CN116535237A - High-temperature-resistant ceramic metal water and preparation method thereof - Google Patents
High-temperature-resistant ceramic metal water and preparation method thereof Download PDFInfo
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- CN116535237A CN116535237A CN202310501013.6A CN202310501013A CN116535237A CN 116535237 A CN116535237 A CN 116535237A CN 202310501013 A CN202310501013 A CN 202310501013A CN 116535237 A CN116535237 A CN 116535237A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 152
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 113
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 113
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 113
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical class [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000003921 oil Substances 0.000 claims abstract description 66
- 241001085205 Prenanthella exigua Species 0.000 claims abstract description 59
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical class [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 54
- 239000010937 tungsten Chemical class 0.000 claims abstract description 54
- MPOKJOWFCMDRKP-UHFFFAOYSA-N gold;hydrate Chemical compound O.[Au] MPOKJOWFCMDRKP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 41
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical class [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000004043 dyeing Methods 0.000 claims abstract description 37
- 239000000945 filler Substances 0.000 claims abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 36
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052797 bismuth Chemical class 0.000 claims abstract description 31
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical class [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 31
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 23
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000010692 aromatic oil Substances 0.000 claims abstract description 21
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 18
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 18
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 18
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 18
- 239000011651 chromium Substances 0.000 claims abstract description 18
- 229910052802 copper Inorganic materials 0.000 claims abstract description 18
- 239000010949 copper Substances 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 18
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 18
- 239000010955 niobium Substances 0.000 claims abstract description 18
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 18
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 18
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 16
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 16
- 239000004863 Frankincense Substances 0.000 claims abstract description 16
- 229930008380 camphor Natural products 0.000 claims abstract description 16
- 229960000846 camphor Drugs 0.000 claims abstract description 16
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 150000003568 thioethers Chemical class 0.000 claims abstract description 11
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- -1 phthalic acid ester Chemical class 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 58
- 239000000243 solution Substances 0.000 claims description 39
- 238000010438 heat treatment Methods 0.000 claims description 35
- 238000003756 stirring Methods 0.000 claims description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
- 238000004821 distillation Methods 0.000 claims description 15
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 15
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 14
- 239000001739 pinus spp. Substances 0.000 claims description 14
- 229940036248 turpentine Drugs 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 10
- 238000011049 filling Methods 0.000 claims description 10
- 239000011261 inert gas Substances 0.000 claims description 10
- 229910017604 nitric acid Inorganic materials 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 239000012192 staining solution Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 7
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 6
- XOKSLPVRUOBDEW-UHFFFAOYSA-N pinane Chemical compound CC1CCC2C(C)(C)C1C2 XOKSLPVRUOBDEW-UHFFFAOYSA-N 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 239000001293 FEMA 3089 Substances 0.000 claims description 4
- 235000011609 Pinus massoniana Nutrition 0.000 claims description 4
- 241000018650 Pinus massoniana Species 0.000 claims description 4
- 229930006728 pinane Natural products 0.000 claims description 3
- 235000005205 Pinus Nutrition 0.000 claims 2
- 241000218602 Pinus <genus> Species 0.000 claims 2
- 235000008582 Pinus sylvestris Nutrition 0.000 claims 1
- 241000218626 Pinus sylvestris Species 0.000 claims 1
- 239000001839 pinus sylvestris Substances 0.000 claims 1
- 239000011214 refractory ceramic Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 abstract description 4
- 239000010931 gold Substances 0.000 abstract description 4
- 238000005282 brightening Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 5
- 241000018646 Pinus brutia Species 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 235000005018 Pinus echinata Nutrition 0.000 description 2
- 241001236219 Pinus echinata Species 0.000 description 2
- 235000017339 Pinus palustris Nutrition 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4511—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application using temporarily supports, e.g. decalcomania transfers or mould surfaces
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/84—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses high-temperature-resistant ceramic metal water which comprises the following raw materials in parts by weight: 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, the nitrified rosin filling agent, and the dissolved oil consists of tetralin, camphor oil-frankincense, cyclohexanone, phthalic acid ester and cyclohexanol. The invention also discloses a preparation method of the high-temperature-resistant ceramic metal water. The invention prepares ceramic gold water by using the brightening liquid, the dyeing liquid, the nitrified rosin filling agent and the dissolved oil, and the gold water containing gold has good golden brightness, strong oxidation resistance and bowl washing resistance.
Description
Technical Field
The invention belongs to the technical field of ceramic printing, and particularly relates to high-temperature-resistant ceramic metal water and a preparation method thereof.
Background
The ceramic gold water is mainly used for ceramic appearance decoration and is suitable for direct painting, mechanical scribing border, spraying and other technical methods, ceramic gold water pigment information: the ceramic metal water is mainly used for decorating the dielectric line drawing edges, has the characteristics of Yan Sejin brightness, noble metal content and the like, is mainly used for decorating the ceramic appearance, and is suitable for direct painting, mechanical scribing boundary edge, spraying and other technical methods.
The existing ceramic gold water and the preparation method thereof have some problems: in the traditional process, gold metal is often added to prepare ceramic gold water, so that the production cost is increased, meanwhile, due to single material, the high temperature resistance is reduced when the ceramic gold water is used for printing, and in addition, the glossiness of the ceramic gold water coated on the surface of the ceramic is lower, so that the use effect is affected.
Disclosure of Invention
The invention aims to provide high-temperature-resistant ceramic metal water and a preparation method thereof, which are used for solving the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions: the high-temperature-resistant ceramic gold water comprises the following raw materials in parts by weight: 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, the nitrified rosin filling agent, and the dissolved oil consists of tetralin, camphor oil-frankincense, cyclohexanone, phthalic acid ester and cyclohexanol.
Preferably, the composition comprises the following raw materials in parts by weight: 35 parts of bright white liquid, 15 parts of dyeing liquid, 40 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99 percent and 18 parts of dissolved oil.
The invention also provides a preparation method of the high-temperature-resistant ceramic metal water, which comprises the following steps:
s1, preparing a bright white liquid: mixing organic sulfides of salts of iridium, tungsten, platinum and bismuth to obtain bright white liquid;
s2, preparing a staining solution: mixing resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper with aromatic oil and rosin to obtain a dyeing liquid;
s3, preparing dissolved oil: mixing tetrahydronaphthalene, camphor oil-olibanum, cyclohexanone, phthalic acid ester and cyclohexanol to obtain dissolved oil;
s4, preparing a nitrified rosin filling agent: raw rosin is heated and melted, nitric acid is dripped in the proportion of rosin to nitric acid=400 to 3 in parts by weight, solid nitrified rosin is obtained after the reaction, and then the nitrified rosin filler is obtained by dissolving and mixing the solid nitrified rosin in the proportion of nitrified rosin to dissolved oil=1 to 0.4-1 in parts by weight;
s5, preparing ceramic gold water: mixing the bright white liquid in the S1, the dyeing liquid in the S2, the nitrified rosin filler in the S4 and the gold powder, and aging for 20-40 days to obtain the high-temperature-resistant ceramic gold water.
Preferably, the preparation of the bright white liquor in the step S1 specifically comprises the following steps:
s101, preparing iridium liquid: mixing 1-3 parts by weight of iridium with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and stirring uniformly to obtain iridium liquid;
s102, preparing tungsten liquid: mixing 1-3 parts by weight of tungsten with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and uniformly stirring to obtain tungsten liquid;
s103, preparing a platinum solution: mixing 1-3 parts by weight of platinum with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and uniformly stirring at the temperature of-4 ℃ to obtain platinum liquid;
s104, preparing bismuth liquid: mixing 1-3 parts by weight of iridium solution with 4-6 parts by weight of rosin and 12-16 parts by weight of aromatic oil, and heating and uniformly stirring the bismuth solution;
s105, preparing bright white liquor: and fully mixing and stirring the iridium solution in S101, the tungsten solution in S102, the platinum solution in S103 and the bismuth solution in S104 to obtain a bright white liquid finished product.
Preferably, the bright white liquid prepared in S105 comprises 5-8 parts by weight of iridium liquid, 5-8 parts by weight of tungsten liquid, 10-16 parts by weight of platinum liquid and 20-30 parts by weight of bismuth liquid.
Preferably, the specific steps of preparing the staining solution in S2 are as follows: 1-3 parts of resinates of metals such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper and rare earth metals, 12-16 parts of aromatic oil and 3-6 parts of rosin are mixed by weight, heated and stirred uniformly to obtain the dyeing liquid.
Preferably, the specific steps for preparing the dissolved oil in S3 are as follows: the raw materials are taken according to the following weight parts, the tetrahydronaphthalene is 30-50 parts, the camphor oil-frankincense is 20-40 parts, the cyclohexanone is 5-15 parts, the phthalate is 8-16 parts, the cyclohexanol is 8-16 parts, and the raw materials are uniformly mixed and stirred to obtain the dissolved oil.
Preferably, the specific steps of preparing the ceramic gold water in the step S5 are as follows: the raw materials are taken according to the following weight parts, 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil are taken, and the bright white liquid finished product is obtained after fully mixing and stirring.
Preferably, the preparation method of the rosin comprises the following steps:
s201, according to 1: mixing Colophonium and solvent at a mass ratio of 0.4-0.8, heating for dissolving, and filtering to obtain Colophonium liquid;
s202, transferring the rosin liquid into a distillation pot;
s203, before distillation is started, detecting the air tightness of the distillation device;
s204, after the air tightness of the device is confirmed to be perfect, adjusting the vacuum degree of the device to-0.1 to-0.095 megapascals, heating to 190-220 ℃ at the heating rate of 1-1.5 ℃/min, closing the vacuum after 10-30 min, filling inert gas until the pressure of the device is zero, and removing turpentine in the turpentine storage tank;
s205, starting vacuum, adjusting the vacuum degree in the device to be 60-180 Pa, slowly heating to 210-230 ℃, preserving heat and distilling for 30-40 minutes, filling inert gas until the pressure of the device is zero, and collecting the distilled residue to obtain rosin.
Preferably, the rosin in S201 is one or more of masson pine resin, wet pine resin, indonesia pine resin and southern pine resin; the solvent is one or more of turpentine oil, turpentine middle oil and pinane.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the ceramic gold water is prepared by the brightening liquid, the dyeing liquid, the nitrified rosin filling agent and the dissolved oil, the gold-containing gold water has good golden brightness and strong oxidation resistance, is resistant to washing by a dish washing machine, and simultaneously reduces the production cost.
Drawings
FIG. 1 is a flow chart of the present invention.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
Referring to fig. 1, the present invention provides a technical solution: the high-temperature-resistant ceramic gold water comprises the following raw materials in parts by weight: 30 parts of bright white liquid, 10 parts of dyeing liquid, 30 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 10 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of the resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, and the nitrified rosin filling agent, and the dissolved oil consists of tetrahydronaphthalene, camphor oil-frankincense, cyclohexanone, phthalate and cyclohexanol.
The invention also provides a preparation method of the high-temperature-resistant ceramic metal water, which comprises the following steps:
s1, preparing a bright white liquid: mixing organic sulfides of salts of iridium, tungsten, platinum and bismuth to obtain bright white liquid;
s2, preparing a staining solution: mixing resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper with aromatic oil and rosin to obtain a dyeing liquid;
s3, preparing dissolved oil: mixing tetrahydronaphthalene, camphor oil-olibanum, cyclohexanone, phthalic acid ester and cyclohexanol to obtain dissolved oil;
s4, preparing a nitrified rosin filling agent: raw rosin is heated and melted, nitric acid is dripped in the proportion of rosin to nitric acid=400 to 3 in parts by weight, solid nitrified rosin is obtained after the reaction, and then the nitrified rosin is dissolved and mixed in the proportion of nitrified rosin to dissolved oil=1 to 0.4 in parts by weight, so that the nitrified rosin filler is obtained;
s5, preparing ceramic gold water: mixing the bright white liquid in the step S1, the dyeing liquid in the step S2, the nitrified rosin filler in the step S4 and the gold powder, and aging for 20 days to obtain the high-temperature-resistant ceramic gold water.
In this embodiment, preferably, the preparation of the bright white liquid in S1 specifically includes the following steps:
s101, preparing iridium liquid: mixing 1 part by weight of iridium with 7 parts by weight of vulcanized oil with the sulfur content of 3%, and heating and stirring uniformly to obtain iridium liquid;
s102, preparing tungsten liquid: mixing 1 part by weight of tungsten with 7 parts by weight of vulcanized oil with the sulfur content of 3%, and heating and uniformly stirring to obtain tungsten liquid;
s103, preparing a platinum solution: mixing 1 part by weight of platinum with 7 parts by weight of vulcanized oil with the sulfur content of 3%, and uniformly stirring at the temperature of-4 ℃ to obtain a platinum solution;
s104, preparing bismuth liquid: mixing 1 part by weight of iridium solution with 4 parts by weight of rosin and 12 parts by weight of aromatic oil, and heating and uniformly stirring the mixture to obtain bismuth solution;
s105, preparing bright white liquor: and fully mixing and stirring the iridium solution in S101, the tungsten solution in S102, the platinum solution in S103 and the bismuth solution in S104 to obtain a bright white liquid finished product.
In this embodiment, preferably, the bright white liquid prepared in S105 includes 5 parts by weight of iridium liquid, 5 parts by weight of tungsten liquid, 10 parts by weight of platinum liquid, and 20 parts by weight of bismuth liquid.
In this embodiment, preferably, the specific steps for preparing the staining solution in S2 are: the dyeing liquid is prepared by mixing 1 part by weight of resinates of metals such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper and rare earth metals, 12 parts by weight of aromatic oil and 3 parts by weight of rosin, heating and stirring uniformly.
In this embodiment, preferably, the specific steps for preparing the dissolved oil in S3 are: the raw materials are taken according to the following weight portions, the tetrahydronaphthalene is 30 portions, the camphor oil-frankincense is 20 portions, the cyclohexanone is 5 portions, the phthalate is 8 portions and the cyclohexanol is 8 portions, and the raw materials are mixed and stirred uniformly to obtain the dissolved oil.
In this embodiment, preferably, the specific steps of preparing the ceramic gold water in S5 are: the raw materials are taken according to the following weight parts, 30 parts of bright white liquid, 10 parts of dyeing liquid, 30 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99% and 10 parts of dissolved oil are taken, and the bright white liquid finished product is obtained after fully mixing and stirring.
In this embodiment, preferably, the preparation method of the rosin includes the following steps:
s201, according to 1: mixing rosin and solvent uniformly in a mass ratio of 0.4, heating for dissolving, and filtering to obtain rosin liquid;
s202, transferring the rosin liquid into a distillation pot;
s203, before distillation is started, detecting the air tightness of the distillation device;
s204, after the air tightness of the device is confirmed to be perfect, adjusting the vacuum degree of the device to-0.1 megapascal, heating to 190 ℃ at a heating rate of 1 ℃/min, closing the vacuum after 10 min, filling inert gas until the pressure of the device is zero, and removing turpentine in the turpentine storage tank;
s205, starting vacuum, adjusting the vacuum degree in the device to be 60 Pa, slowly heating to 210 ℃, preserving heat and distilling for 30 minutes, filling inert gas until the pressure of the device is zero, and collecting the residue to obtain rosin.
In this embodiment, preferably, the rosin in S201 is pinus massoniana rosin; the solvent is turpentine oil.
Example 2
Referring to fig. 1, the present invention provides a technical solution: the high-temperature-resistant ceramic gold water comprises the following raw materials in parts by weight: 40 parts of bright white liquid, 20 parts of dyeing liquid, 50 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 25 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of the resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, and the nitrified rosin filling agent, and the dissolved oil consists of tetrahydronaphthalene, camphor oil-frankincense, cyclohexanone, phthalate and cyclohexanol.
The invention also provides a preparation method of the high-temperature-resistant ceramic metal water, which comprises the following steps:
s1, preparing a bright white liquid: mixing organic sulfides of salts of iridium, tungsten, platinum and bismuth to obtain bright white liquid;
s2, preparing a staining solution: mixing resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper with aromatic oil and rosin to obtain a dyeing liquid;
s3, preparing dissolved oil: mixing tetrahydronaphthalene, camphor oil-olibanum, cyclohexanone, phthalic acid ester and cyclohexanol to obtain dissolved oil;
s4, preparing a nitrified rosin filling agent: raw rosin is heated and melted, nitric acid is dripped in the proportion of rosin to nitric acid=400 to 3 in parts by weight, solid nitrified rosin is obtained after the reaction, and then the nitrified rosin is dissolved and mixed in the proportion of nitrified rosin to dissolved oil=1 to 1 in parts by weight, so that the nitrified rosin filler is obtained;
s5, preparing ceramic gold water: mixing the bright white liquid in the step S1, the dyeing liquid in the step S2, the nitrified rosin filler in the step S4 and the gold powder, and aging for 40 days to obtain the high-temperature-resistant ceramic gold water.
In this embodiment, preferably, the preparation of the bright white liquid in S1 specifically includes the following steps:
s101, preparing iridium liquid: mixing 3 parts by weight of iridium with 10 parts by weight of vulcanized oil with the sulfur content of 5%, and heating and stirring uniformly to obtain iridium liquid;
s102, preparing tungsten liquid: mixing 3 parts by weight of tungsten with 10 parts by weight of vulcanized oil with the sulfur content of 5%, and heating and uniformly stirring to obtain tungsten liquid;
s103, preparing a platinum solution: mixing 3 parts by weight of platinum with 10 parts by weight of vulcanized oil with the sulfur content of 5%, and uniformly stirring at the temperature of-4 ℃ to obtain a platinum solution;
s104, preparing bismuth liquid: 3 parts by weight of iridium liquid, 6 parts by weight of rosin and 16 parts by weight of aromatic oil are mixed, heated and stirred uniformly to form bismuth liquid;
s105, preparing bright white liquor: and fully mixing and stirring the iridium solution in S101, the tungsten solution in S102, the platinum solution in S103 and the bismuth solution in S104 to obtain a bright white liquid finished product.
In this embodiment, preferably, the bright white liquid prepared in S105 includes 8 parts by weight of iridium liquid, 8 parts by weight of tungsten liquid, 16 parts by weight of platinum liquid, and 30 parts by weight of bismuth liquid.
In this embodiment, preferably, the specific steps for preparing the staining solution in S2 are: 3 parts by weight of resinates of metals such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper and rare earth metals are mixed with 16 parts by weight of aromatic oil and 6 parts by weight of rosin, and the mixture is heated and stirred uniformly to obtain the dyeing liquid.
In this embodiment, preferably, the specific steps for preparing the dissolved oil in S3 are: the raw materials are taken according to the following weight parts, 50 parts of tetrahydronaphthalene, 40 parts of camphor oil-frankincense, 15 parts of cyclohexanone, 16 parts of phthalate and 16 parts of cyclohexanol, and the raw materials are mixed and stirred uniformly to obtain the dissolved oil.
In this embodiment, preferably, the specific steps of preparing the ceramic gold water in S5 are: the raw materials are taken according to the following weight parts, 40 parts of bright white liquid, 20 parts of dyeing liquid, 50 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99% and 25 parts of dissolved oil are taken, and the bright white liquid finished product is obtained after fully mixing and stirring.
In this embodiment, preferably, the preparation method of the rosin includes the following steps:
s201, according to 1: mixing rosin and solvent uniformly in a mass ratio of 0.8, heating for dissolving, and filtering to obtain rosin liquid;
s202, transferring the rosin liquid into a distillation pot;
s203, before distillation is started, detecting the air tightness of the distillation device;
s204, after the air tightness of the device is confirmed to be perfect, adjusting the vacuum degree of the device to-0.095 megapascals, heating to 220 ℃ at a heating rate of 1.5 ℃/min, closing the vacuum after 30 min, filling inert gas until the pressure of the device is zero, and removing turpentine in the turpentine storage tank;
s205, starting vacuum, adjusting the vacuum degree in the device to be 180 Pa, slowly heating to 230 ℃, preserving heat and distilling for 40 minutes, filling inert gas until the pressure of the device is zero, and collecting the residue to obtain rosin.
In this embodiment, preferably, the rosin in S201 is wet pine rosin; the solvent is turpentine medium oil.
Example 3
Referring to fig. 1, the present invention provides a technical solution: the high-temperature-resistant ceramic gold water comprises the following raw materials in parts by weight: 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, the nitrified rosin filling agent, and the dissolved oil consists of tetralin, camphor oil-frankincense, cyclohexanone, phthalic acid ester and cyclohexanol.
The invention also provides a preparation method of the high-temperature-resistant ceramic metal water, which comprises the following steps:
s1, preparing a bright white liquid: mixing organic sulfides of salts of iridium, tungsten, platinum and bismuth to obtain bright white liquid;
s2, preparing a staining solution: mixing resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper with aromatic oil and rosin to obtain a dyeing liquid;
s3, preparing dissolved oil: mixing tetrahydronaphthalene, camphor oil-olibanum, cyclohexanone, phthalic acid ester and cyclohexanol to obtain dissolved oil;
s4, preparing a nitrified rosin filling agent: raw rosin is heated and melted, nitric acid is dripped in the proportion of rosin to nitric acid=400 to 3 in parts by weight, solid nitrified rosin is obtained after the reaction, and then the nitrified rosin filler is obtained by dissolving and mixing the solid nitrified rosin in the proportion of nitrified rosin to dissolved oil=1 to 0.4-1 in parts by weight;
s5, preparing ceramic gold water: mixing the bright white liquid in the S1, the dyeing liquid in the S2, the nitrified rosin filler in the S4 and the gold powder, and aging for 20-40 days to obtain the high-temperature-resistant ceramic gold water.
In this embodiment, preferably, the preparation of the bright white liquid in S1 specifically includes the following steps:
s101, preparing iridium liquid: mixing 1-3 parts by weight of iridium with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and stirring uniformly to obtain iridium liquid;
s102, preparing tungsten liquid: mixing 1-3 parts by weight of tungsten with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and uniformly stirring to obtain tungsten liquid;
s103, preparing a platinum solution: mixing 1-3 parts by weight of platinum with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and uniformly stirring at the temperature of-4 ℃ to obtain platinum liquid;
s104, preparing bismuth liquid: mixing 1-3 parts by weight of iridium solution with 4-6 parts by weight of rosin and 12-16 parts by weight of aromatic oil, and heating and uniformly stirring the bismuth solution;
s105, preparing bright white liquor: and fully mixing and stirring the iridium solution in S101, the tungsten solution in S102, the platinum solution in S103 and the bismuth solution in S104 to obtain a bright white liquid finished product.
In this embodiment, preferably, the bright white liquid prepared in S105 includes 5-8 parts by weight of iridium liquid, 5-8 parts by weight of tungsten liquid, 10-16 parts by weight of platinum liquid, and 20-30 parts by weight of bismuth liquid.
In this embodiment, preferably, the specific steps for preparing the staining solution in S2 are: 1-3 parts of resinates of metals such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper and rare earth metals, 12-16 parts of aromatic oil and 3-6 parts of rosin are mixed by weight, heated and stirred uniformly to obtain the dyeing liquid.
In this embodiment, preferably, the specific steps for preparing the dissolved oil in S3 are: the raw materials are taken according to the following weight parts, the tetrahydronaphthalene is 30-50 parts, the camphor oil-frankincense is 20-40 parts, the cyclohexanone is 5-15 parts, the phthalate is 8-16 parts, the cyclohexanol is 8-16 parts, and the raw materials are uniformly mixed and stirred to obtain the dissolved oil.
In this embodiment, preferably, the specific steps of preparing the ceramic gold water in S5 are: the raw materials are taken according to the following weight parts, 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil are taken, and the bright white liquid finished product is obtained after fully mixing and stirring.
In this embodiment, preferably, the preparation method of the rosin includes the following steps:
s201, according to 1: mixing Colophonium and solvent at a mass ratio of 0.4-0.8, heating for dissolving, and filtering to obtain Colophonium liquid;
s202, transferring the rosin liquid into a distillation pot;
s203, before distillation is started, detecting the air tightness of the distillation device;
s204, after the air tightness of the device is confirmed to be perfect, adjusting the vacuum degree of the device to-0.1 to-0.095 megapascals, heating to 190-220 ℃ at the heating rate of 1-1.5 ℃/min, closing the vacuum after 10-30 min, filling inert gas until the pressure of the device is zero, and removing turpentine in the turpentine storage tank;
s205, starting vacuum, adjusting the vacuum degree in the device to be 60-180 Pa, slowly heating to 210-230 ℃, preserving heat and distilling for 30-40 minutes, filling inert gas until the pressure of the device is zero, and collecting the distilled residue to obtain rosin.
In this embodiment, preferably, the rosin in S201 is one or more of masson pine resin, wet pine resin, indonesia pine resin and southern pine resin; the solvent is one or more of turpentine oil, turpentine middle oil and pinane.
The principle and the advantages of the invention are that:
according to the invention, the ceramic gold water is prepared by the brightening liquid, the dyeing liquid, the nitrified rosin filling agent and the dissolved oil, the gold-containing gold water has good golden brightness and strong oxidation resistance, is resistant to washing by a dish washing machine, and simultaneously reduces the production cost.
The following experiments were carried out by selecting the conventional process of the ceramic gold water and the ceramic gold water of the process of the invention, the contents and the results of the experiments are shown in the following table
It can be found through various experiments that the high temperature resistance, the adhesion and the brightness of the ceramic gold water prepared in the embodiment 1, the embodiment 2 and the embodiment 3 are all improved, the production cost is reduced, and the embodiment 2 is the best embodiment.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. A high temperature resistant ceramic metal water is characterized in that: comprises the following raw materials in parts by weight: 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filling agent, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil, wherein the bright white liquid consists of organic sulfides of salts of iridium, tungsten, platinum and bismuth, the dyeing liquid consists of resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper, the mixture of aromatic oil and rosin, the nitrified rosin filling agent, and the dissolved oil consists of tetralin, camphor oil-frankincense, cyclohexanone, phthalic acid ester and cyclohexanol.
2. The refractory ceramic hot metal according to claim 1, wherein: comprises the following raw materials in parts by weight: 35 parts of bright white liquid, 15 parts of dyeing liquid, 40 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99 percent and 18 parts of dissolved oil.
3. A preparation method of high-temperature-resistant ceramic gold water is characterized by comprising the following steps: the method comprises the following steps:
s1, preparing a bright white liquid: mixing organic sulfides of salts of iridium, tungsten, platinum and bismuth to obtain bright white liquid;
s2, preparing a staining solution: mixing resinates of iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper with aromatic oil and rosin to obtain a dyeing liquid;
s3, preparing dissolved oil: mixing tetrahydronaphthalene, camphor oil-olibanum, cyclohexanone, phthalic acid ester and cyclohexanol to obtain dissolved oil;
s4, preparing a nitrified rosin filling agent: raw rosin is heated and melted, nitric acid is dripped in the proportion of rosin to nitric acid=400 to 3 in parts by weight, solid nitrified rosin is obtained after the reaction, and then the nitrified rosin filler is obtained by dissolving and mixing the solid nitrified rosin in the proportion of nitrified rosin to dissolved oil=1 to 0.4-1 in parts by weight;
s5, preparing ceramic gold water: mixing the bright white liquid in the S1, the dyeing liquid in the S2, the nitrified rosin filler in the S4 and the gold powder, and aging for 20-40 days to obtain the high-temperature-resistant ceramic gold water.
4. The method for preparing the high-temperature-resistant ceramic gold water according to claim 3, which is characterized in that: the preparation of the bright white liquor in the step S1 specifically comprises the following steps:
s101, preparing iridium liquid: mixing 1-3 parts by weight of iridium with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and stirring uniformly to obtain iridium liquid;
s102, preparing tungsten liquid: mixing 1-3 parts by weight of tungsten with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and heating and uniformly stirring to obtain tungsten liquid;
s103, preparing a platinum solution: mixing 1-3 parts by weight of platinum with 7-10 parts by weight of vulcanized oil with the sulfur content of 3-5%, and uniformly stirring at the temperature of-4 ℃ to obtain platinum liquid;
s104, preparing bismuth liquid: mixing 1-3 parts by weight of iridium solution with 4-6 parts by weight of rosin and 12-16 parts by weight of aromatic oil, and heating and uniformly stirring the bismuth solution;
s105, preparing bright white liquor: and fully mixing and stirring the iridium solution in S101, the tungsten solution in S102, the platinum solution in S103 and the bismuth solution in S104 to obtain a bright white liquid finished product.
5. The method for preparing the high-temperature-resistant ceramic gold water according to claim 4, which is characterized in that: the bright white liquid prepared in the step S105 comprises 5-8 parts by weight of iridium liquid, 5-8 parts by weight of tungsten liquid, 10-16 parts by weight of platinum liquid and 20-30 parts by weight of bismuth liquid.
6. The method for preparing the high-temperature-resistant ceramic gold water according to claim 3, which is characterized in that: the specific steps of the preparation of the staining solution in the step S2 are as follows: 1-3 parts of resinates of metals such as iron, antimony, chromium, niobium, praseodymium, cerium, vanadium, tungsten and copper and rare earth metals, 12-16 parts of aromatic oil and 3-6 parts of rosin are mixed by weight, heated and stirred uniformly to obtain the dyeing liquid.
7. The method for preparing the high-temperature-resistant ceramic gold water according to claim 3, which is characterized in that: the specific steps for preparing the dissolved oil in the step S3 are as follows: the raw materials are taken according to the following weight parts, the tetrahydronaphthalene is 30-50 parts, the camphor oil-frankincense is 20-40 parts, the cyclohexanone is 5-15 parts, the phthalate is 8-16 parts, the cyclohexanol is 8-16 parts, and the raw materials are uniformly mixed and stirred to obtain the dissolved oil.
8. The method for preparing the high-temperature-resistant ceramic gold water according to claim 3, which is characterized in that: the specific steps of the preparation of the ceramic gold water in the step S5 are as follows: the raw materials are taken according to the following weight parts, 30-40 parts of bright white liquid, 10-20 parts of dyeing liquid, 30-50 parts of nitrified rosin filler, 5-8 parts of gold powder with the purity of more than 99.99% and 10-25 parts of dissolved oil are taken, and the bright white liquid finished product is obtained after fully mixing and stirring.
9. The method for preparing the high-temperature-resistant ceramic gold water according to claim 3, which is characterized in that: the preparation method of the rosin comprises the following steps:
s201, according to 1: mixing Colophonium and solvent at a mass ratio of 0.4-0.8, heating for dissolving, and filtering to obtain Colophonium liquid;
s202, transferring the rosin liquid into a distillation pot;
s203, before distillation is started, detecting the air tightness of the distillation device;
s204, after the air tightness of the device is confirmed to be perfect, adjusting the vacuum degree of the device to-0.1 to-0.095 megapascals, heating to 190-220 ℃ at the heating rate of 1-1.5 ℃/min, closing the vacuum after 10-30 min, filling inert gas until the pressure of the device is zero, and removing turpentine in the turpentine storage tank;
s205, starting vacuum, adjusting the vacuum degree in the device to be 60-180 Pa, slowly heating to 210-230 ℃, preserving heat and distilling for 30-40 minutes, filling inert gas until the pressure of the device is zero, and collecting the distilled residue to obtain rosin.
10. The method for preparing the high-temperature-resistant ceramic gold water according to claim 9, which is characterized in that: the rosin in the step S201 is one or more of Pinus massoniana rosin, pinus martensii rosin, pinus indicus rosin and Pinus sylvestris rosin; the solvent is one or more of turpentine oil, turpentine middle oil and pinane.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042700A (en) * | 1985-07-02 | 1990-06-06 | 魏忠汉 | Base metal, alkene earth metals replacement of gold in golden water and preparation method |
| CN1065281A (en) * | 1991-03-23 | 1992-10-14 | 山东省硅酸盐研究设计院 | Silvery white rare-earth ceramic metal coating |
| CN1069478A (en) * | 1991-08-13 | 1993-03-03 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN105111939A (en) * | 2015-09-29 | 2015-12-02 | 广西梧州日成林产化工股份有限公司 | Preparation method of rosin |
-
2023
- 2023-05-06 CN CN202310501013.6A patent/CN116535237A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042700A (en) * | 1985-07-02 | 1990-06-06 | 魏忠汉 | Base metal, alkene earth metals replacement of gold in golden water and preparation method |
| CN1065281A (en) * | 1991-03-23 | 1992-10-14 | 山东省硅酸盐研究设计院 | Silvery white rare-earth ceramic metal coating |
| CN1069478A (en) * | 1991-08-13 | 1993-03-03 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN105111939A (en) * | 2015-09-29 | 2015-12-02 | 广西梧州日成林产化工股份有限公司 | Preparation method of rosin |
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