CN1069478A - Jinsui River - Google Patents
Jinsui River Download PDFInfo
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- CN1069478A CN1069478A CN 91106515 CN91106515A CN1069478A CN 1069478 A CN1069478 A CN 1069478A CN 91106515 CN91106515 CN 91106515 CN 91106515 A CN91106515 A CN 91106515A CN 1069478 A CN1069478 A CN 1069478A
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Abstract
The present invention relates to the liquid decorative material of silicate products such as pottery, glass, enamel, be characterized in tin and rhodium or make refractory agent with tin merely, other components of Jinsui River have also been done the optimization adjustment according to the situation that tin is made refractory agent.The consumption of Jinsui River of the present invention, heatproof degree height, rhodium reduces by 65-100%, and production cost can reduce by 8% at least.Gold decorations film after the decoration firing meets the ceramic industry technological standard.
Description
The present invention relates to the liquid decorative material of silicate products such as pottery, glass and enamel.
Jinsui River is as the golden clothes jewelry of silicate product as pottery, glass etc., and it is the most convenient to use, and can directly scribble, mechanical printing or print to the surface of implements with other pigment cover, and consumption gold is minimum, and 600-700cm generally can be brushed in every gram Jinsui River
2Area.Jinsui River is since invention, the history in existing more than 100 year, research and development for a long time have Jinsui River of a great variety, that performance is different to come out in succession, but various Jinsui River all is evenly after the composition that ageing is handled by chromogenic reagent, toning agent, adhesive agent, refractory agent, weighting agent and solvent.At present, refractory agent is all made with rhodium in all Jinsui River, as U.S. China ink crane board (Hanorla) Jinsui River and German life board (Suncndmoou) Jinsui River.The price of metal rhodium is very expensive, source of goods shortage, and China is used to prepare about 10 kilograms of the required rhodium in various Jinsui River every year, and funds are surprising.For many years, all once carried out doing the research of refractory agent both at home and abroad with other metal substitute rhodium, Japanese Patent discloses for clear-No. 93567, use in Jinsui River at pottery, partly substitute rhodium with thorium and make refractory agent, with the consumption of minimizing rhodium, but thorium has radioactivity, high-temperature resistant is 700 ℃, far can not satisfy the use temperature requirement in ceramic Jinsui River.Price is also not cheap, so can not apply.
One of purpose of the present invention is that a kind of Jinsui River prescription of making refractory agent with tin and a small amount of rhodium is provided.
Two of purpose of the present invention is that a kind of Jinsui River prescription of making refractory agent with tin is provided.
Above-mentioned two kinds of Jinsui River, cost reduces, and the luminance brightness of metal decorations film improves.
Above-mentioned two kinds of Jinsui River, its technical characterstic are partly or entirely to substitute rhodium with tin to make refractory agent, and other components in Jinsui River have also been done the optimization adjustment according to the situation that tin is made refractory agent.
First kind of Jinsui River of the present invention, be chromogenic reagent, toning agent, adhesive agent, refractory agent, the composition that solvent and weighting agent constitute, the major technique feature is, make refractory agent with the rosinate of tin and the organic sulfide of rhodium, the mol ratio of tin and rhodium is 25-0.8, add-on (for organometallics, below all represent): 0.11-0.22 with the % of metallic element weight and Jinsui River gross weight, the organic resin salt of gold is chromogenic reagent, add-on is 8-12, the rosinate of chromium is a toning agent, and add-on is 0.02-0.07, and the rosinate of bismuth is an adhesive agent, add-on is 0.3-0.52, the 20-40% naphthane, 10-50% camphor oil, 5-10% pimelinketone, the terebinthine mixed solution of 5-10% is made solvent, add-on (following % with adding weight and Jinsui River gross weight represents) is 2-10, makes weighting agent with nitrated rosin, and add-on is 20-50.
Second kind of Jinsui River of the present invention, be chromogenic reagent, toning agent, adhesive agent, refractory agent, the composition that solvent and weighting agent constitute, its major technique feature is, rosinate with tin is made refractory agent, add-on is (for organometallics, below all represent with the % of metallic element weight and Jinsui River gross weight): 0.05-0.10, the organic resin salt of gold is chromogenic reagent, add-on 8-10, and the organic sulfide of the rosinate of chromium and silver is a toning agent, add-on is respectively 0.02-0.07 and 0.21-0.45, the rosinate of bismuth is an adhesive agent, and add-on is 0.30-0.52, the 20-40% naphthane, the 10-50% camphor oil, the 5-10% pimelinketone, the terebinthine mixed solution of 5-10% is made solvent, add-on is 2-10, (following all represent with the % that adds weight and Jinsui River gross weight) makes weighting agent with nitrated rosin, and add-on is 20-50.
For two kinds of above-mentioned Jinsui River,, can be resin acid gold, perfume oil sulfuration face cream gold, turps sulfuration face cream gold, mercaptan gold, with turps sulfuration face cream gold optimum as the organic resin salt of the gold of chromogenic reagent.
For first kind of above-mentioned Jinsui River, the mol ratio of refractory agent tin, rhodium the best is 10.7-1.2.
For first kind of above-mentioned Jinsui River, the add-on of the rosinate of toning agent chromium is preferably 0.02-0.05.
First kind of above-mentioned Jinsui River, the add-on of the rosinate of adhesive agent bismuth is preferably 0.30-0.45.
Above-mentioned first kind of Jinsui River, the organic resin salt of chromogenic reagent gold are turps sulfuration face cream gold.
Second kind of above-mentioned Jinsui River, the add-on of the organic sulfide of the rosinate of toning agent chromium and silver preferably is respectively 0.02-0.05 and 0.21-0.31.
Second kind of above-mentioned Jinsui River, the add-on of the rosinate of adhesive agent bismuth is preferably 0.30-0.45.
Second kind of above-mentioned Jinsui River, the organic resin salt of chromogenic reagent gold are turps sulfuration face cream gold.
Two kinds of Jinsui River of the present invention prescription, make full use of the heat resistance of tin rosinate, provided and be adapted to rational Jinsui River prescription that the tin rosinate is made refractory agent, satisfied the heatproof degree requirement in Jinsui River, the consumption of rhodium reduces 65-100%, and production cost can reduce by 8% at least.The heatproof temperature in first kind of Jinsui River is 850 ℃, and second kind of Jinsui River heatproof temperature is 800 ℃, and the gold decorations film after the decoration firing meets the ceramic industry technological standard.
The method for preparing above-mentioned Jinsui River can be:
1, be 1 with tin protochloride weight, with weight be the rosin of 2-6, weight is the organic solvent of 8-15, Hybrid Heating generates the tin refractory agent.
2, be 1 with rhodium chloride weight, with the vulcanized oil of weight 2-6 sulphur content 8-15%, Hybrid Heating is formed the rhodium refractory agent, is made into tin rhodium refractory agent in the ratio of the mol ratio 10.7-1.2 of tin/rhodium.
3, with chromium chloride weight be 1 with weight be 2-5 rosin, weight is the 8-15 organic solvent, Hybrid Heating is formed toning agent.
4, with Bismuth trinitrate weight be 1 with weight be 2-5 rosin, weight is that 8-15 organic solvent Hybrid Heating makes adhesive agent.
5, with Silver Nitrate weight be 1 with weight be the vulcanized oil of 2-6 sulphur content 8-15%, Hybrid Heating is formed toning agent.
6, be 1 with gold trichloride weight, adding weight is the vulcanized oil of 2-6 sulphur content 8-15%, and Hybrid Heating is formed chromogenic reagent.
7, be 1 with rosin weight, adding weight is 0.3 gram, and concentration is rare nitric acid of 30%, and weight is the 1-1.5 organic solvent, and Hybrid Heating is formed weighting agent.
8, be 20-40 with naphthane weight, camphor oil weight 10-50, pimelinketone weight is 5-10, turps weight is 5-10, mixes and forms organic solvent.
9, with the golden hair toner, mix refractory agent, toning agent and adhesive agent, weighting agent, the organic solvent thorough mixing stirs, and one week of ageing promptly gets Jinsui River.
The embodiment of the invention:
Example 1 porcelain is used Jinsui River
Get 48 portions of golden hair toners respectively, 12 parts of resin bismuths, 1 part of resin chromium, 5 parts are mixed refractory agent, 30 parts of nitrated rosin, through fully mixing, in one week of ageing, the composition metal content is Au12%, Bl0.36%, Cr0.02%, Sn0.1%, the porcelain of Rh0.02% is used 100 parts in Jinsui River.
Example 2 porcelain are used Jinsui River
Get 32 parts of Gold Contents, 25% golden hair toner respectively, 14 parts of bismuth-containing amount 3% resin bismuths, 1.2 parts of chrome content 2% resin chromium, 5.6 part mixing refractory agent, 44 parts of nitrated rosin, 3.2 parts of organic solvents are through fully mixing, one week of ageing, the composition metal content is Au8%, Bl0.42%, Cr0.02%, Sn0.12%, the porcelain of Rh0.03% is used Jinsui River.
Example 3 soft-paste are used Jinsui River
Get 40 parts of Gold Contents, 25% golden hair toner respectively, 13 parts of bismuth-containing amount 3% resin bismuths, 3.5 parts of chrome content 2% resin chromium, 3.1 part stanniferous amount 2.6% resin tin, 6.6 parts of silver content 3% resin silver, 32 parts of nitrated rosin, 3.8 part organic solvent, through fully mixing, in one week of ageing, the composition metal content is Au10%, Bl0.39%, Cr0.07%, Sn0.08%, 100 parts in low-temp ceramics Jinsui River of Ag0.2%.
Claims (13)
1, a kind of Jinsui River, the composition for chromogenic reagent, toning agent, adhesive agent, refractory agent, solvent and weighting agent constitute is characterized in that:
A makes refractory agent with the rosinate of tin and the organic sulfide of rhodium, and the mol ratio of tin and rhodium is 25-0.8, and add-on is (for an organometallics, below all represent with the % of metallic element weight and Jinsui River gross weight): 0.11-0.22,
The organic resin salt of B gold is chromogenic reagent, and add-on is 8-12,
The rosinate of C chromium is a toning agent, and add-on is 0.02-0.07,
The rosinate of D bismuth is an adhesive agent, and add-on is 0.30-0.52,
E20-40% naphthane, 10-50% camphor oil, 5-10% cyclohexanone, the terebinthine mixed solution of 5-10% are made solvent, and add-on (following all represent with the % that adds weight and Jinsui River gross weight) is 2-10,
The nitrated rosin of F is weighting agent, and add-on is 20-50.
According to the described Jinsui River of claim 1, it is characterized in that 2, the mol ratio of described refractory agent tin, rhodium is 10.7-1.2.
According to claim 1 or 2 described Jinsui River, it is characterized in that 3, toning agent chromium rosinate add-on is 0.02-0.05.
According to claim 1 or 2 described Jinsui River, it is characterized in that 4, the add-on of adhesive agent bismuth rosinate is 0.30-0.45.
According to the described Jinsui River of claim 3, it is characterized in that 5, the add-on of the rosinate of adhesive agent bismuth is 0.30-0.45.
According to claim 1 or 2 or 5 described Jinsui River, it is characterized in that 6, the organic resin salt of chromogenic reagent gold is turps sulfuration face cream gold.
According to the described Jinsui River of claim 3, it is characterized in that 7, the organic resin salt of chromogenic reagent gold is turps sulfuration face cream gold.
According to the described Jinsui River of claim 4, it is characterized in that 8, the organic resin salt of chromogenic reagent gold is turps sulfuration face cream gold.
9, a kind of Jinsui River, the composition for chromogenic reagent, toning agent, adhesive agent, refractory agent, solvent, weighting agent constitute is characterized in that:
A makes refractory agent with the rosinate of tin, add-on (for organometallics, below all represent): 0.05-0.10 with the % of metallic element weight and Jinsui River gross weight,
B is a chromogenic reagent with the organic resin salt of gold, add-on 8-10,
C is a toning agent with the rosinate of chromium and the organic sulfide of silver, and add-on is respectively 0.02-0.07 and 0.21-0.45,
The rosinate of D bismuth is an adhesive agent, and add-on is 0.30-0.52,
E 20-40% naphthane, 10-50% white oil of camphor, 5-10% pimelinketone, the terebinthine mixed solution of 5-10% are made solvent, add-on (following all represent): 2-10 with the % that adds weight and Jinsui River gross weight,
The nitrated rosin of F is weighting agent, and add-on is 20-50.
According to the described Jinsui River of claim 9, it is characterized in that 10, the add-on of the organic sulfide of the rosinate of toning agent chromium and silver is respectively 0.02-0.05 and 0.21-0.31.
According to claim 9 or 10 described Jinsui River, it is characterized in that 11, the add-on of the rosinate of adhesive agent bismuth is 0.30-0.45.
According to claim 9 or 10 described Jinsui River, it is characterized in that 12, the organic resin salt of chromogenic reagent gold is turps sulfuration face cream gold.
According to the described Jinsui River of claim 11, it is characterized in that 13, the organic resin salt of chromogenic reagent gold is turps sulfuration face cream gold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106515 CN1069478A (en) | 1991-08-13 | 1991-08-13 | Jinsui River |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106515 CN1069478A (en) | 1991-08-13 | 1991-08-13 | Jinsui River |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1069478A true CN1069478A (en) | 1993-03-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91106515 Pending CN1069478A (en) | 1991-08-13 | 1991-08-13 | Jinsui River |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112735631A (en) * | 2020-12-21 | 2021-04-30 | 有研工程技术研究院有限公司 | Low-viscosity organic gold paste capable of being sintered on surface of circuit board substrate at low temperature |
-
1991
- 1991-08-13 CN CN 91106515 patent/CN1069478A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112735631A (en) * | 2020-12-21 | 2021-04-30 | 有研工程技术研究院有限公司 | Low-viscosity organic gold paste capable of being sintered on surface of circuit board substrate at low temperature |
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