CN1030796A - Novel copper alloy used for gold-like decorative purpose - Google Patents

Novel copper alloy used for gold-like decorative purpose Download PDF

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Publication number
CN1030796A
CN1030796A CN87104511A CN87104511A CN1030796A CN 1030796 A CN1030796 A CN 1030796A CN 87104511 A CN87104511 A CN 87104511A CN 87104511 A CN87104511 A CN 87104511A CN 1030796 A CN1030796 A CN 1030796A
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copper
gold
aluminium
mishmetal
nickel
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CN87104511A
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CN1006304B (en
Inventor
程自强
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LIANYI NON-FERROUS SECTION FACTORY SHANGHAI
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LIANYI NON-FERROUS SECTION FACTORY SHANGHAI
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Priority to CN85102489A priority Critical patent/CN1006304B/en
Publication of CN1030796A publication Critical patent/CN1030796A/en
Publication of CN1006304B publication Critical patent/CN1006304B/en
Expired legal-status Critical Current

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Abstract

The present invention relates to copper alloy used for gold-like decorative purpose, copper removal also comprises zinc, aluminium, titanium or chromium, nickel, tin, manganese or phosphorus and mishmetal outward; Or copper removal also comprises nickel, aluminium, manganese and mishmetal outward, color and luster is true to nature, exactly like gold and karat gold, anti-atmosphere, perspiration resistance and wear resistance all are better than gold and karat gold, life-time service can variable color, and has favorable mechanical and processing characteristics, can be processed into sheet material, wire rod and the profiled material of different shape, can be used for making spectacle frame, the pen cap, nib, watch case, clock shell, watchband, decorative lamp product, jewellery, artwork and various building decoration product, price only is 1/3 of existing rare gold copper-base alloy.

Description

Novel copper alloy used for gold-like decorative purpose
The present invention relates to copper base alloy, particularly a kind of copper alloy used for gold-like decorative purpose.
Yellow Yin Seze beauty, graceful generous and always be the main raw of making senior jewellery, artwork etc., but price of gold costliness, so people replace gold with regard to the imitation gold copper-base alloy of having developed color and luster and exactly liking gold, and this imitation gold copper-base alloy more and more is subjected to people's welcome.This all there is research both at home and abroad.Abroad make referrals in new 500 Japanese yen currencies of dissection one literary composition according to the 1st the 34th page of Japan's " metal " nineteen eighty-three the 53rd volume, France adopts copper 92%, nickel 6% and 10 Francs of coin of aluminium 2% alloy system (reddish yellow gold), West Germany adopts the skin (light golden yellow) of copper 81%, zinc 10% and nickel 9% alloy system 10 mark's coin, and Austria adopts copper 92%, aluminium 6% and nickel 20 shillings of coin of 2% alloy system (golden yellow); Other has the data report Soviet Union to adopt copper 85.0%, zinc 14.5% and aluminium 0.5% as imitation gold copper-base alloy.But above-mentioned alloy all can not satisfy the color and luster of imitation gold copper-base alloy and the requirement on the performance fully, and is true to nature inadequately as color and luster, and it is easy to change etc. to run into sweat stain, needs further improvement.And it is domestic, a kind of copper of the practical electrical equipment Research Institute success in ShaoXing,ZheJiang city rare gold process factory and Ministry of Light Industry Beijing, aluminium and indium rare earth alloy (being called rare gold), though its color and luster and performance all can reach requirement, but indium wherein belongs to rare metal, cost an arm and a leg, and resource is few, large-scale popularization is used certain difficulty, therefore, only be used to make jewellery at present.In addition, at present other imitation gold copper-base alloy on the domestic market all exists color and luster true to nature inadequately, and anti-atmosphere, perspiration resistance, attrition resistant poor-performing, life-time service be shortcoming such as variable color very easily.In a word, domestic and international existing imitation gold copper-base alloy can't reach color and luster and performance is all good, and low-cost again requirement.
The object of the present invention is to provide a kind of copper alloy used for gold-like decorative purpose, color and luster and performance are all good, and price is cheap again.
The present invention is achieved in that
Copper alloy used for gold-like decorative purpose, copper removal also comprise zinc, aluminium, titanium or chromium, nickel, tin, manganese or phosphorus and mishmetal outward; Or copper removal also comprises nickel, aluminium, manganese and mishmetal outward.
Further, the prescription of described copper-based alloy material (in weight %) has:
(1) zinc 14.0~17.0%, aluminium 0.5~1.5%, titanium or chromium 0~0.6%, nickel 0~0.6%, tin 0~0.5%, manganese 0~0.5% or phosphorus 0~0.1% and mishmetal 0~0.1%, surplus is a copper;
(2) aluminium 5.0~8.0%, nickel 0.5~2.5%, manganese 0~0.5% and mishmetal 0~0.1%, surplus is a copper;
(3) nickel 4.5~6.5%, aluminium 0.5~3.0%, manganese 0~0.5% and mishmetal 0~0.1%, surplus is a copper;
(4) zinc 9.0~12.0%, nickel 7.0~11.0%, titanium or chromium 0~0.6%, aluminium 0~0.5%, tin 0~0.5%, manganese 0~0.5% or phosphorus 0~0.1% and mishmetal 0~0.1%, surplus is a copper.
Copper alloy used for gold-like decorative purpose of the present invention is to the further improved result of alloy ingredient on the basis of known imitation gold copper-base alloy, adopt alloy toning method to make, its color and luster beauty is true to nature, exactly like gold and karat gold, anti-atmosphere, perspiration resistance corrosion and wear resistance all are better than gold and various karat gold, life-time service can variable color, and have favorable mechanical and processing characteristics, can be processed into the sheet material of different shape, wire rod and profiled material, can be used for making spectacle frame, the pen cap, nib, watch case, the clock shell, watchband, the decorative lamp product, jewellery, artwork and various building decoration product, price only are 1/3 of existing rare gold copper-base alloy.
Further specify the present invention below by specific examples.
Embodiment 1
A kind of copper alloy used for gold-like decorative purpose, copper removal also comprises zinc, aluminium, titanium or chromium, nickel, tin, manganese or phosphorus and mishmetal outward, its prescription (in weight %) is: zinc 15.0%, aluminium 1.0%, chromium 0.5%, surplus is a copper, add above-mentioned various metals in smelting furnace, smelting temperature is controlled at 1100~1200 ℃.The alloy color is golden yellow, exactly like 22 K gold, anti-atmosphere, perspiration resistance corrosion and wear resisting property are all more excellent, life-time service can variable color, and have favorable mechanical and processing characteristics, sheet material, wire rod and the profiled material of different shape be can be processed into, spectacle frame, the pen cap, nib, watch case, clock shell, watchband, decorative lamp product, jewellery, artwork and various building decoration product can be used for making.
Embodiment 2
A kind of copper alloy used for gold-like decorative purpose, with embodiment 1, but its prescription (in weight %) is: zinc 16.0%, aluminium 0.5%, titanium 0.5%, nickel 0.4%, tin 0.3%, phosphorus 0.05% and mishmetal 0.05%, surplus are copper.
Embodiment 3
A kind of copper alloy used for gold-like decorative purpose, with embodiment 1, but its prescription (in weight %) is: zinc 11.0%, nickel 8.0%, titanium 2.5%, aluminium 0.3%, tin 0.2%, manganese 0.5% and mishmetal 0.05%, surplus are copper, the alloy color is light golden yellow, exactly likes 20 karat golds.
Embodiment 4
A kind of copper alloy used for gold-like decorative purpose, with embodiment 1, but its prescription (in weight %) is: zinc 9.0%, nickel 11.0%, chromium 0.5%, aluminium 0.3%, tin 0.2% and mishmetal 0.05%, surplus are copper, the alloy color is light golden yellow, exactly likes 20 karat golds.
Embodiment 5
A kind of copper alloy used for gold-like decorative purpose, copper removal also comprise nickel, aluminium, manganese and mishmetal outward, and its prescription (in weight %) is: aluminium 8.0%, nickel 1.5%, manganese 0.25% and mishmetal 0.05%, surplus are copper, and all the other are with embodiment 1.
Embodiment 6
A kind of copper alloy used for gold-like decorative purpose, with embodiment 5, but its prescription (in weight %) is: aluminium 7.5%, nickel 1.0%, manganese 0.1% and mishmetal 0.05%, surplus are copper.
Embodiment 7
A kind of copper alloy used for gold-like decorative purpose, with embodiment 5, but its prescription (in weight %) is: nickel 4.5%, aluminium 1.0%, manganese 0.5% and mishmetal 0.05%, surplus are copper, and alloy face is lilac red, exactly like 18 karat golds.
Embodiment 8
A kind of copper alloy used for gold-like decorative purpose, with embodiment 5, but its prescription (in weight %) is: nickel 5.5%, aluminium 1.5%, manganese 0.1% and mishmetal 0.05%, surplus are copper, and the alloy color is a lilac red, exactly like 18 karat golds.
Revisal 87104511
After the preceding revisal of the capable revisal of file name page or leaf
Specification sheets 13 yellow ... gold
3 10 titaniums, 2.5% titanium 0.5%

Claims (7)

1, a kind of copper alloy used for gold-like decorative purpose, copper removal mainly contains zinc and aluminium outward, it is characterized in that described copper-based alloy material also comprises titanium or chromium, nickel, tin, manganese or phosphorus and mishmetal.
2, copper-based alloy material according to claim 1, the prescription (in weight %) that it is characterized in that described copper-based alloy material is: zinc: 14.0~17.0%, aluminium 0.5~1.5%, titanium or chromium 0~0.6%, nickel 0~0.6%, tin 0~0.5%, manganese 0~0.5% or phosphorus 0~0.1% and mishmetal 0~0.1%, surplus are copper.
3, a kind of copper alloy used for gold-like decorative purpose, copper removal mainly contains nickel and aluminium outward, it is characterized in that described copper-based alloy material also comprises manganese and mishmetal.
4, copper-based alloy material according to claim 3, it is characterized in that the prescription (in weight %) of described copper-based alloy material is: aluminium 5.0~8.0%, nickel 0.5~2.5%, manganese 0~0.5% and mishmetal 0~0.1%, surplus are copper.
5, copper-based alloy material according to claim 3, it is characterized in that the prescription (in weight %) of described copper-based alloy material is: nickel 4.5~6.5%, aluminium 0.5~3.0%, manganese 0~0.5% and mishmetal 0~0.1%, surplus are copper.
6, a kind of copper alloy used for gold-like decorative purpose, copper removal mainly contains zinc and nickel outward, it is characterized in that described copper-based alloy material also comprises titanium or chromium, aluminium, tin, manganese or phosphorus and mishmetal.
7, copper-based alloy material according to claim 6, the prescription (in weight %) that it is characterized in that described copper-based alloy material is: zinc 9.0~12.0%, nickel 7.0~11.0%, titanium or chromium 0~0.6%, aluminium 0~0.5%, tin 0~0.5%, manganese 0~0.5% or phosphorus 0~0.1% and mishmetal 0~0.1%, surplus are copper.
CN85102489A 1987-06-27 1987-06-27 Copper alloy used for gold-like decorative purpose Expired CN1006304B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN85102489A CN1006304B (en) 1987-06-27 1987-06-27 Copper alloy used for gold-like decorative purpose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN85102489A CN1006304B (en) 1987-06-27 1987-06-27 Copper alloy used for gold-like decorative purpose

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CN1030796A true CN1030796A (en) 1989-02-01
CN1006304B CN1006304B (en) 1990-01-03

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101787461A (en) * 2010-03-02 2010-07-28 路达(厦门)工业有限公司 Environment-friendly manganese brass alloy and manufacturing method thereof
CN102725430A (en) * 2009-11-10 2012-10-10 Gbc金属有限责任公司 Antitarnish, antimicrobial copper alloys and surfaces made from such alloys
CN102864330A (en) * 2012-09-27 2013-01-09 杭州震达五金机械有限公司 Gold-bearing imitation-gold copper alloy and preparation method thereof
CN106011533A (en) * 2016-07-28 2016-10-12 苏州中色华人铜业有限公司 Tarnish-resistant gold imitation copper alloy material and preparation method thereof
CN107699733A (en) * 2017-11-20 2018-02-16 任超 One Albatra metal and preparation method thereof
CN109865961A (en) * 2019-03-05 2019-06-11 苏州昆腾威新材料科技有限公司 A kind of copper-based spherical powder material and the preparation method and application thereof
CN110923505A (en) * 2019-12-31 2020-03-27 内蒙古工业大学 Cu-Ni-Mn alloy and preparation method and application thereof
CN113564412A (en) * 2021-07-29 2021-10-29 沈阳造币有限公司 Novel easily-processed gold-like copper alloy and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102725430A (en) * 2009-11-10 2012-10-10 Gbc金属有限责任公司 Antitarnish, antimicrobial copper alloys and surfaces made from such alloys
CN101787461A (en) * 2010-03-02 2010-07-28 路达(厦门)工业有限公司 Environment-friendly manganese brass alloy and manufacturing method thereof
CN102864330A (en) * 2012-09-27 2013-01-09 杭州震达五金机械有限公司 Gold-bearing imitation-gold copper alloy and preparation method thereof
CN106011533A (en) * 2016-07-28 2016-10-12 苏州中色华人铜业有限公司 Tarnish-resistant gold imitation copper alloy material and preparation method thereof
CN107699733A (en) * 2017-11-20 2018-02-16 任超 One Albatra metal and preparation method thereof
CN109865961A (en) * 2019-03-05 2019-06-11 苏州昆腾威新材料科技有限公司 A kind of copper-based spherical powder material and the preparation method and application thereof
CN109865961B (en) * 2019-03-05 2021-07-20 苏州昆腾威新材料科技有限公司 Copper-based spherical powder material and preparation method and application thereof
CN110923505A (en) * 2019-12-31 2020-03-27 内蒙古工业大学 Cu-Ni-Mn alloy and preparation method and application thereof
CN113564412A (en) * 2021-07-29 2021-10-29 沈阳造币有限公司 Novel easily-processed gold-like copper alloy and preparation method thereof
CN113564412B (en) * 2021-07-29 2022-05-27 沈阳造币有限公司 Easily-processed gold-like copper alloy and preparation method thereof

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