CN1069479A - Silver water - Google Patents
Silver water Download PDFInfo
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- CN1069479A CN1069479A CN 91106513 CN91106513A CN1069479A CN 1069479 A CN1069479 A CN 1069479A CN 91106513 CN91106513 CN 91106513 CN 91106513 A CN91106513 A CN 91106513A CN 1069479 A CN1069479 A CN 1069479A
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Abstract
The present invention relates to the liquid decorative material of silicate products such as pottery, glass, enamel, be characterized in tin and rhodium or make refractory agent with tin merely, other component of silver-colored water has also been done the optimization adjustment according to the situation that tin is made refractory agent.The consumption of silver-colored water of the present invention, heatproof degree height, rhodium reduces by 65-100%, and production cost can reduce by 8% at least.Silvery white decorations film after the decoration firing meets the ceramic industry technological standard.
Description
The present invention relates to the liquid decorative material of silicate products such as pottery, glass and enamel.
Silver water is as the ornament of pottery, glass etc., uses extensive and conveniently, and metalluster is silvery white in color.Through domestic and international long term studies, exploitation, there is silver-colored water of a great variety, that performance is different to come out in succession.But various silver-colored water all are evenly after the composition that ageing is handled by chromogenic reagent, toning agent, adhesive agent, refractory agent, weighting agent and solvent.Chromogenic reagent constitutes metal decorations mould, send silvery white metalluster, toning agent is used to adjust the tone of metal decorations film, the adhesive agent function is to improve sticking power and the resistance to abrasion of metal decorations film on silicate product, the effect of refractory agent be guarantee metal decorations film when fusing, do not produce assemble and equably spread in the ornaments surface, keep metal decorations film to have uniform luminance brightness, weighting agent is used for adjusting the metal content in Jinsui River, make it have use properties preferably, the effect of solvent is to give silver-colored water with suitable flowability properties and volatility.At present, nearly all silver-colored water is refractory agent with the rhodium all, and the price of rhodium is very expensive, source of goods shortage, and rhodium accounts for the 12-20% of Jinsui River cost, carries out for many years with the research that other base metal replaces rhodium to make refractory agent, does not see yet at present to have breakthrough.
One of purpose of the present invention is that a kind of silver-colored water of making refractory agent with tin or rhodium is provided.
Two of purpose of the present invention is that a kind of silver-colored water of making refractory agent merely with tin is provided.
Above-mentioned two kinds of silver-colored water, cost reduces significantly, and the luminance brightness of metal decorations film increases.
Two kinds of above-mentioned silver-colored water, its technical essential are partly or entirely to substitute rhodium with tin to make refractory agent, and other component of silver-colored water has also been done the optimization adjustment according to the situation that tin is made refractory agent.
First kind of Jinsui River of the present invention, be chromogenic reagent, toning agent, adhesive agent, refractory agent, the composition that solvent and weighting agent constitute, the major technique feature is, make refractory agent with the rosinate of tin and the organic sulfide of rhodium, the mol ratio of tin and rhodium is 20-1, add-on is (for organometallics, below all represent with the % of metallic element weight and silver-colored water gross weight): 0.10-0.25, with gold, palladium or gold, the organic sulfide of platinum is made chromogenic reagent, gold, the mol ratio of palladium is 5-1, gold, the mol ratio of platinum is 6-2, the add-on of this chromogenic reagent is 3.2-8.0, the organic sulfide of the rosinate of chromium and silver is a toning agent, and add-on is respectively 0.02-0.05 and 0.00-0.32, and adhesive agent is the rosinate of bismuth, add-on 0.3-0.6, with nitrated rosin is weighting agent, and add-on is the 20-60% of silver-colored water gross weight, the 20-40% naphthane, the 10-50% camphor oil, the 5-10% pimelinketone, the terebinthine mixed solution of 5-10% is made solvent, and add-on is the 2-10% of silver-colored water gross weight.
Second kind of silver-colored water of the present invention, be chromogenic reagent, toning agent, adhesive agent, refractory agent, the composition that solvent and weighting agent constitute, its major technique feature is, resinate with tin is made refractory agent, add-on is (for organometallics, below all represent with the % of metallic element weight and silver-colored water gross weight): 0.05-0.35, with gold, palladium or gold, the organic sulfide of platinum is made chromogenic reagent, the add-on of gold is 2.2-6.0, the add-on 0.8-2.2 of palladium or platinum, the sulfide that has of the rosinate of chromium and silver is toning agent, add-on is respectively 0.05-0.07 and 0.10-0.35, the rosinate of bismuth is an adhesive agent, add-on 0.32-0.52, nitrated rosin is weighting agent, and add-on is the 20-60% of silver-colored water gross weight, the 20-40% naphthane, the 10-50% camphor oil, the 5-10% pimelinketone, the terebinthine mixed solution of 5-10% is made solvent, and add-on is the 2-10% of silver-colored water gross weight.
For first kind of above-mentioned silver-colored water, the mol ratio of refractory agent tin, rhodium the best is 8.5-1.0.
First kind of above-mentioned silver-colored water, the organic sulfide of chromogenic reagent gold, palladium or gold, platinum are turps sulfuration face cream gold, turps sulfuration face cream palladium, turps sulfuration face cream platinum, and the mol ratio of described gold, palladium is 2.5-1.5, and the mol ratio of gold, platinum is 3.4-4.5.
Above-mentioned first kind of silver-colored water, the add-on of the rosinate of adhesive agent bismuth is 0.32-0.42.
Second kind of above-mentioned silver-colored water, the add-on of the rosinate of refractory agent tin is 0.08-0.21.
Second kind of above-mentioned silver-colored water, the organic sulfide of chromogenic reagent gold, palladium or gold, platinum are turps sulfuration face cream gold, turps sulfuration face cream palladium, turps sulfuration face cream platinum.
Two kinds of silver-colored water of the present invention, screen the rosinate of metallic tin and made refractory agent, provided suitable silver-colored water prescription, the consumption of rhodium reduces 65-100%, cost reduces more than 8%, and first kind of silver-colored water heatproof temperature is 850 ℃, and second kind of silver-colored water heatproof temperature is 800 ℃, the silvery white decorations film that obtains after the decoration firing meets the ceramic industry technological standard.
The method for preparing silver-colored water can be:
1, be 1 with tin protochloride weight, with weight be the rosin of 2-6, weight is that the organic solvent Hybrid Heating of 8-15 is made the tin refractory agent.
2, be 1 with rhodium chloride weight, with weight be the vulcanized oil of 2-6 sulphur content 8-15%, Hybrid Heating is formed the rhodium refractory agent, is mixed with the mixing refractory agent in the ratio of the mol ratio 8.5-1.0 of tin/rhodium.
3, be 1 with chromium chloride weight, with the rosin of weight 2-5, weight is the organic solvent of 8-15, and Hybrid Heating is made toning agent.
4, with Bismuth trinitrate weight be 1 with the rosin of weight 2-5, the organic solvent of weight 8-15%, Hybrid Heating makes adhesive agent.
5, be 1 with Silver Nitrate weight, adding weight is the vulcanized oil of 2-6 sulphur content 8-15%, and Hybrid Heating is made silver-colored toning agent.
6, be 1 with gold trichloride weight, adding weight is the vulcanized oil of 2-6 sulphur content 8-15%, and Hybrid Heating is formed the golden hair toner.
7, be 1 with platinum chloride weight, adding weight is the vulcanized oil of 8-15% for the 2-6 sulphur content, and Hybrid Heating is formed the platinum chromogenic reagent.
8, be 1 with Palladous chloride weight, adding weight is the vulcanized oil of 8-15% for the 2-6 sulphur content, and Hybrid Heating is formed the palladium chromogenic reagent.
9, be 1 with rosin weight, adding weight is that 0.3 gram concentration is 30% rare nitric acid, and weight is the 1-1.5 organic solvent, and Hybrid Heating is formed weighting agent.
10, be 2-40 with naphthane weight, camphor oil weight 10-50, pimelinketone weight is 5-10, turps weight is 5-10, mixes and forms organic solvent.
11, chromogenic reagent, mixing refractory agent, toning agent, adhesive agent, weighting agent, organic solvent thorough mixing are stirred, in one week of ageing, promptly get silver-colored water.
Embodiments of the invention are as follows:
Example 1, silver-colored water (porcelain is used)
Get 24 parts of Gold Contents, 25% golden hair toner respectively, the palladium chromogenic reagent of 16 parts of content 10%, the resin bismuth of 12 parts of bismuth-containing amounts 3%, the resin chromium of 1 part of chrome content 2%, 5 parts are mixed refractory agent, 38 parts of nitrated rosin, 4 parts of organic solvents are through fully mixing one week of ageing, the composition metal content is Au6%, Pd1.6%, Bl0.36%, Cr0.02%, Sn0.10%, 100 parts in the silver-colored water of the porcelain of Rh0.02% gold, palladium color development.
Example 2 silver medal water (porcelain is used)
Get 10.8 parts of Gold Contents, 25% golden hair toner respectively, 9 parts of content 10% platinum chromogenic reagents, 10 parts of bismuth-containing amount 3% resin bismuths, 1 part of content 2% resin chromium, 2.8 parts are mixed refractory agent, 64 parts of nitrated rosin, 2.8 part organic solvent is through fully mixing one week of ageing, the composition metal content is Au2.7%, Pt0.9%, Bl0.30%, Cr0.02%, Sn0.06%, the porcelain of Rh0.01% is with 100 parts in the silver-colored water of golden platinum color development.
The silver-colored water of example 3 soft-paste
Get 22.4 parts of Gold Contents, 25% golden hair toner respectively, 14 parts of content 10% palladium chromogenic reagents, 12 parts of content 3% resin bismuths, 1 part of content 2% resin chromium, 3 parts of stanniferous amount 2.6% resin tin, 6.5 parts of silver content 3% resin silver, 38 parts of nitrated rosin, 3.1 parts of organic solvents are through abundant stirring and evenly mixing, in one week of ageing, the composition metal content is Au5.6%, Pd1.4%, Bl0.36%, Cr0.02%, Sn0.08%, the soft-paste of Ag0.20% is with 100 parts in silver-colored water.
Claims (8)
1, a kind of silver-colored water, the composition for chromogenic reagent, toning agent, adhesive agent, refractory agent, solvent and weighting agent constitute is characterized in that:
A makes refractory agent with the rosinate of tin and the organic sulfide of rhodium, and the mol ratio of tin, rhodium is 20-1, add-on (for organometallics, below all represent): 0.10-0.25 with the % of metallic element weight and silver-colored water gross weight,
B makes chromogenic reagent with the organic sulfide of gold, palladium or gold, platinum, the mol ratio 5-1 of gold, palladium, and the mol ratio of gold, platinum is 6-2, the add-on of this chromogenic reagent is 3.2-8.0,
The organic sulfide of the rosinate of C chromium and silver is a toning agent, and add-on is respectively 0.02-0.05 and 0.00-0.32,
The D adhesive agent is the rosinate of bismuth, add-on 0.3-0.6,
E is a weighting agent with nitrated rosin, and add-on is the 20-60% of silver-colored water gross weight,
F20-40% naphthane, 10-50% camphor oil, 5-10% cyclohexanone, the terebinthine mixed solution of 5-10% are made solvent, and add-on is the 2-10% of silver-colored water gross weight.
According to the described silver-colored water of claim 1, it is characterized in that 2, the mol ratio of refractory agent tin, rhodium is 8.5-1.0.
3, according to claim 1 or 2 described silver-colored water, it is characterized in that, the organic sulfide of described chromogenic reagent gold, palladium or gold, platinum is turps sulfuration face cream gold, turps sulfuration face cream palladium, turps sulfuration face cream platinum, the mol ratio of described gold, palladium is 2.5-1.5, and the mol ratio of gold, platinum is 3.4-4.5.
4, according to claim 1 or 2 described silver-colored water, it is characterized in that the rosinate add-on of adhesive agent bismuth is 0.32-0.42.
According to the described silver-colored water of claim 3, it is characterized in that 5, the rosinate add-on of adhesive agent bismuth is 0.32-0.42.
6, a kind of silver-colored water, the composition for chromogenic reagent, toning agent, adhesive agent, refractory agent, solvent and weighting agent constitute is characterized in that:
A makes refractory agent with the rosinate of tin, add-on (for organometallics, below all represent): 0.05-0.35 with the % of metallic element weight and silver-colored water gross weight,
B makes chromogenic reagent with the organic sulfide of gold, palladium or gold, platinum, and the add-on of gold is 2.2-6.0, and the add-on of palladium or platinum is 0.8-2.2,
C is a toning agent with the rosinate of chromium or the organic sulfide of silver, and add-on is respectively 0.05-0.07 or 0.10-0.35,
D is an adhesive agent with the rosinate of bismuth, and add-on is 0.32-0.52,
The nitrated rosin of E is weighting agent, and add-on is the 20-60% of silver-colored water inventory,
F 20-40% naphthane, 10-50% camphor oil, 5-10% pimelinketone, the terebinthine mixed solution of 5-10% is made solvent, and add-on is the 2-10% of silver-colored water inventory.
According to the described silver-colored water of claim 6, it is characterized in that 7, the add-on of the rosinate of refractory agent tin is 0.08-0.21.
According to claim 6 or 7 described silver-colored water, it is characterized in that 8, the organic sulfide of chromogenic reagent gold, palladium or gold, platinum is turps sulfuration face cream gold, turps sulfuration face cream palladium, turps sulfuration face cream platinum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106513 CN1069479A (en) | 1991-08-13 | 1991-08-13 | Silver water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106513 CN1069479A (en) | 1991-08-13 | 1991-08-13 | Silver water |
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| Publication Number | Publication Date |
|---|---|
| CN1069479A true CN1069479A (en) | 1993-03-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91106513 Pending CN1069479A (en) | 1991-08-13 | 1991-08-13 | Silver water |
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| CN (1) | CN1069479A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113524964A (en) * | 2020-04-17 | 2021-10-22 | Oppo广东移动通信有限公司 | Electronic equipment shell, decoration method thereof and electronic equipment |
-
1991
- 1991-08-13 CN CN 91106513 patent/CN1069479A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113524964A (en) * | 2020-04-17 | 2021-10-22 | Oppo广东移动通信有限公司 | Electronic equipment shell, decoration method thereof and electronic equipment |
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