CN108609919A - A kind of handicraft clay sculpture material and preparation method thereof - Google Patents

A kind of handicraft clay sculpture material and preparation method thereof Download PDF

Info

Publication number
CN108609919A
CN108609919A CN201810387196.2A CN201810387196A CN108609919A CN 108609919 A CN108609919 A CN 108609919A CN 201810387196 A CN201810387196 A CN 201810387196A CN 108609919 A CN108609919 A CN 108609919A
Authority
CN
China
Prior art keywords
parts
clay sculpture
raspberry
borax
handicraft
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810387196.2A
Other languages
Chinese (zh)
Inventor
刘燕
韩姗姗
毕慧娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Institute of Technology
Original Assignee
Henan Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Institute of Technology filed Critical Henan Institute of Technology
Priority to CN201810387196.2A priority Critical patent/CN108609919A/en
Publication of CN108609919A publication Critical patent/CN108609919A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/28Polysaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00956Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Confectionery (AREA)

Abstract

The invention discloses a kind of handicraft clay sculpture materials and preparation method thereof, include the raw material of following parts by weight:13 20 parts of 16 23 parts of borax, 8 14 parts of cocoanut shell, 6 10 parts of gelatine, 10 15 parts of plant amylum, 24 37 parts of plant ash, 58 parts of chitin, 12 16 parts of diatomite, 6 12 parts of agar, 8 15 parts of polyvinyl alcohol, 48 parts of lauryl sodium sulfate and raspberry.Raw material sources of the present invention are extensive, by the way that different raw materials is used different preparation processes, different products is stirred uniformly, adhesive, hardness, toughness and the gas permeability of product are enhanced using the synergistic effect between different material, it prevents from causing to crack and corrode for a long time outdoor, the holding time for extending clay sculpture maintains the integrated ornamental of clay sculpture.

Description

A kind of handicraft clay sculpture material and preparation method thereof
Technical field
The present invention relates to clay sculpture field, specifically a kind of handicraft clay sculpture material.
Background technology
There are many distinctive craftwork of China, clay sculpture is exactly one of which in China.Clay sculpture art work type is various, history is long-drawn-out Long, it is our people's art form loved by all, there is strong place of china characteristic.Clay sculpture is commonly called as " painted sculptures " clay sculpture skill Art is a kind of traditional ancient common folk art of folks of china.A kind of civil craft of various images is made of clay modeling Skill.Production method is that a little cotton fiber is mixed in clay, smash it is even after, kneading is coated at the moulded pottery not yet put in a kiln to bake of various personages through drying in the shade Bottom powder, then bedye and paint.It is shaped using soil as raw material with manual kneading, plain or color, based on personage, animal.Clay sculpture is in the people Between be commonly called as " painted sculptures ", " mud object for appreciation ".Clay sculpture rises in Baoji Fengxiang County, is popular in the ground such as Shaanxi, Tianjin, Jiangsu, Henan, and 2006 On May 20, in, clay sculpture was selected in first List of National Intangible Cultural Heritage.
The aesthetics of clay sculpture is good, but a period of time of current clay sculpture after making, it is easy to will be cracking Situation not only causes the waste of time and resource, can also influence the overall aesthetics of clay sculpture.
Invention content
The purpose of the present invention is to provide a kind of handicraft clay sculpture materials, to solve mentioned above in the background art ask Topic.
To achieve the above object, the present invention provides the following technical solutions:
A kind of handicraft clay sculpture material, includes the raw material of following parts by weight:16-23 parts of borax, 8-14 parts of cocoanut shell, gelatine 6-10 parts, it is 10-15 parts of plant amylum, 24-37 parts of plant ash, 5-8 parts of chitin, 12-16 parts of diatomite, 6-12 parts of agar, poly- 13-20 parts of 8-15 parts of vinyl alcohol, 4-8 parts of lauryl sodium sulfate and raspberry.
As a further solution of the present invention:Plant amylum includes green starch, cornstarch, sorghum starch, rice shallow lake One or several kinds of mixtures in powder and potato starch.
As a further solution of the present invention:The grain size of borax is 0.6-1.5mm, and the grain size of plant ash is 25-65um.
The preparation method of the handicraft clay sculpture material, is as follows:
Step 1 freezes raspberry 30-45 minutes at subzero 40 to subzero 20 degrees Celsius, then under 25-30 degrees Celsius Defrosting is in ice water state to raspberry and is crushed to 80-100 mesh, by raspberry, acetone and ethyl alcohol according to mass ratio 1:18-25: The ratio of 30-50 mixes, and the ultrasonication of 560-680W is used in the environment of 1.6-3.5MPa, then is centrifuged, concentrated And resin adsorption, obtain raspberry extracting solution;
Cocoanut shell and agar are crushed to 50-80 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed, obtains borax suspension by step 3;
Step 4, by cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite mix and to its The middle water that 0.3-0.5 times of total weight is added, is uniformly mixed, obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 60-90rpm by step 5 It mixes 50-75 minutes, obtains the first mixture;
Borax suspension, slurry and the first mixture are uniformly mixed and conserve 3-5 under water vapor atmosphere by step 6 Hour, it dries in the shade naturally and obtains finished product.
As a further solution of the present invention:It is rolled at 15-24MPa after step 6 maintenance.
As a further solution of the present invention:The frequency of the ultrasonication of step 1 is 30-60KHz.
As a further solution of the present invention:The temperature stirred in step 3 is 45-60 degrees Celsius, and the speed of stirring is 900-1350rpm。
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, by by different raw materials Using different preparation processes, different products is stirred uniformly, is enhanced using the synergistic effect between different material Adhesive, hardness, toughness and the gas permeability of product prevent from causing to crack and corrode for a long time outdoor, extend the guarantor of clay sculpture The time is deposited, the integrated ornamental of clay sculpture is maintained.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of handicraft clay sculpture material, includes the raw material of following parts by weight:16 parts of borax, 6 parts of gelatine, is planted at 8 parts of cocoanut shell 10 parts of object starch, 24 parts of plant ash, 5 parts of chitin, 12 parts of diatomite, 6 parts of agar, 8 parts of polyvinyl alcohol, lauryl sodium sulfate 4 parts and 13 parts of raspberry.Plant amylum includes the mixture of green starch, cornstarch and rice fecula.
The preparation method of the handicraft clay sculpture material, is as follows:
Raspberry is freezed 36 minutes at subzero 35 degrees Celsius, then thaws to raspberry and be under 28 degrees Celsius by step 1 Ice water state and 90 mesh are crushed to, by raspberry, acetone and ethyl alcohol according to mass ratio 1:20:37 ratio mixing, in 2.2MPa In the environment of use the ultrasonication of 630W, then centrifuged, concentrated and resin adsorption, obtain raspberry extracting solution;
Cocoanut shell and agar are crushed to 60 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed, obtains borax suspension by step 3;
Step 4, by cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite mix and to its The middle water that 0.4 times of total weight is added, is uniformly mixed, obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 75rpm by step 5 66 minutes, obtain the first mixture;
Borax suspension, slurry and the first mixture are uniformly mixed and conserve 3.5 under water vapor atmosphere by step 6 Hour, it is rolled at 18MPa after maintenance, drying in the shade naturally obtains finished product.
Embodiment 2
A kind of handicraft clay sculpture material, includes the raw material of following parts by weight:19 parts of borax, 10.5 parts of cocoanut shell, gelatine 7.4 Part, 12.6 parts of plant amylum, 29 parts of plant ash, 6.6 parts of chitin, 14 parts of diatomite, 8.8 parts of agar, 11 parts of polyvinyl alcohol, ten 16 parts of 5.5 parts of sodium dialkyl sulfate and raspberry.The grain size of borax is 1.3mm, and the grain size of plant ash is 44um.Plant amylum includes The mixture of cornstarch, sorghum starch, rice fecula and potato starch
The preparation method of the handicraft clay sculpture material, is as follows:
Raspberry is freezed 42 minutes at subzero 30 degrees Celsius, then thaws to raspberry and be under 27 degrees Celsius by step 1 Ice water state and 90 mesh are crushed to, by raspberry, acetone and ethyl alcohol according to mass ratio 1:22:45 ratio mixing, in 3.0MPa In the environment of use the ultrasonication of 660W, the frequency of ultrasonication is 45KHz, then is centrifuged, concentrated and resin is inhaled It is attached, obtain raspberry extracting solution;
Cocoanut shell and agar are crushed to 60 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed by step 3, and the temperature of stirring is taken the photograph for 54 The speed of family name's degree, stirring is 1200rpm, obtains borax suspension;
Step 4, by cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite mix and to its The middle water that 0.5 times of total weight is added, is uniformly mixed, obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 75rpm by step 5 58 minutes, obtain the first mixture;
Step 6, borax suspension, slurry and the first mixture are uniformly mixed and under water vapor atmosphere maintenance it is 4 small When, it dries in the shade naturally and obtains finished product.
Embodiment 3
A kind of handicraft clay sculpture material, includes the raw material of following parts by weight:22 parts of borax, 12.7 parts of cocoanut shell, gelatine 9.2 Part, 14 parts of plant amylum, 35 parts of plant ash, 7.5 parts of chitin, 15.4 parts of diatomite, 11 parts of agar, 13.8 parts of polyvinyl alcohol, 18.5 parts of 7.2 parts of lauryl sodium sulfate and raspberry.Plant amylum uses potato starch.The grain size of borax is 1.3mm, vegetation The grain size of ash is 52um.
The preparation method of the handicraft clay sculpture material, is as follows:
Raspberry is freezed 34 minutes at subzero 26 degrees Celsius, then thaws to raspberry and be under 27 degrees Celsius by step 1 Ice water state and 80 mesh are crushed to, by raspberry, acetone and ethyl alcohol according to mass ratio 1:24:44 ratio mixing, in 2.8MPa In the environment of use the ultrasonication of 580W, the frequency of ultrasonication is 60KHz, then is centrifuged, concentrated and resin is inhaled It is attached, obtain raspberry extracting solution;
Cocoanut shell and agar are crushed to 75 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed by step 3, and the temperature of stirring is taken the photograph for 48 The speed of family name's degree, stirring is 1350rpm, obtains borax suspension;
Step 4, by cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite mix and to its The middle water that 0.4 times of total weight is added, is uniformly mixed, obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 90rpm by step 5 70 minutes, obtain the first mixture;
Step 6, borax suspension, slurry and the first mixture are uniformly mixed and under water vapor atmosphere maintenance it is 4 small When, it is rolled at 22MPa after maintenance, drying in the shade naturally obtains finished product.
Embodiment 4
A kind of handicraft clay sculpture material, includes the raw material of following parts by weight:23 parts of borax, 14 parts of cocoanut shell, 10 parts of gelatine, 15 parts of plant amylum, 37 parts of plant ash, 8 parts of chitin, 16 parts of diatomite, 12 parts of agar, 15 parts of polyvinyl alcohol, dodecyl sulphur 20 parts of 8 parts of sour sodium and raspberry.Plant amylum includes green starch, cornstarch, sorghum starch, rice fecula and potato starch Mixture.The grain size of borax is 1.4mm, and the grain size of plant ash is 60um.
The preparation method of the handicraft clay sculpture material, is as follows:
Raspberry is freezed 45 minutes at subzero 40 degrees Celsius, then thaws to raspberry and be under 27 degrees Celsius by step 1 Ice water state and 80 mesh are crushed to, by raspberry, acetone and ethyl alcohol according to mass ratio 1:23:45 ratio mixing, in 3.1MPa In the environment of use the ultrasonication of 620W, the frequency of ultrasonication is 40KHz, then is centrifuged, concentrated and resin is inhaled It is attached, obtain raspberry extracting solution;
Cocoanut shell and agar are crushed to 60 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed, obtains borax suspension by step 3;
Step 4, by cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite mix and to its The middle water that 0.3 times of total weight is added, is uniformly mixed, obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 60rpm by step 5 55 minutes, obtain the first mixture;
Borax suspension, slurry and the first mixture are uniformly mixed and conserve 3-5 under water vapor atmosphere by step 6 Hour, it is rolled at 20MPa after maintenance, drying in the shade naturally obtains finished product.
Comparative example 1
Except without containing raspberry, remaining raw material and preparation method are same as Example 3.
Comparative example 2
Using existing common clay sculpture material as a comparison case 2.
The product of embodiment 1-4 and each 200 of the production clay sculpture of comparative example 1-2 are used respectively, are placed on identical In air environment and the cracking quantity of different time is observed, the results are shown in Table 1.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Comparative example 1 Comparative example 2
3 months quantity/ 0 0 0 0 5 8
6 months quantity/ 0 1 0 0 12 34
9 months quantity/ 4 6 8 3 32 75
12 months quantity/ 28 26 31 16 74 138
From table 1 it follows that the product of embodiment 1-4 is substantially better than comparative example 1 and comparative example on anti-cracking performance 2, show that holding time of the clay sculpture of the invention made under air environment is considerably longer than current material.
The present invention extracts raspberry and borax is modified in raspberry extracting solution, then by cocoanut shell powder, gelatine, Plant amylum etc. is prepared into slurry, and different raw materials is stirred evenly, and production is enhanced using the synergistic effect between different material Adhesive, hardness, toughness and the gas permeability of product prevent from causing to crack and corrode for a long time outdoor, extend the preservation of clay sculpture Time.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (7)

1. a kind of handicraft clay sculpture material, which is characterized in that include the raw material of following parts by weight:16-23 parts of borax, cocoanut shell 8- 14 parts, 6-10 parts of gelatine, 10-15 parts of plant amylum, 24-37 parts of plant ash, 5-8 parts of chitin, 12-16 parts of diatomite, agar 13-20 parts of 6-12 parts, 8-15 parts of polyvinyl alcohol, 4-8 parts of lauryl sodium sulfate and raspberry.
2. handicraft clay sculpture material according to claim 1, which is characterized in that the plant amylum include green starch, One or several kinds of mixtures in cornstarch, sorghum starch, rice fecula and potato starch.
3. handicraft clay sculpture material according to claim 1, which is characterized in that the grain size of the borax is 0.6-1.5mm, The grain size of plant ash is 25-65um.
4. a kind of preparation method of handicraft clay sculpture material as described in any one of claims 1-3, which is characterized in that specific steps It is as follows:
Raspberry is freezed 30-45 minutes at subzero 40 to subzero 20 degrees Celsius, is then thawed under 25-30 degrees Celsius by step 1 It is in ice water state to raspberry and is crushed to 80-100 mesh, by raspberry, acetone and ethyl alcohol according to mass ratio 1:18-25:30-50 Ratio mixing, the ultrasonication of 560-680W is used in the environment of 1.6-3.5MPa, then centrifuged, concentrated and resin Absorption, obtains raspberry extracting solution;
Cocoanut shell and agar are crushed to 50-80 mesh, obtain cocoanut shell powder and agar powder by step 2 respectively;
Borax is immersed in raspberry extracting solution and high-speed stirred is uniformly dispersed, obtains borax suspension by step 3;
Cocoanut shell powder, gelatine, plant amylum, plant ash, chitin and diatomite are mixed and are added thereto by step 4 The water for entering 0.3-0.5 times of total weight, is uniformly mixed, and obtains slurry;
Agar powder and lauryl sodium sulfate are added in polyvinyl alcohol and are stirred with the rotating speed of 60-90rpm by step 5 50-75 minutes, obtain the first mixture;
Step 6, borax suspension, slurry and the first mixture are uniformly mixed and maintenance 3-5 is small under water vapor atmosphere When, it dries in the shade naturally and obtains finished product.
5. handicraft clay sculpture material according to claim 4, which is characterized in that in 15-24MPa after the step 6 maintenance Under rolled.
6. handicraft clay sculpture material according to claim 4 or 5, which is characterized in that the ultrasonication of the step 1 Frequency be 30-60KHz.
7. handicraft clay sculpture material according to claim 4, which is characterized in that the temperature stirred in the step 3 is 45-60 degrees Celsius, the speed of stirring is 900-1350rpm.
CN201810387196.2A 2018-04-26 2018-04-26 A kind of handicraft clay sculpture material and preparation method thereof Pending CN108609919A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810387196.2A CN108609919A (en) 2018-04-26 2018-04-26 A kind of handicraft clay sculpture material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810387196.2A CN108609919A (en) 2018-04-26 2018-04-26 A kind of handicraft clay sculpture material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108609919A true CN108609919A (en) 2018-10-02

Family

ID=63660807

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810387196.2A Pending CN108609919A (en) 2018-04-26 2018-04-26 A kind of handicraft clay sculpture material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108609919A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111646731A (en) * 2020-04-29 2020-09-11 昆明乐想童年教育信息咨询有限公司 Non-toxic antibacterial artware clay sculpture material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261777A (en) * 2014-09-16 2015-01-07 吴持跃 Clay sculpture Buddha repair material and preparation method thereof
CN104261794A (en) * 2014-09-16 2015-01-07 吴持跃 Handicraft clay sculpture material and preparation method thereof
CN105462126A (en) * 2015-12-15 2016-04-06 铜陵铜官府文化创意股份公司 Environment-friendly copper technology clay sculpture material and preparation method thereof
CN105541283A (en) * 2015-12-15 2016-05-04 铜陵铜官府文化创意股份公司 Anti-cracking copper artware clay sculpture material and preparation method thereof
CN107352973A (en) * 2017-07-25 2017-11-17 合肥达户电线电缆科技有限公司 A kind of preparation method of environment friendly brick

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261777A (en) * 2014-09-16 2015-01-07 吴持跃 Clay sculpture Buddha repair material and preparation method thereof
CN104261794A (en) * 2014-09-16 2015-01-07 吴持跃 Handicraft clay sculpture material and preparation method thereof
CN105462126A (en) * 2015-12-15 2016-04-06 铜陵铜官府文化创意股份公司 Environment-friendly copper technology clay sculpture material and preparation method thereof
CN105541283A (en) * 2015-12-15 2016-05-04 铜陵铜官府文化创意股份公司 Anti-cracking copper artware clay sculpture material and preparation method thereof
CN107352973A (en) * 2017-07-25 2017-11-17 合肥达户电线电缆科技有限公司 A kind of preparation method of environment friendly brick

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王丰等: ""红树莓色素提取及稳定性研究"", 《北方园艺》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111646731A (en) * 2020-04-29 2020-09-11 昆明乐想童年教育信息咨询有限公司 Non-toxic antibacterial artware clay sculpture material
CN111646731B (en) * 2020-04-29 2024-06-21 云南乐想童年教育科技有限公司 Nontoxic antibacterial artware clay sculpture material

Similar Documents

Publication Publication Date Title
CN105481094B (en) It is a kind of for the ceramics filling of sewage disposal, production method and sewage-treatment plant
CN104610988B (en) Biomass carbonization moulding material and preparation method thereof
CN106694798B (en) A kind of powdery lost foam casting coating and its application method and application
CN101492578A (en) Split resistant putty powder and producing process
CN111268985A (en) Autoclaved aerated concrete block and preparation process thereof
WO2020107814A1 (en) Edible, environmentally friendly container for daily use and manufacturing process thereof
CN105295771A (en) Bonding agent and preparation method thereof
CN105088900B (en) Production method for packaging paper
CN108609919A (en) A kind of handicraft clay sculpture material and preparation method thereof
CN104150815B (en) A kind of lightweight brick for building and manufacture method thereof
KR20190109699A (en) Biodegradable mass manufactured by using coffee grounds and brewery byproducts
CN107746609A (en) A kind of glutinous rice metope base layer dope and its processing technology
CN104496339A (en) Concrete building block possessing raw material containing shell-animal shells as aggregate and preparation method thereof
CN103819135B (en) A kind of artificial stone and production technology thereof
CN107815145A (en) A kind of artificial color sand and preparation method thereof
CN107384308A (en) A kind of composite adhesive and preparation method thereof
CN104193500A (en) Organic fertilizer capable of promoting absorption of strawberries to minerals and preparation method of organic fertilizer
WO2016184323A1 (en) Method for producing imitation wood and imitation stone series furniture having natural texture
CN107793087B (en) Clay sculpture material with enhanced viscosity and preparation method thereof
CN102150901B (en) Method for reusing residual starch water from gluten manufacture
CN114316658A (en) Environment-friendly putty for inner wall bottom layer and preparation method thereof
CN108793924A (en) A kind of natural anhydrite base light internal wall plastering gupsum material and preparation method thereof
CN104327528A (en) Degradable perlite tableware and preparation method thereof
CN109913027A (en) A kind of imitation stone lacquer protective glue used additives
CN109970395A (en) A kind of wearable environment protection composite light lacquer and its manufacturing method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181002

RJ01 Rejection of invention patent application after publication