CN102786752A - Wear-resistant polyvinyl chloride (PVC) floor membrane - Google Patents

Wear-resistant polyvinyl chloride (PVC) floor membrane Download PDF

Info

Publication number
CN102786752A
CN102786752A CN2012103124505A CN201210312450A CN102786752A CN 102786752 A CN102786752 A CN 102786752A CN 2012103124505 A CN2012103124505 A CN 2012103124505A CN 201210312450 A CN201210312450 A CN 201210312450A CN 102786752 A CN102786752 A CN 102786752A
Authority
CN
China
Prior art keywords
wear
pvc
floor
polyvinyl chloride
film sticking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012103124505A
Other languages
Chinese (zh)
Inventor
汤洪臣
韩阳
袁东风
张虹
王晶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN TIANSU TECHNOLOGY GROUP Co Ltd FOURTH PLASTIC PRODUCTS FACTORY
Original Assignee
TIANJIN TIANSU TECHNOLOGY GROUP Co Ltd FOURTH PLASTIC PRODUCTS FACTORY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANJIN TIANSU TECHNOLOGY GROUP Co Ltd FOURTH PLASTIC PRODUCTS FACTORY filed Critical TIANJIN TIANSU TECHNOLOGY GROUP Co Ltd FOURTH PLASTIC PRODUCTS FACTORY
Priority to CN2012103124505A priority Critical patent/CN102786752A/en
Publication of CN102786752A publication Critical patent/CN102786752A/en
Pending legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)
  • Floor Finish (AREA)

Abstract

The invention relates to a wear-resistant polyvinyl chloride (PVC) floor membrane and belongs to the technical field of floor membranes. The floor membrane is characterized in that a PVC floor membrane wear-resistant layer comprises, by weight, 50-75 parts of polyvinyl chloride three type resin, 25-50 parts of high polymerization degree polyvinyl chloride resin, 10-40 parts per hundreds of resin (PHR) of dioctyl phthalate, 2-10 PHR of epoxidized soybean oil and 2-5 PHR of heat stabilizers. The floor membrane has the advantages of being good in mechanical property, wear resistant, shock resistant, indeformable, environment-friendly and capable of being reused. The floor membrane can be applied to production of commercial floor membranes widely and has good market prospects.

Description

A kind of wear resistant PVC floor film sticking
Technical field
The invention belongs to the floor film sticking technical field, particularly relate to a kind of wear resistant PVC floor film sticking.
Background technology
At present, the wearing layer of known commercial PVC floor film sticking mainly is to add softening agent, stablizer by SE five type resins, through the polyvinyl chloride film that mixes, plastifies, makes after the processes such as calendering.Wherein, softening agent is main with DOP, and epoxy soybean oil is auxilliary, the plasticity of reinforced polyvinyl chloride resin.But PVC floor film sticking wearing layer with this understanding, wear resistance is bad, and wearing coefficient is lower; Anti-skid is bad in the use; Add common stability, there is technical problems such as using restriction in ground such as public place of having relatively high expectations for public safety such as airport, hospital, kindergarten.
Summary of the invention
The present invention provides a kind of wear resistant PVC floor film sticking for solving the technical problem that exists in the known technology.
The wear resistant PVC floor film sticking that the purpose of this invention is to provide a kind of superpower wear-resistant, shock resistance, indeformable, environmental protection, characteristics such as reusable.Solve the bad problem of PVC floor film sticking wear resistance, the wearing coefficient and the use field of effectively improving floor film sticking for enterprise saves fund, and help environmental protection.
The technical scheme that wear resistant PVC floor film sticking of the present invention is taked is:
A kind of wear resistant PVC floor film sticking is characterized in: PVC floor film sticking wearing layer comprises following component, and it consists of,
SE three type resin 50-75 weight parts;
Polychloroethylene with high polymerization degree resin 25-50 weight part;
DOP 10-40PHR;
Epoxy soybean oil 2-10PHR;
Thermo-stabilizer 2-5PHR.
Wear resistant PVC floor film sticking of the present invention can also adopt following technical scheme:
Described wear resistant PVC floor film sticking is characterized in: SE three type resin 60-70 weight parts; High-polymerization degree (2500) PVC RESINS 30-40 weight part.
Described wear resistant PVC floor film sticking is characterized in: thermo-stabilizer is the barium zinc heat stabilizer.
Advantage and positively effect that the present invention has are:
The wear resistant PVC floor film sticking is owing to adopted brand-new technology scheme of the present invention, and compared with prior art, the present invention uses SE three type resins and high-polymerization degree (2500) PVC RESINS, increases PVC film wearing coefficient.Produce with the barium zinc heat stabilizer, make goods meet the EN71-3 environmental protection standard.Characteristics SE three type resins of the present invention and high-polymerization degree (2500) PVC RESINS mix to be produced.Because PVC three type resins and SE 2500 resin polymerization degree are all high than PVC five type resins, the polymerization degree is high more, and molecular weight is big more, and viscosity is big more, and mechanical property is good more, and thermostability is good more, and wear resistance is good more, but second-order transition temperature and forming process temperature are high more.Therefore the commercial floor film sticking that adopts PVC three type resins and SE 2500 mixed with resin to produce, mechanical property is good, and wear resisting property is good.
The present invention has superpower wear-resistant, shock resistance, indeformable, environmental protection, advantage such as reusable.
Embodiment
For further understanding summary of the invention of the present invention, characteristics and effect, the following examples of giving an example now, and specify as follows:
Embodiment 1
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE three type resins 66 weight parts;
Polychloroethylene with high polymerization degree 2500 resins 34 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing: after each component is weighed, drop into resin at low speed, drop into stablizer, softening agent at a high speed with impeller; 105 ℃ of left and right sides dischargings are stirred through cold then, carry out thermoplastification to middle bucket to the planet machine again; In two open mills, carry out fully mixing more respectively; After forcing machine filters, roll into film by four-roll calender, the film after the moulding is got through drawing, cooling and shaping becomes desired product.
Embodiment 2
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE three type resins 100 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing adopts the process method of embodiment 1 to produce.
Embodiment 3
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE five type resins 100 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium cadmium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing adopts the process method of embodiment 1 to produce.
Embodiment 1, comparative example 2 and comparative example's 3 composition and product performance see the following form:
Table one. embodiment 1, comparative example 2 and comparative example's 3 composition
Table two. embodiment 3, comparative example 4 and comparative example's 5 product physicals
Figure BDA00002070306800042
Figure BDA00002070306800051

Claims (3)

1. wear resistant PVC floor film sticking, it is characterized in that: PVC floor film sticking wearing layer comprises following component, and it consists of,
SE three type resin 50-75 weight parts;
Polychloroethylene with high polymerization degree resin 25-50 weight part;
DOP 10-40PHR;
Epoxy soybean oil 2-10PHR;
Thermo-stabilizer 2-5PHR.
2. wear resistant PVC floor film sticking according to claim 1 is characterized in that: SE three type resin 60-70 weight parts; High-polymerization degree (2500) PVC RESINS 30-40 weight part.
3. according to claim 1,2 described wear resistant PVC floor film stickings, it is characterized in that: thermo-stabilizer is the barium zinc heat stabilizer.
CN2012103124505A 2012-08-29 2012-08-29 Wear-resistant polyvinyl chloride (PVC) floor membrane Pending CN102786752A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012103124505A CN102786752A (en) 2012-08-29 2012-08-29 Wear-resistant polyvinyl chloride (PVC) floor membrane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012103124505A CN102786752A (en) 2012-08-29 2012-08-29 Wear-resistant polyvinyl chloride (PVC) floor membrane

Publications (1)

Publication Number Publication Date
CN102786752A true CN102786752A (en) 2012-11-21

Family

ID=47152352

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012103124505A Pending CN102786752A (en) 2012-08-29 2012-08-29 Wear-resistant polyvinyl chloride (PVC) floor membrane

Country Status (1)

Country Link
CN (1) CN102786752A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289239A (en) * 2013-06-21 2013-09-11 苏州新区佳合塑胶有限公司 Insect-proof and antibacterial floor film
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film
CN105647055A (en) * 2016-01-24 2016-06-08 安徽华星电缆集团有限公司 Formula for cable sheath used at bottom of sea
CN108163287A (en) * 2017-12-27 2018-06-15 新昌县隆豪轴承有限公司 A kind of two-sided film sticking apparatus of PVC board
CN109354804A (en) * 2018-10-24 2019-02-19 江苏名阳高分子新材料有限公司 A kind of PVC floor film of superpower wear-resistant and preparation method thereof
CN109971093A (en) * 2019-03-29 2019-07-05 帝高力装饰材料(江苏)有限公司 A kind of lower shrinkage wearing layer and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090218030A1 (en) * 2008-01-22 2009-09-03 Building Materials Investment Corporation Flooring underlayment membrane
CN101538393A (en) * 2009-04-23 2009-09-23 福建思嘉环保材料科技有限公司 High-elastic wearproof athletic floor material and preparation method thereof
CN102213350A (en) * 2011-04-01 2011-10-12 广东联塑科技实业有限公司 Method for producing polyvinyl chloride (PVC) compound hose

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090218030A1 (en) * 2008-01-22 2009-09-03 Building Materials Investment Corporation Flooring underlayment membrane
CN101538393A (en) * 2009-04-23 2009-09-23 福建思嘉环保材料科技有限公司 High-elastic wearproof athletic floor material and preparation method thereof
CN102213350A (en) * 2011-04-01 2011-10-12 广东联塑科技实业有限公司 Method for producing polyvinyl chloride (PVC) compound hose

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
《塑料科技》 20021006 赵尧森等 "高分子量聚氯乙烯(HMWPVC)树脂电缆护层材料的研究" 第4-9页,第1.4部分 1-3 , 第5期 *
赵尧森等: ""高分子量聚氯乙烯(HMWPVC)树脂电缆护层材料的研究"", 《塑料科技》 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289239A (en) * 2013-06-21 2013-09-11 苏州新区佳合塑胶有限公司 Insect-proof and antibacterial floor film
CN103289239B (en) * 2013-06-21 2015-06-17 苏州新区佳合塑胶有限公司 Insect-proof and antibacterial floor film
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film
CN105647055A (en) * 2016-01-24 2016-06-08 安徽华星电缆集团有限公司 Formula for cable sheath used at bottom of sea
CN108163287A (en) * 2017-12-27 2018-06-15 新昌县隆豪轴承有限公司 A kind of two-sided film sticking apparatus of PVC board
CN109354804A (en) * 2018-10-24 2019-02-19 江苏名阳高分子新材料有限公司 A kind of PVC floor film of superpower wear-resistant and preparation method thereof
CN109971093A (en) * 2019-03-29 2019-07-05 帝高力装饰材料(江苏)有限公司 A kind of lower shrinkage wearing layer and preparation method thereof
CN109971093B (en) * 2019-03-29 2021-04-13 帝高力装饰材料(江苏)有限公司 Low-shrinkage wear-resistant layer and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102786752A (en) Wear-resistant polyvinyl chloride (PVC) floor membrane
CN103589086B (en) A kind of flexible polyvinyl chloride cable material and preparation method thereof
CN102898755A (en) Matting resin modified polyvinyl chloride (PVC) matt film
WO2017118222A1 (en) Tpu composite material for military oil storage bags and method for preparing same
CN101864129B (en) Polyvinyl chloride geomembrane modified by nitrile-butadiene rubber
CN103360695A (en) Durable polyvinyl chloride salt membrane composition and preparation method thereof
CN102174287B (en) Interpenetrating network water-proof paint and preparation method thereof
CN105199371A (en) High-transparency TPU thin film for light guide plate material and preparation method of high-transparency TPU thin film
CN103030905A (en) High-strength and high-stability modified PVC and preparation method thereof
CN104532599A (en) Environment-friendly synthetic leather and preparation method thereof
CN102127283B (en) Polypropylene composite used for injection moulding splicing floor and preparation method thereof
CN105218983A (en) A kind of puncture resistance PVC salt film
CN102344625A (en) Weather-resistant polymer digital internal-printing spray-drawing material and preparation method thereof
CN104194109B (en) A kind of heat oxygen aging resistance epoxidized natural rubber composite material and its preparation method
CN105949745A (en) Transparent TPU (thermoplastic polyurethane) film and preparation method and application thereof
CN103304847A (en) Barium-zinc liquid stabilizer and preparation method thereof
CN109370106A (en) A kind of weather-proof decorative plastic film and preparation method thereof
CN105237947A (en) Abrasion-proof plastic bag and preparation method thereof
CN105086437A (en) Anti-static polyamide composite material and preparation method thereof
CN106008898A (en) High-moisture-resistance cold/heat-resistant thermoplastic polyurethane elastomer and preparation method thereof
CN106751716A (en) A kind of transparent antistatic TPU film and its preparation method and application
CN102344630A (en) Polyvinyl chloride salt film modified by butadiene nitrile rubber
CN104262857A (en) Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof
CN103992594A (en) Oil-resistant plastic product and production method thereof
CN104497444A (en) PVC filler and preparation method, product and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20121121