CN1022480C - Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method - Google Patents
Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method Download PDFInfo
- Publication number
- CN1022480C CN1022480C CN 85105006 CN85105006A CN1022480C CN 1022480 C CN1022480 C CN 1022480C CN 85105006 CN85105006 CN 85105006 CN 85105006 A CN85105006 A CN 85105006A CN 1022480 C CN1022480 C CN 1022480C
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- CN
- China
- Prior art keywords
- weight
- gold
- liquid
- mix
- earth metal
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/27—Mixtures of metals, alloys
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to golden water with gold replaced by base metal and rare-earth metal and a preparation method thereof, namely goldless golden water which belongs to liquid decorative materials for colored drawing of porcelain, fine pottery, glass and enamelware of silicate products. The method mainly comprises the following steps: sulfides, such as base metal, resinate of rare-earth metal, rhodium, etc. are mixed with organic solvents, and golden water without gold is prepared. The golden water can obtain the same effects on the color-forming performance as the gold of 14 K to 22 K, so gold of the nation can be saved; the cost of the golden water is one fifth of that of gold water.
Description
The present invention is the liquid decorative material that the porcelain, fine pottery, glass and the enamelware colored drawing that belong to silicate product used.
In the prior art, 10～12% gold is wherein contained in used Jinsui River of goods such as domestic and international colored drawing porcelain, and all the other are platinum (Pt), rhodium (Rh), chromium (Cr), bismuth metals such as (Bi).Composition as U.S. famous brand China ink crane board Jinsui River (Hanovia) and German famous brand life board Jinsui River (Sun and moon) is gold (Au) 10～12%, platinum be gold 1～1.5%, chromium for gold 0.5～0.8%, rhodium for gold 0.3～0.5%, bismuth is 2.5～3% of gold, the oroide of composition 14K～22K after roasting the burning.A large amount of gold will be consumed in this Jinsui River that contains gold, and China only is used to export Jinsui River of pottery, glasswork every year with regard to the nearly gold more than one ton of need consumption at present.
The objective of the invention is to solve the technology without gold production Jinsui River, and replace gold with base metal and rare earth metal, promptly imitative Jinsui River can be country like this every year and saves a large amount of gold.
The present invention is to use rhodium, platinum, bismuth to form the alloy body of Pt Rh-bismuth, and replaces gold to be golden with the resinate of iron (Fe), antimony (Sb), chromium (Cr), niobium (Nb), praseodymium (Pr), cerium (Ce), vanadium (V) or tungsten (W) base metal and rare earth metal.Its technological process is produced identical with existing Jinsui River that contains gold, just salt and the sulfide without gold reacts, but with the organic sulfide of rhodium, platinum, bismuth and the resinate of base metal and rare earth metal, form bright white liquor and staining fluid respectively, mix with organic solvent again, be finished product after the ageing, this finished product is after the roasting burning of 650～850 ℃ of temperature, and set one deck is with gold form and aspect alloy film together on the surface of decorating body.This Jinsui River also can add yellowish, deep yellow or orange electro-optical water respectively and mix in bright white liquor, increase colour generation.
Jinsui River of the present invention optimum formula scope is:
Bright white liquor is formed with rhodium liquid, platinum liquid, bismuth liquid, and its weight ratio is a rhodium: platinum: bismuth=5～25: 5～35: 10～70.
Staining fluid contains elements such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or tungsten, and its content is 50～80% of bright white liquor.
Other compositions are perfume oil (white oil of camphor, turps), rosin, vulcanized oil (sulphur and perfume oil are formed) and organic solvent (naphthane, chloroform, acetone).
The colouration mechanism of base metal and rare earth metal is a dyeing theory among the present invention, easily says it, that is the alloy of rhodium, platinum, bismuth presents the gold look in non-ferrous metal and the bright white liquor.In order to control 14K～22K golden stepping, the add-on of changeable iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or W elements and adjusting.
The imitative Jinsui River technical process of preparation:
1. be 1 to be that 8～15 perfume oil, weight are that 2～5 rosin mixes with weight with the weight of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or tungsten base metal and rare earth metal salt, staining fluid is formed in heating.
2. with Bi(NO)
3Weight is 1 to be that 2～5 rosin, weight are that 8～15 perfume oil mixes with weight, and bismuth liquid is formed in heating.
3. with Ptcl
3Weight is 1 to be that 8～15 sulphur content are that 3～5% vulcanized oil mixes with weight, forms platinum liquid at low temperature (4 ℃).
4. with Rhcl
3NH
2O weight is 1 to be that 8～15 sulphur content are that 3～5% vulcanized oil mixes with weight, and rhodium liquid is formed in heating.
5. bismuth liquid, platinum liquid, rhodium liquid thorough mixing are stirred, form bright white liquor.
6. be 80～100 with chloroform weight, naphthane, acetone weight are 4～12 mixing, form organic solvent.
7. bright white liquor, staining fluid and the stirring of organic solvent thorough mixing, ageing were got product in one month.
The present invention is just the same with the existing Jinsui River usage that contains gold, but goods such as colored drawing porcelain, glass, fine pottery and enamel, and the existing Jinsui River that contains gold of the finished product after roasting the burning has stronger sticking power, anti-oxidant, corrosion-resistant, good-extensibility, bright orange degree is high, and cost also has only 1/5th of gold Jinsui River.
The embodiment of the invention:
One, preparation bright white liquor, staining fluid, organic solvent
1. staining fluid: with the weight of the base metal of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or tungsten equivalent and rare earth metal salt is 1 to be that 14 perfume oil, weight are that 5 rosin mixes with weight, and it is 20 staining fluid that weight is formed in conventional heating.
2. bright white liquor:
A, with Bi(NO)
3Weight is 1 to be that 5 rosin, weight are that 14 perfume oil mixes with weight, and it is 20 bismuth liquid that weight is formed in conventional heating.
B, with Ptcl
3Weight is 1 to be that 9 sulphur content are that 3～5% vulcanized oil mixes with weight, and forming weight at low temperature (4 ℃) is 10 platinum liquid.
C, with Rhcl
3NH
2O weight is 1 to be that 9 sulphur content are that 3～5% vulcanized oil mixes with weight, and it is 10 rhodium liquid that weight is formed in conventional heating.
D, get that rhodium liquid weight is 10 respectively, platinum liquid weight is 10, bismuth liquid weight is 20, stirs through thorough mixing, forms weight and be 40 bright white liquor.
3, organic solvent: get chloroform weight respectively and be 100, naphthane weight is 5, acetone weight is 5 to mix, form weight and be 110 organic solvent.
Two, imitative Jinsui River of mixed preparing: get bright white liquor weight respectively and be 40, staining fluid weight is 20, organic solvent weight is 110, through fully mixing, ageing one month promptly gets weight and is imitative Jinsui River of 170, is equivalent to 18～22K.
Three, imitative Jinsui River of technology of the present invention preparation blended, its performance meets the technological standard that Jinsui River is arranged, part surpasses, as wear resistance to such as table:
Numbering title friction number of times remarks
1 has Jinsui River 20 to carry out rub(bing)test by country's system Jinsui River standard, promptly uses
2 imitative Jinsui River 200 rub with the top felt material.
Claims (4)
1, a kind of with base metal, the imitative gold Jinsui River of rare earth metal composition, it is characterized in that:
The composition of A, bright white liquor is:
With Bi (No)
3Weight is 1, rosin weight is 2～5, perfume oil weight is 8～15 to mix, and bismuth liquid is formed in conventional heating; With Ptcl
3Weight is 1, sulphur content is that 3～5% vulcanized oil weight is 8～15 to mix, and forms platinum liquid at low temperature (4 ℃); With Rhcl
3NH
2O weight is 1, sulphur content is that 3～5% vulcanized oil weight is 8～15 to mix, and rhodium liquid is formed in conventional heating;
The composition of B, staining fluid is:
With the weight of the base metal of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or tungsten and rare earth metal salt be 1, rosin weight is 2～5, perfume oil weight is 8～15 to mix, staining fluid is formed in conventional heating;
C, be 80～100 with chloroform weight, naphthane, acetone weight are 4～12 to mix, and form organic solvent.
2, imitative gold as claimed in claim 1 Jinsui River composition, it is characterized in that: its weight ratio of optimum formula scope of bright white liquor is a rhodium: platinum: bismuth=5～25: 5～35: 10～70.
3, imitative gold as claimed in claim 1 Jinsui River composition, it is characterized in that: the optimum formula scope of staining fluid is 50～80% of a bright white liquor.
4, imitative gold as claimed in claim 1 Jinsui River preparation of compositions method is characterized in that:
A, Bi(No)
3Weight be 1 be 2～5 with rosin weight, perfume oil weight is 8～15 to mix, bismuth liquid is formed in conventional heating; Ptcl
3Weight is 1 to be 8～15 to mix with vulcanized oil weight, forms platinum liquid at low temperature (4 ℃); Rhcl
3NH
2O weight is 1 to be 8～15 to mix with vulcanized oil weight, and rhodium liquid is formed in conventional heating, bismuth liquid, platinum liquid and rhodium liquid is mixed form bright white liquor;
The weight of B, iron, antimony, chromium, niobium, praseodymium, cerium, vanadium or tungsten base metal and rare earth metal salt is 1 to be that 8～15 perfume oil, weight are that 2～5 rosin mixes with weight, and staining fluid is formed in conventional heating;
C, chloroform weight are 80～100 to be 4～12 to mix with naphthane, acetone weight, form organic solvent;
D, with bright white liquor, staining fluid and organic solvent thorough mixing stir, ageing one month, make imitative gold Jinsui River.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105006 CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 85105006 CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1042700A CN1042700A (en) | 1990-06-06 |
| CN1022480C true CN1022480C (en) | 1993-10-20 |
Family
ID=4794193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 85105006 Expired - Fee Related CN1022480C (en) | 1985-07-02 | 1985-07-02 | Replacement of gold in golden water by base metal and rare-earth metal, and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1022480C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100488918C (en) * | 2006-04-28 | 2009-05-20 | 冯建光 | Method for preparing imitating gold water |
| CN102976789B (en) * | 2012-12-25 | 2015-01-14 | 景德镇陶瓷学院 | Green liquid luster |
| US10329845B2 (en) | 2013-12-06 | 2019-06-25 | Halliburton Energy Services, Inc. | Rotary drill bit including multi-layer cutting elements |
| CN107216165B (en) * | 2016-03-22 | 2019-09-06 | 何赋森 | A kind of ceramics conductive coating and its application method |
| CN116535237A (en) * | 2023-05-06 | 2023-08-04 | 湖北新亚多联新材料有限公司 | High-temperature-resistant ceramic metal water and preparation method thereof |
-
1985
- 1985-07-02 CN CN 85105006 patent/CN1022480C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1042700A (en) | 1990-06-06 |
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| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |