CN104262857A - Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof - Google Patents
Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof Download PDFInfo
- Publication number
- CN104262857A CN104262857A CN201410566334.5A CN201410566334A CN104262857A CN 104262857 A CN104262857 A CN 104262857A CN 201410566334 A CN201410566334 A CN 201410566334A CN 104262857 A CN104262857 A CN 104262857A
- Authority
- CN
- China
- Prior art keywords
- sole material
- high abrasion
- pvc
- pvc sole
- material according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention provides a highly-wear-resistant PVC (Polyvinyl Chloride) sole material which comprises the following components in parts by weight: 50-70 parts of PVC, 0.5-2 parts of nano silicon dioxide, 0.5-2 parts of silane coupling agent, 0.5-5 part of vulcanizing agent, 0.5-5 part of promoter, 1-20 parts of plasticizer, 0.1-3 part of anti-aging agent and 5-15 parts of carbon black. The invention also discloses a manufacturing method of the highly wear-resistant PVC sole material. The wear resistance of the PVC sole material provided by the invention is very good.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of high abrasion PVC sole material and manufacture method thereof.
Background technology:
PVC and Polyvinylchlorid, its major ingredient is that polyvinyl chloride gathers hydrogen ethene, and chemical stability is very high, has good plasticity-.The electrical insulating property of PVC is excellent, generally can not burn, and flame can burn and release HCl, but leaves flame namely from putting out, and is a kind of " self-extinguishing ", " flame retardancy " material.Based on These characteristics, PVC is mainly for the production of fields such as section bar, profiled material, pipe part, sheet material, sheet material, cable sheath, hard or soft pipe, blood transfusion equipment, film, material for sole of shoe.The material for sole of shoe be made up of PVC has excellent mechanical property, the advantage such as easy to process and with low cost, therefore in the ratio that material for sole of shoe market share is larger, but common PVC sole material wear-resistant performance is not fine, can not meet the requirement that modern humans is more and more higher to wear resisting property well.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of high abrasion PVC sole material, has extraordinary wear resisting property.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of high abrasion PVC sole material, its weight part consists of:
Preferably, vulcanizing agent of the present invention is sulphur.
Preferably, promotor of the present invention is promotor TRA or altax.
Preferably, softening agent of the present invention is at least one in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate.
Preferably, anti-aging agent of the present invention is antioxidant 264.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned high abrasion PVC sole material.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for high abrasion PVC sole material, comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Therefore compared with prior art, the present invention has following beneficial effect:
The volume effect of nano silicon and quantum tunneling effect make it produce osmosis, macromolecular compound can be goed deep into, overlap with its electronic cloud, form reticulated structure, thus increasing substantially mechanical strength, the wear resisting property of macromolecular material, the material for sole of shoe adding nano silicon is provided with good wear resisting property; But nano-silicon nitride self is easily assembled, also there is stronger hydrogen bond action, therefore its dispersiveness in elastomeric material is poor, so the present invention carries out surface modification by silane coupling agent to it, effectively can improve its dispersiveness in PVC rubber, improve wear resisting property further.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Embodiment 2
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Embodiment 3
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Embodiment 4
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Embodiment 5
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Embodiment 6
A kind of high abrasion PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (6)
1. a high abrasion PVC sole material, is characterized in that: its weight part consists of:
2. a kind of high abrasion PVC sole material according to claim 1, is characterized in that: described vulcanizing agent is sulphur.
3. a kind of high abrasion PVC sole material according to claim 1, is characterized in that: described promotor is promotor TRA or altax.
4. a kind of high abrasion PVC sole material according to claim 1, is characterized in that: described softening agent is at least one in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate.
5. a kind of high abrasion PVC sole material according to claim 1, is characterized in that: described anti-aging agent is antioxidant 264.
6. the manufacture method of a kind of high abrasion PVC sole material according to Claims 1 to 5 any one, is characterized in that: comprise the following steps:
(1) nano silicon is dissolved in stirring heating in dehydrated alcohol, drips silane coupling agent, take out after stirring and dry, after removing solvent, obtain modified manometer silicon dioxide powder;
(2) PVC and modified manometer silicon dioxide powder are put into rubber mixing machine mixing, then other components in formula are added mixing, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain high abrasion PVC sole material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566334.5A CN104262857A (en) | 2014-10-22 | 2014-10-22 | Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566334.5A CN104262857A (en) | 2014-10-22 | 2014-10-22 | Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104262857A true CN104262857A (en) | 2015-01-07 |
Family
ID=52154454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410566334.5A Pending CN104262857A (en) | 2014-10-22 | 2014-10-22 | Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104262857A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672716A (en) * | 2015-03-06 | 2015-06-03 | 苏州市景荣科技有限公司 | Novel PVC/CPVC (polyvinyl chloride/chlorinated polyvinyl chloride) sole composite material and preparation method thereof |
| CN105694281A (en) * | 2016-02-03 | 2016-06-22 | 台州市峰源卫浴有限公司 | Wear-resistant modified PVC (polyvinyl chloride) for high-pressure pipe sheaths and production method thereof |
| CN111100404A (en) * | 2019-12-30 | 2020-05-05 | 揭阳市圣路保鞋业有限公司 | Inorganic nanoparticle modified PVC composite material technical sole and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987889A (en) * | 2009-08-07 | 2011-03-23 | 焦玉怀 | Rubber and plastic alloy material |
| CN102786747A (en) * | 2012-07-10 | 2012-11-21 | 苏州宝津塑业有限公司 | PVC strengthening plasticizing nano-material |
| CN103214701A (en) * | 2012-11-14 | 2013-07-24 | 际华三五一五皮革皮鞋有限公司 | Oil resistant and antistatic big rubber sole and preparation method thereof |
-
2014
- 2014-10-22 CN CN201410566334.5A patent/CN104262857A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987889A (en) * | 2009-08-07 | 2011-03-23 | 焦玉怀 | Rubber and plastic alloy material |
| CN102786747A (en) * | 2012-07-10 | 2012-11-21 | 苏州宝津塑业有限公司 | PVC strengthening plasticizing nano-material |
| CN103214701A (en) * | 2012-11-14 | 2013-07-24 | 际华三五一五皮革皮鞋有限公司 | Oil resistant and antistatic big rubber sole and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 田满红 等: "纳米SiO2增强增韧聚氯乙烯复合材料的研究", 《聚氯乙烯》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672716A (en) * | 2015-03-06 | 2015-06-03 | 苏州市景荣科技有限公司 | Novel PVC/CPVC (polyvinyl chloride/chlorinated polyvinyl chloride) sole composite material and preparation method thereof |
| CN105694281A (en) * | 2016-02-03 | 2016-06-22 | 台州市峰源卫浴有限公司 | Wear-resistant modified PVC (polyvinyl chloride) for high-pressure pipe sheaths and production method thereof |
| CN111100404A (en) * | 2019-12-30 | 2020-05-05 | 揭阳市圣路保鞋业有限公司 | Inorganic nanoparticle modified PVC composite material technical sole and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102863703B (en) | Low-temperature-resistant high-elasticity chlorinated polyethylene blend and preparation method thereof | |
| CN103524938B (en) | A kind of anti-wear halogen | |
| CN104356441B (en) | A kind of wear-resisting antistatic rubber sole and preparation method thereof | |
| CN102731929A (en) | PVC thermoplastic elastomer material and preparation method thereof | |
| CN104262857A (en) | Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof | |
| CN101250290A (en) | Thermostable, flame-resistant and oil-proof rubber sizing material and production method thereof | |
| MY178274A (en) | Improvements in the mixing and processing of rubber compositions containing polar fillers | |
| CN103275439A (en) | Ageing-resistant HPVC foaming sole material | |
| CN106893012A (en) | A kind of Nano Silver modified graphene crystal composite material and preparation method thereof | |
| KR20200054905A (en) | Conductive elastomer composition, and conductive sheet using the same | |
| CN102504367A (en) | Chemigum composition for preparing rubber flexible pipe | |
| CN106220985A (en) | A kind of oil resistant low temperature resistant fire retardant polyolefin rubber cable material and preparation method thereof | |
| CN103214774A (en) | Polyvinylchloride insulating electric power cable material and preparation method thereof | |
| MY173201A (en) | Epoxidised natural rubber based blend for antistatic footwear application | |
| CN102816390B (en) | Blending type rubber compound and preparation method thereof | |
| CN102786752A (en) | Wear-resistant polyvinyl chloride (PVC) floor membrane | |
| CN103242592A (en) | Insulating rubber for environment-friendly cable | |
| CN102161804B (en) | -R type polrvinyl chloride wire and cable insulation material | |
| CN105949745A (en) | Transparent TPU (thermoplastic polyurethane) film and preparation method and application thereof | |
| CN109776979A (en) | Carbon nano tube-doped Ionic Liquid Modified butyl rubber resilient body and preparation method | |
| CN104277356A (en) | Antistatic PVC foamed sole material and manufacturing method thereof | |
| CN107200945A (en) | A kind of tasteless type cable cover(ing) sizing material and preparation method thereof | |
| MY183778A (en) | Method for manufacturing wet rubber masterbatch, method for manufacturing rubber composition, and method for manufacturing tire | |
| CN103073765B (en) | Highly cold-resistant rubber dam | |
| CN103351556A (en) | Soft polyvinyl chloride electric cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150107 |
|
| RJ01 | Rejection of invention patent application after publication |