CN104234360A - Radiation curing colored paper gypsum plaster decorative board - Google Patents
Radiation curing colored paper gypsum plaster decorative board Download PDFInfo
- Publication number
- CN104234360A CN104234360A CN201410438757.9A CN201410438757A CN104234360A CN 104234360 A CN104234360 A CN 104234360A CN 201410438757 A CN201410438757 A CN 201410438757A CN 104234360 A CN104234360 A CN 104234360A
- Authority
- CN
- China
- Prior art keywords
- radiation curing
- acrylate
- filler
- light trigger
- acrylic ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides a radiation curing colored paper gypsum plaster decorative board. The decorative board comprises a substrate (A), wherein the surface of the substrate (A) is sequentially provided with a radiation curing adhesive priming coat (E) and a color layer (D). By adopting the above scheme, the radiation curing colored paper gypsum plaster decorative board provided by the invention is better in performance, high in intensity, rich in color and full in paint film, is easy to clean, and is capable of replacing woods, stones and other non-renewable resources, and scratch resistance, lightness, antibiosis, fire protection and bio-imitability can be realized, therefore, the decorative board can be extensively applied to interior decoration.
Description
Technical field
The invention belongs to decorative panel Material Field, be related specifically to and utilize radiation curing technology to make colored decorating plate on Paper-faced gyp surface.
Background technology
At present, along with the day by day luxurious and ornament materials demand of increasingly the increasing of ornament materials kind, various decoration strengthens increasingly, country requires also more and more higher to the environmental protection of ornament materials, energy-conservation and fire prevention etc., and therefore, various heat-preserving complex material, fire proofing material occur in succession.In-built market consumption maximum or Thistle board etc. but at present Thistle board also need to carry out follow-up surfacing at the scene in decoration process, cause difficulty and the pollution of construction and environment.
Summary of the invention
For the problem of prior art; the object of the invention is to utilize Thistle board as substrate; a kind of colour image is provided to enrich; the radiation curing colored decorating plate of the non-renewable resources such as environmental protection, ornamental and protectiveness is strong, cost performance is high, alternative timber and stone material, namely provides a kind of radiation curing colored paper gypseous decorating board.
To achieve these goals, present invention employs following technical scheme:
The colored paper gypseous decorating board of a kind of radiation curing, comprises substrate, and the surface of substrate is disposed with radiation curing attachment scratch coat and color layer.
Preferably, be provided with radiation curing attachment scratch coat and radiation curing topcoat on described color layer successively, topcoat mainly plays protection, corrosion-resistant effect.
Or, be provided with radiation curing topcoat on described color layer.
That is,
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing attachment scratch coat, color layer, radiation curing attachment scratch coat and radiation curing topcoat, or,
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing attachment scratch coat, color layer and radiation curing topcoat.
Preferably, radiation curing primary coat coating is provided with between described substrate and radiation curing attachment scratch coat.
That is, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curing attachment scratch coat and color layer.
Or, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curing attachment scratch coat, color layer, radiation curing attachment scratch coat and radiation curing topcoat.
Or, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curing attachment scratch coat, color layer and radiation curing topcoat.
Preferably, radiation curable primer coating is provided with between described radiation curing primary coat coating and radiation curing attachment scratch coat.
That is, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curable primer coating, radiation curing attachment scratch coat and color layer.
Or, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curable primer coating, radiation curing attachment scratch coat, color layer, radiation curing attachment scratch coat and radiation curing topcoat.
Or, the colored paper gypseous decorating board of a kind of radiation curing: comprise substrate, radiation curing primary coat coating, radiation curable primer coating, radiation curing attachment scratch coat, color layer and radiation curing topcoat.
Preferably, described substrate is Thistle board.
Preferably, the percentage by weight that described radiation curing attachment scratch coat accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 60%, acrylate monomer 20 ~ 60%, light trigger 3 ~ 10%, auxiliary agent 0 ~ 5% and filler 0 ~ 5%.
The content of described acrylic ester prepolymer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50% or 55%.
The content of described acrylate monomer is such as 25%, 30%, 35%, 40%, 45%, 50% or 55%.
The content of described light trigger is such as 4%, 5%, 6%, 7%, 8% or 9%.
The content of described auxiliary agent is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
The content of described filler is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
Preferably, the percentage by weight that radiation curing primary coat coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 20 ~ 70%, acrylate monomer 10 ~ 40%, light trigger 2 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 40%.
The content of described acrylic ester prepolymer is such as 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60% or 65%.
The content of described acrylate monomer is such as 14%, 18%, 22%, 26%, 30%, 34% or 38%.
The content of described light trigger is such as 2.2%, 2.4%, 2.6%, 2.8%, 3%, 3.2%, 3.4%, 3.6%, 3.8%, 4%, 4.2%, 4.4%, 4.6% or 4.8%.
The content of described auxiliary agent is such as 0.2%, 0.4%, 0.6%, 0.8%, 1%, 1.2%, 1.4%, 1.6% or 1.8%.
The content of described filler is such as 8%, 11%, 14%, 17%, 20%, 23%, 26%, 29%, 32%, 35% or 38%.
Preferably, the percentage by weight that described radiation curable primer coating (C) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 60%, light trigger 3 ~ 8%, auxiliary agent 0 ~ 5%, pigment 5 ~ 35% and filler 0 ~ 10%.
The content of described acrylic ester prepolymer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60% or 65%.
The content of described acrylate monomer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50% or 55%.
The content of described light trigger is such as 3.3%, 3.6%, 3.9%, 4.2%, 4.5%, 4.8%, 5.1%, 5.4%, 5.7%, 6%, 6.3%, 6.6%, 6.9%, 7.2%, 7.5% or 7.8%.
The content of described auxiliary agent is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
The content of described pigment is such as 8%, 11%, 14%, 17%, 20%, 23%, 26%, 29% or 32%.
The content of described filler is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9% or 9.5%.
Preferably, described color layer and colored colored paint layer, it is for exempting from finish paint transfer film (commercially available prod), needing finish paint transfer film (commercially available prod) or radiation curing coloured coating, and the percentage by weight that wherein radiation curing coloured coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 60%, light trigger 3 ~ 8%, auxiliary agent 0 ~ 5%, pigment 5 ~ 35% and filler 0 ~ 10%.
The content of described acrylic ester prepolymer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60% or 65%.
The content of described acrylate monomer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50% or 55%.
The content of described light trigger is such as 3.3%, 3.6%, 3.9%, 4.2%, 4.5%, 4.8%, 5.1%, 5.4%, 5.7%, 6%, 6.3%, 6.6%, 6.9%, 7.2%, 7.5% or 7.8%.
The content of described auxiliary agent is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
The content of described pigment is such as 8%, 11%, 14%, 17%, 20%, 23%, 26%, 29% or 32%.
The content of described filler is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9% or 9.5%.
Preferably, the percentage by weight that described radiation curing topcoat (F) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 70%, light trigger 3 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 25%.
The content of described acrylic ester prepolymer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60% or 65%.
The content of described acrylate monomer is such as 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50% or 55%.
The content of described light trigger is such as 3.3%, 3.6%, 3.9%, 4.2%, 4.5% or 4.8%.
The content of described auxiliary agent is such as 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4% or 4.5%.
The content of described filler is such as 1%, 3%, 5%, 7%, 9%, 11%, 13%, 15%, 17%, 19%, 21% or 23%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.
Preferably, described acrylic ester prepolymer is the combination of any one or at least two kinds in epoxy acrylate, urethane acrylate, fluorochemical urethane acrylate, polyester acrylate, fluorine-containing polyester acrylate, amino acrylates, pure acrylic acid ester copolymer, fluoro-acrylate copolymer, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylate or silyl acrylate ester copolymer.
Preferably, described acrylate monomer is butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer (EHA), hydroxy-ethyl acrylate (HEA), hydroxyethyl methacrylate (MHEA), tri (propylene glycol) diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), third oxidation neopentylglycol diacrylate (PO-NPGDA), two (diethylene glycol) diacrylate (PDDA) or 1 of phthalic acid, 6 hexanediyl esters (HDDA), trimethylolpropane triacrylate (TMPTA), ethoxyquin trimethylolpropane triacrylate (EO-TMPTA), third oxidation trimethylolpropane triacrylate (PO-TMPTA), the combination of any one or at least two kinds in pentaerythritol triacrylate (PETA) or dipentaerythritol acrylate (DPHA).
Preferably; described light trigger is 2-hydroxy-2-methyl-1-acetone, 1-hydroxy-cyclohexyl-phenyl ketone, 2; 4; 6 (trimethylbenzene acyl group) diphenyl phosphine oxide, 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone, isopropyl thioxanthone anthraquinone (2; 4 isomer mixtures), 2-phenyl Bian-2-dimethyl amine-4;-morphoinopropyl phenyl ketone, two (2; 4,6-trimethylbenzoyl) mixture of any one or at least two kinds in-phenyl phosphine oxide or benzophenone.
Preferably, described auxiliary agent is the mixture of any one or at least two kinds in levelling agent (as MAA), defoamer (as 2700), wetting dispersing agent (as WD264) or adhesion promoter.
Preferably, described filler is that French chalk is or/and flatting silica.
Compared with the prior art, the present invention has following beneficial effect:
The present invention utilizes existing Thistle board, radiation curing material and technology is utilized to carry out colorize at substrate surface, functionalization, owing to adopting above scheme, the better performances of the colored paper gypseous decorating board of radiation curing of the present invention, intensity is high, rich color, paint film is full, hardness can reach 2H, scratch resistance and easy to clean, solvent resistant wiping number of times is greater than 100 times, lightweight, antibacterial, fire prevention and bionical, alternative timber, the non-renewable resources such as stone material, interior decoration can be widely used in, make it have very strong decoration functions, the convenient function etc. of construction, the surcharge of Thistle board is improved, meet the strategy of the resources sustainable development of country.
Accompanying drawing explanation
Fig. 1 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 1.
Fig. 2 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 2.
Fig. 3 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 3.
Fig. 4 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 4.
Fig. 5 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 5.
Fig. 6 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 6.
Fig. 7 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 7.
Fig. 8 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 8.
Fig. 9 is the structural representation of the colored paper gypseous decorating board of radiation curing of embodiment 9.
Figure of description mark is as follows:
A-substrate; B-radiation curing primary coat coating; C-radiation curable primer coating; D-color layer; E-radiation curing attachment scratch coat; F-radiation curing topcoat.
Detailed description of the invention
Technical scheme of the present invention is further illustrated by detailed description of the invention below in conjunction with accompanying drawing.
Specific embodiment 1
The colored paper gypseous decorating board of a kind of radiation curing, comprises substrate A, and the surface of substrate A is disposed with radiation curing attachment scratch coat E and color layer D.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 20%, acrylate monomer 60%, light trigger 10%, auxiliary agent 5% and filler 5%.
Described color layer D and colored colored paint layer, it is radiation curing coloured coating, and the percentage by weight that wherein radiation curing coloured coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10%, acrylate monomer 60%, light trigger 3% and pigment 27%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is epoxy acrylate.Described acrylate monomer is butyl acrylate.Described light trigger is 2-hydroxy-2-methyl-1-acetone.Described auxiliary agent is levelling agent.Described filler is French chalk.
Specific embodiment 2
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing attachment scratch coat E, color layer D, radiation curing attachment scratch coat E and radiation curing topcoat F.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 60%, acrylate monomer 20%, light trigger 10%, auxiliary agent 5% and filler 5%.
Described color layer D and colored colored paint layer, it is radiation curing coloured coating, and the percentage by weight that wherein radiation curing coloured coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 70%, acrylate monomer 10%, light trigger 8%, auxiliary agent 5%, pigment 7%.
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 70%, acrylate monomer 10%, light trigger 3% and filler 17%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is urethane acrylate.Described acrylate monomer is cyclohexyl acrylate.Described light trigger is 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone.Described auxiliary agent is defoamer (2700).Described filler is flatting silica.
Specific embodiment 3
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing attachment scratch coat E, color layer D and radiation curing topcoat F.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 50%, acrylate monomer 47%, light trigger 3%.
Described color layer D and colored colored paint layer, it is radiation curing coloured coating, and the percentage by weight that wherein radiation curing coloured coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 25%, acrylate monomer 25%, light trigger 3%, auxiliary agent 2%, pigment 35% and filler 10%.
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 45%, acrylate monomer 46%, light trigger 4%, auxiliary agent 5%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is the combination of epoxy acrylate and urethane acrylate.Described acrylate monomer is the combination of cyclohexyl acrylate and Isooctyl acrylate monomer (EHA).Described light trigger be 2-hydroxy-2-methyl-1-acetone and 1-hydroxy-cyclohexyl-phenyl ketone, mixture.Described auxiliary agent is wetting dispersing agent (WD264).Described filler is French chalk and flatting silica.
Specific embodiment 4
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curing attachment scratch coat E and color layer D.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 45%, acrylate monomer 45%, light trigger 6%, auxiliary agent 2% and filler 2%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 46%, acrylate monomer 30%, light trigger 3%, auxiliary agent 1% and filler 20%.
Described color layer D and colored colored paint layer, it is for exempting from finish paint transfer film (commercially available prod).
Described acrylic ester prepolymer is the combination of epoxy acrylate, urethane acrylate and fluorochemical urethane acrylate.Described acrylate monomer is the combination of butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer (EHA) and hydroxy-ethyl acrylate (HEA).Described light trigger is 2-hydroxy-2-methyl-1-acetone.Described auxiliary agent is levelling agent (MAA).Described filler is French chalk and flatting silica.
Specific embodiment 5
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curable primer coating C, radiation curing attachment scratch coat E and color layer D.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 35%, acrylate monomer 55%, light trigger 4%, auxiliary agent 3% and filler 3%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 46%, acrylate monomer 20%, light trigger 3%, auxiliary agent 1% and filler 30%.
The percentage by weight that described radiation curable primer coating C accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 15%, acrylate monomer 27%, light trigger 8%, auxiliary agent 5%, pigment 35% and filler 10%.
Described color layer D and colored colored paint layer, it is for needing finish paint transfer film (commercially available prod).
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is fluorine-containing polyester acrylate.Described acrylate monomer is neopentylglycol diacrylate (NPGDA).Described light trigger is 2-hydroxy-2-methyl-1-acetone.Described auxiliary agent is levelling agent (MAA).Described filler is French chalk.
Specific embodiment 6
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curing attachment scratch coat E, color layer D, radiation curing attachment scratch coat E and radiation curing topcoat F.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 50%, light trigger 5%, auxiliary agent 2% and filler 3%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 46%, acrylate monomer 25%, light trigger 1%, auxiliary agent 1% and filler 25%.
Described color layer D and colored colored paint layer, it is for exempting from finish paint transfer film (commercially available prod).
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 35%, light trigger 3%, auxiliary agent 2% and filler 20%.Described acrylic ester prepolymer is epoxy acrylate.Described acrylate monomer is butyl acrylate.Described light trigger is 2-hydroxy-2-methyl-1-acetone.Described auxiliary agent is levelling agent (MAA).Described filler is flatting silica.
Specific embodiment 7
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curable primer coating C, radiation curing attachment scratch coat E, color layer D, radiation curing attachment scratch coat E and radiation curing topcoat F.
Described substrate A is Thistle board.
Preferably, the percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 42%, acrylate monomer 48%, light trigger 4%, auxiliary agent 2% and filler 4%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 31%, light trigger 3%, auxiliary agent 1% and filler 25%.
The percentage by weight that described radiation curable primer coating C accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 20%, acrylate monomer 32%, light trigger 8%, auxiliary agent 5%, pigment 25% and filler 10%.
Described color layer D and colored colored paint layer, it is for needing finish paint transfer film (commercially available prod).
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 45%, acrylate monomer 35%, light trigger 3%, auxiliary agent 2% and filler 15%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is amino acrylates.Described acrylate monomer is the combination of butyl acrylate, cyclohexyl acrylate and Isooctyl acrylate monomer (EHA).Described light trigger is the mixture of two (2,4,6-trimethylbenzoyl)-phenyl phosphine oxide and benzophenone.Described auxiliary agent is the mixture of levelling agent (MAA), defoamer (2700) and wetting dispersing agent (WD264).Described filler is French chalk and flatting silica.
Specific embodiment 8
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curing attachment scratch coat E, color layer D and radiation curing topcoat F.
Described substrate A is Thistle board.
Preferably, the percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 45%, acrylate monomer 45%, light trigger 5%, auxiliary agent 3% and filler 2%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 26%, light trigger 3%, auxiliary agent 1% and filler 25%.
Described color layer D and colored colored paint layer, it is for exempting from finish paint transfer film (commercially available prod).
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 45%, acrylate monomer 30%, light trigger 3%, auxiliary agent 2% and filler 20%.
Described acrylic ester prepolymer is silicon-based polyurethane acrylate.Described acrylate monomer is 1,6 hexanediyl esters (HDDA).Described light trigger is, 2-phenyl Bian-2-dimethyl amine-4 ,-morphoinopropyl phenyl ketone.Described auxiliary agent is the mixture of levelling agent (MAA), defoamer (2700) and wetting dispersing agent (WD264).Described filler is flatting silica.
Specific embodiment 9
The colored paper gypseous decorating board of a kind of radiation curing: comprise substrate A, radiation curing primary coat coating B, radiation curable primer coating C, radiation curing attachment scratch coat E, color layer D and radiation curing topcoat F.
Described substrate A is Thistle board.
The percentage by weight that described radiation curing attachment scratch coat E accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 50%, acrylate monomer 50%, light trigger 4%, auxiliary agent 1% and filler 5%.
The percentage by weight that radiation curing primary coat coating B accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 36%, light trigger 3%, auxiliary agent 1% and filler 20%.
The percentage by weight that described radiation curable primer coating C accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 30%, acrylate monomer 22%, light trigger 8%, auxiliary agent 5%, pigment 25% and filler 10%.
Described color layer D and colored colored paint layer, it is for needing finish paint transfer film (commercially available prod).
The percentage by weight that described radiation curing topcoat F accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 40%, acrylate monomer 35%, light trigger 3%, auxiliary agent 2% and filler 20%.
Described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment.Described acrylic ester prepolymer is epoxy acrylate.Described acrylate monomer is butyl acrylate.Described light trigger is 2-hydroxy-2-methyl-1-acetone.Described auxiliary agent is levelling agent (MAA).Described filler is that French chalk is or/and flatting silica.
Above-described content can combine enforcement individually or in every way, and these variant are all within protection scope of the present invention.
It should be noted that, in this article, term " comprises ", " comprising " or its any other variant are intended to contain comprising of nonexcludability, thus make to comprise the composition of a series of key element or method not only comprises those key elements, but also comprise other key elements clearly do not listed, or also comprise by this composition or the intrinsic key element of method.When not more restrictions, the key element limited by statement " comprising ... ", and be not precluded within the composition or method comprising described key element and also there is other identical element.
The present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (10)
1. the colored paper gypseous decorating board of radiation curing, is characterized in that, comprise substrate (A), and the surface of substrate (A) is disposed with radiation curing attachment scratch coat (E) and color layer (D).
2. decorative panel as claimed in claim 1, it is characterized in that, radiation curing attachment scratch coat (E) and radiation curing topcoat (F) is provided with successively on described color layer (D), or, be provided with radiation curing topcoat (F) on described color layer (D).
3. decorative panel as claimed in claim 1 or 2, is characterized in that, is provided with radiation curing primary coat coating (B) between described substrate (A) and radiation curing attachment scratch coat (E).
4. decorative panel as claimed in claim 3, is characterized in that, is provided with radiation curable primer coating (C) between described radiation curing primary coat coating (B) and radiation curing attachment scratch coat (E).
5. the decorative panel as described in one of claim 1-4, is characterized in that, described substrate (A) is Thistle board.
6. the decorative panel as described in one of claim 1-5, it is characterized in that, the percentage by weight that described radiation curing attachment scratch coat (E) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 60%, acrylate monomer 20 ~ 60%, light trigger 3 ~ 10%, auxiliary agent 0 ~ 5% and filler 0 ~ 5%;
Preferably, color layer (D) is for exempting from finish paint transfer film, needing finish paint transfer film or radiation curing coloured coating, and the percentage by weight that wherein radiation curing coloured coating accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 60%, light trigger 3 ~ 8%, auxiliary agent 0 ~ 5%, pigment 5 ~ 35% and filler 0 ~ 10%.
7. the decorative panel as described in one of claim 2-6, it is characterized in that, the percentage by weight that described radiation curing topcoat (F) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 70%, light trigger 3 ~ 5%, auxiliary agent 0 ~ 5% and filler 0 ~ 25%.
8. the decorative panel as described in one of claim 3-7, it is characterized in that, the percentage by weight that radiation curing primary coat coating (B) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 20 ~ 70%, acrylate monomer 10 ~ 40%, light trigger 2 ~ 5%, auxiliary agent 0 ~ 2% and filler 5 ~ 40%.
9. the decorative panel as described in one of claim 3-8, it is characterized in that, the percentage by weight that described radiation curable primer coating (C) accounts for by each component prepares primarily of following raw material: acrylic ester prepolymer 10 ~ 70%, acrylate monomer 10 ~ 60%, light trigger 3 ~ 8%, auxiliary agent 0 ~ 5%, pigment 5 ~ 35% and filler 0 ~ 10%.
10. the decorative panel as described in one of claim 6-9, it is characterized in that, described pigment is the combination of any one or at least two kinds in titanium dioxide, carbon black, iron oxide, phthalocyanine blue, green, the brown chrome yellow of the phthalein mountain valley with clumps of trees and bamboo, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence, fluorescent material, color intrigue pigment or reflective pigment;
Preferably, described acrylic ester prepolymer is the combination of any one or at least two kinds in epoxy acrylate, urethane acrylate, fluorochemical urethane acrylate, polyester acrylate, fluorine-containing polyester acrylate, amino acrylates, pure acrylic acid ester copolymer, fluoro-acrylate copolymer, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylate or silyl acrylate ester copolymer;
Preferably, described acrylate monomer is butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, hydroxy-ethyl acrylate, hydroxyethyl methacrylate, tri (propylene glycol) diacrylate, propylene glycol diacrylate, neopentylglycol diacrylate, third oxidation neopentylglycol diacrylate, two (diethylene glycol) diacrylate of phthalic acid, 1, 6 hexanediyl esters, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, the combination of any one or at least two kinds in pentaerythritol triacrylate or dipentaerythritol acrylate,
Preferably, described light trigger is 2-hydroxy-2-methyl-1-acetone, 1-hydroxy-cyclohexyl-phenyl ketone, 2,4,6 (trimethylbenzene acyl group) diphenyl phosphine oxide, 2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone, isopropyl thioxanthone anthraquinone (2,4 isomer mixtures), 2-phenyl Bian-2-dimethyl amine-4,-morphoinopropyl phenyl ketone, two (2,4,6-trimethylbenzoyl) mixture of any one or at least two kinds in-phenyl phosphine oxide or benzophenone;
Preferably, described auxiliary agent is the mixture of any one or at least two kinds in levelling agent, defoamer, wetting dispersing agent or adhesion promoter;
Preferably, described filler is that French chalk is or/and flatting silica.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410438757.9A CN104234360A (en) | 2014-08-29 | 2014-08-29 | Radiation curing colored paper gypsum plaster decorative board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410438757.9A CN104234360A (en) | 2014-08-29 | 2014-08-29 | Radiation curing colored paper gypsum plaster decorative board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104234360A true CN104234360A (en) | 2014-12-24 |
Family
ID=52223184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410438757.9A Pending CN104234360A (en) | 2014-08-29 | 2014-08-29 | Radiation curing colored paper gypsum plaster decorative board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104234360A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104989046A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing matte decoration plate and manufacturing method thereof |
| CN104989062A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing color 3D decoration plate and manufacturing method thereof |
| CN106013672A (en) * | 2015-11-30 | 2016-10-12 | 珠海市佳伟力环保科技有限公司 | Radiation curable coating decorative board |
| CN108977053A (en) * | 2018-07-26 | 2018-12-11 | 北京小米移动软件有限公司 | Composite coating material and its preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6111251A (en) * | 1984-06-28 | 1986-01-18 | 大日本印刷株式会社 | Manufacture of decorative material |
| CN103625033A (en) * | 2013-11-25 | 2014-03-12 | 常熟华冶薄板有限公司 | Ultraviolet-curable crackle paint color-precoated steel plate and preparation method thereof |
| CN103774816A (en) * | 2014-01-08 | 2014-05-07 | 珠海市佳伟力环保科技有限公司 | Radiation cured colored decorative sheet |
| CN203854397U (en) * | 2014-01-10 | 2014-10-01 | 珠海市佳伟力环保科技有限公司 | Radiation curing and transferring decorative plate |
| CN204309496U (en) * | 2014-08-29 | 2015-05-06 | 中关村人居环境工程与材料研究院 | A kind of take Thistle board as the radiation curing colored decorating plate of base material |
-
2014
- 2014-08-29 CN CN201410438757.9A patent/CN104234360A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6111251A (en) * | 1984-06-28 | 1986-01-18 | 大日本印刷株式会社 | Manufacture of decorative material |
| CN103625033A (en) * | 2013-11-25 | 2014-03-12 | 常熟华冶薄板有限公司 | Ultraviolet-curable crackle paint color-precoated steel plate and preparation method thereof |
| CN103774816A (en) * | 2014-01-08 | 2014-05-07 | 珠海市佳伟力环保科技有限公司 | Radiation cured colored decorative sheet |
| CN203854397U (en) * | 2014-01-10 | 2014-10-01 | 珠海市佳伟力环保科技有限公司 | Radiation curing and transferring decorative plate |
| CN204309496U (en) * | 2014-08-29 | 2015-05-06 | 中关村人居环境工程与材料研究院 | A kind of take Thistle board as the radiation curing colored decorating plate of base material |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104989046A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing matte decoration plate and manufacturing method thereof |
| CN104989062A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing color 3D decoration plate and manufacturing method thereof |
| CN104989046B (en) * | 2014-12-29 | 2017-10-03 | 中关村人居环境工程与材料研究院 | A kind of ultra-violet curing transfer dumb light decorative panel and its manufacture method |
| CN104989062B (en) * | 2014-12-29 | 2017-11-10 | 中关村人居环境工程与材料研究院 | A kind of ultraviolet curing chromatic 3D decorative panels and its manufacture method |
| CN106013672A (en) * | 2015-11-30 | 2016-10-12 | 珠海市佳伟力环保科技有限公司 | Radiation curable coating decorative board |
| CN108977053A (en) * | 2018-07-26 | 2018-12-11 | 北京小米移动软件有限公司 | Composite coating material and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103774816B (en) | A kind of radiation curing colored decorating plate | |
| CN101941339B (en) | Ultraviolet light cured transfer printing film and preparation method and application thereof | |
| CN105885494B (en) | Radiation curing fluosilicic coating and its preparation method and application | |
| CN101235672B (en) | Ultraviolet light curing overlay film decorative board for wall and method for making same | |
| CN102153899B (en) | Ultraviolet-curable water-based colored paint composition | |
| CN201208874Y (en) | Printing decorated sheet by ultraviolet light curing | |
| CN101158210A (en) | Ultraviolet curing chromatic wall decoration board and preparation method thereof | |
| CN201068629Y (en) | Ultraviolet light curing colorful decorative board for wall | |
| CN202500289U (en) | Ultra violet curing colored decorative plate | |
| CN105647257A (en) | Water-based radiation-cured coating and use thereof | |
| CN201679177U (en) | UV cured transfer film metal decorative board | |
| CN104234360A (en) | Radiation curing colored paper gypsum plaster decorative board | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN103132671B (en) | Novel transfer printing ceramic tile and preparation method thereof | |
| CN203854397U (en) | Radiation curing and transferring decorative plate | |
| CN105882042A (en) | Radiation curing decorative sheet with self-cleaning, anti-microbial and sterilization functions | |
| CN202391056U (en) | Ultraviolet curing painting decorative plate | |
| CN105860778A (en) | Waterborne radiation-curable coating decorative plate and preparation method thereof | |
| CN205100481U (en) | Radiation curing tectorial membrane decorative board | |
| CN201209305Y (en) | Ultraviolet curing and coating decorative board for wall | |
| CN105034670B (en) | A kind of method of inorganic plate heat transfer printing figure line | |
| CN205100480U (en) | Radiation curing color printing decorative plate | |
| CN201566396U (en) | UV curing colored PVC decorative sheet | |
| CN101906862A (en) | UV ink printed metal gusset plate for ceiling decoration | |
| CN106366901A (en) | Doubly solidified coloring UV nanometer paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141224 |
|
| RJ01 | Rejection of invention patent application after publication |