CN104231493A - Anti-static polyvinyl chloride sole material and manufacturing method thereof - Google Patents
Anti-static polyvinyl chloride sole material and manufacturing method thereof Download PDFInfo
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- CN104231493A CN104231493A CN201410566599.5A CN201410566599A CN104231493A CN 104231493 A CN104231493 A CN 104231493A CN 201410566599 A CN201410566599 A CN 201410566599A CN 104231493 A CN104231493 A CN 104231493A
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- polyvinyl chloride
- anlistatig
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- shoe
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Abstract
The invention provides an anti-static polyvinyl chloride sole material, and the anti-static polyvinyl chloride sole material comprises the components in parts by weight as follows; 35-50 parts of polyvinyl chloride, 1-5 parts of anionic antistatic agent, 20-30 parts of plasticizer, 1-5 parts of antioxygen, 2-5 parts of reinforcing agent, 3-8 parts of polyethylene wax, 5-15 parts of chlorinated polyethylene and 3-10 parts of calcium carbonate. The manufacturing method for anti-static polyvinyl chloride sole material is also provided. The anti-static polyvinyl chloride sole material has good anti-static performance applied to the anti-static situation.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of anlistatig polyvinyl chloride material for sole of shoe and manufacture method thereof.
Background technology:
Polyvinyl chloride is the thermoplastic resin be polymerized under initiator effect by vinylchlorid, it is the homopolymer of vinylchlorid, of many uses, can be used for sheet material, tubing, sole, toy, door and window, wire outer skin, stationery, packing box etc., wherein polyvinyl chloride has great occupation rate in footwear material field.The surface resistivity of common polyvinyl chloride shoe material is higher, easily produces electrostatic, and electrostatic can cause the blast of the inflammable articles in the occasions such as chemical industry storehouse, oil depot, colliery, and the accident such as the inefficacy of electronic devices and components.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of anlistatig polyvinyl chloride material for sole of shoe, possesses good antistatic property, is applicable to anti-electrostatic occasion.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Preferably, anionic antistatic agent of the present invention is alkyl sodium sulfonate.
Preferably, the softening agent of the present invention at least one that to be described softening agent be in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
Preferably, oxidation inhibitor of the present invention is the one in lead stearate, dibasic lead stearate or tribasic lead stearate.
Preferably, strengthening agent of the present invention is the one in white carbon black, silicon-dioxide or diatomite.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned anlistatig polyvinyl chloride material for sole of shoe.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for anlistatig polyvinyl chloride material for sole of shoe, comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the anionic antistatic agent after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Therefore compared with prior art, the present invention has following beneficial effect:
Anionic antistatic agent has good antistatic property as a kind of rubber surface promoting agent, and softening agent can increase the distance between macromolecular chain, make molecular motion more easy, improve the porosity of rubber, be conducive to static inhibitor and play antistatic property to product surface migration, improve the antistatic property of material for sole of shoe, antistatic occasion can be applicable to; Oxidation inhibitor can effectively delay or suppress the carrying out of material for sole of shoe oxidising process, thus effectively stops it aging and extend its work-ing life; Strengthening agent can effectively be avoided causing the softening of material for sole of shoe due to adding of anionic antistatic agent, improved hardness and the intensity of material for sole of shoe.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Embodiment 2
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Embodiment 3
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Embodiment 4
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Embodiment 5
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Embodiment 6
A kind of anlistatig polyvinyl chloride material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the quaternary ammonium salt cationic surfactant after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
By the examination criteria of anlistatig polyvinyl chloride material for sole of shoe obtained for embodiment 1 to 6 according to GB GB21148-2007, test its volume resistance respectively, result is respectively 3.5 × 10
7Ω cm, 1.9 × 10
7Ω cm, 6.7 × 10
6Ω cm, 4.1 × 10
7Ω cm, 8.8 × 10
7Ω cm, 6.5 × 10
6Ω cm, all has good antistatic property.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (6)
1. an anlistatig polyvinyl chloride material for sole of shoe, is characterized in that: its weight part consists of:
2. the anlistatig polyvinyl chloride material for sole of shoe of one according to claim 1, is characterized in that: described anionic antistatic agent is alkyl sodium sulfonate.
3. the anlistatig polyvinyl chloride material for sole of shoe of one according to claim 1, is characterized in that: the described softening agent at least one that to be described softening agent be in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
4. the anlistatig polyvinyl chloride material for sole of shoe of one according to claim 1, is characterized in that: described oxidation inhibitor is the one in lead stearate, dibasic lead stearate or tribasic lead stearate.
5. the anlistatig polyvinyl chloride material for sole of shoe of one according to claim 1, is characterized in that: described strengthening agent is the one in white carbon black, silicon-dioxide or diatomite.
6. the manufacture method of a kind of anlistatig polyvinyl chloride material for sole of shoe according to Claims 1 to 5 any one, is characterized in that: comprise the following steps:
(1) dry: to choose anionic antistatic agent by formula, dried;
(2) mixing: by formula by mixing for other component in the anionic antistatic agent after oven dry and formula, to obtain the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrudes and obtain anlistatig polyvinyl chloride granules;
(4) injection moulding: the anlistatig polyvinyl chloride granules that step (3) obtains is added injection moulding machine, injection moulding obtains anlistatig polyvinyl chloride material for sole of shoe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566599.5A CN104231493A (en) | 2014-10-22 | 2014-10-22 | Anti-static polyvinyl chloride sole material and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566599.5A CN104231493A (en) | 2014-10-22 | 2014-10-22 | Anti-static polyvinyl chloride sole material and manufacturing method thereof |
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| CN104231493A true CN104231493A (en) | 2014-12-24 |
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| CN201410566599.5A Pending CN104231493A (en) | 2014-10-22 | 2014-10-22 | Anti-static polyvinyl chloride sole material and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542342A (en) * | 2016-01-20 | 2016-05-04 | 苏州市景荣科技有限公司 | Novel antistatic PVC sole material |
| CN106674799A (en) * | 2016-11-28 | 2017-05-17 | 安徽天安新材料有限公司 | Polyvinyl chloride mixture, polyvinyl chloride film and preparation methods of polyvinyl chloride mixture and polyvinyl chloride film |
| CN109837766A (en) * | 2019-01-25 | 2019-06-04 | 南通倍成劳护用品有限公司 | A kind of antistatic butyronitrile gloves and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542342A (en) * | 2016-01-20 | 2016-05-04 | 苏州市景荣科技有限公司 | Novel antistatic PVC sole material |
| CN106674799A (en) * | 2016-11-28 | 2017-05-17 | 安徽天安新材料有限公司 | Polyvinyl chloride mixture, polyvinyl chloride film and preparation methods of polyvinyl chloride mixture and polyvinyl chloride film |
| CN109837766A (en) * | 2019-01-25 | 2019-06-04 | 南通倍成劳护用品有限公司 | A kind of antistatic butyronitrile gloves and preparation method thereof |
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Application publication date: 20141224 |
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