CN104910506B - A kind of manufacture method of environment protection multifunctional macromolecule health material and its derived product - Google Patents
A kind of manufacture method of environment protection multifunctional macromolecule health material and its derived product Download PDFInfo
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- CN104910506B CN104910506B CN201510343883.0A CN201510343883A CN104910506B CN 104910506 B CN104910506 B CN 104910506B CN 201510343883 A CN201510343883 A CN 201510343883A CN 104910506 B CN104910506 B CN 104910506B
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- powder
- environment protection
- far infrared
- mesh
- protection multifunctional
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
Abstract
The invention provides the manufacture method of a kind of environment protection multifunctional macromolecule health material and its derived product, including ethylene-vinyl acetate copolymer（VA contents are 50%）70 80%, PES (polyethersulfone resin)：1‑10%；Titanate coupling agent：1‑15%；Antioxidant：1‑5%；Nano-silver antibacterial powder：1‑5%；Anion function powder：1‑8；Far infrared powder：1‑8%.Manufacture craft environmental protection, cost is cheap, securely and reliably, is adapted to large-scale production：Technique is simplified, effectively increases yield, is advantageous to a wide range of promotion and application；Product is environmentally friendly and can be recycled；Can natural degradation, and also recyclable reuse；Increasing feature, effective combination of antibacterial+far infrared+anion so that the feature of this material greatly improves, so as to add more applications, meanwhile, the healthcare function of its derived product also greatly promotes.
Description
Technical field
The present invention relates to environment-protecting health-care technical field of function materials, more particularly to a kind of environment protection multifunctional macromolecule health material
The manufacture method of material and its derived product.
Background technology
EVA resin（Ethylene-vinyl acetate copolymer）Be it is a kind of be that there is good flexibility, the same elasticity of rubber,
Remain to that there is preferable reelability at -50 DEG C, the transparency and lustrous surface are good, and chemical stability is good, anti-aging and resistance to smelly
Oxygen intensity is good, non-toxic；Good with the miscibility of filler, coloring and shaping processability are good.This material high polymer material silk merges shape
Structure is reticulated, is supported using the canoe and hauling type of contactless, robust surface and elasticity ten can be formed simultaneously
The inside network structure of foot, use it as packing material made of major ingredient and possess elasticity, and being capable of high permeable and gas permeability.From
After the states such as Japan are as taking novel filling material, it is used for the lifes staying idle at home such as pillow, mattress, is provided for people comfortable and convenient
Life.But cost is higher, it is difficult to is promoted the use of by many people, and simply possesses the most basic function of this material and want
Ask.
The content of the invention
The invention provides the manufacture method of a kind of environment protection multifunctional macromolecule health material and its derived product, makes work
Skill environmental protection, cost is cheap, securely and reliably, is adapted to large-scale production：Technique is simplified, effectively increases yield, is advantageous to big model
Enclose promotion and application；Also will not be polluted to environment, product is environmentally friendly and can be recycled；Because the base-material environmental protection selected is former
Material, abandoned as rubbish, can natural degradation, and also recyclable reuse；Increase feature.Antibacterial+far infrared+anion
Effective combination so that the feature of this material greatly improves, so as to add more applications, meanwhile, it spreads out
The healthcare function of product also greatly promotes.
In order to solve the above technical problems, the embodiment of the present application provides a kind of environment protection multifunctional macromolecule health material, its
Composition is respectively the ethylene-vinyl acetate copolymer 70-80%, PES (polyethersulfone resin) that VA contents are 50% by weight percentage：
1-10%；Titanate coupling agent：1-15%；Antioxidant：1-5%；Nano-silver antibacterial powder：1-5%；Anion function powder：1-8%；It is remote red
Outer function powder：1-8%.
As the preferred embodiment of this programme, described antioxidant is tetrapentaerythritol ester；Described nano-silver antibacterial powder
It is more than the powder of 500 mesh for mesh number, described anion function powder is ten thousand units of burst size 3-4, and mesh number is more than 500 mesh
Powder；Described far infrared powder is that normal direction total emissivity is more than 90%, and mesh number is more than the powder of 500 mesh.
The manufacture method of a kind of environment protection multifunctional macromolecule health material and its derived product that the present embodiment provides, including
Following steps：
S1, sorting：According to the ethylene-vinyl acetate copolymer 75% that VA contents are 50%, PES (polyethersulfone resin)：5%；Titanium
Acid esters coupling agent：10%；Antioxidant：1%；Nano-silver antibacterial powder：1%；Anion function powder：4%；Far infrared powder：4% weight
Amount percentage measures raw material；
S2, after the raw material described in step S1 is uniformly mixed, carry out hot melt, i.e., at a temperature of 200-220 degree, hot melt
For ethylene vinyl acetate copolymer hot melt adhesive composition, as base-material, can be drawn in 150-200 degree temperature ranges
Silk processing, and polymer temperature is constant in drawing process, wire drawing obtains Gao Rou to the silk strip material of diameter 1-2 millimeters
Tough and elastomeric strand shape high molecular functional polymeric material, can be derivative to use in this, as base-material after cooling；
S3, derivative use：According to different product needs, corresponding mould is made, produced silk strip material makes
It is hot-forming with forming machine, during shaping, suppressed with air-pump inflating so that silk strip material is pressurized in mould
Expansion, it is loosely organized, around combination so as to reach space network, that is, obtain corresponding semi-finished product packing material；
The semi-finished product packing material that S4, basis have made, selects different clothes, is cut and sewed, parcel is filled out
Material is filled, combination obtains corresponding finished product.
The one or more technical schemes provided in the embodiment of the present application, have at least the following technical effects or advantages：
1st, material makes and simplifies technique, effectively increases yield, can carry out large-scale production, is advantageous to promote on a large scale
And application；
2nd, the advantages of ensure that its own, its feature is improved；
3rd, derived product adds its feature, expands application；
4th, can be recycled, add using actual effect, extend usage time, and it is recyclable reuse, avoid
The waste of material and social resources；
5th, environment-friendly degradable is handled, and meet the requirement of environmental protection, avoids polluting.
Brief description of the drawings
, below will be to embodiment or existing in order to illustrate more clearly of inventive embodiments or technical scheme of the prior art
The required accompanying drawing used is briefly described in technology description, it should be apparent that, drawings in the following description are only the present invention
Some embodiments, for those of ordinary skill in the art, without having to pay creative labor, can be with root
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the production technological process of the embodiment of the present application.
Embodiment
The invention provides the manufacture method of a kind of environment protection multifunctional macromolecule health material and its derived product, makes work
Skill environmental protection, cost is cheap, securely and reliably, is adapted to large-scale production：Technique is simplified, effectively increases yield, is advantageous to big model
Enclose promotion and application；Also will not be polluted to environment, product is environmentally friendly and can be recycled；Because the base-material environmental protection selected is former
Material, abandoned as rubbish, can natural degradation, and also recyclable reuse；Increase feature.Antibacterial+far infrared+anion
Effective combination so that the feature of this material greatly improves, so as to add more applications, meanwhile, it spreads out
The healthcare function of product also greatly promotes.
In order to be better understood from above-mentioned technical proposal, below in conjunction with Figure of description and specific embodiment to upper
Technical scheme is stated to be described in detail.
A kind of environment protection multifunctional macromolecule health material described in the embodiment of the present application, its composition are distinguished by weight percentage
The ethylene-vinyl acetate copolymer 70-80%, PES (polyethersulfone resin) for being 50% for VA contents：1-10%；Titanate coupling agent：
1-15%；Antioxidant：1-5%；Nano-silver antibacterial powder：1-5%；Anion function powder：1-8；Far infrared powder：1-8%.
Wherein, in the present embodiment, described antioxidant is tetrapentaerythritol ester；Described nano-silver antibacterial powder is mesh number
More than the powder of 500 mesh, described anion function powder is ten thousand units of burst size 3-4, and mesh number is more than the powder of 500 mesh
Body；Described far infrared powder is that normal direction total emissivity is more than 90%, and mesh number is more than the powder of 500 mesh.
As shown in figure 1, the system for a kind of the environment protection multifunctional macromolecule health material and its derived product that the present embodiment provides
Method is made, is comprised the following steps：
S1, sorting：By the ethylene-vinyl acetate copolymer 75% that VA contents are 50%, PES (polyethersulfone resin)：5%；Metatitanic acid
Ester coupling agent：10%；Antioxidant：1%；Nano-silver antibacterial powder：1%；Anion function powder：4%；Far infrared powder：4%；Raw material is matched somebody with somebody
It is standby than being ready to complete；
S2, by above raw material uniformly mixing after, carry out hot melt, i.e., at a temperature of 200-220 degree, heat for ethene-
Acetate ethylene copolymer hot-melt adhesive composition, as base-material, carry out wire drawing process；Because antibacterial powder, far-infrared powder and negative
Ion function powder is inorganic filler, and ethylene-vinyl acetate copolymer is high polymerized organics, both poor compatibilities.Therefore, add
Enter titanate esters, the alkyl that close high polymer on its strand be present, there is also the aliphatic radical of close inorganic matter, so two can be improved well
The compatibility of person, while the mesh number of inorganic filler is more than 500 mesh, may be such that anti-biotic material, far-infrared material and anion
Functional material can be preferably fused in ethylene vinyl acetate copolymer hot melt adhesive composition；In 150-200 degree temperature ranges
Wire drawing process can be carried out, and polymer temperature is constant in drawing process.Wire drawing to diameter 1-2 millimeters silk strip material,
High flexible and elastomeric strand shape high molecular functional polymeric material is obtained, this length of string can be modulated as needed.
, can be derivative to use in this, as base-material after cooling.
S3, derivative use：According to different product needs, such as pillow, seat cushion, mattress equidimension, corresponding mould is made,
By produced silk strip material, coordinate forming machine hot-forming, during shaping, suppressed with air-pump inflating so that silk
Strip material in mould by compression swelling, it is loosely organized, around combination；Pressure can be adjusted according to different product and mould
It is whole, so as to reach space network.Obtain the semi-finished product packing material such as corresponding pillow.
The packing material that S4, basis have made, selects different clothes, this cloth does not limit to material.Cut and
Sewing, parcel, combination obtain corresponding finished product.
The environmental protection of this method manufacture craft, cost is cheap, securely and reliably, is adapted to large-scale production：Technique is simplified, is effectively carried
High yield, is advantageous to a wide range of promotion and application；Also will not be polluted to environment.
Product is environmentally friendly and can be recycled.Because the base-material environmental protection raw material selected.Abandoned as rubbish.Can natural degradation.
It is and also recyclable to reuse.
Increase feature.Effective combination of antibacterial+far infrared+anion.So that the feature of this material greatly improves, from
And more applications can be added.Meanwhile the healthcare function of its derived product also greatly promotes.Health of people is lived
The effect improved be also evident from.
Although preferred embodiments of the present invention have been described, but those skilled in the art once know basic creation
Property concept, then can make other change and modification to these embodiments.So appended claims be intended to be construed to include it is excellent
Select embodiment and fall into having altered and changing for the scope of the invention.
Obviously, those skilled in the art can carry out the essence of various changes and modification without departing from the present invention to the present invention
God and scope.So, if these modifications and variations of the present invention belong to the scope of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to comprising including these changes and modification.
Claims (2)
- A kind of 1. environment protection multifunctional macromolecule health material, it is characterised in that：Its composition is respectively VA contents by weight percentage For 50% ethylene-vinyl acetate copolymer 75%, PES (polyethersulfone resin)：5%；Titanate coupling agent：10%；Antioxidant：1%； Nano-silver antibacterial powder：1%；Anion function powder：4%；Far infrared powder：4%；A kind of manufacture method of environment protection multifunctional macromolecule health material, its step are as follows：S1, sorting：According to the ethylene-vinyl acetate copolymer 75% that VA contents are 50%, PES (polyethersulfone resin)：5%；Titanate esters Coupling agent：10%；Antioxidant：1%；Nano-silver antibacterial powder：1%；Anion function powder：4%；Far infrared powder：4% weight hundred Ratio is divided to measure raw material；S2, after the raw material described in step S1 is uniformly mixed, hot melt is carried out, i.e., at a temperature of 200-220 degree, is heated as second Alkene-acetate ethylene copolymer hot-melt adhesive composition, as base-material, it can be carried out in 150-200 degree temperature ranges at wire drawing Reason, and polymer temperature is constant in drawing process, the silk strip material of wire drawing to diameter 1-2 millimeters, that is, obtain it is high flexible and Elastomeric strand shape high molecular functional polymeric material, can be derivative to use in this, as base-material after cooling；S3, derivative use：According to different product needs, make corresponding mould, by produced silk strip material, using into Type machine is hot-forming, during shaping, is suppressed with air-pump inflating so that silk strip material is pressurized swollen in mould It is swollen, it is loosely organized, around combination so as to reach space network, that is, obtain corresponding semi-finished product packing material；The semi-finished product packing material that S4, basis have made, selects different clothes, is cut and sewed, parcel filling material Material, combination obtain corresponding finished product.
- A kind of 2. environment protection multifunctional macromolecule health material according to claim 1, it is characterised in that：Described antioxidant For tetrapentaerythritol ester；Described nano-silver antibacterial powder is the powder that mesh number is more than 500 mesh, and described anion function powder is to release High-volume ten thousand units of 3-4, and mesh number is more than the powder of 500 mesh；Described far infrared powder is that normal direction total emissivity is 90% More than, and mesh number is more than the powder of 500 mesh.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510343883.0A CN104910506B (en) | 2015-06-21 | 2015-06-21 | A kind of manufacture method of environment protection multifunctional macromolecule health material and its derived product |
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| CN201510343883.0A CN104910506B (en) | 2015-06-21 | 2015-06-21 | A kind of manufacture method of environment protection multifunctional macromolecule health material and its derived product |
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| CN104910506A CN104910506A (en) | 2015-09-16 |
| CN104910506B true CN104910506B (en) | 2017-12-08 |
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| CN109096590A (en) * | 2018-08-03 | 2018-12-28 | 浙江纳巍负离子科技有限公司 | A kind of anion perfume discoloration EVA composite elastic material and preparation method thereof |
| CN110200444B (en) * | 2019-06-18 | 2021-07-02 | 广东科优韵智能家居有限公司 | Semi-automatic spring mattress production process |
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| CN101402761B (en) * | 2008-11-14 | 2011-01-19 | 广州市耐子谷健康科技有限公司 | Ethylene-butylene copolymer composite material with function of generating negative ion, far-infrared ray or antimicrobial mildew resistant function |
| CN102293545A (en) * | 2010-06-25 | 2011-12-28 | 阳加强 | Plastic high polymer mattress |
| CN102532676B (en) * | 2011-12-16 | 2013-11-06 | 周口师范学院 | Protector material with health-care function in athletic sports field and preparation method thereof |
| CN104017262A (en) * | 2014-06-13 | 2014-09-03 | 齐齐哈尔大学 | Multifunctional fresh-keeping material capable of releasing anions and preparation method of material |
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Effective date of registration: 20210712 Address after: 255000 No. H16, phase II, xishouhaimin logistics warehouse, Gaobing village, Fengshui Town, Zhangdian District, Zibo City, Shandong Province Patentee after: Zibo Hercules New Material Technology Co.,Ltd. Address before: 255000 Room 301, unit 2, building 1, yard 5, huluo Road, Hutian Town, Zhangdian District, Zibo City, Shandong Province Patentee before: Wei Jian |
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