CN109096590A - A kind of anion perfume discoloration EVA composite elastic material and preparation method thereof - Google Patents
A kind of anion perfume discoloration EVA composite elastic material and preparation method thereof Download PDFInfo
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- CN109096590A CN109096590A CN201810879100.4A CN201810879100A CN109096590A CN 109096590 A CN109096590 A CN 109096590A CN 201810879100 A CN201810879100 A CN 201810879100A CN 109096590 A CN109096590 A CN 109096590A
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- 150000001450 anions Chemical class 0.000 title claims abstract description 64
- 239000002304 perfume Substances 0.000 title claims abstract description 62
- 239000002131 composite material Substances 0.000 title claims abstract description 57
- 238000002845 discoloration Methods 0.000 title claims abstract description 55
- 239000013013 elastic material Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims description 19
- 239000000843 powder Substances 0.000 claims abstract description 110
- 239000000463 material Substances 0.000 claims abstract description 105
- 239000011347 resin Substances 0.000 claims abstract description 73
- 229920005989 resin Polymers 0.000 claims abstract description 73
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 70
- 239000011159 matrix material Substances 0.000 claims abstract description 65
- 239000004575 stone Substances 0.000 claims abstract description 56
- 239000000945 filler Substances 0.000 claims abstract description 53
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 52
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000003063 flame retardant Substances 0.000 claims abstract description 41
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- 239000004595 color masterbatch Substances 0.000 claims abstract description 14
- 238000001467 acupuncture Methods 0.000 claims abstract description 11
- 230000006911 nucleation Effects 0.000 claims abstract description 11
- 238000010899 nucleation Methods 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 6
- 230000004048 modification Effects 0.000 claims description 73
- 238000012986 modification Methods 0.000 claims description 73
- 229920001577 copolymer Polymers 0.000 claims description 65
- 229920001971 elastomer Polymers 0.000 claims description 64
- 239000000806 elastomer Substances 0.000 claims description 62
- 239000004113 Sepiolite Substances 0.000 claims description 61
- 229910052624 sepiolite Inorganic materials 0.000 claims description 61
- 238000002156 mixing Methods 0.000 claims description 33
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 32
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 27
- 235000019355 sepiolite Nutrition 0.000 claims description 27
- 230000032050 esterification Effects 0.000 claims description 22
- 238000005886 esterification reaction Methods 0.000 claims description 22
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 claims description 22
- 235000019270 ammonium chloride Nutrition 0.000 claims description 16
- -1 alkyl dimethyl ammonium Chemical compound 0.000 claims description 15
- 230000001954 sterilising effect Effects 0.000 claims description 15
- 238000004659 sterilization and disinfection Methods 0.000 claims description 15
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- 125000001706 diarylethene group Chemical group 0.000 claims description 11
- 239000004604 Blowing Agent Substances 0.000 claims description 10
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims description 10
- 239000011521 glass Substances 0.000 claims description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims description 8
- 235000009566 rice Nutrition 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 6
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 229940041616 menthol Drugs 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 5
- 238000007046 ethoxylation reaction Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 240000009215 Nepeta cataria Species 0.000 claims description 4
- 235000010679 Nepeta cataria Nutrition 0.000 claims description 4
- 235000003434 Sesamum indicum Nutrition 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- ZDKZHVNKFOXMND-UHFFFAOYSA-N epinepetalactone Chemical compound O=C1OC=C(C)C2C1C(C)CC2 ZDKZHVNKFOXMND-UHFFFAOYSA-N 0.000 claims description 4
- 239000000341 volatile oil Substances 0.000 claims description 4
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- 239000004005 microsphere Substances 0.000 claims description 3
- 239000011812 mixed powder Substances 0.000 claims description 3
- 150000001282 organosilanes Chemical class 0.000 claims description 3
- 230000005616 pyroelectricity Effects 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 244000000231 Sesamum indicum Species 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 239000002260 anti-inflammatory agent Substances 0.000 abstract description 2
- 230000001741 anti-phlogistic effect Effects 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 230000004089 microcirculation Effects 0.000 abstract description 2
- 230000001225 therapeutic effect Effects 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 24
- 238000000554 physical therapy Methods 0.000 description 8
- 241000209094 Oryza Species 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 241000207961 Sesamum Species 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000077 insect repellent Substances 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 240000000233 Melia azedarach Species 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000017531 blood circulation Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 239000008159 sesame oil Substances 0.000 description 2
- 235000011803 sesame oil Nutrition 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 241000282452 Ailuropoda melanoleuca Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 125000000656 azaniumyl group Chemical group [H][N+]([H])([H])[*] 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 150000001988 diarylethenes Chemical class 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 210000004124 hock Anatomy 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 210000002435 tendon Anatomy 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of anion perfume discoloration EVA composite elastic materials, component including following mass fraction: function modified filler material 320-430 parts, 20-100 parts of thermal control material, 290-350 parts of matrix resin, nucleation fire retardant 50-100 part, 50-100 parts of dispersing agent, 50-60 parts of color masterbatch powder, 30-50 parts of flexibility agent, sterilize fumet 50-150 parts, it is organic colour-changing agent 30-80 parts photic, due to including ring germanium stone needle component, anion can be discharged, the toxic and harmful gas such as formaldehyde, benzene, dimethylbenzene and the VOC in the air of space are removed；, can be emitting far-infrared due to including ring germanium stone acupuncture needle component, wavelength is close with the infrared band of human-body emitting, generates resonance effects, and it is advantageous to microcirculation in human body, it can be in therapeutic treatment bactericidal antiphlogistic material.
Description
Technical field
The present invention relates to special plastic field of material technology, and it is compound to refer specifically to a kind of anion perfume discoloration EVA elastic force
Material and preparation method thereof.
Background technique
One vinyl acetate co-polymer of ethylene (EVA) is that the fourth-largest ethylene series after HDPE, LDPE, LLDPE is total
Polymers, and the most important ethylene atactic copolymer developed in recent years, belong to the rubber and plastic resin in thermoplasticity resin.In EVA
In material, the increase of vinyl acetate (VA) component included with it, elasticity, flexibility, adhesiveness, compatibility, the transparency
Also accordingly improve with performances such as dissolubilities.The size of VA mass fraction component is included according to it, can be subdivided into three categories i.e.: wherein
VA content is mainly used to manufacture wire cable material, film to PE modified in 5% one 40%, commonly referred to as EVA resin class
And other moulded products and mixture；Wherein VA content is main to use in 40% one 70%, commonly referred to as EVA elastomer class
Make rubber elastomer, PVC modifier, auto industry component and toy for children etc.；Wherein VA content is 70% one 95%, usually
Emulsion state, referred to as EVA lotion resin class is made, is mainly used as adhesive and coating, coating etc..
EVA production mostly uses high pressure continuous bulk polymerization method in the world at present, in LDPE high-pressure polymerization process device only
Increase some ancillary equipments, slightly transformation can produce EVA.80% is EVA in the copolymer of U.S.'s LDPE device production.EVA
Resin is compared with polyethylene (PE): EVA resin introduces vinyl acetate monomer in strand, makes in the degree of branching of copolymer
Rise, crystallinity reduce, make its flexibility, the transparency, adherence, impact resistant strength degree, environmental stress crack resistance, it is low temperature resistant,
Non-toxic and optical property improves.The physicochemical properties of general EVA copolymer depend mainly on VA content on strand and
The melt flow rate (MFR) (MFl) of product；And its density is also restricted by VA content and is improved by 5% to 40% such as VA content, it is close
Degree increases to O.974 gram Cm-3 by an O.929 gram Cm-3.The features such as compatibility of EVA and filler and color masterbatch is good.
But its flame resistance of EVA resin is poor, there is also the weakness such as be hardened intolerant to puncture and low temperature, limits for EVA foam product
The application range of EVA elastomer class material is made.
Summary of the invention
The disadvantages of present invention is in order to further increase the excellent performance of EVA resin, overcome inflammability, the present invention use function
Type negative ion far-infrared modified filler, the auxiliary agents such as discolouration, anti-flammability, and selecting VA content is the EVA of 40%-60% as base
Body material, by sport technique segments such as filler modified, blending and modifying and graft modifications, and using EVA and diarylethene molecule,
Color masterbatch, the characteristics such as compatibility is good form a kind of anion perfume by special process and change colour EVA elastic force composite wood
Material.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of anion perfume discoloration EVA composite elastic material, the component including following mass fraction: function modified to fill out
320-430 parts of charge, 20-100 parts of thermal control material, 290-350 parts of matrix resin, nucleation fire retardant 50-100 parts, dispersing agent 50-
100 parts, 50-60 parts of color masterbatch powder, 30-50 parts of flexibility agent, sterilization fumet 50-150 parts, it is organic colour-changing agent 30-80 parts photic.
Preferably, the function modified filler material includes that 300 parts -400 parts of micro-powder, silane are received in the mixing of ring germanium stone needle
20 parts -30 parts of coupling agent；The thermal control material is the hollow glass micropearl that diameter is 0.5 micron；Described matrix resin is EVA bullet
Property body analog copolymer, VA content is 40%-60% in the EVA elastomer analog copolymer；The nucleation fire retardant is double ten alkane
Any one in base alkyl dimethyl ammonium chloride-sepiolite and organic modification montmonrillonite powder；The dispersing agent is ethoxylation base amine；Institute
Stating flexibility agent is ethylene-octene copolymer；The sterilization fumet is 50 parts -150 parts of forest incense-sepiolite, face powder-sepiolite
Any one in 60 parts -70 parts and 65 parts -80 parts of sesame oil-sepiolite；Photic organic colour-changing agent is diarylethene powder.
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 350 parts of matrix resin, -3000H30 parts of blowing agent AC, photic organic colour-changing agent 30-80
Part, 100 parts of fire retardant.
Preferably, the function modified filler material includes that 450 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
50 parts；Described matrix resin is EVA elastomer analog copolymer, and VA content is 30% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder；The fire retardant is organically modified montmorillonite clay powder and organically-modified sepiolite
Any one in powder.
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 400 parts of function modified filler material, 190 parts of thermal control material, 400 parts of matrix resin, 150 parts of fire retardant, photic organic discoloration
30-80 parts of agent causes cool dose 180 parts, 10 parts of menthol.
Preferably, the function modified filler material includes that 370 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
30 parts；The thermal control material includes 100 parts of hollow glass micropearl, 50 parts of mica powder, 20 parts of rutile titanium dioxide, barium sulfate
10 parts, described matrix resin is EVA elastomer analog copolymer, and VA content is 50% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder, and the fire retardant is organically-modified sepiolite powder；It is described cause cool dose include
100 parts of hollow ceramic microspheres, 50 parts of mica powder, 20 parts of rutile titanium dioxide, 10 parts of barium sulfate.
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 400 parts of matrix resin, 30 parts of temperature control filler, 1 part of colour-changing agent, 50 parts of fire retardant, mosquito repellent
11 parts of agent.
Preferably, the function modified filler material is that esterification modification ring germanium stone acupuncture needle receives powder and micron；Described matrix resin is EVA
Elastomer analog copolymer, VA content is 40% in the EVA elastomer analog copolymer；The temperature control filler is nano silica
With the mixture of carbon black, the ratio of the nano silica and carbon black is 100:20；The colour-changing agent is two fragrant alkene；The resistance
Combustion agent is organic sepiolite powder；The culicifuge is the mixture of Lavender and Catnip essential oil.
The invention also discloses one kind according to anion perfume as claimed in claim 1 or 2 discoloration EVA composite elastic material
Proportion preparation method, step includes S1, filler material parent's esterification modification: using silane coupling agent to ring germanium stone needle mixing receive it is micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and putting into matrix resin EVA elastomer analog copolymer melt, then plus
Enter thermal control material；S4, after photic organic colour-changing agent, color masterbatch powder, flexibility agent, dispersing agent and sterilization fumet are blended, S3 is put into
In and fill and be uniformly dispersed；S5, it will be mixed in S1 investment S4, it is multiple to pull out a kind of anion perfume discoloration EVA elastic force by equipment
Condensation material.
The invention also discloses one kind according to the anion perfume discoloration EVA composite elastic material of claim 3 or 4
Proportion preparation method, step includes S1, filler material parent's esterification modification: using silane coupling agent to ring germanium stone needle mixing receive it is micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, blowing agent AC -3000H and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
The invention also discloses one kind according to the anion perfume discoloration EVA composite elastic material of claim 5 or 6
Proportion preparation method, step includes S1, filler material parent's esterification modification: using silane coupling agent to ring germanium stone needle mixing receive it is micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, thermal control material, menthol and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
The invention also discloses one kind according to the anion perfume discoloration EVA composite elastic material of claim 7 or 8
Proportion preparation method, step includes S1, filler material parent's esterification modification: by the high-energy with natural pyroelectricity, piezoelectricity
Micron ring germanium of receiving performs acupunctures with stone needles mixed powder, under organo silane coupling agent effect, is modified to esterification modification ring germanium stone acupuncture needle and receives micron part；S2,
Matrix resin: EVA elastomer analog copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride carries out sepiolite
Organic modification forms didecyl Dimethy ammonium chloride-sepiolite modified powder, and puts into matrix resin EVA elastomer class
In copolymer melt；S4, by colour-changing agent, thermal control material, culicifuge and fire retardant it is mixed after, put into S3 and fill and be uniformly dispersed；S5,
S1 is put into S4 and is mixed, a kind of anion perfume discoloration EVA composite elastic material is pulled out by equipment.
The present invention have the characteristics that it is following and the utility model has the advantages that
By adopting the above technical scheme:
1, due to including ring germanium stone needle component, anion can be discharged, formaldehyde, benzene, dimethylbenzene in the air of space are removed
And the toxic and harmful gas such as VOC；
2, can be emitting far-infrared due to including ring germanium stone acupuncture needle component, wavelength is close with the infrared band of human-body emitting, produces
Raw resonance effects, it is advantageous to microcirculation in human body, it can be in therapeutic treatment bactericidal antiphlogistic material；
3, since the invention new material matrix resin is EvA resin, elasticity is good, and foaming characteristic is good, can make various instruments
Gasket, toy for children；
4, since the material contains forest incense and face powder sesame oil, therefore various sesame oil sachets can be tailored: (since the material can be with
Addition Catnip essential oil makees culicifuge)；
5, since the material contains color masterbatch and the fragrant alkene of colour change function molecule one or two, it may be used as colored article；
6, it is inlayed in EVA material since the material contains hollow glass micropearl, there is refrigerating function, that is, have to sunlight
In main function of the thermal energy radiation into the outer space, another side is distributed nano silver molecule therefore again with having to ultraviolet light and visible light
Reflection function, can be in refrigeration control；
7, anion can be discharged since the material contains six ring stones, germanite and stone needle, extra-far infrared line, infrared ray and super
Sound wave pulse promotes blood circulation of human body prevention and treatment cardiovascular, has refresh function to room air.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
The present invention provides a kind of anion perfume discoloration EVA composite elastic material, the group including following mass fraction
Point: 320 parts of function modified filler material, 20 parts of thermal control material, 290 parts of matrix resin, nucleation 50 parts of fire retardant, 50 parts of dispersing agent,
50 parts of color masterbatch powder, 30 parts of flexibility agent, sterilization 50 parts of fumet, photic 30 parts of organic colour-changing agent.
Preferably, the function modified filler material includes that 300 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
20 parts；The thermal control material is the hollow glass micropearl that diameter is 0.5 micron；Described matrix resin is the copolymerization of EVA elastomer class
Object, VA content is 40%-60% in the EVA elastomer analog copolymer；The nucleation fire retardant is didecyl Dimethy chlorine
Change any one in ammonium-sepiolite and organic modification montmonrillonite powder；The dispersing agent is ethoxylation base amine；The flexibility agent is
Ethylene-octene copolymer；The sterilization fumet is 50 parts of forest incense-sepiolite, 60 parts of face powder-sepiolite and sesame oil-Hai Pao
Any one in 65 parts of stone；Photic organic colour-changing agent is diarylethene powder.
The invention also discloses a kind of systems according to the above-mentioned proportion for stating anion perfume discoloration EVA composite elastic material
Preparation Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent
Micro-powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer
Analog copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, is formed double
Ten alkyl dimethyl ammonium chlorides-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt, then
Thermal control material is added；S4, it after photic organic colour-changing agent, color masterbatch powder, flexibility agent, dispersing agent and sterilization fumet are blended, puts into
In S3 and fills and be uniformly dispersed；S5, it will be mixed in S1 investment S4, a kind of anion perfume discoloration EVA elastic force is pulled out by equipment
Composite material.
Embodiment 2
The present invention provides a kind of anion perfume discoloration EVA composite elastic material, the group including following mass fraction
Point: 370 parts of function modified filler material, 60 parts of thermal control material, 320 parts of matrix resin, nucleation 75 parts of fire retardant, 75 parts of dispersing agent,
55 parts of color masterbatch powder, 40 parts of flexibility agent, sterilization 100 parts of fumet, photic 55 parts of organic colour-changing agent.
Preferably, the function modified filler material includes that 345 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
25 parts；The thermal control material is the hollow glass micropearl that diameter is 0.5 micron；Described matrix resin is the copolymerization of EVA elastomer class
Object, VA content is 40%-60% in the EVA elastomer analog copolymer；The nucleation fire retardant is didecyl Dimethy chlorine
Change any one in ammonium-sepiolite and organic modification montmonrillonite powder；The dispersing agent is ethoxylation base amine；The flexibility agent is
Ethylene-octene copolymer；The sterilization fumet is 100 parts of forest incense-sepiolite, 65 parts of face powder-sepiolite and sesame oil-Hai Pao
Any one in 70 parts of stone；Photic organic colour-changing agent is diarylethene powder.
The invention also discloses a kind of systems according to the above-mentioned proportion for stating anion perfume discoloration EVA composite elastic material
Preparation Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent
Micro-powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer
Analog copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, is formed double
Ten alkyl dimethyl ammonium chlorides-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt, then
Thermal control material is added；S4, it after photic organic colour-changing agent, color masterbatch powder, flexibility agent, dispersing agent and sterilization fumet are blended, puts into
In S3 and fills and be uniformly dispersed；S5, it will be mixed in S1 investment S4, a kind of anion perfume discoloration EVA elastic force is pulled out by equipment
Composite material.
Embodiment 3
The present invention provides a kind of anion perfume discoloration EVA composite elastic material, the group including following mass fraction
Point: 430 parts of function modified filler material, 100 parts of thermal control material, 350 parts of matrix resin, nucleation 100 parts of fire retardant, dispersing agent 100
Part, 60 parts of color masterbatch powder, 50 parts of flexibility agent, sterilization 150 parts of fumet, photic 80 parts of organic colour-changing agent.
Preferably, the function modified filler material includes that 300 parts -400 parts of micro-powder, silane are received in the mixing of ring germanium stone needle
30 parts of coupling agent；The thermal control material is the hollow glass micropearl that diameter is 0.5 micron；Described matrix resin is EVA elastomer
Analog copolymer, VA content is 40%-60% in the EVA elastomer analog copolymer；The nucleation fire retardant is double ten alkyl two
Any one in ammonio methacrylate-sepiolite and organic modification montmonrillonite powder；The dispersing agent is ethoxylation base amine；It is described soft
Tough dose is ethylene-octene copolymer；The sterilization fumet is 150 parts of forest incense-sepiolite, 70 parts of face powder-sepiolite and perfume
Any one in 80 parts of oil-sepiolite；Photic organic colour-changing agent is diarylethene powder.
The invention also discloses a kind of systems according to the above-mentioned proportion for stating anion perfume discoloration EVA composite elastic material
Preparation Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent
Micro-powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer
Analog copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, is formed double
Ten alkyl dimethyl ammonium chlorides-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt, then
Thermal control material is added；S4, it after photic organic colour-changing agent, color masterbatch powder, flexibility agent, dispersing agent and sterilization fumet are blended, puts into
In S3 and fills and be uniformly dispersed；S5, it will be mixed in S1 investment S4, a kind of anion perfume discoloration EVA elastic force is pulled out by equipment
Composite material.
Scheme described in embodiment 1-3, a kind of anion perfume discoloration EVA (temperature control) the elastic force composite wood being prepared
Material provides air refrigeration type soft cushion material predominantly in the room of tropical and subtropical zone region or in passenger car, or production causes cool work
It takes, is suitble to high-temperature operation person works clothes and sportsman's insole making material, or production pressing mold toy material includes person of low position
Shape shows ornament materials；Or the packing box of various superior cosmetics；Or the packaging material and show piece of various craftworks are old
Column platform or wedding celebration material arranged etc..
Embodiment 4
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 350 parts of matrix resin, -3000H30 parts of blowing agent AC, photic 30 parts of organic colour-changing agent,
100 parts of fire retardant.
Preferably, the function modified filler material includes that 450 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
50 parts；Described matrix resin is EVA elastomer analog copolymer, and VA content is 30% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder；The fire retardant is organically modified montmorillonite clay powder and organically-modified sepiolite
Any one in powder.
The invention also discloses a kind of preparations of proportion according to above-mentioned anion perfume discoloration EVA composite elastic material
Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, blowing agent AC -3000H and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
Embodiment 5
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 350 parts of matrix resin, -3000H30 parts of blowing agent AC, photic 80 parts of organic colour-changing agent,
100 parts of fire retardant.
Preferably, the function modified filler material includes that 450 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
50 parts；Described matrix resin is EVA elastomer analog copolymer, and VA content is 30% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder；The fire retardant is organically modified montmorillonite clay powder and organically-modified sepiolite
Any one in powder.
The invention also discloses a kind of preparations of proportion according to above-mentioned anion perfume discoloration EVA composite elastic material
Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, blowing agent AC -3000H and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
Embodiment 6
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 350 parts of matrix resin, -3000H30 parts of blowing agent AC, photic 55 parts of organic colour-changing agent,
100 parts of fire retardant.
Preferably, the function modified filler material includes that 450 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
50 parts；Described matrix resin is EVA elastomer analog copolymer, and VA content is 30% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder；The fire retardant is organically modified montmorillonite clay powder and organically-modified sepiolite
Any one in powder.
The invention also discloses a kind of preparations of proportion according to above-mentioned anion perfume discoloration EVA composite elastic material
Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, blowing agent AC -3000H and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
A kind of anion perfume discoloration EVA (temperature control) elastic force that technical solution described in embodiment 4-6 is prepared is multiple
Condensation material is applicable in (1), caring industry, physical therapy plaster, physical therapy insole is made with new material of the present invention, physical therapy mattress, physical therapy are sat
Chair, physiotherapy kneelet set, physiotherapeutic waistband, physiotherapeutic neck protection sleeve, therapy pillow headgear, physical therapy foot gambrel set, physiotherapy glove, physiotherapeutic cap,
The materials such as physiotherapy glove, (2), Pet house material, pet nursing series of products, (3), zoo preciousness animal care material include
Giant panda nurses series of products.
Embodiment 7
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 400 parts of function modified filler material, 190 parts of thermal control material, 400 parts of matrix resin, 150 parts of fire retardant, photic organic discoloration
50 parts of agent causes cool dose 180 parts, 10 parts of menthol.
Preferably, the function modified filler material includes that 370 parts of micro-powder, silane coupling agent are received in the mixing of ring germanium stone needle
30 parts；The thermal control material includes 100 parts of hollow glass micropearl, 50 parts of mica powder, 20 parts of rutile titanium dioxide, barium sulfate
10 parts, described matrix resin is EVA elastomer analog copolymer, and VA content is 50% in the EVA elastomer analog copolymer；It is described
Photic organic colour-changing agent is diarylethene powder, and the fire retardant is organically-modified sepiolite powder；It is described cause cool dose include
100 parts of hollow ceramic microspheres, 50 parts of mica powder, 20 parts of rutile titanium dioxide, 10 parts of barium sulfate.
The invention also discloses a kind of preparations of proportion according to above-mentioned anion perfume discoloration EVA composite elastic material
Method, which is characterized in that step includes S1, filler material parent's esterification modification: the mixing of ring germanium stone needle is received using silane coupling agent micro-
Rice powder surface, carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class
Copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten
Alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, by light
After causing organic colour-changing agent, thermal control material, menthol and fire retardant mixed, puts into S3 and fill and be uniformly dispersed；S5, S1 is put into S4
Mixing pulls out a kind of anion perfume discoloration EVA composite elastic material by equipment.
Summer sleeping mat product: anion perfume discoloration EVA composite elastic material manufactured in the present embodiment is pulled out flat with wire drawing machine
Silk production summer sleeping mat controlling temperature or tatami seat, the effect of there is refrigerant sense, drop room temperature, coordinate blood circulation, healthy cell, animal husbandry
Facility include deodorization cooling mosquito repellent multiple-effect interior wall curtain can replace water Lian cooling function greenhouse cooling can replace greenhouse water Lian facility,
It is energy-saving, reduce production cost.
Embodiment 8
The invention also discloses a kind of anion perfume discoloration EVA composite elastic materials, including following mass fraction
Component: 500 parts of function modified filler material, 400 parts of matrix resin, 30 parts of temperature control filler, 1 part of colour-changing agent, 50 parts of fire retardant, mosquito repellent
11 parts of agent.
Preferably, the function modified filler material is that esterification modification ring germanium stone acupuncture needle receives powder and micron；Described matrix resin is EVA
Elastomer analog copolymer, VA content is 40% in the EVA elastomer analog copolymer；The temperature control filler is nano silica
With the mixture of carbon black, the ratio of the nano silica and carbon black is 100:20；The colour-changing agent is two fragrant alkene；The resistance
Combustion agent is organic sepiolite powder；The culicifuge is the mixture of Lavender and Catnip essential oil.
The invention also discloses a kind of preparations of proportion according to above-mentioned anion perfume discoloration EVA composite elastic material
Method, which is characterized in that step includes S1, filler material parent's esterification modification: the high-energy with natural pyroelectricity, piezoelectricity is received
Micron ring germanium performs acupunctures with stone needles mixed powder, under organo silane coupling agent effect, is modified to esterification modification ring germanium stone acupuncture needle and receives micron part；S2, base
Body resin: EVA elastomer analog copolymer is melt into melt in a device, and didecyl Dimethy ammonium chloride has sepiolite
Machineization is modified, forms didecyl Dimethy ammonium chloride-sepiolite modified powder, and it is total to put into matrix resin EVA elastomer class
In polymers melt；S4, by colour-changing agent, thermal control material, culicifuge and fire retardant it is mixed after, put into S3 and fill and be uniformly dispersed；S5, general
It is mixed in S1 investment S4, a kind of anion perfume discoloration EVA composite elastic material is pulled out by equipment.
Anion perfume discoloration EVA composite elastic material manufactured in the present embodiment, it is clear to make air suitable for Temperature fall
New agent also can be used as mosquito expelling plaster, and product of the present invention can also make animal relaxing tendons and activating collaterals health care application in no culicifuge.
In addition, it is necessary to explanation, EVA, VA are technical term in file, therefore without specifically describing.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
It include portion to these embodiments in the case where not departing from the principle of the invention and spirit for those skilled in the art
Part carries out a variety of change, modification, replacement and modification, still falls in protection scope of the present invention.
Claims (12)
- A kind of EVA composite elastic material 1. anion perfume changes colour, which is characterized in that the component including following mass fraction: Function modified filler material 320-430 parts, 20-100 parts of thermal control material, 290-350 parts of matrix resin, nucleation fire retardant 50-100 Part, 50-100 parts of dispersing agent, 50-60 parts of color masterbatch powder, 30-50 parts of flexibility agent, sterilization fumet 50-150 parts, photic organic discoloration 30-80 parts of agent.
- The EVA composite elastic material 2. anion perfume according to claim 1 changes colour, which is characterized in that the function Modification material includes that 300 parts -400 parts of micro-powder, 20 parts -30 parts of silane coupling agent are received in the mixing of ring germanium stone needle；The temperature control Material is the hollow glass micropearl that diameter is 0.5 micron；Described matrix resin is EVA elastomer analog copolymer, the EVA elasticity VA content is 40%-60% in body analog copolymer；The nucleation fire retardant is didecyl Dimethy ammonium chloride-sepiolite and has Any one in machine modified montmorillonoid powder；The dispersing agent is ethoxylation base amine；The flexibility agent is ethylene-octene copolymerization Object；The sterilization fumet is 50 parts -150 parts of forest incense-sepiolite, 60 parts -70 parts of face powder-sepiolite and sesame oil-sepiolite Any one in 65 parts -80 parts；Photic organic colour-changing agent is diarylethene powder.
- A kind of EVA composite elastic material 3. anion perfume changes colour, which is characterized in that the component including following mass fraction: 500 parts of function modified filler material, 350 parts of matrix resin, -3000H30 parts of blowing agent AC, organic colour-changing agent 30-80 parts photic, resistance 100 parts of agent of combustion.
- The EVA composite elastic material 4. anion perfume according to claim 3 changes colour, which is characterized in that the function Modification material includes that 450 parts of micro-powder, 50 parts of silane coupling agent are received in the mixing of ring germanium stone needle；Described matrix resin is EVA bullet Property body analog copolymer, VA content is 30% in the EVA elastomer analog copolymer；Photic organic colour-changing agent is diaryl second Alkene powder；The fire retardant is any one in organically modified montmorillonite clay powder and organically-modified sepiolite powder.
- A kind of EVA composite elastic material 5. anion perfume changes colour, which is characterized in that the component including following mass fraction: 400 parts of function modified filler material, 190 parts of thermal control material, 400 parts of matrix resin, 150 parts of fire retardant, photic organic colour-changing agent 50 Part causes cool dose 180 parts, 10 parts of menthol.
- The EVA composite elastic material 6. anion perfume according to claim 5 changes colour, which is characterized in that the function Modification material includes that 370 parts of micro-powder, 30 parts of silane coupling agent are received in the mixing of ring germanium stone needle；The thermal control material includes hollow 100 parts of glass microballoon, 50 parts of mica powder, 20 parts of rutile titanium dioxide, 10 parts of barium sulfate, described matrix resin are EVA bullet Property body analog copolymer, VA content is 50% in the EVA elastomer analog copolymer；Photic organic colour-changing agent is diaryl second Alkene powder, the fire retardant are organically-modified sepiolite powder；It is described to cause cool dose to include 100 parts of hollow ceramic microspheres, mica powder 50 parts, 20 parts of rutile titanium dioxide, 10 parts of barium sulfate.
- A kind of EVA composite elastic material 7. anion perfume changes colour, which is characterized in that the component including following mass fraction: 500 parts of function modified filler material, 400 parts of matrix resin, 30 parts of temperature control filler, 1 part of colour-changing agent, 50 parts of fire retardant, culicifuge 11 Part.
- The EVA composite elastic material 8. anion perfume according to claim 1 changes colour, which is characterized in that the function Modification material is that esterification modification ring germanium stone acupuncture needle receives powder and micron；Described matrix resin is EVA elastomer analog copolymer, the EVA bullet Property body analog copolymer in VA content be 40%；The temperature control filler is the mixture of nano silica and carbon black, the nanometer The ratio of silica and carbon black is 100:20；The colour-changing agent is two fragrant alkene；The fire retardant is organic sepiolite powder；It is described Culicifuge is the mixture of Lavender and Catnip essential oil.
- 9. a kind of preparation side of the proportion according to anion perfume as claimed in claim 1 or 2 discoloration EVA composite elastic material Method, which is characterized in that step includes S1, filler material parent's esterification modification: micron received to the mixing of ring germanium stone needle using silane coupling agent Powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class is total Polymers is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten alkane Base alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt, then it is added Thermal control material；S4, it after photic organic colour-changing agent, color masterbatch powder, flexibility agent, dispersing agent and sterilization fumet are blended, puts into S3 And it fills and is uniformly dispersed；S5, it will be mixed in S1 investment S4, it is compound to pull out a kind of anion perfume discoloration EVA elastic force by equipment Material.
- 10. a kind of preparation side of the proportion according to the anion perfume discoloration EVA composite elastic material of claim 3 or 4 Method, which is characterized in that step includes S1, filler material parent's esterification modification: micron received to the mixing of ring germanium stone needle using silane coupling agent Powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class is total Polymers is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten alkane Base alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, will be photic After organic colour-changing agent, blowing agent AC -3000H and fire retardant are mixed, put into S3 and fill and be uniformly dispersed；S5, S1 is put into S4 and is mixed It closes, a kind of anion perfume discoloration EVA composite elastic material is pulled out by equipment.
- 11. a kind of preparation side of the proportion according to the anion perfume discoloration EVA composite elastic material of claim 5 or 6 Method, which is characterized in that step includes S1, filler material parent's esterification modification: micron received to the mixing of ring germanium stone needle using silane coupling agent Powder surface carries out organic modification, stand-by modification ring germanium stone needle powder is made；S2, matrix resin: EVA elastomer class is total Polymers is melt into melt in a device, and didecyl Dimethy ammonium chloride is carried out organic modification to sepiolite, forms double ten alkane Base alkyl dimethyl ammonium chloride-sepiolite modified powder, and put into matrix resin EVA elastomer analog copolymer melt；S4, will be photic After organic colour-changing agent, thermal control material, menthol and fire retardant are mixed, put into S3 and fill and be uniformly dispersed；S5, S1 is put into S4 and is mixed It closes, a kind of anion perfume discoloration EVA composite elastic material is pulled out by equipment.
- 12. a kind of preparation side of the proportion according to the anion perfume discoloration EVA composite elastic material of claim 7 or 8 Method, which is characterized in that step includes S1, filler material parent's esterification modification: the high-energy with natural pyroelectricity, piezoelectricity being received micro- Rice ring germanium performs acupunctures with stone needles mixed powder, under organo silane coupling agent effect, is modified to esterification modification ring germanium stone acupuncture needle and receives micron part；S2, matrix Resin: EVA elastomer analog copolymer is melt into melt in a device, didecyl Dimethy ammonium chloride carries out sepiolite organic Change and be modified, form didecyl Dimethy ammonium chloride-sepiolite modified powder, and puts into the copolymerization of matrix resin EVA elastomer class In object melt；S4, by colour-changing agent, thermal control material, culicifuge and fire retardant it is mixed after, put into S3 and fill and be uniformly dispersed；S5, by S1 It is mixed in investment S4, a kind of anion perfume discoloration EVA composite elastic material is pulled out by equipment.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447747A (en) * | 1977-09-22 | 1979-04-14 | Tamotsu Ebara | Compositiom for synthetic elastic material and preparation thereof |
| CN104910506A (en) * | 2015-06-21 | 2015-09-16 | 魏健 | Manufacturing method for environment-friendly multifunctional polymer health material and derived products thereof |
| CN106667132A (en) * | 2017-02-15 | 2017-05-17 | 山东鑫海新材料股份有限公司 | Health-care seat cover and seat cushion with function of purifying air |
| CN108047590A (en) * | 2017-11-24 | 2018-05-18 | 湖北名望世家装饰材料股份有限公司 | A kind of quantum functional form fibrous plate and preparation method thereof |
-
2018
- 2018-08-03 CN CN201810879100.4A patent/CN109096590A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447747A (en) * | 1977-09-22 | 1979-04-14 | Tamotsu Ebara | Compositiom for synthetic elastic material and preparation thereof |
| CN104910506A (en) * | 2015-06-21 | 2015-09-16 | 魏健 | Manufacturing method for environment-friendly multifunctional polymer health material and derived products thereof |
| CN106667132A (en) * | 2017-02-15 | 2017-05-17 | 山东鑫海新材料股份有限公司 | Health-care seat cover and seat cushion with function of purifying air |
| CN108047590A (en) * | 2017-11-24 | 2018-05-18 | 湖北名望世家装饰材料股份有限公司 | A kind of quantum functional form fibrous plate and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 潘兆橹、万朴主编: "《应用矿物学》", 30 September 1993, 武汉：武汉工业大学出版社 * |
| 颜红侠主编: "《现代精细化工实验》", 31 January 2015, 西安：西北工业大学出版社 * |
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