CN102786752A - Wear-resistant polyvinyl chloride (PVC) floor membrane - Google Patents
Wear-resistant polyvinyl chloride (PVC) floor membrane Download PDFInfo
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- CN102786752A CN102786752A CN2012103124505A CN201210312450A CN102786752A CN 102786752 A CN102786752 A CN 102786752A CN 2012103124505 A CN2012103124505 A CN 2012103124505A CN 201210312450 A CN201210312450 A CN 201210312450A CN 102786752 A CN102786752 A CN 102786752A
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Abstract
The invention relates to a wear-resistant polyvinyl chloride (PVC) floor membrane and belongs to the technical field of floor membranes. The floor membrane is characterized in that a PVC floor membrane wear-resistant layer comprises, by weight, 50-75 parts of polyvinyl chloride three type resin, 25-50 parts of high polymerization degree polyvinyl chloride resin, 10-40 parts per hundreds of resin (PHR) of dioctyl phthalate, 2-10 PHR of epoxidized soybean oil and 2-5 PHR of heat stabilizers. The floor membrane has the advantages of being good in mechanical property, wear resistant, shock resistant, indeformable, environment-friendly and capable of being reused. The floor membrane can be applied to production of commercial floor membranes widely and has good market prospects.
Description
Technical field
The invention belongs to the floor film sticking technical field, particularly relate to a kind of wear resistant PVC floor film sticking.
Background technology
At present, the wearing layer of known commercial PVC floor film sticking mainly is to add softening agent, stablizer by SE five type resins, through the polyvinyl chloride film that mixes, plastifies, makes after the processes such as calendering.Wherein, softening agent is main with DOP, and epoxy soybean oil is auxilliary, the plasticity of reinforced polyvinyl chloride resin.But PVC floor film sticking wearing layer with this understanding, wear resistance is bad, and wearing coefficient is lower; Anti-skid is bad in the use; Add common stability, there is technical problems such as using restriction in ground such as public place of having relatively high expectations for public safety such as airport, hospital, kindergarten.
Summary of the invention
The present invention provides a kind of wear resistant PVC floor film sticking for solving the technical problem that exists in the known technology.
The wear resistant PVC floor film sticking that the purpose of this invention is to provide a kind of superpower wear-resistant, shock resistance, indeformable, environmental protection, characteristics such as reusable.Solve the bad problem of PVC floor film sticking wear resistance, the wearing coefficient and the use field of effectively improving floor film sticking for enterprise saves fund, and help environmental protection.
The technical scheme that wear resistant PVC floor film sticking of the present invention is taked is:
A kind of wear resistant PVC floor film sticking is characterized in: PVC floor film sticking wearing layer comprises following component, and it consists of,
SE three type resin 50-75 weight parts;
Polychloroethylene with high polymerization degree resin 25-50 weight part;
DOP 10-40PHR;
Epoxy soybean oil 2-10PHR;
Thermo-stabilizer 2-5PHR.
Wear resistant PVC floor film sticking of the present invention can also adopt following technical scheme:
Described wear resistant PVC floor film sticking is characterized in: SE three type resin 60-70 weight parts; High-polymerization degree (2500) PVC RESINS 30-40 weight part.
Described wear resistant PVC floor film sticking is characterized in: thermo-stabilizer is the barium zinc heat stabilizer.
Advantage and positively effect that the present invention has are:
The wear resistant PVC floor film sticking is owing to adopted brand-new technology scheme of the present invention, and compared with prior art, the present invention uses SE three type resins and high-polymerization degree (2500) PVC RESINS, increases PVC film wearing coefficient.Produce with the barium zinc heat stabilizer, make goods meet the EN71-3 environmental protection standard.Characteristics SE three type resins of the present invention and high-polymerization degree (2500) PVC RESINS mix to be produced.Because PVC three type resins and SE 2500 resin polymerization degree are all high than PVC five type resins, the polymerization degree is high more, and molecular weight is big more, and viscosity is big more, and mechanical property is good more, and thermostability is good more, and wear resistance is good more, but second-order transition temperature and forming process temperature are high more.Therefore the commercial floor film sticking that adopts PVC three type resins and SE 2500 mixed with resin to produce, mechanical property is good, and wear resisting property is good.
The present invention has superpower wear-resistant, shock resistance, indeformable, environmental protection, advantage such as reusable.
Embodiment
For further understanding summary of the invention of the present invention, characteristics and effect, the following examples of giving an example now, and specify as follows:
Embodiment 1
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE three type resins 66 weight parts;
Polychloroethylene with high polymerization degree 2500 resins 34 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing: after each component is weighed, drop into resin at low speed, drop into stablizer, softening agent at a high speed with impeller; 105 ℃ of left and right sides dischargings are stirred through cold then, carry out thermoplastification to middle bucket to the planet machine again; In two open mills, carry out fully mixing more respectively; After forcing machine filters, roll into film by four-roll calender, the film after the moulding is got through drawing, cooling and shaping becomes desired product.
Embodiment 2
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE three type resins 100 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing adopts the process method of embodiment 1 to produce.
Embodiment 3
A kind of wear resistant PVC floor film sticking, its wearing layer comprises following component, it consists of:
SE five type resins 100 weight parts;
DOP 30PHR;
Epoxy soybean oil 2PHR;
Barium cadmium zinc heat stabilizer 2.5PHR.
The PVC floor film sticking wearing layer course of processing adopts the process method of embodiment 1 to produce.
Embodiment 1, comparative example 2 and comparative example's 3 composition and product performance see the following form:
Table one. embodiment 1, comparative example 2 and comparative example's 3 composition
Table two. embodiment 3, comparative example 4 and comparative example's 5 product physicals
Claims (3)
1. wear resistant PVC floor film sticking, it is characterized in that: PVC floor film sticking wearing layer comprises following component, and it consists of,
SE three type resin 50-75 weight parts;
Polychloroethylene with high polymerization degree resin 25-50 weight part;
DOP 10-40PHR;
Epoxy soybean oil 2-10PHR;
Thermo-stabilizer 2-5PHR.
2. wear resistant PVC floor film sticking according to claim 1 is characterized in that: SE three type resin 60-70 weight parts; High-polymerization degree (2500) PVC RESINS 30-40 weight part.
3. according to claim 1,2 described wear resistant PVC floor film stickings, it is characterized in that: thermo-stabilizer is the barium zinc heat stabilizer.
Priority Applications (1)
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CN2012103124505A CN102786752A (en) | 2012-08-29 | 2012-08-29 | Wear-resistant polyvinyl chloride (PVC) floor membrane |
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CN2012103124505A CN102786752A (en) | 2012-08-29 | 2012-08-29 | Wear-resistant polyvinyl chloride (PVC) floor membrane |
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CN102786752A true CN102786752A (en) | 2012-11-21 |
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CN2012103124505A Pending CN102786752A (en) | 2012-08-29 | 2012-08-29 | Wear-resistant polyvinyl chloride (PVC) floor membrane |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103289239A (en) * | 2013-06-21 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Insect-proof and antibacterial floor film |
CN105133814A (en) * | 2015-07-24 | 2015-12-09 | 浙江帝龙新材料股份有限公司 | Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film |
CN105647055A (en) * | 2016-01-24 | 2016-06-08 | 安徽华星电缆集团有限公司 | Formula for cable sheath used at bottom of sea |
CN108163287A (en) * | 2017-12-27 | 2018-06-15 | 新昌县隆豪轴承有限公司 | A kind of two-sided film sticking apparatus of PVC board |
CN109354804A (en) * | 2018-10-24 | 2019-02-19 | 江苏名阳高分子新材料有限公司 | A kind of PVC floor film of superpower wear-resistant and preparation method thereof |
CN109971093A (en) * | 2019-03-29 | 2019-07-05 | 帝高力装饰材料(江苏)有限公司 | A kind of lower shrinkage wearing layer and preparation method thereof |
Citations (3)
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US20090218030A1 (en) * | 2008-01-22 | 2009-09-03 | Building Materials Investment Corporation | Flooring underlayment membrane |
CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
CN102213350A (en) * | 2011-04-01 | 2011-10-12 | 广东联塑科技实业有限公司 | Method for producing polyvinyl chloride (PVC) compound hose |
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2012
- 2012-08-29 CN CN2012103124505A patent/CN102786752A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20090218030A1 (en) * | 2008-01-22 | 2009-09-03 | Building Materials Investment Corporation | Flooring underlayment membrane |
CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
CN102213350A (en) * | 2011-04-01 | 2011-10-12 | 广东联塑科技实业有限公司 | Method for producing polyvinyl chloride (PVC) compound hose |
Non-Patent Citations (2)
Title |
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《塑料科技》 20021006 赵尧森等 "高分子量聚氯乙烯(HMWPVC)树脂电缆护层材料的研究" 第4-9页,第1.4部分 1-3 , 第5期 * |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103289239A (en) * | 2013-06-21 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Insect-proof and antibacterial floor film |
CN103289239B (en) * | 2013-06-21 | 2015-06-17 | 苏州新区佳合塑胶有限公司 | Insect-proof and antibacterial floor film |
CN105133814A (en) * | 2015-07-24 | 2015-12-09 | 浙江帝龙新材料股份有限公司 | Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film |
CN105647055A (en) * | 2016-01-24 | 2016-06-08 | 安徽华星电缆集团有限公司 | Formula for cable sheath used at bottom of sea |
CN108163287A (en) * | 2017-12-27 | 2018-06-15 | 新昌县隆豪轴承有限公司 | A kind of two-sided film sticking apparatus of PVC board |
CN109354804A (en) * | 2018-10-24 | 2019-02-19 | 江苏名阳高分子新材料有限公司 | A kind of PVC floor film of superpower wear-resistant and preparation method thereof |
CN109971093A (en) * | 2019-03-29 | 2019-07-05 | 帝高力装饰材料(江苏)有限公司 | A kind of lower shrinkage wearing layer and preparation method thereof |
CN109971093B (en) * | 2019-03-29 | 2021-04-13 | 帝高力装饰材料(江苏)有限公司 | Low-shrinkage wear-resistant layer and preparation method thereof |
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Application publication date: 20121121 |