CN105949642A - Plastic floor with high anti-dirty performance and preparation method of plastic floor - Google Patents

Plastic floor with high anti-dirty performance and preparation method of plastic floor Download PDF

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Publication number
CN105949642A
CN105949642A CN201610316133.9A CN201610316133A CN105949642A CN 105949642 A CN105949642 A CN 105949642A CN 201610316133 A CN201610316133 A CN 201610316133A CN 105949642 A CN105949642 A CN 105949642A
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Prior art keywords
mixing
plastic floor
roll
parts
strong
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CN201610316133.9A
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Chinese (zh)
Inventor
李明华
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Jin Baoli Technology (suzhou) Co Ltd
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Jin Baoli Technology (suzhou) Co Ltd
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Priority to CN201610316133.9A priority Critical patent/CN105949642A/en
Publication of CN105949642A publication Critical patent/CN105949642A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a plastic floor with high anti-dirty performance. The plastic floor comprises raw materials in parts by weight as follows: 55-65 parts of amorphous polyethylene terephthalate, 45-55 parts of PVC (polyvinyl chloride), 30-40 parts of a polyurethane emulsion, 30-40 parts of 2-chloroethyl vinyl ether, 25-35 parts of methylene diphenyl diisocyanate, 20-30 parts of dioctyl phthalate, 15-25 parts of a silicone-acrylic emulsion, 5-15 parts of fumed silica, 5-10 parts of chitin, 5-10 parts of barium stearate, 3-5 parts of an anti-aging agent and 3-5 parts of a cross-linking agent. The plastic floor has excellent anti-dirty performance. The invention further discloses a preparation method of the plastic floor.

Description

Plastic floor that a kind of soil resistance is strong and preparation method thereof
Technical field
The present invention relates to plastic material technical field, be specifically related to strong plastic floor of a kind of soil resistance and preparation method thereof。
Background technology
At present, the floor mainly used in repairs profession is timber floor and marble floor.But, it is easily deformed during the use of timber floor, ftractures, also need periodically to maintain, be heated after making moist and can produce various problem of appearance, the most also having the carcinogen such as methanol is release.The major defect of marble floor is to lay trouble, and processing charges is high, is easily broken, typically can not dismantle.
In order to avoid the problem in above-mentioned application, people have turned one's attention to plastic floor, and plastic floor is pavement more novel in current world building material industry, have that pattern is many, construction simple and fast, light weight, the corrosion-resistant and advantage such as go mouldy.Nowadays, plastic floor is applied in daily life more and more widely, as in market, airport, hospital, the occasion such as factory, usage amount increases the most increasingly.But plastic floor is due to mainly polymeric material, in use becomes easily infected by dirt, and should not remove, serves adverse effect to the application band of plastic floor.Therefore, it is badly in need of developing the strong plastic floor of a kind of antifouling capacity to solve the problems referred to above。
Summary of the invention
For solving above-mentioned technical problem, the present invention provides plastic floor that a kind of soil resistance is strong and preparation method thereof, by using specified raw material to be combined, coordinate corresponding production technology, having obtained a kind of Novel plastic floor, its antifouling capacity is excellent, has a good application prospect.
The purpose of the present invention can be achieved through the following technical solutions:
The plastic floor that a kind of soil resistance is strong, is prepared by the raw materials in: amorphization polyethylene terephthalate 55-65 Part, PVC45-55 Part, polyaminoester emulsion 30-40 Part, ethylene (2- Chloroethyl ) Ether 30-40 Part, methyl diphenylene diisocyanate 25-35 Part, o-phthalic acid dibutyl ester 20-30 Part, silicone acrylic emulsion 15-25 Part, gas-phase silica 5-15 Part, chitin 5-10 Part, barium stearate 5-10 Part, age resistor 3-5 Part, cross-linking agent 3-5 Part.
Preferably, described age resistor is selected from age resistor CPPD , age resistor H , age resistor AW In one or more.
Preferably, one or more in benzoyl peroxide, tetraisocyanate, trimethoxy silane of described cross-linking agent.
The preparation method of the plastic floor that described soil resistance is strong, comprises the following steps:
( 1 ) weigh each raw material according to weight portion；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 160-170 DEG C, carry out the most mixing, mixing time 30-50 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 130-150 DEG C, it is mixing to carry out secondary, mixing time 20-30 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor, cross-linking agent, it is warming up to 180-200 DEG C, carry out three times mixing, mixing time 60-80 Minute；
( 5 ) material mixing through three times is cooled to 60-70 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 155-165 DEG C, middle roll temperature is 170-180 DEG C, lower roll temperatures is 150-160 DEG C, cooling, molding, obtain finished product subsequently.
Preferably, described step ( 5 In), the upper roll temperature of tri-roll press machine is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 ℃。
Compared with prior art, it has the beneficial effect that the present invention
( 1 ) present invention plastic floor with amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate are main component, by adding o-phthalic acid dibutyl ester, silicone acrylic emulsion, gas-phase silica, chitin, barium stearate, age resistor, cross-linking agent, be aided with that three stages are mixing, roll, cool down, the technique such as molding so that the plastic floor being prepared from possesses the antifouling property of excellence.
( 2 ) the plastic floor cheaper starting materials of the present invention, technique is simple, is suitable to heavy industrialization and uses, practical.
Detailed description of the invention
Below in conjunction with specific embodiment, the technical scheme of invention is described in detail.
Embodiment 1
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 55 Part, PVC45 Part, polyaminoester emulsion 30 Part, ethylene (2- Chloroethyl ) Ether 30 Part, methyl diphenylene diisocyanate 25 Part, o-phthalic acid dibutyl ester 20 Part, silicone acrylic emulsion 15 Part, gas-phase silica 5 Part, chitin 5 Part, barium stearate 5 Part, age resistor CPPD 3 Part, benzoyl peroxide 3 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 160 DEG C, carry out the most mixing, mixing time 30 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 130 DEG C, it is mixing to carry out secondary, mixing time 20 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor CPPD , benzoyl peroxide, be warming up to 180 DEG C, carry out three times mixing, mixing time 60 Minute；
( 5 ) material mixing through three times is cooled to 60 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
Embodiment 2
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 60 Part, PVC50 Part, polyaminoester emulsion 35 Part, ethylene (2- Chloroethyl ) Ether 35 Part, methyl diphenylene diisocyanate 30 Part, o-phthalic acid dibutyl ester 25 Part, silicone acrylic emulsion 20 Part, gas-phase silica 10 Part, chitin 8 Part, barium stearate 8 Part, age resistor H 4 Part, tetraisocyanate 4 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 165 DEG C, carry out the most mixing, mixing time 40 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 140 DEG C, it is mixing to carry out secondary, mixing time 25 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor H , tetraisocyanate, be warming up to 190 DEG C, carry out three times mixing, mixing time 70 Minute；
( 5 ) material mixing through three times is cooled to 65 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
Embodiment 3
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 65 Part, PVC55 Part, polyaminoester emulsion 40 Part, ethylene (2- Chloroethyl ) Ether 40 Part, methyl diphenylene diisocyanate 35 Part, o-phthalic acid dibutyl ester 30 Part, silicone acrylic emulsion 25 Part, gas-phase silica 15 Part, chitin 10 Part, barium stearate 10 Part, age resistor AW 5 Part, trimethoxy silane 5 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 170 DEG C, carry out the most mixing, mixing time 50 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 150 DEG C, it is mixing to carry out secondary, mixing time 30 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor AW , trimethoxy silane, be warming up to 200 DEG C, carry out three times mixing, mixing time 80 Minute；
( 5 ) material mixing through three times is cooled to 70 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
Embodiment 4
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 55 Part, PVC55 Part, polyaminoester emulsion 30 Part, ethylene (2- Chloroethyl ) Ether 40 Part, methyl diphenylene diisocyanate 25 Part, o-phthalic acid dibutyl ester 30 Part, silicone acrylic emulsion 15 Part, gas-phase silica 15 Part, chitin 5 Part, barium stearate 10 Part, age resistor CPPD 3 Part, trimethoxy silane 5 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 160 DEG C, carry out the most mixing, mixing time 50 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 150 DEG C, it is mixing to carry out secondary, mixing time 20 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor CPPD , trimethoxy silane, be warming up to 200 DEG C, carry out three times mixing, mixing time 60 Minute；
( 5 ) material mixing through three times is cooled to 60 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
Comparative example 1
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 55 Part, PVC45 Part, ethylene (2- Chloroethyl ) Ether 30 Part, methyl diphenylene diisocyanate 25 Part, o-phthalic acid dibutyl ester 20 Part, gas-phase silica 5 Part, chitin 5 Part, barium stearate 5 Part, age resistor CPPD 3 Part, benzoyl peroxide 3 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate join in muller, are warming up to 160 DEG C, carry out the most mixing, mixing time 30 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester again, it is cooled to 130 DEG C, it is mixing to carry out secondary, mixing time 20 Minute；
( 4 ) the most backward mixing roll adds gas-phase silica, chitin, barium stearate, age resistor CPPD , benzoyl peroxide, be warming up to 180 DEG C, carry out three times mixing, mixing time 60 Minute；
( 5 ) material mixing through three times is cooled to 60 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
Comparative example 2
( 1 ) weigh amorphization polyethylene terephthalate according to weight portion 65 Part, PVC55 Part, polyaminoester emulsion 40 Part, methyl diphenylene diisocyanate 35 Part, o-phthalic acid dibutyl ester 30 Part, silicone acrylic emulsion 25 Part, chitin 10 Part, barium stearate 10 Part, age resistor AW 5 Part, trimethoxy silane 5 Part；
( 2 ) by amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, methyl diphenylene diisocyanate join in muller, be warming up to 170 DEG C, carry out the most mixing, mixing time 50 Minute；
( 3 ) in mixing roll, add o-phthalic acid dibutyl ester, silicone acrylic emulsion again, it is cooled to 150 DEG C, it is mixing to carry out secondary, mixing time 30 Minute；
( 4 ) the most backward mixing roll adds chitin, barium stearate, age resistor AW , trimethoxy silane, be warming up to 200 DEG C, carry out three times mixing, mixing time 80 Minute；
( 5 ) material mixing through three times is cooled to 70 DEG C, use tri-roll press machine to roll subsequently, wherein going up roll temperature is 160 DEG C, middle roll temperature is 175 DEG C, lower roll temperatures is 155 DEG C, cooling, molding, obtain finished product subsequently.
The performance test results such as table of the plastic floor that prepared soil resistance is strong 1 Shown in.
By embodiment 1-4 And comparative example 1-2 The strong plastic floor of soil resistance test respectively its antifouling property (floor to be measured is immersed respectively coloured dirt liquid, 12 h Rear cleaning, observing effect), hardness, environmental-protecting performance.
Table 1
Soil resistance Shore hardness Volatilization gas environmental effect
Embodiment 1 Without vestige 87 Atomic weak
Embodiment 2 Without vestige 79 Atomic weak
Embodiment 3 Without vestige 91 Atomic weak
Embodiment 4 Without vestige 75 Atomic weak
Comparative example 1 Vestige is obvious 52 Atomic weak
Comparative example 2 Vestige is obvious 50 Atomic weak
The present invention with amorphization polyethylene terephthalate, PVC , polyaminoester emulsion, ethylene (2- Chloroethyl ) Ether, methyl diphenylene diisocyanate are main component, by adding o-phthalic acid dibutyl ester, silicone acrylic emulsion, gas-phase silica, chitin, barium stearate, age resistor, cross-linking agent, be aided with that three stages are mixing, roll, cool down, the technique such as molding, the plastic floor being prepared from is made to possess the antifouling property of excellence, hardness height, health environment-friendly simultaneously, application prospect is good, has good social benefit.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, the most in like manner it is included in the scope of patent protection of the present invention。

Claims (5)

1. the plastic floor that a soil resistance is strong, it is characterised in that: it is prepared by the raw materials in: amorphization polyethylene terephthalate 55-65 part, PVC45-55 part, polyaminoester emulsion 30-40 part, ethylene (2-chloroethyl) ether 30-40 part, methyl diphenylene diisocyanate 25-35 part, o-phthalic acid dibutyl ester 20-30 part, silicone acrylic emulsion 15-25 part, gas-phase silica 5-15 part, chitin 5-10 part, barium stearate 5-10 part, age resistor 3-5 part, cross-linking agent 3-5 part.
The plastic floor that soil resistance the most according to claim 1 is strong, it is characterised in that: one or more in age resistor CPPD, antioxidant H, antioxidant A W of described age resistor.
The plastic floor that soil resistance the most according to claim 1 is strong, it is characterised in that: one or more in benzoyl peroxide, tetraisocyanate, trimethoxy silane of described cross-linking agent.
4. according to the preparation method of the strong plastic floor of the arbitrary described soil resistance of claims 1 to 3, it is characterised in that comprise the following steps:
(1) each raw material is weighed according to weight portion；
(2) amorphization polyethylene terephthalate, PVC, polyaminoester emulsion, ethylene (2-chloroethyl) ether, methyl diphenylene diisocyanate are joined in muller, it is warming up to 160-170 DEG C, carry out the most mixing, mixing time 30-50 minute；
(3) adding o-phthalic acid dibutyl ester, silicone acrylic emulsion again in mixing roll, be cooled to 130-150 DEG C, it is mixing to carry out secondary, mixing time 20-30 minute；
(4) in the most backward mixing roll add gas-phase silica, chitin, barium stearate, age resistor, cross-linking agent, be warming up to 180-200 DEG C, carry out three times mixing, mixing time 60-80 minute；
(5) material mixing through three times being cooled to 60-70 DEG C, use tri-roll press machine to roll subsequently, wherein go up roll temperature and be 155-165 DEG C, middle roll temperature is 170-180 DEG C, and lower roll temperatures is 150-160 DEG C, and cooling, molding, obtain finished product subsequently.
The preparation method of the plastic floor that soil resistance the most according to claim 4 is strong, it is characterised in that in described step (5), the upper roll temperature of tri-roll press machine is 160 DEG C, middle roll temperature is 175 DEG C, and lower roll temperatures is 155 DEG C.
CN201610316133.9A 2016-05-13 2016-05-13 Plastic floor with high anti-dirty performance and preparation method of plastic floor Pending CN105949642A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676276A (en) * 2018-04-12 2018-10-19 孟海丽 A kind of plastic floor that antifouling property is strong
CN108892932A (en) * 2018-05-29 2018-11-27 芜湖创科新材料科技有限公司 A kind of high-temperature resistance plastice material and preparation method thereof
CN110466222A (en) * 2019-07-12 2019-11-19 安徽绿谷新材料有限公司 A kind of radiation-resistant environment-friendly type mixing plastic floor tile pad and its processing method

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CN1903926A (en) * 2006-07-15 2007-01-31 庄广盛 Wear resistant type plastic floor and its production technology
CN1911997A (en) * 2006-07-15 2007-02-14 庄广盛 Wear-resistant wood plastic floor and its production technology
CN103396623A (en) * 2013-07-15 2013-11-20 安徽济峰节能材料有限公司 PVC (polyvinyl chloride) micro-foam floor and preparation method thereof
CN103407253A (en) * 2013-07-18 2013-11-27 苏州富通高新材料科技股份有限公司 Sound-insulation elastic plastic floor
CN103408861A (en) * 2013-07-18 2013-11-27 苏州富通高新材料科技股份有限公司 Plastic floor substrate and making method thereof
CN105086382A (en) * 2015-08-04 2015-11-25 金宝丽科技（苏州）有限公司 Heat-conductive anti-static APET composite material and preparing method thereof
CN105419173A (en) * 2016-01-21 2016-03-23 苏州法斯特信息科技有限公司 Low-cost antistatic plastic floor material and preparation method thereof
CN105440497A (en) * 2015-12-24 2016-03-30 刘家容 Antifoulingflame-retardant plastic floor and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1903926A (en) * 2006-07-15 2007-01-31 庄广盛 Wear resistant type plastic floor and its production technology
CN1911997A (en) * 2006-07-15 2007-02-14 庄广盛 Wear-resistant wood plastic floor and its production technology
CN103396623A (en) * 2013-07-15 2013-11-20 安徽济峰节能材料有限公司 PVC (polyvinyl chloride) micro-foam floor and preparation method thereof
CN103407253A (en) * 2013-07-18 2013-11-27 苏州富通高新材料科技股份有限公司 Sound-insulation elastic plastic floor
CN103408861A (en) * 2013-07-18 2013-11-27 苏州富通高新材料科技股份有限公司 Plastic floor substrate and making method thereof
CN105086382A (en) * 2015-08-04 2015-11-25 金宝丽科技（苏州）有限公司 Heat-conductive anti-static APET composite material and preparing method thereof
CN105440497A (en) * 2015-12-24 2016-03-30 刘家容 Antifoulingflame-retardant plastic floor and preparation method thereof
CN105419173A (en) * 2016-01-21 2016-03-23 苏州法斯特信息科技有限公司 Low-cost antistatic plastic floor material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676276A (en) * 2018-04-12 2018-10-19 孟海丽 A kind of plastic floor that antifouling property is strong
CN108892932A (en) * 2018-05-29 2018-11-27 芜湖创科新材料科技有限公司 A kind of high-temperature resistance plastice material and preparation method thereof
CN110466222A (en) * 2019-07-12 2019-11-19 安徽绿谷新材料有限公司 A kind of radiation-resistant environment-friendly type mixing plastic floor tile pad and its processing method

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Application publication date: 20160921