CN108863195A - A kind of molding mud of artistic sculpture and preparation method thereof - Google Patents

A kind of molding mud of artistic sculpture and preparation method thereof Download PDF

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Publication number
CN108863195A
CN108863195A CN201810923656.9A CN201810923656A CN108863195A CN 108863195 A CN108863195 A CN 108863195A CN 201810923656 A CN201810923656 A CN 201810923656A CN 108863195 A CN108863195 A CN 108863195A
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parts
molding
clay
mud
agent
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CN108863195B (en
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江华
刘音
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Huian Polar Star Technology Co., Ltd
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Hunan City University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • B28B3/04Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form with one ram per mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00956Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dental Preparations (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention belongs to artistic sculpture domain variabilities to disclose a kind of molding mud and preparation method thereof of artistic sculpture, and ingredient includes clay, deionized water, epoxy resin, modified firming agent, filler material, bonding agent, moisturizer, additive, coupling molecule, pigment, gelling agent, calcium phosphate mould inhibitor, antibacterial agent, antioxidant, tackifier, surfactant;Preparation method step 1:Mixed clay;Step 2:Filler material is mixed, mixture one is obtained;Step 3:Moisturizer, additive, coupling molecule, pigment, gelling agent, calcium phosphate mould inhibitor, antibacterial agent, antioxidant, tackifier, surfactant are mixed, mixture two is obtained;Step 4:Clay, mixture one, mixture two and epoxy resin are mixed, dough is obtained.The molding mud of artistic sculpture of the present invention is environmentally friendly, it is healthy, sturdy and durable not damage user, is not likely to produce crackle, long service life.

Description

A kind of molding mud of artistic sculpture and preparation method thereof
Technical field
The present invention relates to artistic sculpture technical fields, and in particular to a kind of molding mud of artistic sculpture and its preparation side Method.
Background technique
Artistic sculpture mud in the prior art, main component are mostly natural clay, are needed before carrying out sculpture by clay Crushing is mixed well into appropriate thick, however since moisture content constantly volatilizees during sculpture, the clay that mixes up or is being carved The clay of modeling is easy to exsiccation embrittlement, needs to water drenching on one side while sculpture, ceaselessly water drenching repeatedly, otherwise sculpture is easily dry and cracked And influence quality and artistic ornamental.Moreover, current sculpture mud, since its intensity is low, product is unable to reinforcement production Large-scale product, can only make the product of smallclothes.In addition, in artistic sculpture in the prior art molding mud containing have very much lead, The ingredients such as silver, larger to environmental disruption degree in actual use, the health of be easy to damage sculpture person and user. Moreover, because the inoxidizability of artistic sculpture product, anti-mildew can be all poor, the long-time for being unfavorable for product is saved.
In consideration of it, how to provide it is a kind of it is environmentally friendly, do not damage user it is healthy, it is sturdy and durable, be not likely to produce crackle, Molding mud of artistic sculpture with long service life and preparation method thereof is those skilled in the art's technical issues that need to address.
Summary of the invention
The present invention is big to environmental disruption degree with molding mud for artistic sculpture in the prior art, be easy to damage user and The health of sculpture person is easy to produce the short problem of crackle, service life, and provide it is a kind of it is environmentally friendly, do not damage and make User's molding mud that is healthy, sturdy and durable, being not likely to produce crackle, artistic sculpture with long service life and preparation method thereof.
The present invention using following technical scheme in order to solve the above technical problems, realized:
Design a kind of molding mud of artistic sculpture, the raw material including following parts by weight:80-110 parts of clay, deionized water 60- 80 parts, 8-12 parts of epoxy resin, 8-12 parts of modified firming agent, 6-12 parts of filler material, 6-12 parts of bonding agent, 6-10 parts of moisturizer, 3-15 parts of additive, 0.1-1 parts of coupling molecule, 1-3 parts of pigment, gelling agent 1-3 parts, 0.5-1.5 parts of calcium phosphate mould inhibitor, antibacterial 0.5-1.5 parts of agent, 0.5-1.5 parts of antioxidant, 0.5-1.5 parts of tackifier, 0.5-1.5 parts of surfactant, the addition Agent is arbor broad-leaved fiber.
Preferably, the epoxide number range of the epoxy resin is 0.36-0.47, and fugitive constituent is not more than 1.5%, softening point Temperature range is 20-28 DEG C, and total amine value is not less than 90.
Preferably, the filler material by calcium carbonate, talcum powder, silica, mica, aluminium oxide, tin oxide, charcoal element, glass, Titanium dioxide, silica flour composition.
Preferably, the bonding agent by methylcellulose, ethyl cellulose, hydroxyl ester fiber element, carboxymethyl cellulose, Acrylic acid, polyvinyl acetate composition.
Preferably, the coupling molecule is one of silane couplent, titanium coupling molecule or aluminium coupling molecule or a variety of.
Preferably, the pigment is inorganic pigment comprising titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow, lithopone, charcoal One of black, iron oxide red, iron oxide yellow are a variety of.
Preferably, the gelling agent is one of boric acid, borax, Congo red, vanadic acid or a variety of.
Preferably, the antioxidant is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, lithium carbonate or a variety of.
Design a kind of preparation method for forming mud such as mentioned component artistic sculpture, which is characterized in that including walking as follows Suddenly:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 2-5h is carried out under the conditions of 50-80 DEG C;Finally will Clay after drying carries out natural cooling, and selects parts by weight spare for 80-110 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 5-10 parts is sufficiently mixed, mixture one is obtained, it will One indwelling of mixture is spare;
Step 3:It is 6-10 parts of moisturizer, 3-15 parts of additive, 0.1-1 parts of coupling molecule, 1-3 parts by parts by weight Pigment, 1-3 parts of gelling agent, 0.5-1.5 parts of calcium phosphate mould inhibitor, 0.5-1.5 parts of antibacterial agent, 0.5-1.5 parts anti- Oxidant, 0.5-1.5 parts of tackifier, 0.5-1.5 parts of surfactant are carried out sufficiently mixed by 10-20 parts of deionized water It closes, obtains mixture two, and two indwelling of mixture is spare;
Step 4:Clay, mixture one, mixture two and the parts by weight that step 1 is obtained be 8-12 parts epoxy resin into Row is sufficiently mixed, and remaining deionized water is added, and is sufficiently mixed and is mediated under the conditions of 50-80 DEG C using kneader, Obtain dough;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains the molding mud of clay shape;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
Preferably, the molding machine includes support leg, bottom plate, support rod, forms enclosing, upper cover, cross bar and hydraulic stem, There are four the support leg is set, and it is vertically arranged, and the upper end of support leg is arranged in the bottom plate;The support rod is set There are two, the two sides of bottom plate upper end are vertically arranged in, the lower end of the support rod is fixed in the upper end of bottom plate, the support rod Upper end is interconnected by cross bar;The molding enclosing shape is open column shape structure, and lower end is fixed in the upper end of bottom plate, The hydraulic stem is fixed in the lower end of cross bar vertically, and the upper cover is fixed in the lower end of hydraulic stem, the upper cover and molding Enclosing interference fit.
A kind of molding mud and preparation method thereof of artistic sculpture proposed by the present invention, beneficial effect is:
(1)The main component of the molding mud of artistic sculpture of the present invention includes clay, deionized water, epoxy resin, modified solidified Agent, filler material, bonding agent, moisturizer, additive, coupling molecule, pigment, gelling agent, calcium phosphate mould inhibitor, antibacterial agent, antioxygen Agent, tackifier, surfactant;Wherein modified firming agent overcomes the disadvantage that conventional curing agents toxicity is big, irritation is strong, By with reach the curing performance for improving clay after filler material, being sufficiently mixed of epoxy resin;Continue to add in clay simultaneously Enter to have bonding agent and tackifier, further improves the solidification effect and adhesive effect of product;Moisturizer is mixed in the product, Product solid water characteristic is improved, prevents molding mud moisture loss during sculpture cracking situation that is too fast, and then causing, more Effectively improve the molding effect of product;On the one hand arbor broad-leaved fiber, which is selected, as additive reduces the weight of molding mud Amount forms later transport convenient for subsequent product, carries, and on the other hand, the fiber of broad leaf tree is shorter and equalizes, and is being fabricated to It is easier to disperse when type mud, each component distributing is more uniform in obtained molding mud;In addition, the silane couplent of addition, titanium coupling Connection agent or aluminium coupling molecule improve the dispersion effect of each ingredient, while without introducing heavy metal element, environment protecting and to making User's health has very big guarantee;Change pigment composition moreover, can according to need by addition pigment in order to be thought The color wanted;Gelling agent effectively improves the solidification effect of epoxy resin, further improves the hardness of molding mud;Finally also add Added with calcium phosphate mould inhibitor, antibacterial agent, antioxidant, surfactant, anti-mildew ability, the antibacterial effect of product are effectively increased Fruit, antioxidant effect and surface-active;
(2)The each component environment protecting that the molding mud of artistic sculpture of the invention uses is good, is conducive to user and sculpture person Health;Meanwhile the affixed effect of product is strengthened by epoxy resin, modified firming agent, bonding agent, tackifier, The fastness for improving product, efficiently solves a possibility that product is easily cracked in the prior art;In addition, product is mould proof Change ability, antibacterial effect, antioxidant effect and surface-active have also been greatly improved compared with the prior art;
(3)The preparation method preparation process of the molding mud of artistic sculpture of the present invention is simple, preparation time is short, without harsh preparation Condition, the prospect with industrialized production and popularization.
Detailed description of the invention
The present invention is described in further detail for embodiment in reference to the accompanying drawing, but does not constitute to of the invention Any restrictions.
Fig. 1 is the flow diagram of the method for the present invention;
Fig. 2 is the flow diagram of the method for the present invention;
Fig. 3 is the planar structure schematic diagram of molding machine;
Fig. 4 is the schematic perspective view of molding machine.
In figure:Support leg 1, bottom plate 2, support rod 3, molding enclosing 4, upper cover 5, cross bar 6, hydraulic stem 7.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Embodiment one
A kind of molding mud of artistic sculpture of the invention, the raw material including following parts by weight:80 parts of clay, deionized water 60 Part, 8 parts of epoxy resin, 8 parts of modified firming agent, 6 parts of filler material, 6 parts of bonding agent, 6 parts of moisturizer, 3 parts of additive, coupling molecule 0.1 part, 1 part of pigment, gelling 1 part of agent, 0.5 part of calcium phosphate mould inhibitor, 0.5 part of antibacterial agent, 0.5 part of antioxidant, tackifier 0.5 part, 0.5 part of surfactant;The epoxide number of the epoxy resin is 0.36, and fugitive constituent is not more than 1.5%, softening point temperature Degree is 20 DEG C, and total amine value is not less than 90;The filler material by calcium carbonate, talcum powder, silica, mica, aluminium oxide, tin oxide, Charcoal element, glass, titanium dioxide, silica flour composition;The bonding agent by methylcellulose, ethyl cellulose, hydroxyl ester fiber element, Carboxymethyl cellulose, acrylic acid, polyvinyl acetate composition;The coupling molecule includes silane couplent, titanium coupling molecule and aluminium Coupling molecule;The additive is arbor broad-leaved fiber;The pigment be inorganic pigment comprising titanium white, chrome yellow, barba hispanica, Cadmium red, cadmium yellow, lithopone, carbon black, iron oxide red, iron oxide yellow;The gelling agent includes boric acid, borax, Congo red, vanadium Acid;The antioxidant includes zinc oxide, copper oxide, ammonium dihydrogen phosphate, lithium carbonate.
Refering to shown in attached drawing 1, a kind of preparation method of the molding mud of artistic sculpture a kind of as described above of the invention is wrapped Include following steps:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 2h is carried out under the conditions of 50 DEG C;It finally will drying Clay afterwards carries out natural cooling, and selects parts by weight spare for 80 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 5 parts is sufficiently mixed, mixture one is obtained, will mix It is spare to close one indwelling of object;
Step 3:It is 6 parts of moisturizer, 3 parts of additive, 0.1 part of coupling molecule, 1 part of pigment, 1 part by parts by weight Be gelled agent, 0.5 part of calcium phosphate mould inhibitor, 0.5 part of antibacterial agent, 0.5 part of antioxidant, 0.5 part of tackifier, 0.5 The surfactant of part is sufficiently mixed by 10 parts of deionized water, obtains mixture two, and two indwelling of mixture is standby With;
Step 4:The epoxy resin that clay, mixture one, mixture two and the parts by weight that step 1 is obtained are 8 parts carries out It is sufficiently mixed, and remaining deionized water is added, be sufficiently mixed and mediated under the conditions of 50 DEG C using kneader, rolled into a ball Shape object;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains the molding mud of clay shape;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
Refering to shown in attached drawing 3- attached drawing 4, the molding machine include support leg 1, bottom plate 2, support rod 3, molding enclosing 4, Upper cover 5, cross bar 6 and hydraulic stem 7, there are four the support leg 1 is set, and it is vertically arranged, and the setting of bottom plate 2 is supporting The upper end of foot 1;There are two the support rod 3 is set, the two sides of 2 upper end of bottom plate are vertically arranged in, the lower end of the support rod 3 is solid It connects in the upper end of bottom plate 2, the upper end of the support rod 3 is interconnected by cross bar 6;4 shape of molding enclosing is hollow Column structure, lower end are fixed in the upper end of bottom plate 2, and the hydraulic stem 7 is fixed in the lower end of cross bar 6, the upper cover 5 vertically It is fixed in the lower end of hydraulic stem 7, the upper cover 5 and molding enclosing 4 are interference fitted.
Embodiment two
A kind of molding mud of artistic sculpture of the invention, the raw material including following parts by weight:95 parts of clay, deionized water 70 Part, 10 parts of epoxy resin, 10 parts of modified firming agent, 9 parts of filler material, 9 parts of bonding agent, 8 parts of moisturizer, 9 parts of additive, coupling molecule 0.5 part, 2 parts of pigment, gelling 2 parts of agent, 1 part of calcium phosphate mould inhibitor, 1 part of antibacterial agent, 1 part of antioxidant, 1 part of tackifier, table 1 part of face activating agent;The epoxide number of the epoxy resin is 0.41, and fugitive constituent is not more than 1.5%, and softening point temperature is 24 DEG C, Total amine value is not less than 90.The filler material by calcium carbonate, talcum powder, silica, mica, aluminium oxide, tin oxide, charcoal element, glass, Titanium dioxide, silica flour composition;The bonding agent is by methylcellulose, ethyl cellulose, hydroxyl ester fiber element, carboxymethyl cellulose Element, acrylic acid, polyvinyl acetate composition;The coupling molecule includes silane couplent, titanium coupling molecule or aluminium coupling molecule;It is described Additive be arbor broad-leaved fiber.The pigment is inorganic pigment comprising titanium white, barba hispanica, cadmium red, cadmium yellow, is stood chrome yellow Moral powder, carbon black, iron oxide red, iron oxide yellow;The gelling agent includes boric acid, borax, in Congo red, vanadic acid;Described Antioxidant includes zinc oxide, copper oxide, ammonium dihydrogen phosphate, lithium carbonate.
Refering to shown in attached drawing 1, a kind of preparation method of the molding mud of artistic sculpture a kind of as described above of the invention is wrapped Include following steps:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 3.5h is carried out under the conditions of 65 DEG C;It will finally dry Clay after dry carries out natural cooling, and selects parts by weight spare for 95 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 7.5 parts is sufficiently mixed, mixture one is obtained, it will One indwelling of mixture is spare;
Step 3:It is 8 parts of moisturizer, 9 parts of additive, 0.5 part of coupling molecule, 2 parts of pigment, 2 parts by parts by weight Gelling agent, 1 part of calcium phosphate mould inhibitor, 1 part of antibacterial agent, 1 part of antioxidant, 1 part of tackifier, 1 part of surface are living Property agent is sufficiently mixed by 15 parts of deionized water, obtains mixture two, and two indwelling of mixture is spare;
Step 4:The epoxy resin that clay, mixture one, mixture two and the parts by weight that step 1 is obtained are 10 parts carries out It is sufficiently mixed, and remaining deionized water is added, be sufficiently mixed and mediated under the conditions of 65 DEG C using kneader, rolled into a ball Shape object;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains the molding mud of clay shape;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
Refering to shown in attached drawing 3- attached drawing 4, the molding machine include support leg 1, bottom plate 2, support rod 3, molding enclosing 4, Upper cover 5, cross bar 6 and hydraulic stem 7, there are four the support leg 1 is set, and it is vertically arranged, and the setting of bottom plate 2 is supporting The upper end of foot 1;There are two the support rod 3 is set, the two sides of 2 upper end of bottom plate are vertically arranged in, the lower end of the support rod 3 is solid It connects in the upper end of bottom plate 2, the upper end of the support rod 3 is interconnected by cross bar 6;4 shape of molding enclosing is hollow Column structure, lower end are fixed in the upper end of bottom plate 2, and the hydraulic stem 7 is fixed in the lower end of cross bar 6, the upper cover 5 vertically It is fixed in the lower end of hydraulic stem 7, the upper cover 5 and molding enclosing 4 are interference fitted.
Embodiment three
A kind of molding mud of artistic sculpture of the invention, the raw material including following parts by weight:110 parts of clay, deionized water 80 Part, 12 parts of epoxy resin, 12 parts of modified firming agent, 12 parts of filler material, 12 parts of bonding agent, 10 parts of moisturizer, 15 parts of additive, coupling Join 1 part of agent, 3 parts of pigment, 3 parts of agent of gelling, 1.5 parts of calcium phosphate mould inhibitor, 1.5 parts of antibacterial agent, 1.5 parts of antioxidant, thickening 0.5-1.5 parts of agent, 1.5 parts of surfactant;The epoxide number of the epoxy resin is 0.47, and fugitive constituent is soft no more than 1.5% Changing point temperature is 28 DEG C, and total amine value is not less than 90.The filler material is by calcium carbonate, talcum powder, silica, mica, aluminium oxide, oxygen Change tin, charcoal element, glass, titanium dioxide, silica flour composition;The bonding agent is fine by methylcellulose, ethyl cellulose, hydroxy ester Tie up element, carboxymethyl cellulose, acrylic acid, polyvinyl acetate composition;The coupling molecule includes silane couplent, titanium coupling molecule Or aluminium coupling molecule;The additive is arbor broad-leaved fiber;The pigment is inorganic pigment comprising titanium white, chrome yellow, iron Indigo plant, cadmium red, cadmium yellow, lithopone, carbon black, iron oxide red, iron oxide yellow;The gelling agent includes boric acid, borax, the Congo Red, vanadic acid;The antioxidant includes zinc oxide, copper oxide, ammonium dihydrogen phosphate, lithium carbonate.
Refering to shown in attached drawing 1, a kind of preparation method of the molding mud of artistic sculpture a kind of as described above of the invention is wrapped Include following steps:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 5h is carried out under the conditions of 80 DEG C;It finally will drying Clay afterwards carries out natural cooling, and selects parts by weight spare for 110 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 10 parts is sufficiently mixed, mixture one is obtained, will mix It is spare to close one indwelling of object;
Step 3:It is 10 parts of moisturizer, 15 parts of additive, 1 part of coupling molecule, 3 parts of pigment, 3 parts by parts by weight Be gelled agent, 1.5 parts of calcium phosphate mould inhibitor, 1.5 parts of antibacterial agent, 1.5 parts of antioxidant, 1.5 parts of tackifier, 1.5 The surfactant of part is sufficiently mixed by 20 parts of deionized water, obtains mixture two, and two indwelling of mixture is standby With;
Step 4:The epoxy resin that clay, mixture one, mixture two and the parts by weight that step 1 is obtained are 12 parts carries out It is sufficiently mixed, and remaining deionized water is added, be sufficiently mixed and mediated under the conditions of 80 DEG C using kneader, rolled into a ball Shape object;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains the molding mud of clay shape;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
Refering to shown in attached drawing 3- attached drawing 4, the molding machine include support leg 1, bottom plate 2, support rod 3, molding enclosing 4, Upper cover 5, cross bar 6 and hydraulic stem 7, there are four the support leg 1 is set, and it is vertically arranged, and the setting of bottom plate 2 is supporting The upper end of foot 1;There are two the support rod 3 is set, the two sides of 2 upper end of bottom plate are vertically arranged in, the lower end of the support rod 3 is solid It connects in the upper end of bottom plate 2, the upper end of the support rod 3 is interconnected by cross bar 6;4 shape of molding enclosing is hollow Column structure, lower end are fixed in the upper end of bottom plate 2, and the hydraulic stem 7 is fixed in the lower end of cross bar 6, the upper cover 5 vertically It is fixed in the lower end of hydraulic stem 7, the upper cover 5 and molding enclosing 4 are interference fitted.
Example IV
A kind of molding mud of artistic sculpture of the invention, the raw material including following parts by weight:110 parts of clay, deionized water 80 Part, 12 parts of epoxy resin, 12 parts of modified firming agent, 12 parts of filler material, 12 parts of bonding agent, 10 parts of moisturizer, 15 parts of additive, coupling Join 1 part of agent, 3 parts of pigment, 3 parts of agent of gelling, 1.5 parts of calcium phosphate mould inhibitor, 1.5 parts of antibacterial agent, 1.5 parts of antioxidant, thickening 0.5-1.5 parts of agent, 1.5 parts of surfactant;The epoxide number of the epoxy resin is 0.47, and fugitive constituent is soft no more than 1.5% Changing point temperature is 28 DEG C, and total amine value is not less than 90.The filler material is by calcium carbonate, talcum powder, mica, aluminium oxide, charcoal element, glass Glass, silica flour composition;The bonding agent is by methylcellulose, hydroxyl ester fiber element, carboxymethyl cellulose, polyvinyl acetate Composition;The coupling molecule includes silane couplent, titanium coupling molecule;The additive is arbor broad-leaved fiber;The color Element is inorganic pigment comprising titanium white, barba hispanica, cadmium yellow, lithopone, iron oxide red, iron oxide yellow;The gelling agent includes Boric acid, borax, vanadic acid;The antioxidant includes zinc oxide, copper oxide, lithium carbonate.
Refering to shown in attached drawing 1, a kind of preparation method of the molding mud of artistic sculpture a kind of as described above of the invention is wrapped Include following steps:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 5h is carried out under the conditions of 80 DEG C;It finally will drying Clay afterwards carries out natural cooling, and selects parts by weight spare for 110 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 10 parts is sufficiently mixed, mixture one is obtained, will mix It is spare to close one indwelling of object;
Step 3:It is 10 parts of moisturizer, 15 parts of additive, 1 part of coupling molecule, 3 parts of pigment, 3 parts by parts by weight Be gelled agent, 1.5 parts of calcium phosphate mould inhibitor, 1.5 parts of antibacterial agent, 1.5 parts of antioxidant, 1.5 parts of tackifier, 1.5 The surfactant of part is sufficiently mixed by 20 parts of deionized water, obtains mixture two, and two indwelling of mixture is standby With;
Step 4:The epoxy resin that clay, mixture one, mixture two and the parts by weight that step 1 is obtained are 12 parts carries out It is sufficiently mixed, and remaining deionized water is added, be sufficiently mixed and mediated under the conditions of 80 DEG C using kneader, rolled into a ball Shape object;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains the molding mud of clay shape;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
Refering to shown in attached drawing 3- attached drawing 4, the molding machine include support leg 1, bottom plate 2, support rod 3, molding enclosing 4, Upper cover 5, cross bar 6 and hydraulic stem 7, there are four the support leg 1 is set, and it is vertically arranged, and the setting of bottom plate 2 is supporting The upper end of foot 1;There are two the support rod 3 is set, the two sides of 2 upper end of bottom plate are vertically arranged in, the lower end of the support rod 3 is solid It connects in the upper end of bottom plate 2, the upper end of the support rod 3 is interconnected by cross bar 6;4 shape of molding enclosing is hollow Column structure, lower end are fixed in the upper end of bottom plate 2, and the hydraulic stem 7 is fixed in the lower end of cross bar 6, the upper cover 5 vertically It is fixed in the lower end of hydraulic stem 7, the upper cover 5 and molding enclosing 4 are interference fitted.
The main component of the molding mud of artistic sculpture of the present invention includes clay, deionized water, epoxy resin, modified solidified Agent, filler material, bonding agent, moisturizer, additive, coupling molecule, pigment, gelling agent, calcium phosphate mould inhibitor, antibacterial agent, antioxygen Agent, tackifier, surfactant;Wherein modified firming agent overcomes the disadvantage that conventional curing agents toxicity is big, irritation is strong, By with reach the curing performance for improving clay after filler material, being sufficiently mixed of epoxy resin;Continue to add in clay simultaneously Enter to have bonding agent and tackifier, further improves the solidification effect and adhesive effect of product;Moisturizer is mixed in the product, Product solid water characteristic is improved, prevents molding mud moisture loss during sculpture cracking situation that is too fast, and then causing, more The molding effect for effectively improving product forms the electronic scanner microscope figure of mud for embodiment four refering to shown in attached drawing 2 Piece, by attached drawing 2 it is found that being completely embedded between the molding mud structure of artistic sculpture of the invention, intermolecular force is very strong; On the one hand arbor broad-leaved fiber, which is selected, as additive reduces the weight of molding mud, later fortune is formed convenient for subsequent product Defeated, carrying, on the other hand, the fiber of broad leaf tree is shorter and equalizes, and more easily disperses when production forms mud, obtained molding Each component distributing is more uniform in mud;In addition, silane couplent, titanium coupling molecule or the aluminium coupling molecule of addition improve each ingredient Dispersion effect, while without introducing heavy metal element, environment protecting and there is very big guarantee to user's health;Moreover, It can according to need by addition pigment and change pigment composition in order to obtain desired color;Gelling agent effectively improves epoxy The solidification effect of resin further improves the hardness of molding mud;Finally also it is added with calcium phosphate mould inhibitor, antibacterial agent, antioxygen Agent, surfactant effectively increase anti-mildew ability, antibacterial effect, antioxidant effect and the surface-active of product.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of molding mud of artistic sculpture, which is characterized in that the raw material including following parts by weight:80-110 parts of clay is gone 60-80 parts of ionized water, 8-12 parts of epoxy resin, 8-12 parts of modified firming agent, 6-12 parts of filler material, 6-12 parts of bonding agent, moisturizing 6-10 parts of agent, 3-15 parts of additive, 0.1-1 parts of coupling molecule, 1-3 parts of pigment, gelling agent 1-3 parts, calcium phosphate mould inhibitor 0.5- 1.5 parts, 0.5-1.5 parts of antibacterial agent, 0.5-1.5 parts of antioxidant, 0.5-1.5 parts of tackifier, 0.5-1.5 parts of surfactant; The additive is arbor broad-leaved fiber.
2. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the ring of the epoxy resin Oxygen value range is 0.36-0.47, and fugitive constituent is not more than 1.5%, and softening point temperature range is 20-28 DEG C, and total amine value is not less than 90.
3. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the filler material is by carbonic acid Calcium, talcum powder, silica, mica, aluminium oxide, tin oxide, charcoal element, glass, titanium dioxide, silica flour composition.
4. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the bonding agent is by methyl Cellulose, ethyl cellulose, hydroxyl ester fiber element, carboxymethyl cellulose, acrylic acid, polyvinyl acetate composition.
5. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the coupling molecule is silane One of coupling molecule, titanium coupling molecule or aluminium coupling molecule are a variety of.
6. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the pigment is inorganic face Material comprising one of titanium white, chrome yellow, barba hispanica, cadmium red, cadmium yellow, lithopone, carbon black, iron oxide red, iron oxide yellow are more Kind.
7. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the gelling agent is boron One of acid, borax, Congo red, vanadic acid are a variety of.
8. a kind of molding mud of artistic sculpture according to claim 1, which is characterized in that the antioxidant is oxygen Change one of zinc, copper oxide, ammonium dihydrogen phosphate, lithium carbonate or a variety of.
9. a kind of preparation method of the molding mud of such as any one artistic sculpture of claim 1-9, which is characterized in that including such as Lower step:
Step 1:Firstly, carrying out roughing to clay using the sieve not less than 10 mesh, impurity is removed;Then grinder pair is utilized Clay after removal impurity is fully ground, selected using the sieve progress not less than 20 mesh after grinding, continues to remove big Grain impurity;Then, the clay after will be selected is put into baking oven, and work drying and processing 2-5h is carried out under the conditions of 50-80 DEG C;Finally will Clay after drying carries out natural cooling, and selects parts by weight spare for 80-110 parts of clay sealings;
Step 2:The deionized water that filler material addition parts by weight are 5-10 parts is sufficiently mixed, mixture one is obtained, it will One indwelling of mixture is spare;
Step 3:It is 6-10 parts of moisturizer, 3-15 parts of additive, 0.1-1 parts of coupling molecule, 1-3 parts by parts by weight Pigment, 1-3 parts of gelling agent, 0.5-1.5 parts of calcium phosphate mould inhibitor, 0.5-1.5 parts of antibacterial agent, 0.5-1.5 parts anti- Oxidant, 0.5-1.5 parts of tackifier, 0.5-1.5 parts of surfactant are carried out sufficiently mixed by 10-20 parts of deionized water It closes, obtains mixture two, and two indwelling of mixture is spare;
Step 4:Clay, mixture one, mixture two and the parts by weight that step 1 is obtained be 8-12 parts epoxy resin into Row is sufficiently mixed, and remaining deionized water is added, and is sufficiently mixed and is mediated under the conditions of 50-80 DEG C using kneader, Obtain dough;
Step 5:The dough that step 4 obtains is subjected to rolloff by rolling in material machine, obtains clay shape mud;
Step 6:The clay shape mud that step 5 obtains is placed in molding machine and carries out forming processes, just obtains the molding Mud.
10. a kind of preparation method of the molding mud of artistic sculpture according to claim 9, which is characterized in that described Molding machine includes support leg(1), bottom plate(2), support rod(3), molding enclosing(4), upper cover(5), cross bar(6)And hydraulic stem(7), The support leg(1)If there are four, and it is vertically arranged, the bottom plate(2)It is arranged in support leg(1)Upper end;It is described Support rod(3)There are two if, it is vertically arranged in bottom plate(2)The two sides of upper end, the support rod(3)Lower end be fixed in bottom plate (2)Upper end, the support rod(3)Upper end pass through cross bar(6)It interconnects;The molding enclosing(4)Shape is hollow Column structure, lower end are fixed in bottom plate(2)Upper end, the hydraulic stem(7)It is fixed in cross bar vertically(6)Lower end, institute State upper cover(5)It is fixed in hydraulic stem(7)Lower end, the upper cover(5)With molding enclosing(4)Interference fit.
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EP2393644A2 (en) * 2009-02-05 2011-12-14 Playtex Products, Llc Microcellular injection molding processes for personal and consumer care products and packaging
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