CN105924766A - Far-infrared polyolefin elastomer material, and preparation method and application thereof - Google Patents
Far-infrared polyolefin elastomer material, and preparation method and application thereof Download PDFInfo
- Publication number
- CN105924766A CN105924766A CN201610569199.9A CN201610569199A CN105924766A CN 105924766 A CN105924766 A CN 105924766A CN 201610569199 A CN201610569199 A CN 201610569199A CN 105924766 A CN105924766 A CN 105924766A
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- China
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- parts
- far infrared
- composite material
- antioxidant
- polyolefin elastomer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47C—CHAIRS; SOFAS; BEDS
- A47C27/00—Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/10—Pillows
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
Abstract
The invention discloses a polyolefin elastomer composite material. The polyolefin elastomer composite material comprises, by weight, 80-90 parts of polyolefin elastomer, 6-15 parts of lubricating oil, 1-5 parts of an antioxidant, and 6-20 parts of far-infrared functional powder. The polyolefin elastomer composite material has excellent far-infrared functions under specific composition and ratio conditions, and the normal total emissivity reaches up to 79% or above, so the polyolefin elastomer composite material is very suitable for making home life supplies, and is in favor of improving the use comfort level and the healthy health preserving of the furniture life supplies.
Description
Technical field
The present invention relates to a kind of polyolefin elastic composite material and its preparation method and application, be specifically related to one and have
Polyolefin elastic composite material of far-infrared functional and its preparation method and application.
Background technology
Polyolefin elastomer material (POE) be a kind of be that there is good flexibility and the same elasticity of rubber, have
Preferably reelability, the transparency, nontoxicity, lustrous surface is good, chemical stability is good, and anti-aging and resistance to ozone intensity is excellent
Different；Meanwhile, POE material is good with the miscibility of other filler, and coloring and shaping processability are excellent；It is a kind of safety and environmental protection, purposes
Health environment-friendly material widely；POE macromolecular material merges through wire drawing can form network structure, uses contactless canoe
Support with hauling type, the inside network structure of robust surface and resilient enough can be concurrently formed, use it as major ingredient system
The bedding packing materials such as the pillow of one-tenth, seat cushion, mattress possess good elasticity, and have high permeable and gas permeability.
At present, the material as life staying idle at home articles for use such as pillow, seat cushion, mattresses is mainly ethylene-vinyl acetate copolymer
Elastomeric material (EVA elastomeric material), and EVA elastomeric material, although also possess above-mentioned advantage, but have the disadvantage that the most hardening and
Turning yellow, stability is not enough.From states such as Japan using POE material as after taking novel filling material, often it is extended and is applied to pillow, mattress
Etc. life staying idle at home articles for use, provide comfortable for people and live easily.But polyolefin elastomer material (POE material) is made
Simply simply POE material is carried out wire drawing, shaping for life staying idle at home articles for use, only possesses the excellent properties of POE material itself,
And do not possess the performances such as far infrared.
Summary of the invention
It is an object of the invention to provide a kind of polyolefin elastic composite material with far-infrared functional.
A kind of polyolefin elastic composite material that the present invention provides, it is characterised in that: it includes following parts by weight
Component: polyolefin elastomer 80 parts～90 parts, lubricating oil 6 parts～15 parts, antioxidant 1～5 parts, far infrared powder 6 parts～20
Part.
Further, it is made up of the component of following parts by weight: polyolefin elastomer 80 parts～90 parts, lubricating oil 6
Part～15 parts, antioxidant 1～5 parts, far infrared powder 6 parts～20 parts.
Further, it is made up of the component of following parts by weight:
Polyolefin elastomer 86 parts, lubricating oil 10 parts, 1 part of antioxidant, far infrared powder 8 parts；
Or,
Polyolefin elastomer 89 parts, lubricating oil 12 parts, 2 parts of antioxidant, far infrared powder 12 parts.
Further,
Described lubricating oil in paraffin oil, naphthenic oil, the white oil any one or two or more；
Described antioxidant selected from four (β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester, 2, tri-grades of butyl of 6--
In 4-methylphenol, double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether any one or two or more.
Further, described far infrared powder is nano titanium oxide.
Present invention also offers a kind of method preparing said polyolefins elastic composite, it comprises the following steps:
, take polyolefin elastomer, lubricating oil, antioxidant, mixing, obtain mixed material；
, by stepGained mixed material carries out wire drawing, obtains thread or strip-shaped product, is coated with on its surface and is covered with nano-silica
Change titanium, obtain polyolefin elastic composite material.
Further, the temperature of described wire drawing is 150 DEG C～220 DEG C, keeps thread during described coated with nano titanium dioxide
Or the temperature of strip-shaped product is 60 DEG C～110 DEG C.
Present invention also offers said polyolefins elastic composite and manufacture or making answering in life staying idle at home articles for use
With.
Further, described life staying idle at home articles for use are pillow, seat cushion or mattress.
Manufacture pillow described above, seat cushion, the method for mattress, it comprises the following steps:
(1) according to different product needed, such as pillow, seat cushion, mattress equidimension, make corresponding mould, produced is gathered
Olefm elastomeric composite material, coordinates forming machine hot-forming, during shaping, coordinates air-pump inflating to suppress so that poly-
Olefm elastomeric composite material by compression swelling, is formed loosely organized in mould, around the semifinished material of combination.Pressure
Can be adjusted according to different product and mould, thus reach space network, i.e. obtain corresponding pillow, bedding core etc. partly becomes
Product packing material.
(2) according to the packing material made, selecting different clothes, this cloth does not limit to material.In addition cutting and
Sewing, parcel, combination i.e. obtains corresponding finished product.
Compared with prior art, the method have the advantages that
(1) the polyolefin elastic composite material of the present invention, it is tough for strengthening it for being suitably added the lubricating oil such as paraffin oil, naphthenic oil
Property and pliability, during keeping polymer constant temperature (150 ° of C～220 ° of C), carry out wire drawing process, wire drawing is to diameter 1～2
The silk strip material of millimeter, simultaneously by the solution spraying containing nano titanium oxide at the hot strand shape material of 60 ° of C～110 ° of C
Material surface, or by the hot silk strip material of 60 ° of C～110 ° of C by the U-tube of the solution containing nano titanium oxide or U
In the moulds such as type groove, at high temperature nano titanium oxide can uniformly be coated to the thread or surface of strip material, is i.e. had
There is the polyolefin elastic composite material of far-infrared functional.
(2) the polyolefin elastic composite material of the present invention, because wherein with the addition of nano titanium oxide far-infrared functional
Powder component adds the functional of common POE material, and the far-infrared functional with excellence makes composite add far infrared
Performance；It is highly suitable for preparing life staying idle at home articles for use, such as: pillow, seat cushion, mattress etc..
(3) method that the present invention prepares polyolefin elastic composite material, technique is simple and convenient to operate, cost is relatively low, non-
Often it is suitable for manufacturing multifunctinoal health environment-friendly products, such as: the furniture daily necessitiess such as pillow, seat cushion, mattress.
(4) the polyolefin elastic composite material of the present invention, selects POE material to compare EVA resin class material, solves
EVA material easily turns yellow and hardening problem, makes and simplifies technique, is effectively increased yield, can carry out large-scale production, have
It is beneficial to promotion and application on a large scale；The advantage that ensure that himself, improves it functional；Its article of manufacture manufactured is used to increase
It is functional, expands range of application, has a good application prospect；Can be recycled, add use actual effect, extend
Use time, and recyclable reuse, it is to avoid the waste of material and social resources；POE material can carry out environment-friendly degradable
Process, meet the requirement of environmental protection, it is to avoid pollute.
The polyolefin elastic composite material of the present invention, under specific composition and conditions of mixture ratios, has the reddest of excellence
Outer function, and normal direction total emissivity is up to more than 79%, is especially suitable for manufacturing or making life staying idle at home articles for use, is conducive to improving house
The comfort level that tool daily necessities uses.
Obviously, according to the foregoing of the present invention, according to ordinary technical knowledge and the customary means of this area, without departing from
Under the present invention above-mentioned basic fundamental thought premise, it is also possible to make the amendment of other various ways, replace or change.
Accompanying drawing explanation
Fig. 1 is the preparation technology flow chart of polyolefin elastic composite material of the present invention.
Below by way of the embodiment in detailed description of the invention, the foregoing of the present invention is described in further detail.
But this should not being interpreted as, the scope of the above-mentioned theme of the present invention is only limitted to Examples below.All real based on foregoing of the present invention institute
Existing technology belongs to the scope of the present invention.
Detailed description of the invention
The raw material, the equipment that use in the specific embodiment of the invention are known product, obtain by buying commercially available prod.
Embodiment 1
A, take 8g nano titanium oxide and put in beaker, add 0.4L distilled water, mix, obtain nanometer titanium dioxide titanium solution,
B, the nanometer titanium dioxide titanium solution in step a is encased in watering can；
C, take 86g polyolefin elastomer, 10g paraffin oil, 1g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester, mixing, obtain mixed material；
D, the mixed material in step c is carried out at a temperature of 180～220 ° of C wire drawing, obtain thread or strip semi-finished product, meanwhile,
Maintaining thread or strip semi-finished product temperature is 110 ° of C, sprays the nano titanium oxide aqueous solution of step b gained at silk uniformly
Shape or strip surface of semi-finished, i.e. obtain strand shape polyolefin elastic composite material；
Said polyolefins elastic composite is joined in mould, uses heat pressing forming machines hot-forming, in the mistake of shaping
Cheng Zhong, coordinate air-pump inflating suppress so that polyolefin elastic composite material in mould by compression swelling, loosely organized,
Around combination, finally give the sample of 10*10*10cm.
Embodiment 2
A, take 12g nano titanium oxide and put in beaker, add 0.5L distilled water, mix, obtain nanometer titanium dioxide titanium solution,
B, the nanometer titanium dioxide titanium solution in step a is encased in steel U-tube；
C, take 89g polyolefin elastomer, 12g naphthenic oil, 2g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester, mixing, obtain mixed material；
D, the mixed material in step c is carried out at a temperature of 200 ° of C wire drawing, obtain strand shape semi-finished product, meanwhile, maintain strand shape
80 ° of C of semi-finished product temperature are at the uniform velocity by, in steel U-tube or steel U-type groove mould, i.e. obtaining strand shape polyolefin elastic bluk recombination
Material；
Said polyolefins elastic composite is joined in mould, uses heat pressing forming machines hot-forming, in the mistake of shaping
Cheng Zhong, coordinate air-pump inflating suppress so that polyolefin elastic composite material in mould by compression swelling, loosely organized,
Around combination, finally give the sample of 10*10*10cm.
Comparative example 1
Comparative example 1 is with the difference of embodiment 1,2: comparative example 1 only selects POE raw material to carry out wire drawing, then carries out hot pressing
Shaping.
A, take 89g polyolefin elastomer, 12g naphthenic oil, 2g tetra-(β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) season
Doutrate, mixing, obtain mixed material,
B, the mixed material in step a is carried out at a temperature of 200 ° of C wire drawing, obtain thread or strip polyolefin elastomer material；
Said polyolefins elastomeric material is joined in mould, uses plastic hot pressing machine hot-forming, in the mistake of shaping
Cheng Zhong, coordinates air-pump inflating to suppress so that polyolefin elastomer material by compression swelling, obtains loosely organized in mould,
Around the sample of combination, finally give the sample of 10*10*10cm.
Retardant POE compound material and the POE material of comparative example in order to beneficial effects of the present invention is described, to the embodiment of the present invention
Material carries out following performance test, and test result is shown in Table 1.
The above results illustrates: the polyolefin elastomer material (POE material) being not added with any functional material does not has far infrared
Launching effect, the polyolefin elastic composite material of addition nano titanium oxide far infrared powder possesses good far infrared and sends out
Penetrate effect.
To sum up, the polyolefin elastic composite material of the present invention, under specific composition and conditions of mixture ratios, there is excellence
Far-infrared functional, and normal direction total emissivity is up to more than 79%, is especially suitable for manufacturing or making life staying idle at home articles for use, is conducive to carrying
The comfort level of high furniture daily necessities use and health care.
Claims (9)
1. a polyolefin elastic composite material, it is characterised in that: it includes the component of following parts by weight: polyolefin elastic
Body 80 parts～90 parts, lubricating oil 6 parts～15 parts, antioxidant 1～5 parts, far infrared powder 6 parts～20 parts.
Composite the most according to claim 1, it is characterised in that: it is made up of the component of following parts by weight: poly-
Olefin elastomer 80 parts～90 parts, lubricating oil 6 parts～15 parts, antioxidant 1～5 parts, far infrared powder 6 parts～20 parts.
Composite the most according to claim 1, it is characterised in that: it is made up of the component of following parts by weight:
Polyolefin elastomer 86 parts, lubricating oil 10 parts, 1 part of antioxidant, far infrared powder 8 parts；
Or,
Polyolefin elastomer 89 parts, lubricating oil 12 parts, 2 parts of antioxidant, far infrared powder 12 parts.
4. according to the composite described in claims 1 to 3 any one, it is characterised in that:
Described lubricating oil in paraffin oil, naphthenic oil, the white oil any one or two or more；
Described antioxidant selected from four (β-(3,5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester, 2, tri-grades of butyl of 6--
In 4-methylphenol, double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether any one or two or more.
5. according to the composite described in claims 1 to 3 any one, it is characterised in that: described far infrared powder is for receiving
Rice titanium dioxide.
6. prepare the method for polyolefin elastic composite material described in Claims 1 to 5 any one for one kind, it is characterised in that:
It comprises the following steps:
, take polyolefin elastomer, lubricating oil, antioxidant, mixing, obtain mixed material；
, by stepGained mixed material carries out wire drawing, obtains thread or strip-shaped product, is coated with on its surface and is covered with far infrared merit
Energy powder, obtains polyolefin elastic composite material.
Method the most according to claim 7, it is characterised in that: the temperature of described wire drawing is 150 DEG C～220 DEG C, described painting
Keeping thread or strip-shaped product temperature when covering far infrared powder is 60 DEG C～110 DEG C.
8. polyolefin elastic composite material described in claim 1～6 any one is manufacturing or is making in life staying idle at home articles for use
Application.
Application the most according to claim 9, it is characterised in that: described life staying idle at home articles for use are pillow, seat cushion or mattress.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610569199.9A CN105924766A (en) | 2016-07-19 | 2016-07-19 | Far-infrared polyolefin elastomer material, and preparation method and application thereof |
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| CN201610569199.9A CN105924766A (en) | 2016-07-19 | 2016-07-19 | Far-infrared polyolefin elastomer material, and preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106923562A (en) * | 2017-03-18 | 2017-07-07 | 匠仙（上海）床垫科技有限公司 | A kind of mattress construction |
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| CN101402761A (en) * | 2008-11-14 | 2009-04-08 | 广州市申万电子科技有限公司 | Ethylene-butylene copolymer composite material with function of generating negative ion, far-infrared ray or antimicrobial mildew resistant function |
| CN104194137A (en) * | 2014-08-21 | 2014-12-10 | 上海宇强贸易有限公司 | Elastic material and application thereof |
| CN104921533A (en) * | 2015-07-10 | 2015-09-23 | 魏健 | Environment-friendly multifunctional macromolecule health care pillow and manufacturing method thereof |
-
2016
- 2016-07-19 CN CN201610569199.9A patent/CN105924766A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402761A (en) * | 2008-11-14 | 2009-04-08 | 广州市申万电子科技有限公司 | Ethylene-butylene copolymer composite material with function of generating negative ion, far-infrared ray or antimicrobial mildew resistant function |
| CN104194137A (en) * | 2014-08-21 | 2014-12-10 | 上海宇强贸易有限公司 | Elastic material and application thereof |
| CN104921533A (en) * | 2015-07-10 | 2015-09-23 | 魏健 | Environment-friendly multifunctional macromolecule health care pillow and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
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| 张景: "《一通检索记录表》", 1 November 2017 * |
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|---|---|---|---|---|
| CN106923562A (en) * | 2017-03-18 | 2017-07-07 | 匠仙（上海）床垫科技有限公司 | A kind of mattress construction |
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Application publication date: 20160907 |
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