CN105199170A - Rubber soles of firemen's boots for high-risk environment - Google Patents
Rubber soles of firemen's boots for high-risk environment Download PDFInfo
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- CN105199170A CN105199170A CN201510775907.XA CN201510775907A CN105199170A CN 105199170 A CN105199170 A CN 105199170A CN 201510775907 A CN201510775907 A CN 201510775907A CN 105199170 A CN105199170 A CN 105199170A
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Abstract
The invention relates to rubber soles of firemen's boots for a high-risk environment. The rubber soles are prepared from the following two parts of raw materials: nitrile rubber buna, neoprene, zinc oxide, octadecanoic acid, magnesium oxide, N-isopropyl-N-phenyl p-phenylenediamine, 2,2,4-trimethyl-1,2-dihydroquinoline, a reinforcing agent, a brominated flame retardant, antimonous oxide, dioctyl sebacate and coumarone-indene resin as the first part, and sulphur, an accelerant 1,2-mercaptoimidazoline, an accelerant CZ and an accelerant TMTD added on the basis of the first part as the second part. The rubber soles of the firemen's boots are small in oil resistance and volume change, and free of a serious damage phenomenon caused by combustion, leakage, fusion or bubbles at a temperature of 250 DEG C.
Description
Technical field
The invention belongs to article of footwear technical field, use at the bottom of fire fighter's boots glue under being specifically related to a kind of high-risk environment.
Background technology
Fire fighter's boots is the essential product of firefighter, the environment used due to fire fighter's boots is more severe, therefore, traditional fire fighter's boots is during fabrication through being everlasting bottom it and top adds and anti-puncture, anti-ly pounds with steel plate, add anti-puncture, the anti-fire fighter's boots pounding steel plate although this and can meet service requirements in the presence of a harsh environment, but, this fire fighter's boots has larger weight, user wears very uncomfortable in use, and this kind of fire fighter's boots also have impact on the flexibility ratio of user when walking widely and affect fire-fighting efficiency.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and provide with at the bottom of fire fighter's boots glue under a kind of high-risk environment, at the bottom of this fire fighter's boots glue, oil resistance volume change is little, at 250 DEG C of temperature at the bottom of glue without the damage serious phenomenon of burning, water clock, fusing or bubble initiation.
In order to achieve the above object, the present invention adopts following technical scheme:
Use under the invention provides a kind of high-risk environment at the bottom of fire fighter's boots glue, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43-35.46, chloroprene rubber 14.159-15.20, zinc oxide 2.60-2.65, octadecanoic acid 1.01-1.10, magnesium oxide 1.99-2.10, N-sec.-propyl-4-aminodiphenylamine 0.70-0.76, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.45-0.53, strengthening agent 25.29-25.35, bromide fire retardant 4.50-4.60, antimonous oxide 1.48-1.52, SA dibutyl ester 6.50-6.60, cumarone resin 2.49-2.54, second section is the add-on on first part every kilogram basis, and it is sulphur 7 ~ 9g, promotor 1,2-thiol group tetrahydroglyoxaline 1 ~ 3g, accelerant CZ 7 ~ 9g, Vulcanization accelerator TMTD 2.5 ~ 3.5g.
According to using at the bottom of fire fighter's boots glue under above-mentioned high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43-35.46, chloroprene rubber 14.159-15.20, zinc oxide 2.60-2.65, octadecanoic acid 1.01-1.10, magnesium oxide 1.99-2.10, N-sec.-propyl-4-aminodiphenylamine 0.70-0.76, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.45-0.53, strengthening agent 25.29-25.35, bromide fire retardant 4.50-4.60, antimonous oxide 1.48-1.52, SA dibutyl ester 6.50-6.60, cumarone resin 2.49-2.54, second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
According to using at the bottom of fire fighter's boots glue under above-mentioned high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.5-35.2, chloroprene rubber 14.16-15.0, zinc oxide 2.62-2.63, octadecanoic acid 1.03-1.06, magnesium oxide 2.0-2.10, N-sec.-propyl-4-aminodiphenylamine 0.71-0.73, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.48-0.52, strengthening agent 25.3-25.32, bromide fire retardant 4.52-4.56, antimonous oxide 1.49-1.50, SA dibutyl ester 6.52-6.58, cumarone resin 2.51-2.53, second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
Use at the bottom of fire fighter's boots glue according under above-mentioned high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.2, chloroprene rubber 14.72, zinc oxide 2.63, octadecanoic acid 1.05, magnesium oxide 2.0, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.49, strengthening agent 25.31, bromide fire retardant 4.53, antimonous oxide 1.50, SA dibutyl ester 6.55, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
Described strengthening agent is carbon black N339, carbon black N330, carbon black N220 or white carbon black.
Compared with prior art, the beneficial effect that obtains of the present invention:
1. adopt nitrile rubber and chloroprene rubber to combine according to a certain ratio as material of main part in the present invention's formula, meet snappiness and wear resistance; Be combined with efficient vulcanization system, the resistant to elevated temperatures sizing material for rubber shoe sole produced, reduces production cost, improves the strength and stability that sole and upper bond.
2. use at the bottom of fire fighter's boots glue through third party's test in laboratory under the high-risk environment that formula of the present invention obtains; fire fighter's boots oil resistance volume change is 1%; in resistance toheat test; sand-bath temperature 250 DEG C ± 5 DEG C will be put at the bottom of glue; after heating 40min is cooled to room temperature, without the damage serious phenomenon that burning, water clock, fusing or bubble cause at the bottom of glue.In resistance to flame test, after removing flame at the bottom of glue, its combustion time is no more than 2s, and the scorching hot time is no more than 5s, meets completely in home or overseas standard performance requriements at the bottom of every glue of specific fire prevention fire fighter's boots.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit content of the present invention.
embodiment 1
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43-35.46, chloroprene rubber 14.159-15.20, zinc oxide 2.60-2.65, octadecanoic acid 1.01-1.10, magnesium oxide 1.99-2.10, N-sec.-propyl-4-aminodiphenylamine 0.70-0.76, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.45-0.53, strengthening agent 25.29-25.35, bromide fire retardant 4.50-4.60, antimonous oxide 1.48-1.52, SA dibutyl ester 6.50-6.60, cumarone resin 2.49-2.54, second section is the add-on on first part every kilogram basis, and it is sulphur 7 ~ 9g, promotor 1,2-thiol group tetrahydroglyoxaline 1 ~ 3g, accelerant CZ 7 ~ 9g, Vulcanization accelerator TMTD 2.5 ~ 3.5g.
The present invention fill a prescription under the high-risk environment that obtains with at the bottom of fire fighter's boots glue through third party's test in laboratory, fire fighter's boots oil resistance volume change is 1%; In resistance toheat test, sand-bath temperature 250 DEG C ± 5 DEG C will be put at the bottom of glue, after heating 40min is cooled to room temperature, without the damage serious phenomenon that burning, water clock, fusing or bubble cause at the bottom of glue.In resistance to flame test, after removing flame at the bottom of glue, its combustion time is no more than 2s, and the scorching hot time is no more than 5s, meets completely in home or overseas standard performance requriements at the bottom of every glue of specific fire prevention fire fighter's boots.
embodiment 2
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.2, chloroprene rubber 14.72, zinc oxide 2.63, octadecanoic acid 1.05, magnesium oxide 2.0, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.49, carbon black N33925.31, bromide fire retardant 4.53, antimonous oxide 1.50, SA dibutyl ester 6.55, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
embodiment 3
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43, chloroprene rubber 15.20, zinc oxide 2.60, octadecanoic acid 1.10, magnesium oxide 1.99, N-sec.-propyl-4-aminodiphenylamine 0.76,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.45, carbon black N33925.35, bromide fire retardant 4.50, antimonous oxide 1.52, SA dibutyl ester 6.50, cumarone resin 2.54; Second section is the add-on on first part every kilogram basis, and it is sulphur 7g, promotor 1,2-thiol group tetrahydroglyoxaline 3g, accelerant CZ 7g, Vulcanization accelerator TMTD 3.5g.
embodiment 4
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.62, chloroprene rubber 15.10, zinc oxide 2.62, octadecanoic acid 1.08, magnesium oxide 2.0, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.47, carbon black N33025.32, bromide fire retardant 4.53, antimonous oxide 1.51, SA dibutyl ester 6.52, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.6g, promotor 1,2-thiol group tetrahydroglyoxaline 1.8g, accelerant CZ 8.6g, Vulcanization accelerator TMTD 3.2g.
embodiment 5
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.54, chloroprene rubber 15.0, zinc oxide 2.64, octadecanoic acid 1.03, magnesium oxide 2.02, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.46, strengthening agent 25.31, bromide fire retardant 4.54, antimonous oxide 1.49, SA dibutyl ester 6.57, cumarone resin 2.51; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.4g, promotor 1,2-thiol group tetrahydroglyoxaline 2.3g, accelerant CZ 8.2g, Vulcanization accelerator TMTD 3.2g.
embodiment 6
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.46, chloroprene rubber 14.8, zinc oxide 2.63, octadecanoic acid 1.07, magnesium oxide 2.01, N-sec.-propyl-4-aminodiphenylamine 0.75,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.48, strengthening agent 25.30, bromide fire retardant 4.58, antimonous oxide 1.49, SA dibutyl ester 6.54, cumarone resin 2.51; Second section is the add-on on first part every kilogram basis, and it is sulphur 8.2g, promotor 1,2-thiol group tetrahydroglyoxaline 1.6g, accelerant CZ 7.2g, Vulcanization accelerator TMTD 2.6g.
embodiment 7
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.58, chloroprene rubber 14.32, zinc oxide 2.64, octadecanoic acid 1.08, magnesium oxide 2.03, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.46, carbon black N22025.41, bromide fire retardant 4.53, antimonous oxide 1.49, SA dibutyl ester 6.57, cumarone resin 2.53; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.2g, promotor 1,2-thiol group tetrahydroglyoxaline 1.8g, accelerant CZ 8.1g, Vulcanization accelerator TMTD 3.4g.
embodiment 8
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.72, chloroprene rubber 14.53, zinc oxide 2.63, octadecanoic acid 1.08, magnesium oxide 2.04, N-sec.-propyl-4-aminodiphenylamine 0.75,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.48, white carbon black 25.31, bromide fire retardant 4.52, antimonous oxide 1.51, SA dibutyl ester 6.57, cumarone resin 2.50; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.2g, promotor 1,2-thiol group tetrahydroglyoxaline 2.2g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 3.2g.
embodiment 9
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.48, chloroprene rubber 14.47, zinc oxide 2.63, octadecanoic acid 1.08, magnesium oxide 1.99, N-sec.-propyl-4-aminodiphenylamine 0.73,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.47, carbon black N33025.34, bromide fire retardant 4.57, antimonous oxide 1.49, SA dibutyl ester 6.56, cumarone resin 2.53; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.8g, promotor 1,2-thiol group tetrahydroglyoxaline 1.2g, accelerant CZ 7.2g, Vulcanization accelerator TMTD 2.8g.
embodiment 10
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 35.16, chloroprene rubber 14.84, zinc oxide 2.64, octadecanoic acid 1.10, magnesium oxide 1.99, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.48, white carbon black 25.31, bromide fire retardant 4.55, antimonous oxide 1.51, SA dibutyl ester 6.53, cumarone resin 2.51; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.8g, promotor 1,2-thiol group tetrahydroglyoxaline 2.5g, accelerant CZ 8.4g, Vulcanization accelerator TMTD 2.7g.
embodiment 11
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 35.26, chloroprene rubber 14.17, zinc oxide 2.63, octadecanoic acid 1.04, magnesium oxide 2.10, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.47, white carbon black 25.32, bromide fire retardant 4.52, antimonous oxide 1.51, SA dibutyl ester 6.57, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.4g, promotor 1,2-thiol group tetrahydroglyoxaline 2.6g, accelerant CZ 8.3g, Vulcanization accelerator TMTD 2.6g.
embodiment 12
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.26, chloroprene rubber 14.89, zinc oxide 2.63, octadecanoic acid 1.02, magnesium oxide 2.05, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.48, carbon black N22025.31, bromide fire retardant 4.52, antimonous oxide 1.49, SA dibutyl ester 6.55, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 8.2g, promotor 1,2-thiol group tetrahydroglyoxaline 1.6g, accelerant CZ 7.2g, Vulcanization accelerator TMTD 3.2g.
embodiment 13
With at the bottom of fire fighter's boots glue under a kind of high-risk environment, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.36, chloroprene rubber 14.36, zinc oxide 2.62, octadecanoic acid 1.03, magnesium oxide 2.01, N-sec.-propyl-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.48, strengthening agent 25.29, bromide fire retardant 4.58, antimonous oxide 1.49, SA dibutyl ester 6.54, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 7.6g, promotor 1,2-thiol group tetrahydroglyoxaline 1.8g, accelerant CZ 8.4g, Vulcanization accelerator TMTD 3.1g.
The embodiment of the present invention 2 ~ 13 fill a prescription under the high-risk environment that obtains with at the bottom of fire fighter's boots glue through third party's test in laboratory, fire fighter's boots oil resistance volume change is 1 ~ 1.1%; In resistance toheat test, sand-bath temperature 250 DEG C ± 5 DEG C will be put at the bottom of glue, after heating 40min is cooled to room temperature, without the damage serious phenomenon that burning, water clock, fusing or bubble cause at the bottom of glue.In resistance to flame test, after removing flame at the bottom of glue, its combustion time is no more than 2s, and the scorching hot time is no more than 5s, meets completely in home or overseas standard performance requriements at the bottom of every glue of specific fire prevention fire fighter's boots.
Claims (5)
1. use under a high-risk environment at the bottom of fire fighter's boots glue, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43-35.46, chloroprene rubber 14.159-15.20, zinc oxide 2.60-2.65, octadecanoic acid 1.01-1.10, magnesium oxide 1.99-2.10, N-sec.-propyl-4-aminodiphenylamine 0.70-0.76, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.45-0.53, strengthening agent 25.29-25.35, bromide fire retardant 4.50-4.60, antimonous oxide 1.48-1.52, SA dibutyl ester 6.50-6.60, cumarone resin 2.49-2.54, second section is the add-on on first part every kilogram basis, and it is sulphur 7 ~ 9g, promotor 1,2-thiol group tetrahydroglyoxaline 1 ~ 3g, accelerant CZ 7 ~ 9g, Vulcanization accelerator TMTD 2.5 ~ 3.5g.
2. use under high-risk environment according to claim 1 at the bottom of fire fighter's boots glue, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.43-35.46, chloroprene rubber 14.159-15.20, zinc oxide 2.60-2.65, octadecanoic acid 1.01-1.10, magnesium oxide 1.99-2.10, N-sec.-propyl-4-aminodiphenylamine 0.70-0.76, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.45-0.53, strengthening agent 25.29-25.35, bromide fire retardant 4.50-4.60, antimonous oxide 1.48-1.52, SA dibutyl ester 6.50-6.60, cumarone resin 2.49-2.54, second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
3. use under high-risk environment according to claim 2 at the bottom of fire fighter's boots glue, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 33.5-35.2, chloroprene rubber 14.16-15.0, zinc oxide 2.62-2.63, octadecanoic acid 1.03-1.06, magnesium oxide 2.0-2.10, N-sec.-propyl-4-aminodiphenylamine 0.71-0.73, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.48-0.52, strengthening agent 25.3-25.32, bromide fire retardant 4.52-4.56, antimonous oxide 1.49-1.50, SA dibutyl ester 6.52-6.58, cumarone resin 2.51-2.53, second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
4. use under high-risk environment according to claim 3 at the bottom of fire fighter's boots glue, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: nitrile rubber 34.2, chloroprene rubber 14.72, zinc oxide 2.63, octadecanoic acid 1.05, magnesium oxide 2.0, N-sec.-propyls-4-aminodiphenylamine 0.72,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.49, strengthening agent 25.31, bromide fire retardant 4.53, antimonous oxide 1.50, SA dibutyl ester 6.55, cumarone resin 2.52; Second section is the add-on on first part every kilogram basis, and it is sulphur 8g, promotor 1,2-thiol group tetrahydroglyoxaline 2g, accelerant CZ 8g, Vulcanization accelerator TMTD 3g.
5. use at the bottom of fire fighter's boots glue under high-risk environment according to claim 1, it is characterized in that: described strengthening agent is carbon black N339, carbon black N330, carbon black N220 or white carbon black.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105924707A (en) * | 2016-05-11 | 2016-09-07 | 刘中华 | Industrial shoe mucilage and industrial shoes prepared from same |
CN115772288A (en) * | 2022-12-07 | 2023-03-10 | 江苏盾王科技集团有限公司 | Flame-retardant insulating sole rubber material and refining process thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1036390A (en) * | 1988-04-07 | 1989-10-18 | 唐德森 | Insulation oil resisting rubber goods and manufacture method |
CN101250290A (en) * | 2008-04-02 | 2008-08-27 | 际华三五一四制革制鞋有限公司 | Thermostable, flame-resistant and oil-proof rubber sizing material and production method thereof |
CN103102522A (en) * | 2012-11-14 | 2013-05-15 | 际华三五一五皮革皮鞋有限公司 | Oilproof and wear-resistant sizing material for special environment and preparation method thereof |
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2015
- 2015-11-14 CN CN201510775907.XA patent/CN105199170A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1036390A (en) * | 1988-04-07 | 1989-10-18 | 唐德森 | Insulation oil resisting rubber goods and manufacture method |
CN101250290A (en) * | 2008-04-02 | 2008-08-27 | 际华三五一四制革制鞋有限公司 | Thermostable, flame-resistant and oil-proof rubber sizing material and production method thereof |
CN103102522A (en) * | 2012-11-14 | 2013-05-15 | 际华三五一五皮革皮鞋有限公司 | Oilproof and wear-resistant sizing material for special environment and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105924707A (en) * | 2016-05-11 | 2016-09-07 | 刘中华 | Industrial shoe mucilage and industrial shoes prepared from same |
CN115772288A (en) * | 2022-12-07 | 2023-03-10 | 江苏盾王科技集团有限公司 | Flame-retardant insulating sole rubber material and refining process thereof |
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Application publication date: 20151230 |