CN104046148A - Fireproof coating used for wooden furniture and preparation method thereof - Google Patents

Fireproof coating used for wooden furniture and preparation method thereof Download PDF

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Publication number
CN104046148A
CN104046148A CN201410289907.4A CN201410289907A CN104046148A CN 104046148 A CN104046148 A CN 104046148A CN 201410289907 A CN201410289907 A CN 201410289907A CN 104046148 A CN104046148 A CN 104046148A
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China
Prior art keywords
parts
wood furniture
retardant coating
frie retardant
distilled water
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CN201410289907.4A
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Chinese (zh)
Inventor
丁演
王玥
过俊宏
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Wuxi Chongan District Technology Innovation Service Center
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Wuxi Chongan District Technology Innovation Service Center
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Priority to CN201410289907.4A priority Critical patent/CN104046148A/en
Publication of CN104046148A publication Critical patent/CN104046148A/en
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Abstract

The invention relates to fireproof coating used for wooden furniture and a preparation method thereof. The fireproof coating used for the wooden furniture is prepared from the following raw materials in parts by mass: 42-55 parts of styrene-acrylic emulsion, 5-12 parts of polyurethane, 6-18 parts of ammonium polyphosphate, 5-10 parts of zinc borate, 35-50 parts of aluminium oxide, 18-28 parts of dicyanodiamide, 7-17 parts of titanium dioxide, 10-18 parts of sepiolite, 0.2-0.8 part of chlorinated paraffin, 0.2-0.7 part of zinc stearate and 32-45 parts of distilled water. The fireproof coating provided by the invention is odourless, non-inflammable and non-toxic, an adhesive force between the fireproof coating and a base material is strong, and the fireproof coating is tough and firm, has excellent flame resistance, water resistance, chemical resistance, abrasion resistance and weather resistance and has good protection and decoration effects on the wooden furniture.

Description

A kind of frie retardant coating and preparation method thereof for wood furniture
Technical field
The present invention relates to paint field, relate in particular to a kind of wood furniture frie retardant coating and preparation method thereof.
Background technology
Benzene emulsion is to be obtained through emulsion copolymerization by vinylbenzene and acrylate monomer.Benzene emulsion is in letex polymerization, to study more system, and there are one of ten large non-crosslinked type emulsions of essential industry using value the Ye Shi world today.Acrylic emulsion sticking power is good, and glued membrane is transparent, and water-fast, oil resistant, heat-resisting, ageing-resistant performance is good.The phosphorus content of ammonium polyphosphate is up to 30%~32%, and nitrogenous is 14%~16%, is excellent fire retardant, and raw cigarette amount when its most outstanding feature is burning is extremely low, does not produce hydrogen halide.The coating made from ammonium polyphosphate has excellent fire performance equally.
Wood furniture has attractive and durable, and the feature of rich classical beauty is the first-selection of a lot of Home furniture finishing use.But existing wood furniture is covered with paint, lacquer, colour wash, etc. with flame resistivity, water resistance, chemical resistance and the weather resistance of coating not high, can not effectively prevent fires in the time that fire occurs, and can not effectively prevent the infringement of chemical.Meanwhile, the poor adhesive force of coating and wood substrate, easy peeling of long duration comes off.
Summary of the invention
the technical problem solving:cover with paint, lacquer, colour wash, etc. the not high shortcoming of flame resistivity, water resistance, chemical resistance and weather resistance with coating for existing wood furniture, the invention provides a kind of wood furniture frie retardant coating and preparation method thereof.
technical scheme:a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 42~55 parts of benzene emulsions, 5~12 parts of urethane, 6~18 parts of ammonium polyphosphates, 5~10 parts of zinc borates, 35~50 parts of aluminium sesquioxides, 18~28 parts of Dyhard RU 100s, 7~17 parts of titanium dioxides, 10~18 parts of sepiolites, 0.2~0.8 part of clorafin, 0.2~0.7 part of Zinic stearas, 32~45 parts of distilled water.
A kind of wood furniture frie retardant coating described above, made by mass parts by following raw material: 48~53 parts of benzene emulsions, 7~10 parts of urethane, 12~15 parts of ammonium polyphosphates, 7~9 parts of zinc borates, 40~45 parts of aluminium sesquioxides, 22~25 parts of Dyhard RU 100s, 10~15 parts of titanium dioxides, 13~15 parts of sepiolites, 0.4~0.6 part of clorafin, 0.4~0.6 part of Zinic stearas, 38~42 parts of distilled water.
A kind of wood furniture frie retardant coating described above, made by mass parts by following raw material: 50 parts of benzene emulsions, 8.5 parts of urethane, 14 parts of ammonium polyphosphates, 8 parts of zinc borates, 42 parts of aluminium sesquioxides, 24 parts of Dyhard RU 100s, 12 parts of titanium dioxides, 14 parts of sepiolites, 0.5 part of clorafin, 0.5 part of Zinic stearas, 40 parts of distilled water.
A kind of wood furniture described above is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 110~130r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity to the 290~310r/min of raising reactor, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
Stirring velocity in step (1) described above is 120r/min, and the stirring velocity in step (2) is 300r/min.
In step (3) described above, be ground to fineness≤70 μ m with conoidal mill.
beneficial effect:frie retardant coating and preparation method thereof for a kind of wood furniture provided by the invention; this coating odorlessness, do not fire, nontoxic; film and base material strong adhesion; tough and tensile firm; there is good flame resistivity, water tolerance, chemical-resistant, wear resistance, weathering resistance, wood furniture is had to good protection and decorative effect.
Embodiment
embodiment 1
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 42 parts of benzene emulsions, 5 parts of urethane, 6 parts of ammonium polyphosphates, 5 parts of zinc borates, 35 parts of aluminium sesquioxides, 18 parts of Dyhard RU 100s, 7 parts of titanium dioxides, 10 parts of sepiolites, 0.2 part of clorafin, 0.2 part of Zinic stearas, 32 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 110r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 290r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
embodiment 2
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 44 parts of benzene emulsions, 6 parts of urethane, 7 parts of ammonium polyphosphates, 6 parts of zinc borates, 38 parts of aluminium sesquioxides, 20 parts of Dyhard RU 100s, 8 parts of titanium dioxides, 11 parts of sepiolites, 0.3 part of clorafin, 0.3 part of Zinic stearas, 34 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 110r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 290r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
embodiment 3
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 54 parts of benzene emulsions, 10 parts of urethane, 17 parts of ammonium polyphosphates, 9 parts of zinc borates, 48 parts of aluminium sesquioxides, 26 parts of Dyhard RU 100s, 16 parts of titanium dioxides, 17 parts of sepiolites, 0.7 part of clorafin, 0.6 part of Zinic stearas, 43 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 130r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 310r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
embodiment 4
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 55 parts of benzene emulsions, 12 parts of urethane, 18 parts of ammonium polyphosphates, 10 parts of zinc borates, 50 parts of aluminium sesquioxides, 28 parts of Dyhard RU 100s, 17 parts of titanium dioxides, 18 parts of sepiolites, 0.8 part of clorafin, 0.7 part of Zinic stearas, 45 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 130r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 310r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
embodiment 5
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 48 parts of benzene emulsions, 7 parts of urethane, 12 parts of ammonium polyphosphates, 7 parts of zinc borates, 40 parts of aluminium sesquioxides, 22 parts of Dyhard RU 100s, 10 parts of titanium dioxides, 13 parts of sepiolites, 0.4 part of clorafin, 0.4 part of Zinic stearas, 38 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 120r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 300r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤70 μ m with conoidal mill afterwards, get product.
embodiment 6
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 53 parts of benzene emulsions, 10 parts of urethane, 15 parts of ammonium polyphosphates, 9 parts of zinc borates, 45 parts of aluminium sesquioxides, 25 parts of Dyhard RU 100s, 15 parts of titanium dioxides, 15 parts of sepiolites, 0.6 part of clorafin, 0.6 part of Zinic stearas, 42 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 120r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 300r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤70 μ m with conoidal mill afterwards, get product.
embodiment 7
The present embodiment provides a kind of wood furniture frie retardant coating, made by mass parts by following raw material: 50 parts of benzene emulsions, 8.5 parts of urethane, 14 parts of ammonium polyphosphates, 8 parts of zinc borates, 42 parts of aluminium sesquioxides, 24 parts of Dyhard RU 100s, 12 parts of titanium dioxides, 14 parts of sepiolites, 0.5 part of clorafin, 0.5 part of Zinic stearas, 40 parts of distilled water.
A kind of wood furniture is as follows by the preparation process of frie retardant coating:
(1) distilled water is added in reactor, low whipping speed is under 120r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity that improves reactor, to 300r/min, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤70 μ m with conoidal mill afterwards, get product.
Wood furniture prepared by the present invention contrasts by the performance of frie retardant coating and commercially available aqueous fire-proof coating, and the data obtained is as follows:
Detected result
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (6)

1. a wood furniture frie retardant coating, it is characterized in that being made by mass parts by following raw material: 42~55 parts of benzene emulsions, 5~12 parts of urethane, 6~18 parts of ammonium polyphosphates, 5~10 parts of zinc borates, 35~50 parts of aluminium sesquioxides, 18~28 parts of Dyhard RU 100s, 7~17 parts of titanium dioxides, 10~18 parts of sepiolites, 0.2~0.8 part of clorafin, 0.2~0.7 part of Zinic stearas, 32~45 parts of distilled water.
2. a kind of wood furniture frie retardant coating according to claim 1, it is characterized in that being made by mass parts by following raw material: 48~53 parts of benzene emulsions, 7~10 parts of urethane, 12~15 parts of ammonium polyphosphates, 7~9 parts of zinc borates, 40~45 parts of aluminium sesquioxides, 22~25 parts of Dyhard RU 100s, 10~15 parts of titanium dioxides, 13~15 parts of sepiolites, 0.4~0.6 part of clorafin, 0.4~0.6 part of Zinic stearas, 38~42 parts of distilled water.
3. a kind of wood furniture frie retardant coating according to claim 1, it is characterized in that being made by mass parts by following raw material: 50 parts of benzene emulsions, 8.5 parts of urethane, 14 parts of ammonium polyphosphates, 8 parts of zinc borates, 42 parts of aluminium sesquioxides, 24 parts of Dyhard RU 100s, 12 parts of titanium dioxides, 14 parts of sepiolites, 0.5 part of clorafin, 0.5 part of Zinic stearas, 40 parts of distilled water.
4. the preparation method of frie retardant coating for a kind of wood furniture as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
(1) distilled water is added in reactor, low whipping speed is under 110~130r/min, to add urethane, ammonium polyphosphate, zinc borate, aluminium sesquioxide, Dyhard RU 100, titanium dioxide and sepiolite;
(2) stirring velocity to the 290~310r/min of raising reactor, is uniformly mixed;
(3) in reactor, add benzene emulsion, clorafin and Zinic stearas, mix and be ground to fineness≤80 μ m with conoidal mill afterwards, get product.
5. the preparation method of frie retardant coating for a kind of wood furniture according to claim 4, is characterized in that: the stirring velocity in described step (1) is 120r/min, and the stirring velocity in step (2) is 300r/min.
6. the preparation method of frie retardant coating for a kind of wood furniture according to claim 4, is characterized in that: in described step (3), be ground to fineness≤70 μ m with conoidal mill.
CN201410289907.4A 2014-06-26 2014-06-26 Fireproof coating used for wooden furniture and preparation method thereof Withdrawn CN104046148A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194423A (en) * 2014-09-18 2014-12-10 苏州圣谱拉新材料科技有限公司 Fireproof coating for wooden furniture and preparation method thereof
CN105647300A (en) * 2016-02-19 2016-06-08 徐冉 Expandable fireproof paint and preparation method thereof
CN107201098A (en) * 2017-07-26 2017-09-26 合肥铭佑高温技术有限公司 A kind of high abrasion oil resistant fireproof coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2053083A1 (en) * 2007-10-22 2009-04-29 Johns Manville Fire retardant coating composition for fibrous mat
CN102675992A (en) * 2011-03-07 2012-09-19 嘉宝莉化工集团股份有限公司 Expanded type aqueous facing fireproof coating and preparation method thereof
CN103627265A (en) * 2013-11-14 2014-03-12 江苏博思源防火材料科技有限公司 Fireproof coating for tunnels
CN103694832A (en) * 2013-12-10 2014-04-02 张家港市民扬塑胶科技有限公司 Intumescent fire-retardant coating material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2053083A1 (en) * 2007-10-22 2009-04-29 Johns Manville Fire retardant coating composition for fibrous mat
CN102675992A (en) * 2011-03-07 2012-09-19 嘉宝莉化工集团股份有限公司 Expanded type aqueous facing fireproof coating and preparation method thereof
CN103627265A (en) * 2013-11-14 2014-03-12 江苏博思源防火材料科技有限公司 Fireproof coating for tunnels
CN103694832A (en) * 2013-12-10 2014-04-02 张家港市民扬塑胶科技有限公司 Intumescent fire-retardant coating material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194423A (en) * 2014-09-18 2014-12-10 苏州圣谱拉新材料科技有限公司 Fireproof coating for wooden furniture and preparation method thereof
CN105647300A (en) * 2016-02-19 2016-06-08 徐冉 Expandable fireproof paint and preparation method thereof
CN107201098A (en) * 2017-07-26 2017-09-26 合肥铭佑高温技术有限公司 A kind of high abrasion oil resistant fireproof coating and preparation method thereof

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Application publication date: 20140917