can reach and the same effect of 14K-22K gold color generation property, thereby is that country saves gold, and its cost has only 1/5th of gold Jinsui River.
Description
The present invention is the liquid decorative material that the porcelain, fine pottery, glass and the enamelware colored drawing that belong to silicate product used.
In the prior art, 10～12% gold is wherein contained in used Jinsui River of goods such as domestic and international colored drawing porcelain, and all the other are platinum (Pt), rhodium (Rh), chromium (Cr), bismuth metals such as (Bi).Composition as U.S. famous brand China ink crane board Jinsui River (Hanoria) and West Germany famous brand life board Jinsui River (Suncndmoon) is gold (Au) 10～12%, platinum be gold 1～1.5%, chromium for gold 0.5～0.8%, rhodium for gold 0.3～0.5%, bismuth is 2.5～3% of gold, the oroide of composition 14K-22K after roasting the burning.A large amount of gold will be consumed in this Jinsui River that contains gold, and China only is used to export Jinsui River of pottery, glasswork every year with regard to the nearly gold more than one ton of need consumption at present.
The objective of the invention is to solve technology, and replace gold, promptly do not have Jinsui River, can be country like this every year and save a large amount of gold with base metal and rare earth metal without gold production Jinsui River.
The present invention is to use rhodium, platinum, bismuth is formed the alloy body of Pt Rh-bismuth, and with iron (Fe), antimony (Sb), chromium (Cr), niobium (Nb), praseodymium (Pr), cerium (Ce), vanadium (V), tungsten (W), the resinate of copper (Cu) base metal and rare earth metal replaces gold to be golden, its technological process is produced identical with existing Jinsui River that contains gold, just salt and the sulfide without gold reacts, but use rhodium, platinum, the resinate of the organic sulfide of bismuth and base metal and rare earth metal, form bright white liquor and staining fluid respectively, mix with organic solvent again, be finished product after the ageing, this finished product is after the roasting burning of 650～850 ℃ of temperature, and set one deck is with gold form and aspect alloy film together on the surface of decorating body.This Jinsui River also can add yellowish, deep yellow or orange electro-optical water respectively and mix in bright white liquor, increase colour generation.
Jinsui River of the present invention optimum formula scope is:
Bright white liquor is formed with rhodium liquid, platinum liquid, bismuth liquid, and its weight ratio is a rhodium: platinum: bismuth=5～25: 5～35: 10～70.
Staining fluid contains elements such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten, copper, and its content is 50～80% of bright white liquor.
Other compositions are perfume oil (white oil of camphor, turps), rosin, vulcanized oil (sulphur and perfume oil are formed) and organic solvent (naphthane, chloroform, acetone).
The colouration mechanism of base metal and rare earth metal is a dyeing theory among the present invention, easily says it, that is the alloy of rhodium, platinum, bismuth presents the gold look in non-ferrous metal and the bright white liquor.In order to control 14K-22K golden stepping, the add-on of changeable chromium, niobium, praseodymium, cerium, iron, antimony, vanadium, tungsten, copper and adjusting.
Prepare the technical process of no Jinsui River as scheming:
1, with resinate (2) weight of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten, copper base metal and rare earth metal be 1 with weight be that 8～15 perfume oil (1), weight are that 2～5 rosin (3) Hybrid Heating (4) are formed staining fluid (5).
2, with Bi(No)
3(8) weight be 1 with weight be that 2～5 rosin (7), weight are that 8～15 perfume oil (6) Hybrid Heating (9) are formed bismuth liquid (10).
3, with Ptcl
3(12) weight is 1 to be that 8～15 sulphur content are that 3～5% vulcanized oil (11) mixes with weight, forms platinum liquid (14) at low temperature (4 ℃) (13).
4, with Rhcl
3NH
2O(16) weight be 1 with weight be that 8～15 sulphur content are that 3～5% vulcanized oil (15) Hybrid Heating (17) is formed rhodium liquid (18).
5, bismuth liquid (10), platinum liquid (14), rhodium liquid (18) thorough mixing are stirred (19) and form bright white liquor (20).
6, be 80～100 with chloroform weight, naphthane, acetone weight are that organic solvent (21) is formed in 4～12 mixing.
7, bright white liquor (20), staining fluid (5) and organic solvent (21) thorough mixing are stirred (22), ageing (23) months get product (24).
The present invention is just the same with the existing Jinsui River usage that contains gold, but goods such as colored drawing porcelain, glass, fine pottery and enamel, and the existing Jinsui River that contains gold of the finished product after roasting the burning has stronger sticking power, anti-oxidant, corrosion-resistant, good-extensibility, bright orange degree is high, and cost also has only 1/5th of gold Jinsui River.
The embodiment of the invention:
One, preparation bright white liquor, staining fluid, organic solvent
1, staining fluid: with the resinate weight of the base metal of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten, copper equivalent and rare earth metal is 1 to be that 14 perfume oil, 5 rosin mix with weight, and it is 20 staining fluid that weight is formed in conventional heating.
2, bright white liquor:
A, with Bi(No)
3Weight is 1 to be that 5 rosin, 14 perfume oil mix with weight, and it is 20 bismuth liquid that weight is formed in conventional heating.
B, with Ptcl
3Weight is 1 to be that 9 sulphur content are that 3～5% vulcanized oil mixes with weight, and forming weight at low temperature (4 ℃) is 10 platinum liquid.
C, with Rhcl
3NH
2O weight is 1 to be that 9 sulphur content are that 3～5% vulcanized oil mixes with weight, and it is 10 rhodium liquid that weight is formed in conventional heating.
D, get that rhodium liquid weight is 10 respectively, platinum liquid is 10, bismuth liquid is 20, stirs through thorough mixing that to form weight be 40 bright white liquor.
3, organic solvent: get chloroform weight respectively and be 100, naphthane weight is 5, acetone weight is 5 to mix that to form weight be 110 organic solvent.
Two, mixed preparing does not have Jinsui River: get bright white liquor weight respectively and be 40, staining fluid weight is 20, organic solvent weight is 110, through fully mixing, ageing one month promptly gets weight and is nothing gold Jinsui River of 170, is equivalent to 18～22K.
Three, technology of the present invention preparation blended does not have Jinsui River, and its performance meets the technological standard that Jinsui River is arranged, and part surpasses, as wear resistance to such as table:
| Numbering | Title | The friction number of | Remarks | |
| 12 | There is Jinsui River not have Jinsui River | More than 20 200 | Carry out rub(bing)test by country's system Jinsui River standard, promptly rub with the felt material. |
Claims (5)
1, a kind of with base metal, rare earth metal replacement of gold in golden water, it is characterized in that:
A, replace gold to make Jinsui River with base metal and rare earth metal.
B, form bright white liquor with the organic sulfide of the salt of rhodium, platinum, bismuth.Resinate and perfume oil, rosin with iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten, copper are formed staining fluid.Form organic solvent with chloroform, naphthane, acetone.
C, be mixed into no Jinsui River by bright white liquor, staining fluid and organic solvent.
2,, it is characterized in that adding respectively in the bright white liquor yellowish, deep yellow or orange electro-optical water as claim 1 described base metal, rare earth metal replacement of gold in golden water.
3, as the preparation method of claim 1 described base metal, rare earth metal replacement of gold in golden water, it is characterized in that:
(1) composition of bright white liquor is:
A, Bi(No)
3Weight be 1 with weight be that 2～5 rosin, 8～15 perfume oil Hybrid Heating are formed bismuth liquid.
B, Ptcl
3Weight is 1 to be that 8～15 sulphur content are that 3～5% vulcanized oil mixes with weight, forms platinum liquid at low temperature (4 ℃).
C, Rhcl
3NH
2O weight be 1 with weight be that 8～15 sulphur content are that 3～5% vulcanized oil Hybrid Heating is formed rhodium liquid.
(2) composition of staining fluid is: the resinate weight of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten, copper base metal and rare earth metal be 1 with weight be that 8～15 perfume oil, 2～5 rosin Hybrid Heating are formed staining fluid.
(3) composition of organic solvent is 80～100 for chloroform weight, and naphthane, acetone weight are that 4～12 mixing are formed.
4, as the preparation method of claim 3 described base metals, rare earth metal replacement of gold in golden water: its weight ratio of optimum formula scope that it is characterized in that bright white liquor is a rhodium: platinum: bismuth=5～25: 5～35: 10～70.
5, as the preparation method of claim 3 described base metals, rare earth metal replacement of gold in golden water, the optimum formula scope that it is characterized in that the staining fluid element is 50～80% of a bright white liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105006 CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105006 CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1042700A true CN1042700A (en) | 1990-06-06 |
| CN1022480C CN1022480C (en) | 1993-10-20 |
Family
ID=4794193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 85105006 Expired - Fee Related CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1022480C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100488918C (en) * | 2006-04-28 | 2009-05-20 | 冯建光 | Method for preparing imitating gold water |
| CN102976789A (en) * | 2012-12-25 | 2013-03-20 | 景德镇陶瓷学院 | Green liquid luster |
| CN107216165A (en) * | 2016-03-22 | 2017-09-29 | 何赋森 | A kind of ceramic electrically-conducting paint and its application method |
| US10329845B2 (en) | 2013-12-06 | 2019-06-25 | Halliburton Energy Services, Inc. | Rotary drill bit including multi-layer cutting elements |
-
1985
- 1985-07-02 CN CN 85105006 patent/CN1022480C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100488918C (en) * | 2006-04-28 | 2009-05-20 | 冯建光 | Method for preparing imitating gold water |
| CN102976789A (en) * | 2012-12-25 | 2013-03-20 | 景德镇陶瓷学院 | Green liquid luster |
| CN102976789B (en) * | 2012-12-25 | 2015-01-14 | 景德镇陶瓷学院 | Green liquid luster |
| US10329845B2 (en) | 2013-12-06 | 2019-06-25 | Halliburton Energy Services, Inc. | Rotary drill bit including multi-layer cutting elements |
| US10781642B2 (en) | 2013-12-06 | 2020-09-22 | Halliburton Energy Services, Inc. | Rotary drill bit including multi-layer cutting elements |
| CN107216165A (en) * | 2016-03-22 | 2017-09-29 | 何赋森 | A kind of ceramic electrically-conducting paint and its application method |
| CN107216165B (en) * | 2016-03-22 | 2019-09-06 | 何赋森 | A kind of ceramics conductive coating and its application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1022480C (en) | 1993-10-20 |
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