CN101250290A - Thermostable, flame-resistant and oil-proof rubber sizing material and production method thereof - Google Patents
Thermostable, flame-resistant and oil-proof rubber sizing material and production method thereof Download PDFInfo
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- CN101250290A CN101250290A CNA2008100547272A CN200810054727A CN101250290A CN 101250290 A CN101250290 A CN 101250290A CN A2008100547272 A CNA2008100547272 A CN A2008100547272A CN 200810054727 A CN200810054727 A CN 200810054727A CN 101250290 A CN101250290 A CN 101250290A
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Abstract
The invention discloses rubber compound which is high temperature resistant, fire-proof and grease-proof and a production process, which is formed by raw materials with following weight: 100phr acrylonitrile butadiene, 2-3phr vulcanizing agent, 5-7phr zinc oxide, 2-3phr octadecanoic acid, 1-2phr medium accelerator, 3-4phr ultra fast accelerator, 30-40phr carbon black, 15-25phr softening agent 3-6phr anti-aging agent and 70-100phr halogen-free flame retardant. High temperature resistant and fire-proof sizing material which is produced through the sizing material formulation and the process realizes the high temperature resistance and fire-proof properties of acrylonitrile butadiene at the premise of non halogen-free environmental protection, is used to shoemaking production, and is suitable for work footwear under the condition of high temperature and temporary open flame.
Description
Technical field
The present invention relates to a kind of high temperature resistant, fire-retardant, oil resisting rubber sizing material and production method thereof of the special-purpose labour protection aspects such as footwear boots that can be used to put out a fire.
Background technology
At special-purpose labour protection footwear production field, use general or half conventional rubber production possesses at the bottom of the glue of high temperature resistant, fire-retardant and oil resistance simultaneously, precedent is not arranged as yet.Similar sole performance, desired value does not reach the performance of regulation, and possesses the environmental-protecting performance of halogen-free flameproof.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of paracril that uses and has realized high temperature resistant and rubber size and production method thereof flame retardant effect.
The technical scheme that the present invention solves the problems of the technologies described above employing is:
High temperature resistant, fire-retardant, oil resisting rubber sizing material is characterized in that it forms [phr: with rubber is 100 parts, other materials and its weight ratio] by the raw material of following weight: paracril: 100phr; Vulcanizing agent: 2～3phr; Zinc oxide: 5～7phr; Stearic acid: 2～3phr; Moderate accelerator: 1～2phr; Ultra fast accelerator: 3～4phr; Carbon black: 30～40phr; Tenderizer: 15～25phr; Anti-aging agent: 3～6phr; Halogen-free flame retardants: 70～100phr;
Described vulcanizing agent is wherein a kind of or its combination in dimorpholinyl disulfide, the tetramethyl-thiuram disulfide; Described moderate accelerator is wherein a kind of or its combination in N cyclohexyl 2 benzothiazole sulfenamide or the dibenzothiazyl disulfide; Described ultra fast accelerator is wherein a kind of or its combination in zinc diethyldithiocarbamate or the zinc dibutyl dithiocarbamate; Described tenderizer is a dioctyl phthalate (DOP); Described anti-aging agent is resinoid 2,2,4-trimethylammonium-1, wherein a kind of or its combination in 2-dihyaroquinoline polymer or N-sec.-propyl-N '-diphenyl-para-phenylene diamine; Described halogen-free flame retardants is meant wherein a kind of or its combination in magnesium hydroxide or weisspiessglanz or the red phosphorus.
The production method of high temperature resistant, fire-retardant, oil resisting rubber sizing material is characterized in that this method is as follows:
The first step: use paracril and halogen-free flame retardants to make rubber master batch;
Second step: it is mixing that above-mentioned rubber master batch is added zinc oxide, stearic acid, moderate accelerator, carbon black, tenderizer, anti-aging agent according to prescription again, makes rubber unvulcanizate;
The 3rd step: above-mentioned rubber unvulcanizate is added vulcanizing agent, ultra fast accelerator more separately promptly get this high temperature resistant, fire-retardant, oil resisting rubber sizing material.
The technical progress that the present invention obtains is:
The heat-resistant fireproof sizing material that uses above-mentioned sizing compound formula and method to produce has been realized nitrile rubber sizing material high temperature resistant and flame retardant properties under the halogen-free environmental prerequisite, is used for shoemaking production, is applicable to the labour protection footwear boots under high temperature, the temporary transient naked light condition.The rubber size performance that application the inventive method is produced is as follows:
Annotate 1: high temperature resistant detection, baking is 8 minutes in 300 ℃ of sintering ovens;
Annotate 2: flame retardant properties, be the working strength test piece after spirit lamp is lighted 10 seconds, metering time behind fire.
Embodiment
Embodiment 1
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Dimorpholinyl disulfide: 2phr; Zinc oxide: 5phr; Stearic acid: 2phr; N cyclohexyl 2 benzothiazole sulfenamide: 1phr; Zinc diethyldithiocarbamate: 3phr; Carbon black: 30phr; Dioctyl phthalate (DOP): 15phr; 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymer: 3phr; Magnesium hydroxide: 70phr;
The production method of high temperature resistant, fire-retardant, oil resisting rubber sizing material, this method is as follows:
The first step: use paracril and magnesium hydroxide to make rubber master batch;
Second step: above-mentioned rubber master batch is added zinc oxide, stearic acid, N cyclohexyl 2 benzothiazole sulfenamide, carbon black, dioctyl phthalate (DOP), 2,2 according to prescription again, 4-trimethylammonium-1,2-dihyaroquinoline polymer is mixing, makes rubber unvulcanizate;
The 3rd step: above-mentioned rubber unvulcanizate is added dimorpholinyl disulfide, zinc diethyldithiocarbamate more separately promptly get this high temperature resistant, fire-retardant, oil resisting rubber sizing material.
Embodiment 2
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Dimorpholinyl disulfide: 3phr; Zinc oxide: 7phr; Stearic acid: 3phr; N cyclohexyl 2 benzothiazole sulfenamide: 2phr; Zinc diethyldithiocarbamate: 4phr; Carbon black: 40phr; Dioctyl phthalate (DOP): 25phr; 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymer: 6phr; Magnesium hydroxide: 100phr;
Production method is with embodiment one.
Embodiment 3
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Dimorpholinyl disulfide: 2.5phr; Zinc oxide: 6phr; Stearic acid: 2.5phr; N cyclohexyl 2 benzothiazole sulfenamide: 1.5phr; Zinc diethyldithiocarbamate: 3.5phr; Carbon black: 35phr; Dioctyl phthalate (DOP): 20phr; 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymer: 4.5phr; Magnesium hydroxide: 85phr;
Production method is with embodiment one.
Embodiment 4
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Tetramethyl-thiuram disulfide: 2phr; Zinc oxide: 5phr; Stearic acid: 2phr; Dibenzothiazyl disulfide: 1phr; Zinc dibutyl dithiocarbamate: 3phr; Carbon black: 30phr; Dioctyl phthalate (DOP): 15phr; N-sec.-propyl-N '-diphenyl-para-phenylene diamine: 3phr; Weisspiessglanz: 70phr;
The production method of high temperature resistant, fire-retardant, oil resisting rubber sizing material, this method is as follows:
The first step: use paracril and weisspiessglanz to make rubber master batch;
Second step: it is mixing that above-mentioned rubber master batch is added zinc oxide, stearic acid, dibenzothiazyl disulfide carbon black, dioctyl phthalate (DOP), N-sec.-propyl-N '-diphenyl-para-phenylene diamine according to prescription again, makes rubber unvulcanizate;
The 3rd step: above-mentioned rubber unvulcanizate is added tetramethyl-thiuram disulfide, zinc dibutyl dithiocarbamate more separately promptly get this high temperature resistant, fire-retardant, oil resisting rubber sizing material.
Embodiment 5
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Tetramethyl-thiuram disulfide: 3phr; Zinc oxide: 7phr; Stearic acid: 3phr; Dibenzothiazyl disulfide: 2phr; Zinc dibutyl dithiocarbamate: 4phr; Carbon black: 40phr; Dioctyl phthalate (DOP): 25phr; N-sec.-propyl-N '-diphenyl-para-phenylene diamine: 6phr; Weisspiessglanz: 100phr;
Production method is with embodiment four.
Embodiment 6
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Tetramethyl-thiuram disulfide: 2.5phr; Zinc oxide: 6phr; Stearic acid: 2.5phr; Dibenzothiazyl disulfide: 1.5phr; Zinc dibutyl dithiocarbamate: 3.5phr; Carbon black: 35phr; Dioctyl phthalate (DOP): 20phr; N-sec.-propyl-N '-diphenyl-para-phenylene diamine: 4.5phr; Weisspiessglanz: 85phr;
Production method is with embodiment four.
Embodiment 7
High temperature resistant, fire-retardant, oil resisting rubber sizing material, prescription is: paracril: 100phr; Dimorpholinyl disulfide 1phr, tetramethyl-thiuram disulfide 2phr; Zinc oxide: 5phr; Stearic acid: 2phr; N cyclohexyl 2 benzothiazole sulfenamide 1phr, dibenzothiazyl disulfide 2phr; Zinc diethyldithiocarbamate 1phr, zinc dibutyl dithiocarbamate 3phr; Carbon black: 30phr; Dioctyl phthalate (DOP) 15phr; Resinoid 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymer 3phr, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 3phr; Magnesium hydroxide 30phr, weisspiessglanz 20phr, red phosphorus 30phr.The production method of high temperature resistant, fire-retardant, oil resisting rubber sizing material, this method is as follows:
The first step: use paracril and magnesium hydroxide, weisspiessglanz, red phosphorus to make rubber master batch;
Second step: above-mentioned rubber master batch is added zinc oxide, stearic acid, N cyclohexyl 2 benzothiazole sulfenamide, dibenzothiazyl disulfide, carbon black, dioctyl phthalate (DOP), resinoid 2 according to prescription again, 2,4-trimethylammonium-1,2-dihyaroquinoline polymer, N-sec.-propyl-N '-diphenyl-para-phenylene diamine are mixing, make rubber unvulcanizate;
The 3rd step: above-mentioned rubber unvulcanizate is added dimorpholinyl disulfide, tetramethyl-thiuram disulfide, zinc diethyldithiocarbamate, zinc dibutyl dithiocarbamate more separately promptly get this high temperature resistant, fire-retardant, oil resisting rubber sizing material.
Claims (2)
1. high temperature resistant, fire-retardant, oil resisting rubber sizing material is characterized in that it is made up of the raw material of following weight: paracril: 100phr; Vulcanizing agent: 2～3phr; Zinc oxide: 5～7phr; Stearic acid: 2～3phr; Moderate accelerator: 1～2phr; Ultra fast accelerator: 3～4phr; Carbon black: 30～40phr; Tenderizer: 15～25phr; Anti-aging agent: 3～6phr; Halogen-free flame retardants: 70～100phr;
Described vulcanizing agent is wherein a kind of or its combination in dimorpholinyl disulfide, the tetramethyl-thiuram disulfide; Described moderate accelerator is wherein a kind of or its combination in N cyclohexyl 2 benzothiazole sulfenamide or the dibenzothiazyl disulfide; Described ultra fast accelerator is wherein a kind of or its combination in zinc diethyldithiocarbamate or the zinc dibutyl dithiocarbamate; Described tenderizer is a dioctyl phthalate (DOP); Described anti-aging agent is resinoid 2,2,4-trimethylammonium-1, wherein a kind of or its combination in 2-dihyaroquinoline polymer or N-sec.-propyl-N '-diphenyl-para-phenylene diamine; Described halogen-free flame retardants is meant wherein a kind of or its combination in magnesium hydroxide or weisspiessglanz or the red phosphorus.
2. the production method of high temperature resistant, fire-retardant, oil resisting rubber sizing material according to claim 1 is characterized in that this method is as follows:
The first step: use paracril and halogen-free flame retardants to make rubber master batch;
Second step: it is mixing that above-mentioned rubber master batch is added zinc oxide, stearic acid, moderate accelerator, carbon black, tenderizer, anti-aging agent according to prescription again, makes rubber unvulcanizate;
The 3rd step: above-mentioned rubber unvulcanizate is added vulcanizing agent, ultra fast accelerator more separately promptly get this high temperature resistant, fire-retardant, oil resisting rubber sizing material.
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| CNB2008100547272A CN100569840C (en) | 2008-04-02 | 2008-04-02 | High temperature resistant, fire-retardant, oil resisting rubber sizing material and production method thereof |
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| CNB2008100547272A CN100569840C (en) | 2008-04-02 | 2008-04-02 | High temperature resistant, fire-retardant, oil resisting rubber sizing material and production method thereof |
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| CN101250290A true CN101250290A (en) | 2008-08-27 |
| CN100569840C CN100569840C (en) | 2009-12-16 |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101716834A (en) * | 2009-12-07 | 2010-06-02 | 天津鹏翎胶管股份有限公司 | Automobile power-steering pipe structure and rubber formula |
| CN101792544A (en) * | 2010-03-30 | 2010-08-04 | 上海工程技术大学 | Environment-friendly flame retardant rubber material and preparation method thereof |
| CN101993557A (en) * | 2010-11-15 | 2011-03-30 | 杭州顺豪橡胶工程有限公司 | High-temperature resistant halogen-free fire-retarding rubber conveyer belt rubber material and conveyer belt made thereof |
| CN102020793A (en) * | 2011-01-14 | 2011-04-20 | 尚盟运动用品(惠阳)有限公司 | Heat-preservation folding-resistance vamp material and preparation method thereof |
| CN102181083A (en) * | 2011-05-05 | 2011-09-14 | 茂泰(福建)鞋材有限公司 | Oil-resistant anti-slip rubber for soles and preparation method thereof |
| CN101619147B (en) * | 2009-07-25 | 2011-09-21 | 四川明星电缆股份有限公司 | Oil resistant butadiene-acrylonitrile rubber and preparation method thereof |
| CN102746540A (en) * | 2012-06-26 | 2012-10-24 | 芜湖宏达橡塑阀门制造有限公司 | High temperature-resistant rubber resisting temperature of 140 DEG C |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
| CN103724730A (en) * | 2013-12-20 | 2014-04-16 | 柳州日高橡胶制品有限责任公司 | Rubber and preparation method thereof |
| CN103819763A (en) * | 2013-12-21 | 2014-05-28 | 芜湖禾田汽车工业有限公司 | Sealing element rubber |
| CN103819764A (en) * | 2013-12-21 | 2014-05-28 | 芜湖禾田汽车工业有限公司 | Rubber material of sealing component |
| CN105199170A (en) * | 2015-11-14 | 2015-12-30 | 际华三五一五皮革皮鞋有限公司 | Rubber soles of firemen's boots for high-risk environment |
| CN106750641A (en) * | 2016-11-29 | 2017-05-31 | 芜湖集拓橡胶技术有限公司 | A kind of fire-retardant nitrile rubber formula |
| CN106867056A (en) * | 2017-03-21 | 2017-06-20 | 柳州日高汽车减振技术有限责任公司 | A kind of nitrile rubber for making oil-resisting and heat-resisting corrugated hose |
| CN109054126A (en) * | 2018-07-26 | 2018-12-21 | 合肥远科服装设计有限公司 | A kind of high-low temperature resistant sizing material for rubber shoe sole and preparation method thereof |
| CN110556713A (en) * | 2018-06-01 | 2019-12-10 | 中国电力科学研究院有限公司 | anti-seismic structure for pillar type electrical equipment |
| CN110564022A (en) * | 2019-08-21 | 2019-12-13 | 芜湖集拓橡胶技术有限公司 | Flame-retardant nitrile rubber |
| KR102208513B1 (en) * | 2019-10-11 | 2021-01-28 | 한국신발피혁연구원 | Outsole composition for fire fighting shoes of extinguishing fire |
| CN113462046A (en) * | 2021-07-29 | 2021-10-01 | 北京市城南橡塑技术研究所 | NBR-ECTFE-ACS oil-resistant cold-resistant rubber and preparation method thereof |
| CN113881118A (en) * | 2021-11-25 | 2022-01-04 | 南阳天一密封股份有限公司 | Low-compression permanent deformation NBR (nitrile-butadiene rubber) material and preparation process thereof |
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2008
- 2008-04-02 CN CNB2008100547272A patent/CN100569840C/en not_active Expired - Fee Related
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101619147B (en) * | 2009-07-25 | 2011-09-21 | 四川明星电缆股份有限公司 | Oil resistant butadiene-acrylonitrile rubber and preparation method thereof |
| CN101716834A (en) * | 2009-12-07 | 2010-06-02 | 天津鹏翎胶管股份有限公司 | Automobile power-steering pipe structure and rubber formula |
| CN101792544A (en) * | 2010-03-30 | 2010-08-04 | 上海工程技术大学 | Environment-friendly flame retardant rubber material and preparation method thereof |
| CN101993557A (en) * | 2010-11-15 | 2011-03-30 | 杭州顺豪橡胶工程有限公司 | High-temperature resistant halogen-free fire-retarding rubber conveyer belt rubber material and conveyer belt made thereof |
| CN101993557B (en) * | 2010-11-15 | 2012-02-01 | 杭州顺豪橡胶工程有限公司 | High-temperature resistant halogen-free fire-retarding rubber conveyer belt rubber material and conveyer belt made thereof |
| CN102020793A (en) * | 2011-01-14 | 2011-04-20 | 尚盟运动用品(惠阳)有限公司 | Heat-preservation folding-resistance vamp material and preparation method thereof |
| CN102020793B (en) * | 2011-01-14 | 2013-05-29 | 中潜股份有限公司 | Heat-preservation folding-resistance vamp material and preparation method thereof |
| CN102181083A (en) * | 2011-05-05 | 2011-09-14 | 茂泰(福建)鞋材有限公司 | Oil-resistant anti-slip rubber for soles and preparation method thereof |
| CN102746540A (en) * | 2012-06-26 | 2012-10-24 | 芜湖宏达橡塑阀门制造有限公司 | High temperature-resistant rubber resisting temperature of 140 DEG C |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
| CN103724730A (en) * | 2013-12-20 | 2014-04-16 | 柳州日高橡胶制品有限责任公司 | Rubber and preparation method thereof |
| CN103819763A (en) * | 2013-12-21 | 2014-05-28 | 芜湖禾田汽车工业有限公司 | Sealing element rubber |
| CN103819764A (en) * | 2013-12-21 | 2014-05-28 | 芜湖禾田汽车工业有限公司 | Rubber material of sealing component |
| CN105199170A (en) * | 2015-11-14 | 2015-12-30 | 际华三五一五皮革皮鞋有限公司 | Rubber soles of firemen's boots for high-risk environment |
| CN106750641A (en) * | 2016-11-29 | 2017-05-31 | 芜湖集拓橡胶技术有限公司 | A kind of fire-retardant nitrile rubber formula |
| CN106867056A (en) * | 2017-03-21 | 2017-06-20 | 柳州日高汽车减振技术有限责任公司 | A kind of nitrile rubber for making oil-resisting and heat-resisting corrugated hose |
| CN110556713A (en) * | 2018-06-01 | 2019-12-10 | 中国电力科学研究院有限公司 | anti-seismic structure for pillar type electrical equipment |
| CN109054126A (en) * | 2018-07-26 | 2018-12-21 | 合肥远科服装设计有限公司 | A kind of high-low temperature resistant sizing material for rubber shoe sole and preparation method thereof |
| CN110564022A (en) * | 2019-08-21 | 2019-12-13 | 芜湖集拓橡胶技术有限公司 | Flame-retardant nitrile rubber |
| KR102208513B1 (en) * | 2019-10-11 | 2021-01-28 | 한국신발피혁연구원 | Outsole composition for fire fighting shoes of extinguishing fire |
| CN113462046A (en) * | 2021-07-29 | 2021-10-01 | 北京市城南橡塑技术研究所 | NBR-ECTFE-ACS oil-resistant cold-resistant rubber and preparation method thereof |
| CN113881118A (en) * | 2021-11-25 | 2022-01-04 | 南阳天一密封股份有限公司 | Low-compression permanent deformation NBR (nitrile-butadiene rubber) material and preparation process thereof |
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