JP2014136744A - Foamable fire-resistive coating material composition - Google Patents
Foamable fire-resistive coating material composition Download PDFInfo
- Publication number
- JP2014136744A JP2014136744A JP2013005827A JP2013005827A JP2014136744A JP 2014136744 A JP2014136744 A JP 2014136744A JP 2013005827 A JP2013005827 A JP 2013005827A JP 2013005827 A JP2013005827 A JP 2013005827A JP 2014136744 A JP2014136744 A JP 2014136744A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- foamable
- fire
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 239000000463 material Substances 0.000 title abstract description 21
- 238000000576 coating method Methods 0.000 title abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000003063 flame retardant Substances 0.000 claims abstract description 26
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 23
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 23
- 230000009970 fire resistant effect Effects 0.000 claims abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000003973 paint Substances 0.000 claims description 20
- 239000008199 coating composition Substances 0.000 claims description 19
- 229920000877 Melamine resin Polymers 0.000 claims description 17
- 239000004640 Melamine resin Substances 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 13
- -1 phosphorus-aluminum compound Chemical class 0.000 claims description 11
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 9
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 9
- 238000010000 carbonizing Methods 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 239000004254 Ammonium phosphate Substances 0.000 claims description 4
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 4
- SFRDXVJWXWOTEW-UHFFFAOYSA-N 2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)CO SFRDXVJWXWOTEW-UHFFFAOYSA-N 0.000 claims description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 3
- LCANECIWPMDASZ-UHFFFAOYSA-N 2-isocyanatoethanol Chemical compound OCCN=C=O LCANECIWPMDASZ-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- 239000007983 Tris buffer Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- GJIGNWZPXORWIK-UHFFFAOYSA-N hexane-1,6-diol;propane-1,2-diol Chemical compound CC(O)CO.OCCCCCCO GJIGNWZPXORWIK-UHFFFAOYSA-N 0.000 claims description 3
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 3
- 229960000367 inositol Drugs 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 2
- 239000001294 propane Substances 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 12
- 239000011574 phosphorus Substances 0.000 abstract description 12
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 12
- 238000003763 carbonization Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000000758 substrate Substances 0.000 description 6
- 150000007974 melamines Chemical class 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
本発明は、火災発生時に加熱により発泡層を形成し、基材の温度上昇を遅延する発泡性耐火塗料組成物に関する。 The present invention relates to a foamable refractory paint composition that forms a foamed layer by heating in the event of a fire and delays the temperature rise of a substrate.
壁紙、合板、木材、無機質ボード、コンクリート、モルタル、ＦＲＰ、プラスチック類、金属等の基材を火災から保護する材料として、火災時の温度上昇によって発泡層を形成する発泡性耐火塗料が知られている。 As a material that protects base materials such as wallpaper, plywood, wood, inorganic board, concrete, mortar, FRP, plastics, metal, etc. from fire, foaming fireproof paint that forms a foamed layer due to temperature rise at the time of fire is known Yes.
このような発泡性耐火塗料としては、特許文献１に発泡剤としてリン酸塩系、炭火層生成剤として多糖類・多価アルコール類、無機質粉末、メラミン樹脂とアクリル樹脂を添加してなる発泡耐火塗料が開示されている。 As such a foam fire-resistant paint, a foam-based fire-resistant paint obtained by adding a phosphate-based phosphate as a foaming agent and a polysaccharide / polyhydric alcohol, an inorganic powder, a melamine resin and an acrylic resin as a charcoal layer forming agent in Patent Document 1. A paint is disclosed.
また、特許文献２に自己架橋型水性樹脂、リン系難燃剤、発泡剤、多糖類及び／又は多価アルコール類を主成分とする発泡剤型耐火塗料組成物が開示されている。 Further, Patent Document 2 discloses a foaming agent-type fireproof coating composition mainly composed of a self-crosslinking aqueous resin, a phosphorus-based flame retardant, a foaming agent, a polysaccharide and / or a polyhydric alcohol.
従来の発泡性耐火塗料は、耐火性能、耐水性能は優れているものの、柔軟性のある基材に塗料を塗布乾燥後形成される塗膜は基材の柔軟性を損なうものであった。また、自動車や飛行機等動きのある基材に塗料を塗付した場合、塗膜材が基材との追従性において不十分であったため、剥離する等の問題が生じていた。 Although conventional foaming fireproof paints are excellent in fireproof performance and water resistance performance, a coating film formed after applying and drying a paint on a flexible base material impairs the flexibility of the base material. In addition, when a paint is applied to a moving base material such as an automobile or an airplane, the coating material is insufficient in followability with the base material, which causes problems such as peeling.
そこで本発明は、柔軟性のある基材や自動車や飛行機等の動きのある基材についても適用可能であり、塗料を塗付乾燥後形成される塗膜が基材の柔軟性を失うことなく、耐火性能、耐水性能に優れた発泡性耐火塗料組成物を提供することを目的とする。 Therefore, the present invention can also be applied to a flexible base material or a base material having movement such as an automobile or an airplane, and the coating film formed after applying and drying the paint does not lose the flexibility of the base material. An object of the present invention is to provide a foamable fire-resistant paint composition having excellent fire resistance and water resistance.
本発明は、（Ａ）アクリル系樹脂エマルションと、該（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して、（Ｂ）リン系難燃剤を６５〜２００重量部、（Ｃ）被覆剤を２０〜６０重量部、（Ｄ）炭化剤を１５〜１００重量部、（Ｅ）難燃性充填剤を１５〜５５重量部含有する発泡性耐火塗料組成物である。 The present invention includes (A) an acrylic resin emulsion and 65 to 200 parts by weight of (B) a phosphorus-based flame retardant with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion. 20 to 60 parts by weight of the agent, (D) 15 to 100 parts by weight of the carbonizing agent, and (E) 15 to 55 parts by weight of the flame retardant filler.
本発明における（Ｂ）リン系難燃剤は、リン酸アンモニウム、ポリリン酸アンモニウム、マイクロカプセル化ポリリン酸アンモニウム及び発泡性リン・アルミニウム系化合物から選ばれる少なくとも１種であるのが良い。 The (B) phosphorus flame retardant in the present invention may be at least one selected from ammonium phosphate, ammonium polyphosphate, microencapsulated ammonium polyphosphate, and a foamable phosphorus-aluminum compound.
本発明における（Ｃ）被覆剤は、メラミン樹脂であるのが良い。 The (C) coating agent in the present invention is preferably a melamine resin.
本発明における（Ｄ）炭化剤は、グルコース、蔗糖、ペンタエリスリトール、ジペンタエリスリトール、ポリペンタエリスルトール、トリス（２−ヒドロキシエチル）イソシアネート、トリエチレングリコール、ソルビトール、レゾルシノール、グリセリン、トリメチロールメタン、トリメチロールプロパン、ジエチレングルコール、プロピレングリコールヘキサメチレングリコールおよびイノシトールから選ばれる少なくとも１種であるのが良い。 The carbonizing agent (D) in the present invention is glucose, sucrose, pentaerythritol, dipentaerythritol, polypentaerythritol, tris (2-hydroxyethyl) isocyanate, triethylene glycol, sorbitol, resorcinol, glycerin, trimethylolmethane, It may be at least one selected from trimethylolpropane, diethylene glycol, propylene glycol hexamethylene glycol and inositol.
本発明における（Ｅ）難燃性充填剤は、水酸化アルミニウム又は水酸化マグネシウムから選ばれる少なくとも１種であるのが良い。 The flame retardant filler (E) in the present invention may be at least one selected from aluminum hydroxide or magnesium hydroxide.
本発明においては、主成分（Ａ）〜（Ｅ）に加えて、（Ｆ）顔料を前記（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して、３〜１５重量部含有するのが良い。 In the present invention, in addition to the main components (A) to (E), the pigment (F) is contained in an amount of 3 to 15 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion. Is good.
本発明の発泡性耐火塗料組成物は、優れた耐火性能、耐水性能を有する上に基材の柔軟性を保持する能力が著しく向上したため、壁紙、合板、木材、無機質ボード、コンクリート、モルタル、ＦＲＰ、プラスチック類、金属の他柔軟性のある基材、例えば、紙、布、繊維、合成樹脂、ゴム、シリコン等に特に有用である。 The foamable fire-resistant paint composition of the present invention has excellent fire resistance and water resistance, and the ability to retain the flexibility of the base material has been remarkably improved. Therefore, wallpaper, plywood, wood, inorganic board, concrete, mortar, FRP It is particularly useful for plastics, metals and other flexible substrates such as paper, cloth, fibers, synthetic resins, rubber, silicon and the like.
本発明の発泡性耐火塗料組成物は、（Ａ）アクリル系樹脂エマルション、（Ｂ）リン系難燃剤、（Ｃ）被覆剤、（Ｄ）炭化剤、（Ｅ）難燃性充填剤を含有するものである。 The foamable fire-resistant coating composition of the present invention contains (A) an acrylic resin emulsion, (B) a phosphorus flame retardant, (C) a coating agent, (D) a carbonizing agent, and (E) a flame retardant filler. Is.
本発明の発泡性耐火塗料組成物における（Ａ）アクリル系樹脂エマルションは、アクリル系樹脂が水中に分散したものであり、通常水を約４０〜５０％含んでいる。（Ａ）アクリル系樹脂エマルションの構成成分であるアクリル系樹脂としては、メタクリル酸、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ブチル、メタクリル酸２エチルヘキシル、アクリル酸、アクリル酸メチル、アクリル酸エチル、アクリル酸ブチル、アクリル酸２エチルヘキシル、アクリロニトリル、メタクリロニトリル、アクリルアミド、ジメチルアクリルアミド等のアクリル系モノマーから生成されるホモポリマー又はコポリマー、あるいは、前記アクリル系モノマーと他のモノマーとのコポリマーが挙げられる。他のモノマーとしては、スチレン、ビニルトルエン、イタコン酸、クロトン酸、フマル酸、マレイン酸等が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。なお、本発明の発泡性耐火塗料組成物においては、コポリマーを用いるのが好ましい。 The (A) acrylic resin emulsion in the foamable fireproof coating composition of the present invention is an acrylic resin dispersed in water, and usually contains about 40 to 50% of water. (A) As the acrylic resin that is a constituent of the acrylic resin emulsion, methacrylic acid, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, acrylic acid, methyl acrylate, ethyl acrylate, acrylic Examples thereof include homopolymers or copolymers produced from acrylic monomers such as butyl acid, 2-ethylhexyl acrylate, acrylonitrile, methacrylonitrile, acrylamide and dimethylacrylamide, or copolymers of the acrylic monomer with other monomers. Examples of other monomers include styrene, vinyl toluene, itaconic acid, crotonic acid, fumaric acid, maleic acid and the like. These may be used alone or in combination of two or more. In addition, it is preferable to use a copolymer in the foamable fireproof coating composition of the present invention.
本発明の発泡性耐火塗料組成物における（Ｂ）リン系難燃剤としては、リン酸アンモニウム、ポリリン酸アンモニウム、マイクロカプセル化ポリリン酸アンモニウム及び発泡性リン・アルミニウム系化合物等が好ましく、耐水性及び耐火性の良好な塗膜を形成することができる点で、リン酸アンモニウム、ポリリン酸アンモニウム、ポリリン酸アンモニウムを樹脂によりコーティングしたマイクロカプセル化ポリリン酸アンモニウムを用いるのが特に好ましい。これらは単独で用いてもよく、２種以上を併用してもよい。なお、リン系難燃剤は、発泡剤としての役割をも果たすものである。 As the (B) phosphorus flame retardant in the foamable fire-resistant coating composition of the present invention, ammonium phosphate, ammonium polyphosphate, microencapsulated ammonium polyphosphate, foamable phosphorus-aluminum compound, and the like are preferable. It is particularly preferred to use microencapsulated ammonium polyphosphate obtained by coating ammonium phosphate, ammonium polyphosphate, or ammonium polyphosphate with a resin in that a coating film with good properties can be formed. These may be used alone or in combination of two or more. The phosphorus-based flame retardant also serves as a foaming agent.
本発明の発泡性耐火塗料組成物における（Ｂ）リン系難燃剤は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して約６５〜２００重量部含有するのが好ましい。 The (B) phosphorus flame retardant in the foamable fire-resistant paint composition of the present invention preferably contains about 65 to 200 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion.
本発明の発泡性耐火塗料組成物における（Ｃ）被覆剤としてはメラミン樹脂が好ましく、メラミン樹脂はメラミンとホルムアルデヒドとの重縮合により得られる樹脂及びその各種誘導体であれば特に限定されない。例えば、メチルエーテル化メラミン樹脂、エチルエーテル化メラミン樹脂、プロピルエーテル化メラミン樹脂、ブチルエーテル化メラミン樹脂等のアルキル化メラミン樹脂、メチル化メラミン樹脂、エチル化メラミン樹脂、プロピル化メラミン樹脂、ブチル化メラミン樹脂等のアルキル化メラミン樹脂等が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。なおメラミン樹脂は、市販のものを用いることができる。被覆剤は、（Ｂ）リン系難燃剤や（Ｅ）難燃性充填剤を被覆して、湿気を吸収するのを妨げる役割を果たす。 The (C) coating agent in the foamable fire-resistant paint composition of the present invention is preferably a melamine resin, and the melamine resin is not particularly limited as long as it is a resin obtained by polycondensation of melamine and formaldehyde and various derivatives thereof. For example, methyl etherified melamine resin, ethyl etherified melamine resin, propyl etherified melamine resin, alkylated melamine resin such as butyl etherified melamine resin, methylated melamine resin, ethylated melamine resin, propylated melamine resin, butylated melamine resin And alkylated melamine resins. These may be used alone or in combination of two or more. A commercially available melamine resin can be used. A coating agent plays the role which coat | covers (B) phosphorus flame retardant and (E) flame retardant filler, and prevents moisture absorption.
本発明の発泡性耐火塗料組成物における（Ｃ）被覆剤は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して約２０〜６０重量部含有するのが好ましい。 The coating agent (C) in the foamable fire-resistant paint composition of the present invention preferably contains about 20 to 60 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion.
本発明の発泡性耐火塗料組成物における（Ｄ）炭化剤としては、多糖類、多価アルコール類等が好ましく、例えば、グルコース、蔗糖等の多糖類、ペンタエリスリトール、ジペンタエリスリトール、ポリペンタエリスルトール、トリス（２−ヒドロキシエチル）イソシアネート、トリエチレングリコール、ソルビトール、レゾルシノール、グリセリン、トリメチロールメタン、トリメチロールプロパン、ジエチレングルコール、プロピレングリコールヘキサメチレングリコール、イノシトール等の多価アルコール類を挙げることができる。これらは単独で用いてもよく、２種以上を併用してもよい。 As the carbonizing agent (D) in the foamable fire-resistant coating composition of the present invention, polysaccharides, polyhydric alcohols and the like are preferable. For example, polysaccharides such as glucose and sucrose, pentaerythritol, dipentaerythritol, polypentaerythritol Examples include polyhydric alcohols such as tall, tris (2-hydroxyethyl) isocyanate, triethylene glycol, sorbitol, resorcinol, glycerin, trimethylol methane, trimethylol propane, diethylene glycol, propylene glycol hexamethylene glycol, and inositol. it can. These may be used alone or in combination of two or more.
本発明の発泡性耐火塗料組成物における（Ｄ）炭化剤は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して約１５〜１００重量部含有するのが好ましい。 The carbonizing agent (D) in the foamable fire-resistant coating composition of the present invention preferably contains about 15 to 100 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion.
本発明の発泡性耐火塗料組成物における（Ｅ）難燃性充填剤は、水酸化アルミニウム又は水酸化マグネシウム等を挙げることができる。これらは単独で用いてもよく、２種以上を併用してもよい。 Examples of the flame retardant filler (E) in the foamable fireproof coating composition of the present invention include aluminum hydroxide and magnesium hydroxide. These may be used alone or in combination of two or more.
本発明の発泡性耐火塗料組成物における（Ｅ）難燃性充填剤は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して約１５〜５５重量部含有するのが好ましい。 The flame-retardant filler (E) in the foamable fire-resistant coating composition of the present invention preferably contains about 15 to 55 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion.
本発明の発泡性耐火塗料組成物においては、前記主成分の他に、必要に応じて（Ｆ）顔料を含有することができる。顔料としては、着色顔料、体質顔料、防錆顔料等が挙げられ、例えば、酸化チタン、酸化亜鉛、カーボンブラック、酸化第二鉄（ベンガラ）、クロム酸鉛（モリブデートオレンジ）、黄鉛、黄色酸化鉄、オーカー、群青コバルトグリーン等の無機系着色顔料、アゾ系、ナフトール系、ピラゾロン系、アントラキノン系、ペリレン系、キナクリドン系、ジスアゾ系、イソインドリノン系、ベンゾイミダゾール系、フタロシアニン系、キノフタロン系等の有機系着色顔料、重質炭酸カルシウム、クレー、カオリン、タルク、沈降性硫酸バリウム、炭酸バリウム、ホワイトカーボン、珪藻土等が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。 In the foamable fireproof coating composition of the present invention, in addition to the main component, (F) a pigment can be contained as required. Examples of the pigment include coloring pigments, extender pigments, rust preventive pigments, and the like, for example, titanium oxide, zinc oxide, carbon black, ferric oxide (Bengara), lead chromate (molybdate orange), yellow lead, yellow Inorganic color pigments such as iron oxide, ocher, ultramarine cobalt green, azo, naphthol, pyrazolone, anthraquinone, perylene, quinacridone, disazo, isoindolinone, benzimidazole, phthalocyanine, quinophthalone Organic pigments such as heavy calcium carbonate, clay, kaolin, talc, precipitated barium sulfate, barium carbonate, white carbon, diatomaceous earth and the like. These may be used alone or in combination of two or more.
本発明の発泡性耐火塗料組成物における（Ｆ）顔料は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対して約３〜１５重量部含有するのが好ましい。 The (F) pigment in the foamable fireproof coating composition of the present invention preferably contains about 3 to 15 parts by weight with respect to 100 parts by weight of the resin solid content of the (A) acrylic resin emulsion.
本発明の発泡性耐火塗料組成物においては、さらに必要に応じて、通常塗料分野で用いられている増粘剤、消泡剤、防腐剤、防かび剤、分散剤を含有することができる。本発明の発泡性耐火塗料組成物は、上記各成分を従来公知の方法で攪拌混合することにより製造できる。 The foamable fire-resistant coating composition of the present invention may further contain a thickener, an antifoaming agent, an antiseptic, a fungicide, and a dispersant that are usually used in the paint field, if necessary. The foamable fireproof coating composition of the present invention can be produced by stirring and mixing the above-mentioned components by a conventionally known method.
本発明に使用することのできる増粘剤としては、水性の増粘剤であればいずれも使用することができるが、例えばポリビニルアルコール、ポリビニルピロリドン、メチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、水性セルロース、ポリアクリルアミド、ポリエチレンオキサイド等の有機系増粘剤、ベントナイト等の無機系増粘剤が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。 As the thickener that can be used in the present invention, any aqueous thickener can be used. For example, polyvinyl alcohol, polyvinyl pyrrolidone, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, aqueous cellulose, Examples thereof include organic thickeners such as polyacrylamide and polyethylene oxide, and inorganic thickeners such as bentonite. These may be used alone or in combination of two or more.
本発明に使用することのできる消泡剤としては、例えば、低級アルコール類、高級アルコール類、油脂類、脂肪酸類、脂肪酸エステル類、リン酸エステル類、金属石けん系、鉱物油系等の低分子消泡剤や、ポリエーテル系、シリコン系の高分子消泡剤等が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。 Examples of the antifoaming agent that can be used in the present invention include low molecular weight compounds such as lower alcohols, higher alcohols, fats and oils, fatty acids, fatty acid esters, phosphate esters, metal soaps, and mineral oils. Examples include antifoaming agents, polyether-based, and silicon-based polymer antifoaming agents. These may be used alone or in combination of two or more.
本発明に使用することのできる分散剤としては、エポキシ樹脂、ポリアミン、顔料等の分散安定性を向上させるものであれば特に限定されず、公知のものを使用することができる。これらは単独で用いてもよく、２種以上を併用してもよい。 The dispersant that can be used in the present invention is not particularly limited as long as it improves the dispersion stability of epoxy resins, polyamines, pigments, and the like, and known ones can be used. These may be used alone or in combination of two or more.
また、本発明の発泡性耐火塗料組成物は、（Ａ）アクリル系樹脂エマルション、（Ｂ）リン系難燃剤、（Ｃ）被覆剤、（Ｄ）炭化剤、（Ｅ）難燃性充填剤、（Ｆ）顔料等に水を添加して調整することができる。水を添加する方法としては、水に（Ａ）アクリル系樹脂エマルション、（Ｂ）リン系難燃剤、（Ｃ）被覆剤、（Ｄ）炭化剤、（Ｅ）難燃性充填剤、（Ｆ）顔料等を一括又は別々に添加し、次いで撹拌等により混合、均一分散させればよい。あるいは（Ａ）アクリル系樹脂エマルション、（Ｂ）リン系難燃剤、（Ｃ）被覆剤、（Ｄ）炭化剤、（Ｅ）難燃性充填剤、（Ｆ）顔料等に水を添加し、次いで撹拌等により混合、均一分散させてもよい。なお、（Ｇ）水の温度は、約２５℃〜５０℃が好ましい。 In addition, the foamable fire-resistant paint composition of the present invention comprises (A) an acrylic resin emulsion, (B) a phosphorus flame retardant, (C) a coating agent, (D) a carbonizing agent, (E) a flame retardant filler, (F) It can be adjusted by adding water to the pigment or the like. Methods for adding water include: (A) an acrylic resin emulsion, (B) a phosphorus flame retardant, (C) a coating agent, (D) a carbonizing agent, (E) a flame retardant filler, (F) What is necessary is just to add a pigment etc. collectively or separately, and to mix and disperse | distribute uniformly by stirring etc. then. Or (A) acrylic resin emulsion, (B) phosphorus flame retardant, (C) coating agent, (D) carbonization agent, (E) flame retardant filler, (F) water is added to the pigment, It may be mixed and uniformly dispersed by stirring or the like. In addition, the temperature of (G) water is preferably about 25 ° C to 50 ° C.
本発明に使用することができる（Ｇ）水としては、一般に使用されるものであれば特に限定されるものではない。例えば、工業用水、水道水、井戸水、イオン交換水、純水等が挙げられる。これらは単独で用いてもよく、２種以上を併用してもよい。 The (G) water that can be used in the present invention is not particularly limited as long as it is generally used. For example, industrial water, tap water, well water, ion exchange water, pure water and the like can be mentioned. These may be used alone or in combination of two or more.
調整する際に添加する（Ｇ）水は、（Ａ）アクリル系樹脂エマルションの樹脂固形分１００重量部に対し約３０〜２００重量部加えるのが好ましい。 It is preferable to add about 30 to 200 parts by weight of (G) water to be added at the time of adjustment with respect to 100 parts by weight of resin solid content of (A) acrylic resin emulsion.
かくして得られる本発明の発泡性耐火塗料組成物は、優れた耐火性能、耐水性能を有し、かつ、基材の柔軟性を保持する能力が著しく向上したため、壁紙、合板、木材、無機質ボード、コンクリート、モルタル、ＦＲＰ、プラスチック類、金属の他特に柔軟性のある基材、例えば、紙、布、繊維、合成樹脂、ゴム、シリコン等に用いることができる。なお、本発明の発泡性耐火塗料組成物の塗布方法としては特に限定されず、刷毛、コテ、ローラ、スプレー等の一般の塗装方法で簡単に塗付することが可能である。これらの塗布方法は、基材の使用目的に応じて適宜選択される。 The foamable fire-resistant paint composition of the present invention thus obtained has excellent fire resistance and water resistance, and the ability to retain the flexibility of the base material has been significantly improved, so wallpaper, plywood, wood, inorganic board, It can be used for concrete, mortar, FRP, plastics, metals and particularly flexible substrates such as paper, cloth, fibers, synthetic resins, rubber, silicon and the like. In addition, it does not specifically limit as a coating method of the foamable fireproof coating composition of this invention, It is possible to apply simply by common coating methods, such as a brush, a trowel, a roller, and a spray. These coating methods are appropriately selected according to the purpose of use of the substrate.
本発明の発泡性耐火塗料組成物は耐火性能、耐水性能に優れている上に、基材の柔軟性を保持する能力が著しく向上したため、特に柔軟性のある基材、例えば、紙、布、繊維、合成樹脂、ゴム、シリコン等の火災による延焼を防ぐことができる。 The foamable fire-resistant coating composition of the present invention is excellent in fire resistance and water resistance, and the ability to retain the flexibility of the substrate has been remarkably improved, so that a particularly flexible substrate such as paper, cloth, The spread of fire due to fire of fibers, synthetic resins, rubber, silicon, etc. can be prevented.
また、本発明の発泡性耐火塗料組成物は、塗膜材が基材に追従するため、自動車や飛行機等の動く基材に好適に使用することができ、火災による延焼を防ぐことができる。
Moreover, since the coating material follows the base material, the foamable fireproof coating composition of the present invention can be suitably used for moving base materials such as automobiles and airplanes, and can prevent the spread of fire due to fire.
Claims (6)
In addition to the main components (A) to (E), the pigment (F) is contained in an amount of 3 to 15 parts by weight with respect to 100 parts by weight of the resin solid content of the acrylic resin emulsion (A). The foamable fireproof coating composition according to any one of the above.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013005827A JP2014136744A (en) | 2013-01-17 | 2013-01-17 | Foamable fire-resistive coating material composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013005827A JP2014136744A (en) | 2013-01-17 | 2013-01-17 | Foamable fire-resistive coating material composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2014136744A true JP2014136744A (en) | 2014-07-28 |
Family
ID=51414460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013005827A Pending JP2014136744A (en) | 2013-01-17 | 2013-01-17 | Foamable fire-resistive coating material composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2014136744A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194423A (en) * | 2014-09-18 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Fireproof coating for wooden furniture and preparation method thereof |
| CN104449142A (en) * | 2014-12-09 | 2015-03-25 | 苏州明轩地坪涂料有限公司 | Fire-resistant elastic coating |
| CN104845457A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Fireproof coating with superior fireproof performance |
| CN106752528A (en) * | 2016-12-26 | 2017-05-31 | 哈尔滨拓百世环保涂料有限公司 | Roofing energy-saving waterproof coating with fire-proof function and preparation method thereof |
| KR101792765B1 (en) | 2017-06-01 | 2017-11-20 | 양홍주 | Forming type-flame retandant cloth for preventing spark-scattering and product using the same |
| CN107513317A (en) * | 2016-06-17 | 2017-12-26 | 清远市普塞呋磷化学有限公司 | A kind of aqueous double-component water proof anti-soil flame-retardant coatings glue and preparation method thereof |
| CN108252116A (en) * | 2018-03-31 | 2018-07-06 | 江苏奥力广告材料股份有限公司 | A kind of tent special purpose spray-drawing canvas and its production method |
| CN108641527A (en) * | 2018-05-10 | 2018-10-12 | 合肥昂诺新材料有限公司 | A kind of fire proof and thermo-insulation coating material for building and preparation method thereof |
| RU2669839C1 (en) * | 2016-09-05 | 2018-10-16 | Цзянсу Алмайн Нью Материалс Сток Ко., Лтд | Refractory reel and method of its manufacture |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5332397A (en) * | 1976-09-04 | 1978-03-27 | Dainippon Toryo Kk | Fire prevention paint for electric wire |
| JPS5911377A (en) * | 1982-07-08 | 1984-01-20 | Nippon Synthetic Chem Ind Co Ltd:The | Fire-resistant coating composition |
| JPH0874497A (en) * | 1994-09-01 | 1996-03-19 | Kyoritsu Kagaku Sangyo Kk | Internal wall forming method for tunnel structure |
| JPH08178404A (en) * | 1994-12-20 | 1996-07-12 | Takasago Thermal Eng Co Ltd | Duct for air-conditioning and exhaust gas |
| JPH08253710A (en) * | 1995-03-17 | 1996-10-01 | Chisso Corp | Intumescent fire resistant coating material |
| JPH0959009A (en) * | 1995-06-15 | 1997-03-04 | Chisso Corp | Ammonium polyphosphate treated with triazine derivative, its production and fireproof coating produced by using the compound |
| JPH10265722A (en) * | 1997-03-24 | 1998-10-06 | Kansai Paint Co Ltd | Thick film-form elastic heat-insulating coating material and coating heat-insulating technique using the same |
| JP2001164192A (en) * | 1999-12-08 | 2001-06-19 | Kikusui Chemical Industries Co Ltd | Expandable type fire-resistant coating |
| JP2002146088A (en) * | 2000-11-10 | 2002-05-22 | Kanegafuchi Chem Ind Co Ltd | Coated material of styrenic resin foam |
| JP2003238902A (en) * | 2002-02-22 | 2003-08-27 | Kowa Chem Ind Co Ltd | Composition for intumescent fireproof coating for indoor use |
| JP2003238903A (en) * | 2002-02-22 | 2003-08-27 | Kubota Corp | Intumescent fireproof coating |
| US20040054035A1 (en) * | 2002-09-13 | 2004-03-18 | Gerald Hallissy | Flexible, insulative fire protective coatings and conduits, utilitarian components, and structural materials coated therewith |
| JP2004331705A (en) * | 2003-04-30 | 2004-11-25 | Sakai Chem Ind Co Ltd | Flame-retardant coating agent composition and its use |
| JP2005113002A (en) * | 2003-10-08 | 2005-04-28 | Kikusui Chemical Industries Co Ltd | Water-based foaming/fire-retarding coating |
| JP2006028305A (en) * | 2004-07-14 | 2006-02-02 | Sekisui Chem Co Ltd | Flame-retardant resin coating composition and method for producing the same |
| JP2007169496A (en) * | 2005-12-22 | 2007-07-05 | Shin Etsu Chem Co Ltd | Foamable fireproof coating |
-
2013
- 2013-01-17 JP JP2013005827A patent/JP2014136744A/en active Pending
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5332397A (en) * | 1976-09-04 | 1978-03-27 | Dainippon Toryo Kk | Fire prevention paint for electric wire |
| JPS5911377A (en) * | 1982-07-08 | 1984-01-20 | Nippon Synthetic Chem Ind Co Ltd:The | Fire-resistant coating composition |
| JPH0874497A (en) * | 1994-09-01 | 1996-03-19 | Kyoritsu Kagaku Sangyo Kk | Internal wall forming method for tunnel structure |
| JPH08178404A (en) * | 1994-12-20 | 1996-07-12 | Takasago Thermal Eng Co Ltd | Duct for air-conditioning and exhaust gas |
| JPH08253710A (en) * | 1995-03-17 | 1996-10-01 | Chisso Corp | Intumescent fire resistant coating material |
| JPH0959009A (en) * | 1995-06-15 | 1997-03-04 | Chisso Corp | Ammonium polyphosphate treated with triazine derivative, its production and fireproof coating produced by using the compound |
| JPH10265722A (en) * | 1997-03-24 | 1998-10-06 | Kansai Paint Co Ltd | Thick film-form elastic heat-insulating coating material and coating heat-insulating technique using the same |
| JP2001164192A (en) * | 1999-12-08 | 2001-06-19 | Kikusui Chemical Industries Co Ltd | Expandable type fire-resistant coating |
| JP2002146088A (en) * | 2000-11-10 | 2002-05-22 | Kanegafuchi Chem Ind Co Ltd | Coated material of styrenic resin foam |
| JP2003238902A (en) * | 2002-02-22 | 2003-08-27 | Kowa Chem Ind Co Ltd | Composition for intumescent fireproof coating for indoor use |
| JP2003238903A (en) * | 2002-02-22 | 2003-08-27 | Kubota Corp | Intumescent fireproof coating |
| US20040054035A1 (en) * | 2002-09-13 | 2004-03-18 | Gerald Hallissy | Flexible, insulative fire protective coatings and conduits, utilitarian components, and structural materials coated therewith |
| JP2004331705A (en) * | 2003-04-30 | 2004-11-25 | Sakai Chem Ind Co Ltd | Flame-retardant coating agent composition and its use |
| JP2005113002A (en) * | 2003-10-08 | 2005-04-28 | Kikusui Chemical Industries Co Ltd | Water-based foaming/fire-retarding coating |
| JP2006028305A (en) * | 2004-07-14 | 2006-02-02 | Sekisui Chem Co Ltd | Flame-retardant resin coating composition and method for producing the same |
| JP2007169496A (en) * | 2005-12-22 | 2007-07-05 | Shin Etsu Chem Co Ltd | Foamable fireproof coating |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194423A (en) * | 2014-09-18 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Fireproof coating for wooden furniture and preparation method thereof |
| CN104449142A (en) * | 2014-12-09 | 2015-03-25 | 苏州明轩地坪涂料有限公司 | Fire-resistant elastic coating |
| CN104845457A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Fireproof coating with superior fireproof performance |
| CN107513317A (en) * | 2016-06-17 | 2017-12-26 | 清远市普塞呋磷化学有限公司 | A kind of aqueous double-component water proof anti-soil flame-retardant coatings glue and preparation method thereof |
| RU2669839C1 (en) * | 2016-09-05 | 2018-10-16 | Цзянсу Алмайн Нью Материалс Сток Ко., Лтд | Refractory reel and method of its manufacture |
| CN106752528A (en) * | 2016-12-26 | 2017-05-31 | 哈尔滨拓百世环保涂料有限公司 | Roofing energy-saving waterproof coating with fire-proof function and preparation method thereof |
| KR101792765B1 (en) | 2017-06-01 | 2017-11-20 | 양홍주 | Forming type-flame retandant cloth for preventing spark-scattering and product using the same |
| CN108252116A (en) * | 2018-03-31 | 2018-07-06 | 江苏奥力广告材料股份有限公司 | A kind of tent special purpose spray-drawing canvas and its production method |
| CN108641527A (en) * | 2018-05-10 | 2018-10-12 | 合肥昂诺新材料有限公司 | A kind of fire proof and thermo-insulation coating material for building and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2014136744A (en) | Foamable fire-resistive coating material composition | |
| US7652087B2 (en) | Protective coating | |
| CN104884542B (en) | intumescent coating composition | |
| GB2385856A (en) | Water-based, fire retarding coating composition | |
| WO2015096562A1 (en) | Aqueous expandable nano fireproof coating for cables and preparation method therefor | |
| CN101323727A (en) | Environment-friendly aqueous expansion type fireproof coating and preparation thereof | |
| KR101762309B1 (en) | Non-combustible inorganic paint composition having a heat insulating function and method for manufacturing thereof | |
| CN102061119A (en) | Solvent-free epoxy resin fire-resistant coating for ultrathin steel structure | |
| CN104673036A (en) | Water-based intumescent fire-retardant coating for timber structure and preparation method of coating | |
| CN105176247A (en) | Water-resistant fireproof coating | |
| KR20190066360A (en) | Fire resistant coating composition | |
| CN104559679A (en) | Water-based waterproof coating added with calcium sulfate whiskers and preparation method of coating | |
| WO2009013532A2 (en) | Coating compositions | |
| US11267974B2 (en) | Slurry compositions for use in flame retardant and hydrophobic coatings | |
| JP6414857B2 (en) | Flexible fireproof sheet, laminated fireproof sheet, and methods for producing the same | |
| CN104341891A (en) | Fireproof paint | |
| JP6181489B2 (en) | Water-based foamable coating composition and coated body | |
| JP5534887B2 (en) | Foam fireproof paint | |
| TWI694120B (en) | Foam refractory coating | |
| JP2008248188A (en) | Damping coating | |
| JP6995230B1 (en) | A composition for a foamable refractory paint and a method for producing a foamable refractory coating film using the same. | |
| JP6535263B2 (en) | Jet-black water-based paint composition for interior use | |
| SK5976Y1 (en) | Fireproof paint coat matter | |
| WO2023095773A1 (en) | Aqueous foaming fireproof coating composition | |
| JP2022147769A (en) | Aqueous foamable fireproof coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20151209 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20151209 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160107 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160930 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20161108 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20161226 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20170509 |