CN104261794B - A kind of handicraft clay sculpture material and preparation method thereof - Google Patents
A kind of handicraft clay sculpture material and preparation method thereof Download PDFInfo
- Publication number
- CN104261794B CN104261794B CN201410475610.7A CN201410475610A CN104261794B CN 104261794 B CN104261794 B CN 104261794B CN 201410475610 A CN201410475610 A CN 201410475610A CN 104261794 B CN104261794 B CN 104261794B
- Authority
- CN
- China
- Prior art keywords
- weight portion
- weight
- parts
- calcium carbonate
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004927 clay Substances 0.000 title claims abstract description 55
- 239000000463 material Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 56
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 55
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 34
- 235000013312 flour Nutrition 0.000 claims abstract description 32
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 28
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 28
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 28
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000010445 mica Substances 0.000 claims abstract description 28
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 28
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 28
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 24
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 24
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 24
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 17
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 17
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 17
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021538 borax Inorganic materials 0.000 claims description 20
- 239000004328 sodium tetraborate Substances 0.000 claims description 20
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 14
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 235000010216 calcium carbonate Nutrition 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 7
- 238000003756 stirring Methods 0.000 abstract description 3
- 241000209094 Oryza Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 3
- 235000012245 magnesium oxide Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
Landscapes
- Dental Preparations (AREA)
- Toys (AREA)
Abstract
The invention discloses a kind of handicraft clay sculpture material, it is made up of the raw material of following weight portion: 2～3 weight portion Boraxs, 1～2 parts by weight of phosphoric acid ammonium dihydrogen, 4～6 weight portion magnesium oxide, 0.5～1 weight portion aluminum chloride, 0.5～1 weight portion sodium humate, 50～60 parts by weight kaolin clay, 10～20 weight parts of calcium carbonate, 30～40 weight portion silica flours, 10～20 weight portion white mica powders, 1～3 weight portion Gypsum Fibrosum, 0.5～1 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product.The handicraft clay sculpture material of the present invention can use under any condition, the reasonable science of formula, and raw material is easy to get, and cost is low, easily disperses stirring, and in hardening process, work surface is not likely to produce dry and cracked, and surface compact is smooth, can be widely used for the fields such as sculpture, clay sculpture, model.The preparation method that the invention also discloses a kind of handicraft clay sculpture material, this preparation method processing step is simple, workable.
Description
Technical field
The present invention relates to clay sculpture technical field, especially relate to a kind of handicraft clay sculpture material and preparation method thereof.
Background technology
The clay sculpture art work is of a great variety, with a long history, is our people's artistic form loved by all, has strong place of china characteristic.Traditional clay sculpture material, with clay for raw material, adds various auxiliary agent, water use regulation viscosity.But traditional clay sculpture hardened material time is long, it is generally required to several days or longer, easily causing artware deformation, heap collapses, and for shortening firm time, generally carries out heat setting to artware, heat setting energy consumption is high, and very easily causes handicraft surface to ftracture.
Authorization Notice No. CN102887696B, the Chinese patent of authorized announcement date 2014.04.23 discloses a kind of self-hardening sculpture clay and preparation method thereof, this self-hardening sculpture clay includes following raw materials according and makes: nano-kaoline 5 weight portion, magnesium oxide 1-2 weight portion, magnesium chloride 1-0.5 weight portion, dry pulp 1-0.5 weight portion, glutinous rice flour 1-0.5 weight portion, total Water is aequum.It is disadvantageous in that: this sculpture clay firm time is long, within least 8 hours, could harden；This sculpture clay adds glutinous rice flour to improve adhesion strength, but glutinous rice flour is high at temperature, high humidity time easily ferment, mildew, corrupt, glutinous rice flour after fermentation has acid smell, surface blistering, long green hair, viscosity is substantially reduced, affect the processing that bonds normally so that the application of this sculpture clay is restricted, simultaneously, glutinous rice flour is conglomeration very easily, not easily dispersed with stirring；This sculpture clay is in hardening process, and surface is easy to crack.
Summary of the invention
The present invention is to solve the problems referred to above existing for the clay sculpture material of prior art, it is provided that a kind of reasonable science of formula, and raw material is easy to get, and cost is low, and plasticity is good with cohesive force, can harden voluntarily, the handicraft clay sculpture material that surface is not easy to crack in hardening process.
The preparation method that present invention also offers a kind of handicraft clay sculpture material, the method processing step is simple, workable.
To achieve these goals, the present invention is by the following technical solutions:
A kind of handicraft clay sculpture material, is made up of the raw material of following weight portion: 2～3 weight portion Boraxs, 1～2 parts by weight of phosphoric acid ammonium dihydrogen, 4～6 weight portion magnesium oxide, 0.5～1 weight portion aluminum chloride, 0.5～1 weight portion sodium humate, 50～60 parts by weight kaolin clay, 10～20 weight parts of calcium carbonate, 30～40 weight portion silica flours, 10～20 weight portion white mica powders, 1～3 weight portion Gypsum Fibrosum, 0.5～1 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product.In the handicraft clay sculpture material of the present invention, ammonium dihydrogen phosphate can with magnesium oxide generation hydration reaction, generate water-fast product, carrying out along with hydration reaction, product is constantly grown up and is cross-linked with each other, ultimately form the firming body with some strength, ammonium dihydrogen phosphate can make the clay sculpture material of the present invention harden with magnesium oxide, follow-up sinter-hardened without carrying out again, but ammonium dihydrogen phosphate can be very fast with magnesian hydration reaction speed, the operability making material is poor, molding inconvenience, and be unfavorable for works are repaired improving, therefore the present invention adds Borax to solve this problem, Borax plays the effect of slow setting, the condensation firm time of the present invention can be slowed down, be conducive to improving operability, ammonium dihydrogen phosphate is very crucial with magnesian proportioning, if magnesium oxide is very little, the non-complete reaction of ammonium dihydrogen phosphate after material solidification, works intensity difference, it is unfavorable for molding, and magnesium oxide is too many, response speed is too fast, make operating range too little, it is unfavorable for using, therefore ammonium dihydrogen phosphate must strictly be controlled with magnesian addition to ensure to make the clay sculpture material of the present invention have good performance indications；AL in aluminum chloride3+Product can be made to form the tridimensional network of crosslinking, be conducive to the raising of firming body intensity；Sodium humate can improve plasticity and the binding ability of clay sculpture material of the present invention, reduces works deformation, works also can be avoided to ftracture in dry hardening process；Kaolin, calcium carbonate, silica flour, white mica powder collectively forms the pug in clay sculpture material of the present invention, by Kaolin, calcium carbonate, quartz, synergism between white mica powder, can improve plasticity and the binding ability of the clay sculpture material of the present invention, thus meeting the requirement of moulding process；Gypsum Fibrosum can improve mouldability and the intensity of clay sculpture material of the present invention, and make work surface fine and close smooth and do not play ash, does not shrink, flawless in hardening process, can improve the quality of works；Hydroxyethyl cellulose has the effect of water conservation, thickening, thickening, not only contributes to improve mouldability and the plasticity of clay sculpture material of the present invention, but also can avoid the phenomenon that works cause work surface to ftracture because inside and outside moisture evaporation speed is inconsistent.
As preferably, described magnesian particle diameter is 5～10 μm.Magnesian size affects the solidification rate of clay sculpture material of the present invention, granule is more little, solidification rate is more fast, setting time is more short, is unfavorable for carrying out works repairing improving, and granule is more big, the plasticity of clay sculpture material of the present invention reduces with operability, and work surface is comparatively coarse, of poor quality, therefore the present invention must by magnesian size controlling at 5～10 μm.
As preferably, described Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 40～100 orders.
The preparation method of a kind of handicraft clay sculpture material, comprises the following steps:
(1) by 2～3 weight portion Boraxs, 1～2 parts by weight of phosphoric acid ammonium dihydrogen, 4～6 weight portion magnesium oxide, 0.5～1 weight portion aluminum chloride, 0.5～1 weight portion sodium humate, 50～60 parts by weight kaolin clay, 10～20 weight parts of calcium carbonate, 30～40 weight portion silica flours, 10～20 weight portion white mica powders, 1～3 weight portion Gypsum Fibrosum, after the weight of 0.5～1 weight portion hydroxyethyl cellulose weighs each raw material, Kaolin, calcium carbonate, silica flour are mixed homogeneously with white mica powder, obtains pug；
(2) Borax, ammonium dihydrogen phosphate are mixed homogeneously with magnesium oxide, obtain solidifying substance；
(3), after pug, solidifying substance being mixed homogeneously with aluminum chloride, sodium humate, Gypsum Fibrosum, hydroxyethyl cellulose, add the desired amount of water, be stirred continuously to become dough mouldable state product.
As preferably, in step (2), magnesian particle diameter is 5～10 μm.
As preferably, described Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 40～100 orders.
Therefore, the invention have the advantages that: can using under any condition, the plastic time is 2～3h, both ensure that enough time allowed creator carry out works repairing improvement, shorten again firm time, it addition, the handicraft reasonable science of clay sculpture material prescription of the present invention, raw material is easy to get, cost is low, easily disperses stirring, and in hardening process, work surface is not likely to produce dry and cracked, surface compact is smooth, can be widely used for the fields such as sculpture, clay sculpture, model.
Detailed description of the invention
Below by detailed description of the invention, the present invention will be further described.
Embodiment 1
A kind of handicraft clay sculpture material, it is made up of the raw material of following weight portion: 3 weight portion Boraxs, 2 parts by weight of phosphoric acid ammonium dihydrogens, 6 weight portion magnesium oxide, 1 weight portion aluminum chloride, 1 weight portion sodium humate, 60 parts by weight kaolin clay, 20 weight parts of calcium carbonate, 40 weight portion silica flours, 20 weight portion white mica powders, 3 weight portion Gypsum Fibrosum, 1 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product, and wherein, magnesian particle diameter is 10 μm, Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 100 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) Borax, Kaolin, calcium carbonate, silica flour and white mica powder are crossed respectively 100 mesh sieves, magnesium oxide is crossed the sieve that aperture is 10 μm, after weighing Borax, ammonium dihydrogen phosphate, magnesium oxide, aluminum chloride, sodium humate, Kaolin, calcium carbonate, silica flour, white mica powder, Gypsum Fibrosum and hydroxyethyl cellulose by above-mentioned weight proportion, by Kaolin, calcium carbonate, silica flour and white mica powder mix homogeneously, obtain pug.
(2) Borax, ammonium dihydrogen phosphate are mixed homogeneously with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed homogeneously with aluminum chloride, sodium humate, Gypsum Fibrosum, hydroxyethyl cellulose, add the desired amount of water, be stirred continuously to become dough mouldable state product, be available for sculpture, clay sculpture etc. use.
Embodiment 2
A kind of handicraft clay sculpture material, it is made up of the raw material of following weight portion: 2 weight portion Boraxs, 1 parts by weight of phosphoric acid ammonium dihydrogen, 4 weight portion magnesium oxide, 0.5 weight portion aluminum chloride, 0.5 weight portion sodium humate, 50 parts by weight kaolin clay, 10 weight parts of calcium carbonate, 30 weight portion silica flours, 10 weight portion white mica powders, 1 weight portion Gypsum Fibrosum, 0.5 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product, and wherein, magnesian particle diameter is 5 μm, Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 40 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) Borax, Kaolin, calcium carbonate, silica flour and white mica powder are crossed respectively 40 mesh sieves, magnesium oxide is crossed the sieve that aperture is 5 μm, after weighing Borax, ammonium dihydrogen phosphate, magnesium oxide, aluminum chloride, sodium humate, Kaolin, calcium carbonate, silica flour, white mica powder, Gypsum Fibrosum and hydroxyethyl cellulose by above-mentioned weight proportion, by Kaolin, calcium carbonate, silica flour and white mica powder mix homogeneously, obtain pug.
(2) Borax, ammonium dihydrogen phosphate are mixed homogeneously with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed homogeneously with aluminum chloride, sodium humate, Gypsum Fibrosum, hydroxyethyl cellulose, add the desired amount of water, be stirred continuously to become dough mouldable state product, be available for sculpture, clay sculpture etc. use.
Embodiment 3
A kind of handicraft clay sculpture material, it is made up of the raw material of following weight portion: 2.5 weight portion Boraxs, 1.5 parts by weight of phosphoric acid ammonium dihydrogens, 5 weight portion magnesium oxide, 0.6 weight portion aluminum chloride, 0.7 weight portion sodium humate, 55 parts by weight kaolin clay, 15 weight parts of calcium carbonate, 35 weight portion silica flours, 12 weight portion white mica powders, 2 weight portion Gypsum Fibrosum, 0.8 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product, and wherein, magnesian particle diameter is 6 μm, Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 60 orders.
The preparation method of this handicraft clay sculpture material, comprises the following steps:
(1) Borax, Kaolin, calcium carbonate, silica flour and white mica powder are crossed respectively 60 mesh sieves and magnesium oxide is crossed the sieve that aperture is 6 μm, after weighing Borax, ammonium dihydrogen phosphate, magnesium oxide, aluminum chloride, sodium humate, Kaolin, calcium carbonate, silica flour, white mica powder, Gypsum Fibrosum and hydroxyethyl cellulose by above-mentioned weight proportion, by Kaolin, calcium carbonate, silica flour and white mica powder mix homogeneously, obtain pug.
(2) Borax, ammonium dihydrogen phosphate are mixed homogeneously with magnesium oxide, obtain solidifying substance.
(3), after pug, solidifying substance being mixed homogeneously with aluminum chloride, sodium humate, Gypsum Fibrosum, hydroxyethyl cellulose, add the desired amount of water, be stirred continuously to become dough mouldable state product, be available for sculpture, clay sculpture etc. use.
Embodiment described above is the one preferably scheme of the present invention, not the present invention is done any pro forma restriction, also has other variant and remodeling under the premise without departing from the technical scheme described in claim.
Claims (4)
1. a handicraft clay sculpture material, it is characterized in that, it is made up of the raw material of following weight portion: 2～3 weight portion Boraxs, 1～2 parts by weight of phosphoric acid ammonium dihydrogen, 4～6 weight portion magnesium oxide, 0.5～1 weight portion aluminum chloride, 0.5～1 weight portion sodium humate, 50～60 parts by weight kaolin clay, 10～20 weight parts of calcium carbonate, 30～40 weight portion silica flours, 10～20 weight portion white mica powders, 1～3 weight portion Gypsum Fibrosum, 0.5～1 weight portion hydroxyethyl cellulose, total Water is become the aequum of dough mouldable state to product, and described magnesian particle diameter is 5～10 μm.
2. a kind of handicraft clay sculpture material according to claim 1, it is characterised in that described Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 40～100 orders.
3. the preparation method of a handicraft clay sculpture material as claimed in claim 1, it is characterised in that comprise the following steps:
(1) by 2～3 weight portion Boraxs, 1～2 parts by weight of phosphoric acid ammonium dihydrogen, 4～6 weight portion magnesium oxide, 0.5～1 weight portion aluminum chloride, 0.5～1 weight portion sodium humate, 50～60 parts by weight kaolin clay, 10～20 weight parts of calcium carbonate, 30～40 weight portion silica flours, 10～20 weight portion white mica powders, 1～3 weight portion Gypsum Fibrosum, after the weight of 0.5～1 weight portion hydroxyethyl cellulose weighs each raw material, Kaolin, calcium carbonate, silica flour are mixed homogeneously with white mica powder, obtains pug；
(2) Borax, ammonium dihydrogen phosphate are mixed homogeneously with magnesium oxide, obtain solidifying substance；
(3), after pug, solidifying substance being mixed homogeneously with aluminum chloride, sodium humate, Gypsum Fibrosum, hydroxyethyl cellulose, add the desired amount of water, be stirred continuously to become dough mouldable state product.
4. preparation method according to claim 3, it is characterised in that described Borax, Kaolin, calcium carbonate, silica flour, the particle diameter of white mica powder is 40～100 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410475610.7A CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410475610.7A CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104261794A CN104261794A (en) | 2015-01-07 |
| CN104261794B true CN104261794B (en) | 2016-06-29 |
Family
ID=52153416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410475610.7A Expired - Fee Related CN104261794B (en) | 2014-09-16 | 2014-09-16 | A kind of handicraft clay sculpture material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104261794B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541285A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-kaolin copper artware clay sculpture model and preparation method thereof |
| CN105504614A (en) * | 2015-12-15 | 2016-04-20 | 铜陵铜官府文化创意股份公司 | Loess-chernozem copper craft clay model and preparing method thereof |
| CN105541284A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Loess-white clay copper artware clay sculpture model and preparation method thereof |
| CN105541196A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | High-strength copper artware clay sculpture material and preparation method thereof |
| CN105462126A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Environment-friendly copper technology clay sculpture material and preparation method thereof |
| CN105541283A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Anti-cracking copper artware clay sculpture material and preparation method thereof |
| CN105541195A (en) * | 2015-12-15 | 2016-05-04 | 铜陵铜官府文化创意股份公司 | Concussion crack-resistant copper artware clay sculpture material and preparation method thereof |
| CN105461285A (en) * | 2015-12-15 | 2016-04-06 | 铜陵铜官府文化创意股份公司 | Loess-dark loessial soil copper technology clay model and preparation method thereof |
| CN105859235B (en) * | 2016-03-30 | 2018-10-26 | 厦门海石生态环境股份有限公司 | Mud material for carving on it and preparation method thereof |
| CN105948566A (en) * | 2016-04-29 | 2016-09-21 | 南京晨光艺术工程有限公司 | High-strength sculpture material formula |
| CN107640945A (en) * | 2017-11-02 | 2018-01-30 | 陈礼成 | It is a kind of can carving material and preparation method thereof in the high intensity room of rapid shaping |
| CN108609919A (en) * | 2018-04-26 | 2018-10-02 | 河南工学院 | A kind of handicraft clay sculpture material and preparation method thereof |
| CN108863195B (en) * | 2018-08-11 | 2020-11-24 | 惠安极地星空科技有限公司 | Molding mud for art sculpture and preparation method thereof |
| CN110126530A (en) * | 2019-05-13 | 2019-08-16 | 湖南农业大学 | A kind of production method of art soil ball |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2686112B1 (en) * | 1992-01-09 | 1994-05-06 | William Cruaud | PROCESS FOR THE MANUFACTURE AND FORMWORK OF A RETAILLABLE CONCRETE AND CONCRETE THUS OBTAINED. |
| CN1071289C (en) * | 1997-07-16 | 2001-09-19 | 吕淳锵 | Compsns. for mfg. carving material and carving material therefrom |
| CN1159375C (en) * | 2000-12-15 | 2004-07-28 | 刘孝慈 | Art and craft sculpture clay |
| CN102887696B (en) * | 2012-09-20 | 2014-04-23 | 金星铜集团有限公司 | Self-hardening sculpture mud and preparation method thereof |
| CN103342534B (en) * | 2013-06-13 | 2014-11-19 | 中北大学 | Sculpture material containing loess |
-
2014
- 2014-09-16 CN CN201410475610.7A patent/CN104261794B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104261794A (en) | 2015-01-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104261794B (en) | A kind of handicraft clay sculpture material and preparation method thereof | |
| CN104261777A (en) | Clay sculpture Buddha repair material and preparation method thereof | |
| CN103086738A (en) | Preparation method for gypsum mold raw materials and gypsum mold | |
| US20090163641A1 (en) | Natural aluminosilicate composites and aggregates synthesized in alkaline environment and their manufacturing process | |
| CN105384419B (en) | A kind of preparation method of antibacterial and antimildew function mortar | |
| CN111574147B (en) | Formula and preparation method of snowflake white inorganic artificial stone raw material | |
| CN108623268A (en) | A kind of self-heat-insulating bearing concrete and preparation method thereof based on 3D printing performance | |
| CN105693178A (en) | Method for preparing A3.5B05-grade autoclaved aerated concrete block by quartz weathered sand and application thereof to wall | |
| CN101941046B (en) | Composite sodium silicate binder for sand mold and preparing method thereof | |
| CN105272134A (en) | Light-weight mildew-proof composite glass magnesium board and preparation method thereof | |
| CN107053447B (en) | A kind of maintenance process of cement products | |
| CN105060838A (en) | Lightweight mildew-resistant composite glass magnesium board and preparation method thereof | |
| CN107266000A (en) | A kind of interior wall render gypsum of cracking resistance and preparation method thereof | |
| CN106495554A (en) | A kind of preparation method of stable type alkali-free quick-coagulant | |
| CN105753420B (en) | A3.5 B05 levels autoclave aerated concrete building blocks and its application on wall prepared by a kind of quartzy Weathered Sand | |
| WO2016184323A1 (en) | Method for producing imitation wood and imitation stone series furniture having natural texture | |
| CN105541247A (en) | Modification technology of 3D printing-molded powder material | |
| CN105837094B (en) | A kind of medium-sized fused cast refractories mo(u)ld blacking | |
| US1901052A (en) | Composition for molding investment inlays | |
| CN104909706A (en) | Fracture-resistant glass magnesium board containing modifying agents such as EVA emulsion, and preparation method thereof | |
| CN108689603A (en) | Dry technology for production for ancient building glazed tiles | |
| CN107459276A (en) | A kind of colorful dry granular piece preparation method of grinding stone for being used to manufacture stone-like coating | |
| KR20040035130A (en) | Production method of artificial marble | |
| CN105170871A (en) | High-strength molding sand | |
| CN106365543B (en) | A kind of diatom ooze powder and a kind of diatom ooze goods of furniture for display rather than for use and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Kun Inventor before: Wu Chiyue |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160526 Address after: 450005 Huanghe Science and Technology College, No. 94 middle navigation road, 27 District, Henan, Zhengzhou Applicant after: Li Kun Address before: Song Shan Zhen Tang Xia Cun 322105 Zhejiang city of Dongyang province 1-63 Applicant before: Wu Chiyue |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161024 Address after: 450005 Huanghe Science and Technology College, No. 666 Zi Shan Road, Henan, Zhengzhou Patentee after: Huanghe S & T College Address before: 450005 Huanghe Science and Technology College, No. 94 middle navigation road, 27 District, Henan, Zhengzhou Patentee before: Li Kun |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160629 Termination date: 20160916 |