CN104194423A - Fireproof coating for wooden furniture and preparation method thereof - Google Patents

Fireproof coating for wooden furniture and preparation method thereof Download PDF

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Publication number
CN104194423A
CN104194423A CN201410478589.6A CN201410478589A CN104194423A CN 104194423 A CN104194423 A CN 104194423A CN 201410478589 A CN201410478589 A CN 201410478589A CN 104194423 A CN104194423 A CN 104194423A
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parts
water
coating
sodium
silica
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CN201410478589.6A
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CN104194423B (en
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费金华
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Zhuhai sunshine coating Co., Ltd.
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Suzhou Shengpula New Material Technology Co Ltd
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Publication of CN104194423B publication Critical patent/CN104194423B/en
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  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Paints Or Removers (AREA)
  • Fireproofing Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a fireproof coating for wooden furniture and a preparation method thereof. The coating comprises the following components in parts by weight: 30-42 parts of water, 0.3-1 part of sodium dodecylbenzene sulfonate, 90-110 parts of ammonium polyphosphate, 1-4 parts of diethylene glycol methyl ethyl ether acetate, 1-4.8 parts of melamine formaledehyde resin, 10-22 parts of trimerization oxygen phosphorus, 8-16 parts of chlorohydrin, 2.8-6 parts of chlorcosane, 1.5-2.9 parts of dioctyl phthalate, 2-5 parts of sodium fluorosilicate, 0.15-0.25 part of turpentine, 4-10 parts of cobalt naphthenate, and 5-12 parts of silica. The coating provided by the invention has good protective effects on the wooden furniture, the drying speed of coatings is high, the coating has high fireproof performance and high corrosion prevention performance. When fire happens, the coating can effectively prevent fire and can stop the erosion of chemicals.

Description

Frie retardant coating and preparation method thereof for a kind of wood furniture
Technical field
The present invention relates to paint field, relate in particular to frie retardant coating and preparation method thereof for a kind of wood furniture.
Background technology
The phosphorus content of ammonium polyphosphate is up to 30%~32%, and nitrogenous is 14%~16%, is excellent fire retardant, and raw cigarette amount when its most outstanding feature is burning is extremely low, does not produce hydrogen halide.The coating made from ammonium polyphosphate has excellent fire performance equally.
Wood furniture has attractive and durable, and the feature of rich classical beauty is the first-selection of a lot of Home furniture finishing use.But existing wood furniture is covered with paint, lacquer, colour wash, etc. with fire resistance and the Corrosion Protection of coating not high, can not effectively prevent fires when fire occurs, and can not effectively prevent the infringement of chemical.
Summary of the invention
The technical problem solving: for coating fire resistance and the not high shortcoming of Corrosion Protection for existing wood furniture, the invention provides frie retardant coating and preparation method thereof for a kind of wood furniture.
Technical scheme: a kind of wood furniture frie retardant coating, contains following composition in mass parts: 30~42 parts, water, 0.3~1 part of Sodium dodecylbenzene sulfonate, 90~110 parts of ammonium polyphosphates, 1~4 part of glycol ether the first and second base ether acetic acid ester, 1~4.8 part of melamino-formaldehyde resin, three 10~22 parts, polyoxy phosphorus, 8~16 parts of chloroethanols, 2.8~6 parts of clorafins, 1.5~2.9 parts of o-phthalic acid dibutyl esters, 2~5 parts of Sodium Silicofluorides, 0.15~0.25 part, turps, 4~10 parts of cobalt naphthenates, 5~12 parts, silica.
A kind of wood furniture frie retardant coating described above, contains following composition in mass parts: 36 parts, water, 0.65 part of Sodium dodecylbenzene sulfonate, 100 parts of ammonium polyphosphates, 2.5 parts of glycol ether the first and second base ether acetic acid esters, 3 parts of melamino-formaldehyde resins, three 16 parts, polyoxy phosphorus, 12 parts of chloroethanols, 4.4 parts of clorafins, 2.2 parts of o-phthalic acid dibutyl esters, 3.5 parts of Sodium Silicofluorides, 0.2 part, turps, 7 parts of cobalt naphthenates, 8 parts, silica.
A kind of wood furniture described above is as follows by the preparation process of frie retardant coating: first three polyoxy phosphorus and chloroethanol are mixed, the 2h that refluxes in temperature is the water-bath of 60~70 ℃ then distills 0.5h at 65 ℃, then adds the water of 1/3rd mass parts, at 65 ℃, distill 2h, obtain fire retardant; Again ammonium polyphosphate, glycol ether the first and second base ether acetic acid esters, melamino-formaldehyde resin and silica are mixed, then add Sodium dodecylbenzene sulfonate, clorafin, o-phthalic acid dibutyl ester and remaining water, mix, finally add fire retardant that above-mentioned reaction obtains and Sodium Silicofluoride, turps, cobalt naphthenate, mix and get product.
Beneficial effect: frie retardant coating and preparation method thereof for a kind of wood furniture provided by the invention; this coating has good provide protection to wood furniture, and the rate of drying of coating is fast, and fire prevention and Corrosion Protection are high; at fire, be effectively to prevent fires, and can stop the erosion of chemical.
Embodiment
Embodiment 1
The present embodiment provides a kind of wood furniture frie retardant coating, in mass parts, contains following composition: 30 parts, water, 0.3 part of Sodium dodecylbenzene sulfonate, 90 parts of ammonium polyphosphates, 1 part of glycol ether the first and second base ether acetic acid ester, 1 part of melamino-formaldehyde resin, three 10 parts, polyoxy phosphorus, 8 parts of chloroethanols, 2.8 parts of clorafins, 1.5 parts of o-phthalic acid dibutyl esters, 2 parts of Sodium Silicofluorides, 0.15 part, turps, 4 parts of cobalt naphthenates, 5 parts, silica.
A kind of wood furniture is as follows by the preparation process of frie retardant coating: first three polyoxy phosphorus and chloroethanol are mixed, the 2h that refluxes in temperature is the water-bath of 60 ℃ then distills 0.5h at 65 ℃, then adds the water of 1/3rd mass parts, at 65 ℃, distill 2h, obtain fire retardant; Again ammonium polyphosphate, glycol ether the first and second base ether acetic acid esters, melamino-formaldehyde resin and silica are mixed, then add Sodium dodecylbenzene sulfonate, clorafin, o-phthalic acid dibutyl ester and remaining water, mix, finally add fire retardant that above-mentioned reaction obtains and Sodium Silicofluoride, turps, cobalt naphthenate, mix and get product.
Embodiment 2
The present embodiment provides a kind of wood furniture frie retardant coating, in mass parts, contains following composition: 42 parts, water, 1 part of Sodium dodecylbenzene sulfonate, 110 parts of ammonium polyphosphates, 4 parts of glycol ether the first and second base ether acetic acid esters, 4.8 parts of melamino-formaldehyde resins, three 22 parts, polyoxy phosphorus, 16 parts of chloroethanols, 6 parts of clorafins, 2.9 parts of o-phthalic acid dibutyl esters, 5 parts of Sodium Silicofluorides, 0.25 part, turps, 10 parts of cobalt naphthenates, 12 parts, silica.
A kind of wood furniture is as follows by the preparation process of frie retardant coating: first three polyoxy phosphorus and chloroethanol are mixed, the 2h that refluxes in temperature is the water-bath of 70 ℃ then distills 0.5h at 65 ℃, then adds the water of 1/3rd mass parts, at 65 ℃, distill 2h, obtain fire retardant; Again ammonium polyphosphate, glycol ether the first and second base ether acetic acid esters, melamino-formaldehyde resin and silica are mixed, then add Sodium dodecylbenzene sulfonate, clorafin, o-phthalic acid dibutyl ester and remaining water, mix, finally add fire retardant that above-mentioned reaction obtains and Sodium Silicofluoride, turps, cobalt naphthenate, mix and get product.
Embodiment 3
The present embodiment provides a kind of wood furniture frie retardant coating, in mass parts, contains following composition: 36 parts, water, 0.65 part of Sodium dodecylbenzene sulfonate, 100 parts of ammonium polyphosphates, 2.5 parts of glycol ether the first and second base ether acetic acid esters, 3 parts of melamino-formaldehyde resins, three 16 parts, polyoxy phosphorus, 12 parts of chloroethanols, 4.4 parts of clorafins, 2.2 parts of o-phthalic acid dibutyl esters, 3.5 parts of Sodium Silicofluorides, 0.2 part, turps, 7 parts of cobalt naphthenates, 8 parts, silica.
A kind of wood furniture is as follows by the preparation process of frie retardant coating: first three polyoxy phosphorus and chloroethanol are mixed, the 2h that refluxes in temperature is the water-bath of 65 ℃ then distills 0.5h at 65 ℃, then adds the water of 1/3rd mass parts, at 65 ℃, distill 2h, obtain fire retardant; Again ammonium polyphosphate, glycol ether the first and second base ether acetic acid esters, melamino-formaldehyde resin and silica are mixed, then add Sodium dodecylbenzene sulfonate, clorafin, o-phthalic acid dibutyl ester and remaining water, mix, finally add fire retardant that above-mentioned reaction obtains and Sodium Silicofluoride, turps, cobalt naphthenate, mix and get product.
The technical performance index of frie retardant coating for a kind of wood furniture of above-described embodiment 1~embodiment 3, its detected result is as follows:
Detected result
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, the thought according to the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (3)

1. a wood furniture frie retardant coating, is characterized in that containing following composition in mass parts: 30~42 parts, water, 0.3~1 part of Sodium dodecylbenzene sulfonate, 90~110 parts of ammonium polyphosphates, 1~4 part of glycol ether the first and second base ether acetic acid ester, 1~4.8 part of melamino-formaldehyde resin, three 10~22 parts, polyoxy phosphorus, 8~16 parts of chloroethanols, 2.8~6 parts of clorafins, 1.5~2.9 parts of o-phthalic acid dibutyl esters, 2~5 parts of Sodium Silicofluorides, 0.15~0.25 part, turps, 4~10 parts of cobalt naphthenates, 5~12 parts, silica.
2. a kind of wood furniture frie retardant coating according to claim 1, is characterized in that containing following composition in mass parts: 36 parts, water, 0.65 part of Sodium dodecylbenzene sulfonate, 100 parts of ammonium polyphosphates, 2.5 parts of glycol ether the first and second base ether acetic acid esters, 3 parts of melamino-formaldehyde resins, three 16 parts, polyoxy phosphorus, 12 parts of chloroethanols, 4.4 parts of clorafins, 2.2 parts of o-phthalic acid dibutyl esters, 3.5 parts of Sodium Silicofluorides, 0.2 part, turps, 7 parts of cobalt naphthenates, 8 parts, silica.
3. the preparation method of frie retardant coating for a kind of wood furniture as claimed in claim 1, the preparation process that it is characterized in that the method is as follows: first three polyoxy phosphorus and chloroethanol are mixed, 2h refluxes in temperature is the water-bath of 60~70 ℃, then at 65 ℃, distill 0.5h, then the water that adds 1/3rd mass parts, at 65 ℃, distill 2h, obtain fire retardant; Again ammonium polyphosphate, glycol ether the first and second base ether acetic acid esters, melamino-formaldehyde resin and silica are mixed, then add Sodium dodecylbenzene sulfonate, clorafin, o-phthalic acid dibutyl ester and remaining water, mix, finally add fire retardant that above-mentioned reaction obtains and Sodium Silicofluoride, turps, cobalt naphthenate, mix and get product.
CN201410478589.6A 2014-09-18 2014-09-18 A kind of wood furniture fireproof coating and preparation method thereof Expired - Fee Related CN104194423B (en)

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Application Number Priority Date Filing Date Title
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CN104194423B CN104194423B (en) 2016-08-31

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2011151296A (en) * 2011-12-15 2013-06-20 Юрий Владимирович Кривцов FIRE-PROTECTIVE COMPOSITION ON CABLE "KL-1V"
CN103627291A (en) * 2013-11-14 2014-03-12 江苏博思源防火材料科技有限公司 Expanded transparent fire-retardant paint
JP2014136744A (en) * 2013-01-17 2014-07-28 Hideki Kojiya Foamable fire-resistive coating material composition
CN103992708A (en) * 2014-05-22 2014-08-20 安徽嘉木橡塑工业有限公司 Fireproof coating for waterborne cable
CN104046148A (en) * 2014-06-26 2014-09-17 无锡市崇安区科技创业服务中心 Fireproof coating used for wooden furniture and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2011151296A (en) * 2011-12-15 2013-06-20 Юрий Владимирович Кривцов FIRE-PROTECTIVE COMPOSITION ON CABLE "KL-1V"
JP2014136744A (en) * 2013-01-17 2014-07-28 Hideki Kojiya Foamable fire-resistive coating material composition
CN103627291A (en) * 2013-11-14 2014-03-12 江苏博思源防火材料科技有限公司 Expanded transparent fire-retardant paint
CN103992708A (en) * 2014-05-22 2014-08-20 安徽嘉木橡塑工业有限公司 Fireproof coating for waterborne cable
CN104046148A (en) * 2014-06-26 2014-09-17 无锡市崇安区科技创业服务中心 Fireproof coating used for wooden furniture and preparation method thereof

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Inventor after: Yuan Chenghui

Inventor before: Fei Jinhua

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Effective date of registration: 20160923

Address after: 519050 Guangdong province Zhuhai Gaolan Port Economic Zone Fine Chemical Zone Dongrong northbound

Patentee after: Zhuhai sunshine coating Co., Ltd.

Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu Province Tianlong 215101 No. 378 building room 4721

Patentee before: SUZHOU SHENGPULA NEW MATERIAL TECHNOLOGY CO., LTD.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160831

Termination date: 20190918