CN104231492A - Anti-static PVC sole material and manufacturing method thereof - Google Patents
Anti-static PVC sole material and manufacturing method thereof Download PDFInfo
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- CN104231492A CN104231492A CN201410566331.1A CN201410566331A CN104231492A CN 104231492 A CN104231492 A CN 104231492A CN 201410566331 A CN201410566331 A CN 201410566331A CN 104231492 A CN104231492 A CN 104231492A
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- sole material
- quaternary ammonium
- ammonium salt
- pvc sole
- anlistatig pvc
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Abstract
The invention provides an anti-static PVC sole material, and the anti-static PVC sole material comprises the components in parts by weight as follows; 55-65 parts of PVC, 3-5 parts of quaternary ammonium salt cationic surface active agent, 1-3 parts of carbon fiber powder, 20-30 parts of plasticizer, 2-5 parts of foaming agent, 3-8 parts of white carbon black and 5-10 parts of filler. The manufacturing method for anti-static PVC sole material is also provided. The anti-static PVC sole material has good anti-static performance applied to the anti-static shoes.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of anlistatig PVC sole material and manufacture method thereof.
Background technology:
The production plant of the microelectronics industry such as anti-static shoes (Anti-static shoes) is electronic semiconductor components (Electronic semiconductor devices), robot calculator (The electronic computer), electronics (Electronic communication equipment) and unicircuit (integrated circuit) and senior testing laboratory reduce or eliminate a kind of footware that static hazard wears.Anti-static shoes by electrostatic from human body guiding the earth, thus can eliminate static electricity on human body, and walk about the produced dust of the personnel that simultaneously also restrained effectively in dust free chamber, is suitable for pharmaceutical factory, food factory, Electronics Factory's dust proof workshop, laboratory etc.Anti-static shoes adopts PU or PVC material to make sole, and common PVC sole material can not be applicable to anti-static shoes.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of anlistatig PVC sole material, possesses good antistatic property, is applicable to anti-static shoes.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of anlistatig PVC sole material, its weight part consists of:
Preferably, quaternary ammonium salt cationic surfactant of the present invention is at least one in octadecylamine Soxylat A 25-7 bi-quaternary ammonium salt, lauryl amine Soxylat A 25-7 bi-quaternary ammonium salt, two lauryl amine Soxylat A 25-7 three quaternary ammonium salt.
Preferably, carbon fiber powder of the present invention is PAN-based carbon fiber powder.
Preferably, the softening agent of the present invention at least one that to be described softening agent be in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
Preferably, whipping agent of the present invention is Cellmic C 121.
Preferably, white carbon black of the present invention is thermal silica.
Preferably, weighting agent of the present invention is potter's clay or calcium sulfate or barium sulfate.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned anlistatig PVC sole material.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for anlistatig PVC sole material, comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Therefore compared with prior art, the present invention has following beneficial effect:
Quaternary ammonium salt cationic surfactant has good antistatic property, under the synergy of carbon fiber powder, PVC sole material is made to have good antistatic property, and effectively prevent the problem of the sole deliquescing caused due to adding of static inhibitor, larger impact can not be produced on the hardness of sole, therefore be applicable to anti-static shoes.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Embodiment 2
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Embodiment 3
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Embodiment 4
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Embodiment 5
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Embodiment 6
A kind of anlistatig PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
By the examination criteria of anlistatig PVC sole material obtained for embodiment 1 to 6 according to GB GB21148-2007, test its volume resistance respectively, result is respectively 7.8 × 10
6Ω cm, 1.5 × 10
7Ω cm, 3.1 × 10
7Ω cm, 8.9 × 10
6Ω cm, 2.6 × 10
7Ω cm, 9.3 × 10
6Ω cm, all possesses good antistatic property.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (8)
1. an anlistatig PVC sole material, is characterized in that: its weight part consists of:
2. the anlistatig PVC sole material of one according to claim 1, is characterized in that: described quaternary ammonium salt cationic surfactant is at least one in octadecylamine Soxylat A 25-7 bi-quaternary ammonium salt, lauryl amine Soxylat A 25-7 bi-quaternary ammonium salt, two lauryl amine Soxylat A 25-7 three quaternary ammonium salt.
3. the anlistatig PVC sole material of one according to claim 1, is characterized in that: described carbon fiber powder is PAN-based carbon fiber powder.
4. the anlistatig PVC sole material of one according to claim 1, is characterized in that: the described softening agent at least one that to be described softening agent be in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
5. the anlistatig PVC sole material of one according to claim 1, is characterized in that: described whipping agent is Cellmic C 121.
6. the anlistatig PVC sole material of one according to claim 1, is characterized in that: described white carbon black is thermal silica.
7. the anlistatig PVC sole material of one according to claim 1, is characterized in that: described weighting agent is potter's clay or calcium sulfate or barium sulfate.
8. the manufacture method of a kind of anlistatig PVC sole material according to claim 1 ~ 7 any one, is characterized in that: comprise the following steps:
(1) dry: to choose quaternary ammonium salt cationic surfactant by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain anlistatig PVC pellet;
(4) injection moulding: anlistatig PVC pellet step (3) obtained adds injection moulding machine, and injection moulding obtains anlistatig PVC sole material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566331.1A CN104231492A (en) | 2014-10-22 | 2014-10-22 | Anti-static PVC sole material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566331.1A CN104231492A (en) | 2014-10-22 | 2014-10-22 | Anti-static PVC sole material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104231492A true CN104231492A (en) | 2014-12-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410566331.1A Pending CN104231492A (en) | 2014-10-22 | 2014-10-22 | Anti-static PVC sole material and manufacturing method thereof |
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| CN (1) | CN104231492A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038025A (en) * | 2015-07-31 | 2015-11-11 | 苏州天健竹业科技有限公司 | Carbon fiber pedal for bicycle and preparation method thereof |
| CN107286509A (en) * | 2017-07-12 | 2017-10-24 | 宁波市中迪鞋业有限公司 | A kind of PVC sole material and preparation method thereof |
| CN108164882A (en) * | 2018-01-25 | 2018-06-15 | 温州鑫彩鸿安防科技有限公司 | A kind of Anti-static safety shoes and its manufacturing method |
| CN114634681A (en) * | 2022-03-16 | 2022-06-17 | 达州市嘉源体育用品有限公司 | High-elastic anti-static sole and preparation method thereof |
| CN114908434A (en) * | 2022-06-01 | 2022-08-16 | 方荣 | Skin-friendly soft fabric and preparation method thereof |
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| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
| CN103113692A (en) * | 2013-01-28 | 2013-05-22 | 安徽龙庵电缆集团有限公司 | Cold-resistant flame-retardant anti-static polyvinyl chloride sheathing material for coal mine cable |
| CN103275439A (en) * | 2013-06-21 | 2013-09-04 | 苏州市景荣科技有限公司 | Ageing-resistant HPVC foaming sole material |
| CN103275422A (en) * | 2013-05-31 | 2013-09-04 | 苏州市景荣科技有限公司 | Antistatic PVC (Polyvinyl Chloride) sole material |
| CN103571091A (en) * | 2013-10-15 | 2014-02-12 | 苏州市景荣科技有限公司 | Antistatic PVC (Polyvinyl Chloride) sole material |
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2014
- 2014-10-22 CN CN201410566331.1A patent/CN104231492A/en active Pending
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| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
| CN103113692A (en) * | 2013-01-28 | 2013-05-22 | 安徽龙庵电缆集团有限公司 | Cold-resistant flame-retardant anti-static polyvinyl chloride sheathing material for coal mine cable |
| CN103275422A (en) * | 2013-05-31 | 2013-09-04 | 苏州市景荣科技有限公司 | Antistatic PVC (Polyvinyl Chloride) sole material |
| CN103275439A (en) * | 2013-06-21 | 2013-09-04 | 苏州市景荣科技有限公司 | Ageing-resistant HPVC foaming sole material |
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| 欧育湘等: "《塑料助剂性能与选用速查手册》", 31 January 2012, article "抗静电剂ASA-156" * |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038025A (en) * | 2015-07-31 | 2015-11-11 | 苏州天健竹业科技有限公司 | Carbon fiber pedal for bicycle and preparation method thereof |
| CN107286509A (en) * | 2017-07-12 | 2017-10-24 | 宁波市中迪鞋业有限公司 | A kind of PVC sole material and preparation method thereof |
| CN108164882A (en) * | 2018-01-25 | 2018-06-15 | 温州鑫彩鸿安防科技有限公司 | A kind of Anti-static safety shoes and its manufacturing method |
| CN114634681A (en) * | 2022-03-16 | 2022-06-17 | 达州市嘉源体育用品有限公司 | High-elastic anti-static sole and preparation method thereof |
| CN114908434A (en) * | 2022-06-01 | 2022-08-16 | 方荣 | Skin-friendly soft fabric and preparation method thereof |
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Application publication date: 20141224 |
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