CN104261794A - Handicraft clay sculpture material and preparation method thereof - Google Patents
Handicraft clay sculpture material and preparation method thereof Download PDFInfo
- Publication number
- CN104261794A CN104261794A CN201410475610.7A CN201410475610A CN104261794A CN 104261794 A CN104261794 A CN 104261794A CN 201410475610 A CN201410475610 A CN 201410475610A CN 104261794 A CN104261794 A CN 104261794A
- Authority
- CN
- China
- Prior art keywords
- weight
- weight part
- parts
- clay sculpture
- handicraft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004927 clay Substances 0.000 title claims abstract description 57
- 239000000463 material Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 56
- 239000000843 powder Substances 0.000 claims abstract description 55
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 54
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 34
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 28
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 28
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 28
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000010445 mica Substances 0.000 claims abstract description 28
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 28
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 28
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 24
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 24
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 24
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910021538 borax Inorganic materials 0.000 claims abstract description 21
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 21
- 239000010440 gypsum Substances 0.000 claims abstract description 17
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 26
- 239000004021 humic acid Substances 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 16
- 159000000000 sodium salts Chemical class 0.000 claims description 16
- 235000010216 calcium carbonate Nutrition 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 abstract description 3
- 239000010453 quartz Substances 0.000 abstract description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 235000013312 flour Nutrition 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
Landscapes
- Dental Preparations (AREA)
- Toys (AREA)
Abstract
The invention discloses a handicraft clay sculpture material. The handicraft clay sculpture material is prepared from the following raw materials in parts by weight: 2-3 parts by weight of borax, 1-2 parts by weight of ammonium dihydrogen phosphate, 4-6 parts by weight of magnesium oxide, 0.5-1 part by weight of aluminum chloride, 0.5-1 part by weight of sodium humate, 50-60 parts by weight of kaolin, 10-20 parts by weight of calcium carbonate, 30-40 parts by weight of quartz powder, 10-20 parts by weight of white mica powder, 1-3 parts by weight of gypsum, 0.5-1 part by weight of hydroxyethyl cellulose and water, wherein the total amount of the water is the required amount for realizing a dough-like plastic state of a product. The handicraft clay sculpture material disclosed by the invention can be used under any conditions, has the advantages of reasonable and scientific formula, easiness in obtainment of the raw materials, low cost and easiness in dispersion and stirring, the surface of a work is less prone to cracking in a hardening process and is dense and smooth, and the handicraft clay sculpture material can be widely used in the fields of sculptures, clay sculptures, models and the like. The invention further discloses a preparation method of the handicraft clay sculpture material, and the preparation method has the advantages of simple process steps and strong operability.
Description
Technical field
The present invention relates to clay sculpture technical field, especially relate to a kind of handicraft clay sculpture material and preparation method thereof.
Background technology
Clay sculpture artwork is of a great variety, with a long history, is our people's art form loved by all, has strong place of china characteristic.Traditional clay sculpture material is raw material with clay, adds various auxiliary agent, water use regulation viscosity.But traditional clay sculpture hardened material time is long, general to need several days or longer, easily cause artwork to be out of shape, heap collapses, be shorten setting time, usually carry out heat setting to artwork, heat setting energy consumption is high, and very easily causes handicraft surface to ftracture.
Authorization Notice No. CN102887696B, the Chinese patent of authorized announcement date 2014.04.23 discloses a kind of self-hardening sculpture clay and preparation method thereof, this self-hardening sculpture clay comprises following raw materials according and makes: nano-kaoline 5 weight part, magnesium oxide 1-2 weight part, magnesium chloride 1-0.5 weight part, dry pulp 1-0.5 weight part, sticky rice flour 1-0.5 weight part, total Water is aequum.Its weak point is: this sculpture clay setting time is long, ability sclerosis at least 8 hours; Sticky rice flour is added to improve cohesive strength in this sculpture clay, but sticky rice flour is high at temperature, high humidity time easily ferment, mildew, corrupt, sticky rice flour after fermentation has acid smell, surface blistering, long green hair, viscosity reduces greatly, affect the processing that bonds normally, the application of this sculpture clay is restricted, simultaneously, sticky rice flour is conglomeration very easily, not easily dispersed with stirring; This sculpture clay is in process of setting, and surface is easy to crack.
Summary of the invention
The present invention is the problems referred to above existing for the clay sculpture material in order to solve prior art, and provide the reasonable science of a kind of formula, raw material is easy to get, cost is low, plasticity-and cohesive force good, can harden voluntarily, surface handicraft clay sculpture material not easy to crack in process of setting.
Present invention also offers a kind of preparation method of handicraft clay sculpture material, the method processing step is simple, workable.
To achieve these goals, the present invention is by the following technical solutions:
A kind of handicraft clay sculpture material, is made up of the raw material of following weight part: 2 ~ 3 weight part boraxs, 1 ~ 2 parts by weight of phosphoric acid ammonium dihydrogen, 4 ~ 6 weight part magnesium oxide, 0.5 ~ 1 weight part aluminum chloride, 0.5 ~ 1 weight part Sodium salts humic acids, 50 ~ 60 parts by weight kaolin clay, 10 ~ 20 weight parts of calcium carbonate, 30 ~ 40 weight part silica powders, 10 ~ 20 weight part white mica powders, 1 ~ 3 weight part gypsum, 0.5 ~ 1 weight part Natvosol, total Water is become the aequum of dough plastic stage to product.In handicraft clay sculpture material of the present invention, primary ammonium phosphate can with magnesium oxide generation hydration reaction, generate water-fast product, along with the carrying out of hydration reaction, product is constantly grown up and is cross-linked with each other, final formation has the cured body of some strength, primary ammonium phosphate can be able to make clay sculpture material of the present invention harden with magnesium oxide, follow-up sinter-hardened without the need to carrying out again, but primary ammonium phosphate can with magnesian hydration reaction speed quickly, make the operability of material poor, shaping inconvenience, and be unfavorable for repairing works improving, therefore borax is added in the present invention to address this problem, borax plays the effect of slow setting, the setting and harden time of the present invention can be slowed down, be conducive to improving operability, primary ammonium phosphate and magnesian proportioning very crucial, if magnesium oxide very little, the non-complete reaction of primary ammonium phosphate after material cured, works intensity difference, be unfavorable for shaping, and magnesium oxide is too many, speed of response is too fast, make between operational zone too little, be unfavorable for using, therefore primary ammonium phosphate and magnesian add-on must strictly be controlled to ensure to make clay sculpture material of the present invention have good performance index, AL in aluminum chloride
3+product can be made to form crosslinked tridimensional network, be conducive to the raising of cured body intensity, Sodium salts humic acids can improve plasticity-and the binding ability of clay sculpture material of the present invention, reduces works distortion, works also can be avoided to ftracture in dry process of setting, kaolin, calcium carbonate, silica powder, white mica powder forms the pug in clay sculpture material of the present invention jointly, by kaolin, calcium carbonate, quartz, synergy between white mica powder, can improve plasticity-and the binding ability of clay sculpture material of the present invention, thus meet the requirement of moulding process, gypsum can improve formability and the intensity of clay sculpture material of the present invention, and makes work surface fine and close smooth and do not play ash, does not shrink, flawless in process of setting, can improve the quality of works, Natvosol has the effect of water conservation, thickening, thickening, is not only conducive to formability and the plasticity-of improving clay sculpture material of the present invention, but also can avoids the phenomenon that works cause work surface to ftracture because inside and outside moisture evaporation speed is inconsistent.
As preferably, described magnesian particle diameter is 5 ~ 10 μm.Magnesian size affects the solidification rate of clay sculpture material of the present invention, particle is less, solidification rate is faster, time of coagulation is shorter, be unfavorable for that carrying out repairing to works improves, and particle is larger, plasticity-and the operability of clay sculpture material of the present invention reduce, and work surface is comparatively coarse, of poor quality, therefore the present invention must by magnesian size controlling at 5 ~ 10 μm.
As preferably, described borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 40 ~ 100 orders.
A preparation method for handicraft clay sculpture material, comprises the following steps:
(1) by 2 ~ 3 weight part boraxs, 1 ~ 2 parts by weight of phosphoric acid ammonium dihydrogen, 4 ~ 6 weight part magnesium oxide, 0.5 ~ 1 weight part aluminum chloride, 0.5 ~ 1 weight part Sodium salts humic acids, 50 ~ 60 parts by weight kaolin clay, 10 ~ 20 weight parts of calcium carbonate, 30 ~ 40 weight part silica powders, 10 ~ 20 weight part white mica powders, 1 ~ 3 weight part gypsum, after the weight of 0.5 ~ 1 weight part Natvosol takes each raw material, kaolin, calcium carbonate, silica powder are mixed with white mica powder, obtains pug;
(2) borax, primary ammonium phosphate are mixed with magnesium oxide, obtain solidifying substance;
(3), after pug, solidifying substance being mixed with aluminum chloride, Sodium salts humic acids, gypsum, Natvosol, add the water of aequum, be constantly stirred to into dough plastic stage product.
As preferably, in step (2), magnesian particle diameter is 5 ~ 10 μm.
As preferably, described borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 40 ~ 100 orders.
Therefore, the beneficial effect that the present invention has is: can use under any condition, and the plastic time is 2 ~ 3h, both ensure that enough time allowed creator carry out repairing to works and improves, shorten setting time again, in addition, the reasonable science of handicraft clay sculpture material prescription of the present invention, raw material is easy to get, cost is low, easily disperses to stir, and in process of setting, work surface not easily produces dry and cracked, surface compact is smooth, can be widely used in the fields such as sculpture, clay sculpture, model.
Embodiment
Below by embodiment, the present invention will be further described.
Embodiment 1
A kind of handicraft clay sculpture material, be made up of the raw material of following weight part: 3 weight part boraxs, 2 parts by weight of phosphoric acid ammonium dihydrogens, 6 weight part magnesium oxide, 1 weight part aluminum chloride, 1 weight part Sodium salts humic acids, 60 parts by weight kaolin clay, 20 weight parts of calcium carbonate, 40 weight part silica powders, 20 weight part white mica powders, 3 weight part gypsum, 1 weight part Natvosol, total Water is become the aequum of dough plastic stage to product, and wherein, magnesian particle diameter is 10 μm, borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 100 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) borax, kaolin, calcium carbonate, silica powder and white mica powder are crossed 100 mesh sieves respectively, magnesium oxide is crossed the sieve that aperture is 10 μm, after taking borax, primary ammonium phosphate, magnesium oxide, aluminum chloride, Sodium salts humic acids, kaolin, calcium carbonate, silica powder, white mica powder, gypsum and Natvosol by above-mentioned weight proportion, kaolin, calcium carbonate, silica powder and white mica powder are mixed, obtains pug.
(2) borax, primary ammonium phosphate are mixed with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed with aluminum chloride, Sodium salts humic acids, gypsum, Natvosol, add the water of aequum, be constantly stirred to into dough plastic stage product, can for sculpture, clay sculpture etc.
Embodiment 2
A kind of handicraft clay sculpture material, be made up of the raw material of following weight part: 2 weight part boraxs, 1 parts by weight of phosphoric acid ammonium dihydrogen, 4 weight part magnesium oxide, 0.5 weight part aluminum chloride, 0.5 weight part Sodium salts humic acids, 50 parts by weight kaolin clay, 10 weight parts of calcium carbonate, 30 weight part silica powders, 10 weight part white mica powders, 1 weight part gypsum, 0.5 weight part Natvosol, total Water is become the aequum of dough plastic stage to product, and wherein, magnesian particle diameter is 5 μm, borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 40 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) borax, kaolin, calcium carbonate, silica powder and white mica powder are crossed 40 mesh sieves respectively, magnesium oxide is crossed the sieve that aperture is 5 μm, after taking borax, primary ammonium phosphate, magnesium oxide, aluminum chloride, Sodium salts humic acids, kaolin, calcium carbonate, silica powder, white mica powder, gypsum and Natvosol by above-mentioned weight proportion, kaolin, calcium carbonate, silica powder and white mica powder are mixed, obtains pug.
(2) borax, primary ammonium phosphate are mixed with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed with aluminum chloride, Sodium salts humic acids, gypsum, Natvosol, add the water of aequum, be constantly stirred to into dough plastic stage product, can for sculpture, clay sculpture etc.
Embodiment 3
A kind of handicraft clay sculpture material, be made up of the raw material of following weight part: 2.5 weight part boraxs, 1.5 parts by weight of phosphoric acid ammonium dihydrogens, 5 weight part magnesium oxide, 0.6 weight part aluminum chloride, 0.7 weight part Sodium salts humic acids, 55 parts by weight kaolin clay, 15 weight parts of calcium carbonate, 35 weight part silica powders, 12 weight part white mica powders, 2 weight part gypsum, 0.8 weight part Natvosol, total Water is become the aequum of dough plastic stage to product, wherein, magnesian particle diameter is 6 μm, borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 60 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) borax, kaolin, calcium carbonate, silica powder and white mica powder are crossed respectively 60 mesh sieves and magnesium oxide is crossed the sieve that aperture is 6 μm, after taking borax, primary ammonium phosphate, magnesium oxide, aluminum chloride, Sodium salts humic acids, kaolin, calcium carbonate, silica powder, white mica powder, gypsum and Natvosol by above-mentioned weight proportion, kaolin, calcium carbonate, silica powder and white mica powder are mixed, obtains pug.
(2) borax, primary ammonium phosphate are mixed with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed with aluminum chloride, Sodium salts humic acids, gypsum, Natvosol, add the water of aequum, be constantly stirred to into dough plastic stage product, can for sculpture, clay sculpture etc.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.
Claims (6)
1. a handicraft clay sculpture material, it is characterized in that, be made up of the raw material of following weight part: 2 ~ 3 weight part boraxs, 1 ~ 2 parts by weight of phosphoric acid ammonium dihydrogen, 4 ~ 6 weight part magnesium oxide, 0.5 ~ 1 weight part aluminum chloride, 0.5 ~ 1 weight part Sodium salts humic acids, 50 ~ 60 parts by weight kaolin clay, 10 ~ 20 weight parts of calcium carbonate, 30 ~ 40 weight part silica powders, 10 ~ 20 weight part white mica powders, 1 ~ 3 weight part gypsum, 0.5 ~ 1 weight part Natvosol, total Water is become the aequum of dough plastic stage to product.
2. a kind of handicraft clay sculpture material according to claim 1, it is characterized in that, described magnesian particle diameter is 5 ~ 10 μm.
3. a kind of handicraft clay sculpture material according to claim 1, it is characterized in that, described borax, kaolin, calcium carbonate, silica powder, the particle diameter of white mica powder is 40 ~ 100 orders.
4. a preparation method for handicraft clay sculpture material as claimed in claim 1, is characterized in that, comprise the following steps:
(1) by 2 ~ 3 weight part boraxs, 1 ~ 2 parts by weight of phosphoric acid ammonium dihydrogen, 4 ~ 6 weight part magnesium oxide, 0.5 ~ 1 weight part aluminum chloride, 0.5 ~ 1 weight part Sodium salts humic acids, 50 ~ 60 parts by weight kaolin clay, 10 ~ 20 weight parts of calcium carbonate, 30 ~ 40 weight part silica powders, 10 ~ 20 weight part white mica powders, 1 ~ 3 weight part gypsum, after the weight of 0.5 ~ 1 weight part Natvosol takes each raw material, kaolin, calcium carbonate, silica powder are mixed with white mica powder, obtains pug;
(2) borax, primary ammonium phosphate are mixed with magnesium oxide, obtain solidifying substance;
(3), after pug, solidifying substance being mixed with aluminum chloride, Sodium salts humic acids, gypsum, Natvosol, add the water of aequum, be constantly stirred to into dough plastic stage product.
5. preparation method according to claim 4, is characterized in that, in step (2), magnesian particle diameter is 5 ~ 10 μm.
6. preparation method according to claim 4, is characterized in that, described borax, kaolin, calcium carbonate, silica powder, and the particle diameter of white mica powder is 40 ~ 100 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410475610.7A CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410475610.7A CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104261794A true CN104261794A (en) | 2015-01-07 |
| CN104261794B CN104261794B (en) | 2016-06-29 |
Family
ID=52153416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410475610.7A Expired - Fee Related CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104261794B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462126A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Environment-friendly copper technology clay sculpture material and preparation method thereof |
| CN105461285A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Loess-dark loessial soil copper technology clay model and preparation method thereof |
| CN105504614A (en) * | 2015-12-15 | 2016-04-20 | 铜陵铜官府文化创意股份公司 | Loess-chernozem copper craft clay model and preparing method thereof |
| CN105541195A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Concussion crack-resistant copper artware clay sculpture material and preparation method thereof |
| CN105541285A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-kaolin copper artware clay sculpture model and preparation method thereof |
| CN105541196A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | High-strength copper artware clay sculpture material and preparation method thereof |
| CN105541283A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Anti-cracking copper artware clay sculpture material and preparation method thereof |
| CN105541284A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-white clay copper artware clay sculpture model and preparation method thereof |
| CN105859235A (en) * | 2016-03-30 | 2016-08-17 | 广西盈益环保建材科技股份有限公司 | Clay sculpture material and preparation method thereof |
| CN105948566A (en) * | 2016-04-29 | 2016-09-21 | 南京晨光艺术工程有限公司 | High-strength sculpture material formula |
| CN107640945A (en) * | 2017-11-02 | 2018-01-30 | 陈礼成 | It is a kind of can carving material and preparation method thereof in the high intensity room of rapid shaping |
| CN108609919A (en) * | 2018-04-26 | 2018-10-02 | 河南工学院 | A kind of handicraft clay sculpture material and preparation method thereof |
| CN108863195A (en) * | 2018-08-11 | 2018-11-23 | 湖南城市学院 | A kind of molding mud of artistic sculpture and preparation method thereof |
| CN110126530A (en) * | 2019-05-13 | 2019-08-16 | 湖南农业大学 | A kind of production method of art soil ball |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478390A (en) * | 1992-01-09 | 1995-12-26 | Cruaud; William | Cuttable concrete, its process of manufacture and its process of molding |
| CN1205312A (en) * | 1997-07-16 | 1999-01-20 | 吕淳锵 | Compsns. for mfg. carving material and carving material therefrom |
| CN1358789A (en) * | 2000-12-15 | 2002-07-17 | 刘孝慈 | Art and craft sculpture clay |
| CN102887696A (en) * | 2012-09-20 | 2013-01-23 | 金星铜集团有限公司 | Self-hardening sculpture mud and preparation method thereof |
| CN103342534A (en) * | 2013-06-13 | 2013-10-09 | 中北大学 | Sculpture material containing loess |
-
2014
- 2014-09-16 CN CN201410475610.7A patent/CN104261794B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478390A (en) * | 1992-01-09 | 1995-12-26 | Cruaud; William | Cuttable concrete, its process of manufacture and its process of molding |
| CN1205312A (en) * | 1997-07-16 | 1999-01-20 | 吕淳锵 | Compsns. for mfg. carving material and carving material therefrom |
| CN1358789A (en) * | 2000-12-15 | 2002-07-17 | 刘孝慈 | Art and craft sculpture clay |
| CN102887696A (en) * | 2012-09-20 | 2013-01-23 | 金星铜集团有限公司 | Self-hardening sculpture mud and preparation method thereof |
| CN103342534A (en) * | 2013-06-13 | 2013-10-09 | 中北大学 | Sculpture material containing loess |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541283A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Anti-cracking copper artware clay sculpture material and preparation method thereof |
| CN105462126A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Environment-friendly copper technology clay sculpture material and preparation method thereof |
| CN105504614A (en) * | 2015-12-15 | 2016-04-20 | 铜陵铜官府文化创意股份公司 | Loess-chernozem copper craft clay model and preparing method thereof |
| CN105541195A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Concussion crack-resistant copper artware clay sculpture material and preparation method thereof |
| CN105541285A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-kaolin copper artware clay sculpture model and preparation method thereof |
| CN105541196A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | High-strength copper artware clay sculpture material and preparation method thereof |
| CN105461285A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Loess-dark loessial soil copper technology clay model and preparation method thereof |
| CN105541284A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-white clay copper artware clay sculpture model and preparation method thereof |
| CN105859235A (en) * | 2016-03-30 | 2016-08-17 | 广西盈益环保建材科技股份有限公司 | Clay sculpture material and preparation method thereof |
| CN105948566A (en) * | 2016-04-29 | 2016-09-21 | 南京晨光艺术工程有限公司 | High-strength sculpture material formula |
| CN107640945A (en) * | 2017-11-02 | 2018-01-30 | 陈礼成 | It is a kind of can carving material and preparation method thereof in the high intensity room of rapid shaping |
| CN108609919A (en) * | 2018-04-26 | 2018-10-02 | 河南工学院 | A kind of handicraft clay sculpture material and preparation method thereof |
| CN108863195A (en) * | 2018-08-11 | 2018-11-23 | 湖南城市学院 | A kind of molding mud of artistic sculpture and preparation method thereof |
| CN108863195B (en) * | 2018-08-11 | 2020-11-24 | 惠安极地星空科技有限公司 | Molding mud for art sculpture and preparation method thereof |
| CN110126530A (en) * | 2019-05-13 | 2019-08-16 | 湖南农业大学 | A kind of production method of art soil ball |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104261794B (en) | 2016-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104261794B (en) | A kind of handicraft clay sculpture material and preparation method thereof | |
| CN104261777A (en) | Clay sculpture Buddha repair material and preparation method thereof | |
| CN103086738A (en) | Preparation method for gypsum mold raw materials and gypsum mold | |
| CN111574147B (en) | Formula and preparation method of snowflake white inorganic artificial stone raw material | |
| CN105693178A (en) | Method for preparing A3.5B05-grade autoclaved aerated concrete block by quartz weathered sand and application thereof to wall | |
| CN106082761A (en) | A kind of retardation setting type cement grinding aid | |
| CN105272134A (en) | Light-weight mildew-proof composite glass magnesium board and preparation method thereof | |
| CN107053447B (en) | A kind of maintenance process of cement products | |
| CN101941046A (en) | Composite sodium silicate binder for sand mold and preparing method thereof | |
| CN105060838A (en) | Lightweight mildew-resistant composite glass magnesium board and preparation method thereof | |
| CN107266000A (en) | A kind of interior wall render gypsum of cracking resistance and preparation method thereof | |
| CN106495554A (en) | A kind of preparation method of stable type alkali-free quick-coagulant | |
| CN104909706A (en) | Fracture-resistant glass magnesium board containing modifying agents such as EVA emulsion, and preparation method thereof | |
| CN105693185A (en) | Heat-insulation vermiculite artificial culture stone and preparation method thereof | |
| CN105837094B (en) | A kind of medium-sized fused cast refractories mo(u)ld blacking | |
| CN104891947A (en) | Additional-modifier-based magnesium oxide board capable of enhancing strength and preparation method thereof | |
| CN105541247A (en) | Modification technology of 3D printing-molded powder material | |
| CN108689603A (en) | Dry technology for production for ancient building glazed tiles | |
| CN105753420A (en) | A3.5B05 level autoclaved aerated concrete building block prepared from quartz weathered sand and application of building block to wall body | |
| KR100473783B1 (en) | Production method of artificial marble | |
| CN113149524A (en) | Energy-saving environment-friendly concrete member and preparation method thereof | |
| WO2016184323A1 (en) | Method for producing imitation wood and imitation stone series furniture having natural texture | |
| CN105170871A (en) | High-strength molding sand | |
| CN106734858A (en) | A kind of preparation method of the hard phosphate casting sand type of modified heat | |
| CN105127359A (en) | High-thermal-stability sand |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Kun Inventor before: Wu Chiyue |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160526 Address after: 450005 Huanghe Science and Technology College, No. 94 middle navigation road, 27 District, Henan, Zhengzhou Applicant after: Li Kun Address before: Song Shan Zhen Tang Xia Cun 322105 Zhejiang city of Dongyang province 1-63 Applicant before: Wu Chiyue |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161024 Address after: 450005 Huanghe Science and Technology College, No. 666 Zi Shan Road, Henan, Zhengzhou Patentee after: Huanghe S & T College Address before: 450005 Huanghe Science and Technology College, No. 94 middle navigation road, 27 District, Henan, Zhengzhou Patentee before: Li Kun |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160629 Termination date: 20160916 |