CN103571091A - Antistatic PVC (Polyvinyl Chloride) sole material - Google Patents
Antistatic PVC (Polyvinyl Chloride) sole material Download PDFInfo
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- CN103571091A CN103571091A CN201310481888.0A CN201310481888A CN103571091A CN 103571091 A CN103571091 A CN 103571091A CN 201310481888 A CN201310481888 A CN 201310481888A CN 103571091 A CN103571091 A CN 103571091A
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- carbon black
- sole material
- sole
- antistatic
- antistatic pvc
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Abstract
The invention discloses an antistatic PVC (Polyvinyl Chloride) sole material. The antistatic PVC sole material comprises the following components in percentage by weight: 50%-70% of PVC, 5%-20% of phthalic acid ester, 10%-30% of conductive carbon black powder and 1%-3% of calcium-zinc stabilizer, wherein the conductive carbon black powder is pretreated by using a coupling agent. The antistatic PVC sole material has an excellent antistatic function; the conductive carbon black powder is uniformly distributed in the sole material and can form a durable and effective conductive network.
Description
Technical field:
The present invention relates to footwear material technical field, be specifically related to a kind of antistatic PVC material for sole of shoe.
Background technology:
City shoe material mainly be take PVC, PU, EVA etc. and is prepared from as base material adds auxiliary agent, but these macromolecule shoe materials do not have anlistatig function, can not be by the static guiding of human body to the earth.And in electron production workshop, the static that human body produces and gathers can damage electronic devices and components and cause, gathering discharge generation electrical spark and may make combustible and explosive articles blast petrochemical industry workshop static electricity on human body.Therefore, in electronics, field of petrochemical industry, the antistatic property of footwear material has been proposed to requirement.
Summary of the invention:
The object of the present invention is to provide a kind of PVC material for sole of shoe with anti-static function, it has the advantages that composition is simple, production cost is low, antistatic effect is good.
For achieving the above object, a kind of antistatic PVC material for sole of shoe of the present invention consists of following component by weight percentage:
Graphitized carbon black powder will carry out pre-treatment with coupling agent.
As technique scheme preferably, described graphitized carbon black diameter of particle is at 20nm-100nm.
As technique scheme preferably, described graphitized carbon black powder is Shawinigan black.
As technique scheme preferably, the content of described graphitized carbon black powder is 15%-25%.
Beneficial effect of the present invention is: this material for sole of shoe has good anti-static function, and graphitized carbon black is evenly distributed in material for sole of shoe, can form lasting effectively conductive network.
Embodiment:
Key step prepared by antistatic PVC material for sole of shoe of the present invention is as follows:
(a) graphitized carbon black powder carries out pre-treatment with coupling agent;
Described coupling agent is stearic acid-coupling agent, by stearic acid, coupling agent in mass ratio 1:2 after mixing, be dissolved in ethanol and make pretreatment fluid, then graphitized carbon black is added in pretreatment fluid 100 ℃ of reactions, finally by product drying for standby.
(b) press above-mentioned mass percent by PVC material, phthalic ester, pretreated graphitized carbon black, calcium zinc class stablizer mixes under 80 ℃ of temperature condition, then sends into screw extrusion press extruding pelletization;
(c) by pellet extrusion moulding under 160 ℃ of conditions, make antistatic PVC material for sole of shoe.
Embodiment 1
70 parts of PVC materials, 14 parts of phthalic esters, 15 parts of Shawinigan blacks, 1 part of calcium zinc class stablizer mixes under 80 ℃ of temperature condition, then sends into extruding pelletization in twin screw extruder, then that pellet is dry by injection moulding in injection moulding machine.Press the method for GB21148-2007, the volume resistance recording: 5.6 * 10
5Ω .cm.
Embodiment 2
50 parts of PVC materials, 20 parts of phthalic esters, 27 parts of Shawinigan blacks, 3 parts of calcium zinc class stablizers mix under 80 ℃ of temperature condition, then send into extruding pelletization in twin screw extruder, then that pellet is dry by injection moulding in injection moulding machine.Press the method for GB21148-2007, the volume resistance recording: 2.1 * 10
4Ω .cm.
Embodiment 3
60 parts of PVC materials, 15 parts of phthalic esters, 23 parts of Shawinigan blacks, 2 parts of calcium zinc class stablizers mix under 80 ℃ of temperature condition, then send into extruding pelletization in twin screw extruder, then that pellet is dry by injection moulding in injection moulding machine.Press the method for GB21148-2007, the volume resistance recording: 5.8 * 10
4Ω .cm.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (4)
1. an antistatic PVC material for sole of shoe, is characterized in that: following component, consist of by weight percentage:
Graphitized carbon black powder will carry out pre-treatment with coupling agent.
2. a kind of antistatic PVC material for sole of shoe according to claim 1, is characterized in that: described graphitized carbon black diameter of particle is at 20nm-100nm.
3. a kind of antistatic PVC material for sole of shoe according to claim 1, is characterized in that: described graphitized carbon black powder is Shawinigan black.
4. a kind of antistatic PVC material for sole of shoe according to claim 1, is characterized in that; The content of described graphitized carbon black powder is 15%-25%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310481888.0A CN103571091A (en) | 2013-10-15 | 2013-10-15 | Antistatic PVC (Polyvinyl Chloride) sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310481888.0A CN103571091A (en) | 2013-10-15 | 2013-10-15 | Antistatic PVC (Polyvinyl Chloride) sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103571091A true CN103571091A (en) | 2014-02-12 |
Family
ID=50043845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310481888.0A Pending CN103571091A (en) | 2013-10-15 | 2013-10-15 | Antistatic PVC (Polyvinyl Chloride) sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103571091A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231493A (en) * | 2014-10-22 | 2014-12-24 | 苏州市景荣科技有限公司 | Anti-static polyvinyl chloride sole material and manufacturing method thereof |
| CN104231492A (en) * | 2014-10-22 | 2014-12-24 | 苏州市景荣科技有限公司 | Anti-static PVC sole material and manufacturing method thereof |
| CN110885515A (en) * | 2019-12-17 | 2020-03-17 | 含山县仁盛鞋业有限公司 | Preparation process of anti-static plastic slipper material |
| CN112175327A (en) * | 2020-10-20 | 2021-01-05 | 界首市旭升塑胶制品有限公司 | Preparation method of PVC (polyvinyl chloride) plastic for wear-resistant and antibacterial rubber shoes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1150803A (en) * | 1967-01-10 | 1969-05-07 | Ici Ltd | Vinyl Chloride Polymer Compositions |
| CN101159174A (en) * | 2007-09-03 | 2008-04-09 | 上海斯瑞聚合体科技有限公司 | Explosion prevention PVC sheath material for mine cable and preparation method thereof |
| CN103289240A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Antistatic PVC sole production method |
-
2013
- 2013-10-15 CN CN201310481888.0A patent/CN103571091A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1150803A (en) * | 1967-01-10 | 1969-05-07 | Ici Ltd | Vinyl Chloride Polymer Compositions |
| CN101159174A (en) * | 2007-09-03 | 2008-04-09 | 上海斯瑞聚合体科技有限公司 | Explosion prevention PVC sheath material for mine cable and preparation method thereof |
| CN103289240A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Antistatic PVC sole production method |
Non-Patent Citations (1)
| Title |
|---|
| 丁健等: "抗静电半硬质PVC材料的制备及性能", 《塑料科技》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231493A (en) * | 2014-10-22 | 2014-12-24 | 苏州市景荣科技有限公司 | Anti-static polyvinyl chloride sole material and manufacturing method thereof |
| CN104231492A (en) * | 2014-10-22 | 2014-12-24 | 苏州市景荣科技有限公司 | Anti-static PVC sole material and manufacturing method thereof |
| CN110885515A (en) * | 2019-12-17 | 2020-03-17 | 含山县仁盛鞋业有限公司 | Preparation process of anti-static plastic slipper material |
| CN112175327A (en) * | 2020-10-20 | 2021-01-05 | 界首市旭升塑胶制品有限公司 | Preparation method of PVC (polyvinyl chloride) plastic for wear-resistant and antibacterial rubber shoes |
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Application publication date: 20140212 |