CN105949605A - Multifunctional polyolefin elastomer composite material and preparation method and application thereof - Google Patents
Multifunctional polyolefin elastomer composite material and preparation method and application thereof Download PDFInfo
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- CN105949605A CN105949605A CN201610569243.6A CN201610569243A CN105949605A CN 105949605 A CN105949605 A CN 105949605A CN 201610569243 A CN201610569243 A CN 201610569243A CN 105949605 A CN105949605 A CN 105949605A
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- 239000002131 composite material Substances 0.000 title claims abstract description 42
- 229920006124 polyolefin elastomer Polymers 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title description 5
- 150000001450 anions Chemical class 0.000 claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 38
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000010687 lubricating oil Substances 0.000 claims abstract description 14
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 59
- 229920000098 polyolefin Polymers 0.000 claims description 32
- 230000000895 acaricidal effect Effects 0.000 claims description 31
- 239000000642 acaricide Substances 0.000 claims description 31
- 239000004332 silver Substances 0.000 claims description 24
- 229910052709 silver Inorganic materials 0.000 claims description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 20
- 238000005491 wire drawing Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 8
- -1 pentaerythritol ester Chemical class 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 7
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims description 5
- 235000019260 propionic acid Nutrition 0.000 claims description 5
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 4
- 241001597008 Nomeidae Species 0.000 claims description 4
- 239000005662 Paraffin oil Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229940125904 compound 1 Drugs 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 15
- 239000000203 mixture Substances 0.000 abstract description 13
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 8
- 230000003115 biocidal effect Effects 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 239000011265 semifinished product Substances 0.000 description 5
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 239000013536 elastomeric material Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- 241000723353 Chrysanthemum Species 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 101000905241 Mus musculus Heart- and neural crest derivatives-expressed protein 1 Proteins 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/30—Applications used for thermoforming
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a polyolefin elastomer composite material. The polyolefin elastomer composite material is prepared from, by weight, 80-90 parts of polyolefin elastomer, 10-15 parts of lubricating oil, 1-5 parts of an antioxidant, 1-10 parts of nano titanium dioxide, 1-5 parts of nano silver, 1-10 parts of a mite-removing and mold-proof finishing agent and 1-10 parts of nano anion powder. The polyolefin elastomer composite material has mite-removing and antibacterial functions under the conditions of specific composition and proportion, the phobotaxis rate of mite removal is as high as 80% or above, the antibacterial rate is as high as 70% or above, and the polyolefin elastomer composite material is very suitable for manufacturing or production of household articles for daily use. In addition, the polyolefin elastomer composite material can also release a large number of negative ions, facilitates improvement of comfort and has high normal total emissivity.
Description
Technical field
The present invention relates to a kind of multi-functional polyolefin elastic composite material and its preparation method and application, be specifically related to
A kind of polyolefin elastic composite material with far infrared, anion, acaricide and antibacterial functions and preparation method thereof and
Application.
Background technology
Polyolefin elastomer material (POE) be a kind of be that there is good flexibility and the same elasticity of rubber, have
Preferably reelability, the transparency, avirulence, lustrous surface property is good, chemical stability good, and aging resistance and resistance to ozone intensity are excellent
Different；Meanwhile, POE material is good with the miscibility of other filler, and coloring and shaping processability are excellent；It is a kind of safety and environmental protection, purposes
Health environment-friendly material widely；POE macromolecular material merges through wire drawing can form network structure, uses contactless canoe
Support with hauling type, the inside network structure of robust surface and resilient enough can be concurrently formed, use it as major ingredient system
The bedding packing materials such as the pillow core of one-tenth, seat cushion, mattress possess good elasticity, and have high permeable and breathability.
At present, the material as life staying idle at home articles for use such as pillow core, seat cushion, mattresses is mainly ethylene-vinyl acetate copolymer
Elastomeric material (EVA elastomeric material), and EVA elastomeric material, although also possess above-mentioned advantage, but have the disadvantage that the most hardening and
Turning yellow, stability is not enough.From states such as Japan using POE material as after taking novel filling material, often it is extended and is applied to pillow core, mattress
Etc. life staying idle at home articles for use, provide comfortable for people and live easily.But polyolefin elastomer material (POE material) is made
Simply simply POE material is carried out wire drawing, molding for life staying idle at home articles for use, only possesses the excellent properties of POE material itself,
And do not possess other the performance such as sterilization, acaricide, far infrared and anion releasing.
Summary of the invention
It is an object of the invention to provide a kind of far infrared, anion, acaricide and the polyolefin elastic of antibacterial complex function
Composite material.
A kind of polyolefin elastic composite material that the present invention provides, it includes the component of following parts by weight: polyolefin
80 parts～90 parts of elastomer, lubricating oil 10 parts～15 parts, 1 part～5 parts of antioxidant, nano titanium oxide 1 part～10 parts, nanometer silver
1 part～5 parts, acaricide mildew-proofing finishing agent 1 part～10 parts, nanometer anion powder 1 part～10 parts.
Further, it is made up of the component of following parts by weight: polyolefin elastomer 80 parts～90 parts, lubricating oil 10
Part～15 parts, 1 part～5 parts of antioxidant, nano titanium oxide 1 part～10 parts, nanometer silver 1 part～5 parts, acaricide mildew-proofing finishing agent 1
Part～10 parts, nanometer anion powder 1 part～10 parts.
Further, it is made up of the component of following parts by weight:
Polyolefin elastomer 84 parts, lubricating oil 10 parts, 1 part of antioxidant, nano titanium oxide 2 parts, nanometer silver 2 parts, acaricide mildew-resistant
Finishing agent 2 parts, nanometer anion powder 2 parts；
Or,
Polyolefin elastomer 88 parts, lubricating oil 12 parts, 2 parts of antioxidant, nano titanium oxide 6 parts, nanometer silver 2 parts, acaricide mildew-resistant
Finishing agent 6 parts, nanometer anion powder 6 parts.
Further,
Described lubricating oil in paraffin oil, naphthenic oil, the white oil any one or two or more；
Described antioxidant selected from four (β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propanoic acid) pentaerythritol ester, 2, tri-grades of butyl of 6--
In 4-methylphenol, double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether any one or two or more.
Further, described nano titanium oxide is water soluble nano titanium dioxide；Described nanometer silver is water-soluble nano
Silver；Described nanometer anion powder is water-soluble nano anion powder.
Further, described acaricide mildew-proofing finishing agent is made up of the component of following parts by weight: benzene halide epoxide chemical combination
Thing 1 part～5 parts, chrysanthemum ester derivant 1 part～5 parts.
Present invention also offers a kind of method preparing said polyolefins elastic composite, it comprises the following steps:
, take polyolefin elastomer, lubricating oil, antioxidant, mixing, obtain mixed material；
, by stepGained mixed material carries out wire drawing, obtains thread or strip-shaped product, nano-silica in its surface-coated
Change titanium, nanometer silver, acaricide mildew-proofing finishing agent and nanometer anion powder, obtain polyolefin elastic composite material.
Further, the temperature of described wire drawing is 150 DEG C～220 DEG C, described coated with nano titanium dioxide, nanometer silver, removes
Keeping thread or strip-shaped product temperature when demodicid mite mildew-proofing finishing agent and nanometer anion powder is 60 DEG C～110 DEG C.
Present invention also offers said polyolefins elastic composite and manufacture or making answering in life staying idle at home articles for use
With.
Further, described life staying idle at home articles for use are pillow core, seat cushion or mattress.
Manufacture pillow core described above, seat cushion, the method for mattress, it comprises the following steps:
(1) according to different product needed, such as pillow core, seat cushion, mattress equidimension, make corresponding mould, produced is gathered
Olefm elastomeric composite material, coordinates forming machine hot-forming, during molding, coordinates air-pump inflating to suppress so that poly-
Olefin elastomer material by compression swelling, is formed loosely organized in mould, around the semifinished material of combination.Pressure can root
It is adjusted according to different product and mould, thus reaches space network, i.e. obtain corresponding pillow core, the semi-finished product such as bedding core.
(2) according to the packing material that made, selecting different clothes, this cloth does not limit to material, in addition cutting and
Sewing, parcel, combination i.e. obtains corresponding finished product.
Compared with prior art, the method have the advantages that
(1) the polyolefin elastic composite material of the present invention, it is tough for strengthening it for being suitably added the lubricating oil such as paraffin oil, naphthenic oil
Property and pliability, during keeping polymer constant temperature (150 ° of C～220 ° of C), carry out wire drawing process, wire drawing is to diameter 1～2
The silk strip material of millimeter, simultaneously by containing nanometer silver, acaricide mildew-proofing finishing agent, nano titanium oxide, nanometer anion powder
Mixed liquor sprays the hot strand shape material surface at 60 ° of C～110 ° of C, or by the hot silk strip material of 60 ° of C～110 ° of C
By containing nanometer silver, acaricide mildew-proofing finishing agent, nano titanium oxide, the U-tube of nanometer anion powder mixed liquor, at high temperature
Nanometer silver, acaricide mildew-proofing finishing agent, nano titanium oxide, nanometer anion powder can the most i.e. obtain high pliable and tough and high resiliency
Strand shape macromolecule complex function polymeric material.
(2) the polyolefin elastic composite material of the present invention, because wherein with the addition of nano-silver antibacterial powder, acaricide mildew-resistant is whole
Reason agent, nano titanium oxide and anion function powder component add the functional of common POE material, have the anti-of excellence
Bacterium property, acaricide and have anion function, nano titanium oxide has the far-infrared functional of excellence and makes composite wood simultaneously
Material adds far infrared performance；It is applicable to prepare multi-functional life staying idle at home articles for use, such as: pillow core, seat cushion, mattress etc.；Meanwhile,
Owing to multifunctinoal health environment-friendly materials have antibacterial+far infrared+anion+acaricide quadruple function, so that use it to manufacture
Life staying idle at home articles for use healthy functions be greatly promoted.
(3) method that the present invention prepares polyolefin elastic composite material, technique is simple and convenient to operate, cost is relatively low, non-
Often it is suitable for manufacturing multifunctinoal health environment-friendly products, such as: the furniture the articles for daily uses such as pillow core, seat cushion, mattress.
(4) the polyolefin elastic composite material of the present invention, selects POE material to compare EVA resin class material, solves
EVA material easily turns yellow and hardening problem, makes and simplifies technique, is effectively increased yield, can carry out large-scale production, have
It is beneficial to promotion and application on a large scale；The advantage that ensure that himself, improves it functional；Its article of manufacture manufactured is used to increase
It is functional, expands range of application, has a good application prospect；Can be recycled, add use actual effect, extend
Use time, and recyclable reuse, it is to avoid the waste of material and social resources；POE material can carry out environment-friendly degradable
Process, meet the requirement of environmental protection, it is to avoid pollute.
The polyolefin elastic composite material of the present invention, under specific composition and conditions of mixture ratios, have simultaneously acaricide and
Antibacterial functions, and the rate of walking quickly and keeping away of acaricide is up to more than 80%, antibiotic rate is up to more than 70%, is especially suitable for manufacturing or to make household raw
Apply flexibly product；Additionally, the polyolefin elastic composite material of the present invention, additionally it is possible to discharge substantial amounts of anion, be conducive to improving and relax
Appropriateness, and there is higher normal direction total emissivity.
Obviously, according to the foregoing of the present invention, according to ordinary technical knowledge and the customary means of this area, without departing from
Under the present invention above-mentioned basic fundamental thought premise, it is also possible to make the amendment of other various ways, replace or change.
Accompanying drawing explanation
Fig. 1 is the preparation technology flow chart of polyolefin elastic composite material of the present invention.
Below by way of the embodiment in detailed description of the invention, the foregoing of the present invention is described in further detail.
But this should not being interpreted as, the scope of the above-mentioned theme of the present invention is only limitted to Examples below.All real based on foregoing of the present invention institute
Existing technology belongs to the scope of the present invention.
Detailed description of the invention
The raw material, the equipment that use in the specific embodiment of the invention are known product, obtain by buying commercially available prod.
Embodiment 1
A, take four beakers, and be numbered 1,2,3,4
Take 2g nano titanium oxide and put in No. 1 beaker, add 0.1L distilled water, mix homogeneously, obtain nanometer titanium dioxide titanium solution,
Take 2g nanometer silver and put in No. 2 beakers, add 1L distilled water, mix homogeneously, obtain nanometer silver solution,
Take 1g benzene halide oxo-compound and 1g chrysanthemum ester derivant is put in No. 3 beakers, addition 22ml distilled water, mix homogeneously,
Obtain acaricide mildew resistant finish agent solution,
Take 2g anion powder and put in No. 4 beakers, add 2ml distilled water, mix homogeneously, obtain negative solution；
B, the nanometer titanium dioxide titanium solution by step a, nanometer silver solution, acaricide mildew resistant finish agent solution, negative solution, mixed
Close uniformly, obtain mixed liquor, be encased in watering can or spray gun；
C, take 84g polyolefin elastomer, 10g paraffin oil, 1g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propanoic acid) Ji Wusi
Alcohol ester, mixing, obtain mixed material；
D, the mixed material in step c is carried out at a temperature of 180～220 ° of C wire drawing, obtain thread or strip semi-finished product, meanwhile,
Maintaining strand shape semi-finished product temperature is 110 ° of C, is sprayed uniformly by the mixed liquor of step b gained and is coated in thread or strip half one-tenth
Product surface, i.e. obtains strand shape polyolefin elastic composite material；
Said polyolefins elastic composite is joined in mould, uses heat pressing forming machines hot-forming, in the mistake of molding
Cheng Zhong, coordinate air-pump inflating suppress so that polyolefin elastomer material in mould by compression swelling, loosely organized, cincture
Combination, finally gives the sample of 10*10*10cm.
Embodiment 2
A, take four beakers, and be numbered 1,2,3,4
Take 6g nano titanium oxide and put in No. 1 beaker, add 0.1L distilled water, mix homogeneously, obtain nanometer titanium dioxide titanium solution,
Take 2g nanometer silver and put in No. 6 beakers, add 1L distilled water, mix homogeneously, obtain nanometer silver solution,
Take 3g benzene halide oxo-compound and 3g chrysanthemum ester derivant is put in No. 3 beakers, addition 66mL distilled water, mix homogeneously,
Obtain acaricide mildew resistant finish agent solution,
Take 6g anion powder and put in No. 4 beakers, add 6mL distilled water, mix homogeneously, obtain negative solution；
B, the nanometer titanium dioxide titanium solution by step a, nanometer silver solution, acaricide mildew resistant finish agent solution, negative solution, mixed
Close uniformly, obtain mixed liquor, be encased in steel U-tube or steel U-type groove mould；
C, take 88g polyolefin elastomer, 12g naphthenic oil, 2g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propanoic acid) Ji Wusi
Alcohol ester, mixing, obtain mixed material；
D, the mixed material in step c is carried out at a temperature of 200 ° of C wire drawing, obtain strand shape semi-finished product, meanwhile, maintain strand shape
80 ° of C of semi-finished product temperature are at the uniform velocity by, in steel U-tube or U-type groove, obtaining strand shape polyolefin elastic composite material；
Said polyolefins elastic composite is joined in mould, uses heat pressing forming machines hot-forming, in the mistake of molding
Cheng Zhong, coordinate air-pump inflating suppress so that polyolefin elastic composite material in mould by compression swelling, loosely organized,
Around combination, finally give the sample of 10*10*10cm.
Comparative example 1
Comparative example 1 is with the difference of embodiment 1,2: comparative example 1 only selects POE raw material to carry out wire drawing, then carries out hot pressing
Molding.
A, take 88g polyolefin elastomer, 12g naphthenic oil, 2g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propanoic acid) season
Doutrate, mixing, obtain mixed material,
B, the mixed material in step a is carried out at a temperature of 200～220 ° of C wire drawing, obtain thread or strip polyolefin elastomer
Material；
Said polyolefins elastomeric material is joined in mould, uses plastic hot pressing machine hot-forming, in the mistake of molding
Cheng Zhong, coordinates air-pump inflating to suppress so that polyolefin elastomer material by compression swelling, obtains loosely organized in mould,
Around the sample of combination, finally give the sample of 10*10*10cm.
Retardant POE compound material and the POE material of comparative example in order to beneficial effects of the present invention is described, to the embodiment of the present invention
Material carries out following performance test, and test result is shown in Table 1 respectively, table 2, table 3, table 4.
The above results illustrates: be not added with the POE material anion number of any functional material be in natural air bear from
Sub-number, the polyolefin elastic composite material adding far infrared powder, anion function powder and nano-silver antibacterial powder is born
Ion number significantly improves, and the number of anion increases with the increase of anion function powder content.
The above results illustrates: the POE material being not added with any functional material does not has far infrared transmission effect, adds far infrared
The polyolefin elastic composite material (POE material) of function powder, anion function powder and nano-silver antibacterial powder possesses well
Far infrared transmission effect, and normal direction total emissivity is up to more than 75%.
The above results illustrates: being not added with the POE material acaricide of any functional material, to walk quickly and keep away rate the lowest, adds far-infrared functional
The POE material of powder, anion function powder and nano-silver antibacterial powder possesses good acarid and walks quickly and keeps away rate, can suppress and reduce demodicid mite
Worm.
The above results illustrates: the POE material antibiotic rate being not added with any functional material is the lowest；Addition far infrared powder,
The POE material of anion function powder and nano-silver antibacterial powder possesses good antibiotic rate, and antibiotic rate is up to more than 70%,
Can effectively suppress the breeding of antibacterial.
Above-mentioned four testing results explanation: the polyolefin elastomer material (POE material) being not added with any functional material removes
Demodicid mite walks quickly and keeps away that rate is the lowest, anion number is the anion number in natural air, does not has far infrared transmission effect and antibiotic rate
The lowest；Add the composite polyolefine material tool of nano titanium oxide, nanometer anion powder, nanometer silver and acaricide antibacterial finishing agent
Standby good acarid walks quickly and keeps away rate, can suppress and reduce acarid, and anion number significantly improves, and possesses good far infrared transmission
Effect, possesses good antibiotic rate, can effectively suppress the breeding of antibacterial.
To sum up, the polyolefin elastic composite material of the present invention, under specific composition and conditions of mixture ratios, have simultaneously and remove
Demodicid mite and antibacterial functions, and the rate of walking quickly and keeping away of acaricide is up to more than 80%, antibiotic rate is up to more than 70%, is especially suitable for manufacturing or making house
Occupy the articles for daily use；Additionally, the polyolefin elastic composite material of the present invention, additionally it is possible to discharge substantial amounts of anion, be conducive to carrying
High degree of comfort, and there is higher normal direction total emissivity.
Claims (10)
1. a polyolefin elastic composite material, it is characterised in that: it includes the component of following parts by weight: polyolefin elastic
Body 80 parts～90 parts, lubricating oil 10 parts～15 parts, 1 part～5 parts of antioxidant, nano titanium oxide 1 part～10 parts, nanometer silver 1 part
～5 parts, acaricide mildew-proofing finishing agent 1 part～10 parts, nanometer anion powder 1 part～10 parts.
Composite the most according to claim 1, it is characterised in that: it is made up of the component of following parts by weight: poly-
Olefin elastomer 80 parts～90 parts, lubricating oil 10 parts～15 parts, 1 part～5 parts of antioxidant, nano titanium oxide 1 part～10 parts, receive
Rice silver 1 part～5 parts, acaricide mildew-proofing finishing agent 1 part～10 parts, nanometer anion powder 1 part～10 parts.
Composite the most according to claim 1, it is characterised in that: it is made up of the component of following parts by weight:
Polyolefin elastomer 84 parts, lubricating oil 10 parts, 1 part of antioxidant, nano titanium oxide 2 parts, nanometer silver 2 parts, acaricide mildew-resistant
Finishing agent 2 parts, nanometer anion powder 2 parts；
Or,
Polyolefin elastomer 88 parts, lubricating oil 12 parts, 2 parts of antioxidant, nano titanium oxide 6 parts, nanometer silver 2 parts, acaricide mildew-resistant
Finishing agent 6 parts, nanometer anion powder 6 parts.
4. according to the composite described in claims 1 to 3 any one, it is characterised in that:
Described lubricating oil in paraffin oil, naphthenic oil, the white oil any one or two or more；
Described antioxidant selected from four (β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propanoic acid) pentaerythritol ester, 2, tri-grades of butyl of 6--
In 4-methylphenol, double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether any one or two or more.
5. according to the composite described in claims 1 to 3 any one, it is characterised in that: described nano titanium oxide is water
Dissolubility nano titanium oxide；Described nanometer silver is water-soluble nano silver；Described nanometer anion powder is water-soluble nano anion
Powder.
6. according to the composite described in claims 1 to 3 any one, it is characterised in that: described acaricide mildew-proofing finishing agent is
It is made up of the component of following parts by weight: benzene halide oxo-compound 1 part～5 parts, chrysanthemum ester derivant 1 part～5 parts.
7. prepare the method for polyolefin elastic composite material described in claim 1～6 any one for one kind, it is characterised in that:
It comprises the following steps:
, take polyolefin elastomer, lubricating oil, antioxidant, mixing, obtain mixed material；
, by stepGained mixed material carries out wire drawing, obtains thread or strip-shaped product, nano-silica in its surface-coated
Change titanium, nanometer silver, acaricide mildew-proofing finishing agent and nanometer anion powder, obtain polyolefin elastic composite material.
Method the most according to claim 7, it is characterised in that: the temperature of described wire drawing is 150 DEG C～220 DEG C, described painting
Thread or the temperature of strip-shaped product is kept when covering nano titanium oxide, nanometer silver, acaricide mildew-proofing finishing agent and nanometer anion powder
It it is 60 DEG C～110 DEG C.
9. polyolefin elastic composite material described in claim 1～6 any one is manufacturing or is making in life staying idle at home articles for use
Application.
Application the most according to claim 9, it is characterised in that: described life staying idle at home articles for use are pillow core, seat cushion or bed
Pad.
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| CN108410046A (en) * | 2018-02-23 | 2018-08-17 | 何新桥 | A kind of antibiotic and sterilizing release anion pad capable of washing and preparation method thereof |
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Application publication date: 20160921 |