CN104186606A - Healthcare biscuit with squillid heads and squillid shells and manufacturing method thereof - Google Patents

Abstract

The invention relates to a healthcare biscuit with squillid heads and squillid shells and a manufacturing method of the healthcare biscuit. According to the raw material formula, the healthcare biscuit comprises, by weight, 45 percent to 70 percent of flour, seven percent to 11 percent of squillid enzymic protein powder, three percent to six percent of glucosamine hydrochloride, 0.2 percent to 0.7 percent of pectin, three percent to six percent of caryopteris incana, two percent to five percent of galinsoga parviflora, six percent to ten percent of stachyose, two percent to five percent of herpetospermum seed oil, six percent to ten percent of pigeon eggs and 0.8 percent to 1.3 percent of dried yeast. The raw materials are made into the biscuit through processing methods of a variety of ways, the surface is smooth, and hardness, the bulkiness intensity and chewiness are better. The problem that the squillid enzymic protein powder is heavy in bitter fishy smell, and cannot be adopted as food base materials is solved, the nutrition and health care value of the biscuit is better, and meanwhile the biscuit has the advantages of being higher in edible safety, crispy in flavor and pure in taste. If the biscuit is eaten frequently, the function of the human body can be adjusted, the physique can be strengthened, the disease resistance of the human body can be improved, aging can be resisted, and the life can be prolonged. Waste is comprehensively utilized, and great social, ecological, environmental and economical benefits are contained.

Description

A kind of health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell and preparation method thereof

Technical field

The present invention relates to a kind of health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell and preparation method thereof, belong to technical field of food biotechnology.

Background technology

Mantis shrimp is commonly called as shrimp and climbs son, squill, mouthful mantis shrimp etc., and Along Zhejiang Coast one band is commonly called as and relies urine shrimp, shrimp to pull out bullet, crawfish hook bullet, is subordinate to Arthropoda, Crustachia, Stomatopoda, Gu Xia section, the economic shell-fish of perennial marine products.Happiness is dwelt in Yu Qianchao and deep-sea silt or reef crack, distribution is extremely wide, from Muscovite large Peter bay to Japan and coastal area of china, Philippine, the Malay Peninsula, Hawaiian Islands all have distribution, maximum with the Chinese Huanghai Sea, the Bohai Sea, Hainan and East Sea kind.Mantis shrimp fine and tender taste deliciousness, individual large, be divided into cephalothorax and belly two parts, 20 body segments of tool altogether, head 5 saves, and chest 8 saves, belly 7 saves, the front 4 joint healings of head and chest form cephalothorax, are covered on it by carapace, and after chest, 4 joints expose outside carapace, the front end of carapace 2 pairs of feelers, the 1 pair of big jaw, the 2 pairs of small palates and the compound eye with handle, belly is slightly flat flat, is made up of 6 uromeres and flat 1 periproct, and anus is opened on the periproct outside of belly.Squilla Oratoria Shell fleshiness is few, can produce a large amount of mantis shrimp heads, Squilla Oratoria Shell (account for mantis shrimp body weight 65%～75%) in processing, edible process.Only have and be used on a small quantity produce the low value products such as feed at present, major part is dropped, and has caused environmental pollution.In fact, mantis shrimp head, Squilla Oratoria Shell are if rationally utilize, it is worth not under its meat, except containing the mineral matters such as protein, chitin, astaxanthin, calcium, zinc, magnesium and phosphorus, mantis shrimp head also contains [Zhang Qiang, " mantis shrimp head fatty acid analysis " " Journal of Nutrition " the 1st phases in 1998] such as each seed amino acids of abundant cephalin, fat, carrotene and needed by human.Its BA and pharmacological action are confirmed by the experimental results, have improve immunity of organisms, anti-oxidant, antibacterial, anti-ageing, antitumor, improve cerebral function, improve memory, the effects such as step-down, fat-reducing liver-protecting and prevention cardiovascular and cerebrovascular disease, and high to human safety.Therefore, recent domestic scholar is devoted to seek to mantis shrimp head, Squilla Oratoria Shell deep process technology, mainly concentrate on " preparing the research of chitin and chitosan from Squilla Oratoria Shell " [Yang Dan etc., " Food Science " 12 phases in 2006] and mantis shrimp head be processed into the aspects [Guo's civil division etc., " cultivation of coastal area of china mantis shrimp and comprehensive utilization " " extraordinary Economic animals and plants " o. 11th in 2011] such as mantis shrimp oil, mantis shrimp head powder, mantis shrimp head sauce, mixed feed, extraction protein.But be directly processed into mantis shrimp head powder, be of low nutritive value, can only serve as common or low-grade feed; If extract protein in mantis shrimp head by enzymatic isolation method, tend to produce heavier bitter off-flavors in hydrolytic process, weak flavor, cannot serve as foodstuff base material.

It is all the more so that biscuit is that people like popular bakery, particularly teenager and the children of food very much.Along with science and technology and growth in the living standard, also there is great variety in the strain of biscuit, from simply soft, rigid biscuit develop into that current waffle is dry, fruits and vegetables biscuit, soda cracker etc., in recent years, various strengthening mineral matters also arose at the historic moment as calcium, zinc, selenium and vitamine biscuit.But a lot of production firms are in order to regulate biscuit mouthfeel, increase the shelf-life, in producing, biscuit all can add a certain amount of sodium pyrosulfite etc. as leavening agent, and sulphite has sulfur dioxide residue in biscuit through high-temperature baking, excessive absorption causes potential hazard to health, does not meet concept of modern health.In addition, though the biscuit that existing market is sold has the effect of certain reinforcement nutrition, in mouthfeel, reach people's requirement, but still ubiquity nutritional labeling deficiency, local flavor is not good enough, health care is outstanding not, be difficult for by defects such as human body absorb, and the rupture rate of biscuit is high, make moist easily feel like jelly, moldy metamorphism even, the shelf-life is short.Therefore, people solve the problems referred to above in the urgent need to a kind of new technical scheme.Through retrieval, not yet find that so far mantis shrimp head, Squilla Oratoria Shell are carried out to biotechnology processing and be applied to biscuit make it have that local flavor is better, nutritional labeling is abundanter, health care is more outstanding, more easily by the precedent that human body absorbs, security is higher, also have no bibliographical information.

Summary of the invention

The object of the invention is to abandon it for current mantis shrimp head, Squilla Oratoria Shell as discarded object, cause the problem of resource serious waste, provide technique, a kind of health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell and preparation method thereof is provided, both solved mantis shrimp enzymolysis protein powder bitter off-flavors weight, weak flavor, cannot serve as the problem of foodstuff base material, when making again biscuit healthy nutritive value even better, have that taste flavor is better, the utilization rate that is absorbed by the body is better, and natural green, edible safety is higher, and hardness, bulkiness and chewiness are better.

In order to realize object of the present invention, the inventor studies and persistent exploration by lot of experiments, has finally obtained following technical scheme:

A kind of health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell, this composition of raw materials is by weight percentage: flour 45～70%, mantis shrimp enzymolysis protein powder 7～11%, aminoglucose hydrochloride 3～6%, pectin 0.2～0.7%, herpetospermum pedunculosum seed oil 2～5%, cayropteris incana 3～6%, smallflower galinsoga herb 2～5%, stachyose 6～10%, pigeon egg 6～10%, dry ferment 0.8～1.3%; Described pectin is to be made by the fiery sour jujube fruit of the cape gooseberry 25～75% and 25～75% of weight percentage 25～75%; Its preparation method comprises following processing step:

1. prepare mantis shrimp enzymolysis protein powder, gather fresh mantis shrimp head, clean, pour in pot for solvent extraction, and add the water of 2～5 times of the nose heave amounts of mantis shrimp, boil 10～20 minutes, filter, filter residue carries out defibrination with colloid mill, limit edging adds the water of 3～6 times of filter residue weight, pH is adjusted to 7.5～9, add again the trypsase of filter residue weight 0.2～1.1%, enzymolysis 2～5 hours under 40～75 DEG C of conditions, enzyme 20 minutes goes out under 80～95 DEG C of conditions, centrifugal, get supernatant, add the squash polyoses of supernatant weight 3～7%, the de-raw meat of 0.1～0.3% citric acid and 0.3～0.6% glycine debitterize, reduced pressure concentration, spraying is dry, obtain mantis shrimp enzymolysis protein powder,

2. prepare aminoglucose hydrochloride: gather fresh Squilla Oratoria Shell, clean, dry, being ground into 15～25 order shell sheets pours in pot for solvent extraction, and to add concentration by 3～6 times of heavy amounts of shell sheet be the HCI solution of 3～7wt%, under room temperature, soak 12～16 hours, be washed to neutrality, drain, adding concentration by 2～5 times of heavy amounts of shell sheet is again the NaOH solution of 3～7wt%, 85～95 DEG C of conditions are hydrolyzed 3 hours, filter, filter residue is washed to neutrality, dry, the concentration that adds 3～6 times of filter residue weight is 25～37wt%HCI solution, 50～65 DEG C of ultrasonic water bath 35 minutes, then add the active carbon of filter residue weight 3% to decolour, filter while hot, when filtrate is concentrated into 1/3 volume, the ethanol that the concentration that adds 4 times of volumes of concentrate is 80～95wt%, stir after 5 minutes, leave standstill and be cooled to 3～6 DEG C, crystallization, slough ethanol, get crystallizing and drying, pulverized 100 mesh sieves, obtain aminoglucose hydrochloride,

3. prepare pectin: the cape gooseberry that takes fresh state by formula, fire sour jujube fruit, remove respectively foreign material and the fruit of rotting, clean, drain, mix, sterilizing, being ground into 20～30 mesh sieve fragments pours in pot for solvent extraction, and add the water of 3 times of fragment weight to stir, add salt acid for adjusting pH value to 1.5～3, in 75～90 DEG C of Water Under solutions 2 hours, filter, collect filtrate, in filtrate, add the activated carbon decolorizing of filtrate weight 0.3～0.7%, liquid vacuum after decolouring is concentrated into 2/3 of original volume, in concentrate, adding isopyknic absolute ethyl alcohol to carry out alcohol analyses, the ethanol washing that to leach precipitate be 35～85wt% by concentration again 2 times, slough ethanol, dry, obtain pectin,

4. prepare herpetospermum pedunculosum seed oil: gather without the Semen Herpetospermi that goes mouldy, dry to water content and be less than 5%, be ground into 50～80 order fine powders, pass through supercritical CO ₂the method of extracting makes herpetospermum pedunculosum seed oil;

5. take cayropteris incana, the smallflower galinsoga herb of fresh state by formula, impurity elimination respectively, clean, mix, be ground into 30～50 order meal and put into beater, and add the water of 2～9 times of meal weight, making beating, squeezing, obtains pressed liquor and press residue, 35～65 DEG C of hot water lixiviates 1～3 hour for press residue, filter, obtain squeezing juice, squeezing juice and pressed liquor merge, and filtrate is crossed D101 large pore resin absorption column, first water, then the ethanol elution that is 35～75wt% by concentration, collects eluent, reduced pressure concentration, spraying is dry, obtains mixed powder;

6. take pigeon egg by formula, shell, put into eggbeater, and add pectin, the stachyose of formula ratio to beat evenly, form egg sugar material, in egg sugar material, add the water of 0.2 times of amount of egg sugar material, continue to beat 5～10 minutes, obtain egg liquid glucose;

7. take dry ferment by formula, activate into yeast juice with the water of 15～20 DEG C;

8. take flour, mantis shrimp enzymolysis protein powder, aminoglucose hydrochloride, step mixed powder 5. by formula and put into dough mixing machine, stir, add herpetospermum pedunculosum seed oil, step egg liquid glucose, the step yeast juice 7. 6. of formula ratio, water regulates humidity while stirring, and becomes dough;

The dough of 9. 8. step being become reconciled is placed in 35～40 DEG C of environment and ferments 30～50 minutes, then sending into roller pricks machine central roll and is bundled into and wears, to wear roller cuts and is molded into cake embryo again, put into 220～250 DEG C of baking oven bakings 3～5 minutes, come out of the stove, cooling, obtain the health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell.

In above-mentioned preparation method, the de-raw meat mechanism of action of mantis shrimp enzymolysis protein powder debitterize is, squash polyoses is as the antioxidant that suppresses fishy smell and produce, and can effectively remove free radical in enzymolysis protein liquid, stop or delay the oxidation of unrighted acid; Glycine has anti-oxidant and characteristics anti-corrosive properties, between itself and squash polyoses, has good synergy, brings into play better seasoning, improves the effect of taste, can optimize and slough bitter off-flavors effect; Citric acid is that local flavor regulates additive, makes enzymolysis liquid present the fragrance of lemon, tarts up, and improves mouthfeel; Its reaction condition gentleness, nutrition and active component to enzymolysis liquid are protected to greatest extent.Zai is Yu the nutritional labeling of Betel sauce leaf, Solandra nitida Zucc leaf and active material compatibility on this basis, has complementary functions, Synergistic, in the situation that ensureing protein loss reduction, bitter off-flavors removed substantially, and has to render palatable and increase fresh effect.

The mantis shrimp enzymolysis protein powder obtaining by above-mentioned preparation method is the mixture of a kind of micromolecule polypeptide, amino acid, flavour nucleotide, multivitamin and trace element.Its molecular weight is little, and biologically active is high, in human body, is almost all directly absorbed.Regulating gastrointestinal movement, improve physiological function, regulate immune system, improve cerebral function, delay senility, reducing blood lipid, hypotensive, antibacterial, anti-oxidant, antifatigue, antiviral, anticancer, remove free radical and promote mineral element to absorb aspects such as improving bioavailability and play an important role.

The aminoglucose hydrochloride obtaining by above-mentioned preparation method, is a kind of known natural mucopolysaccharide, and molecule is less, is easy to digest and assimilate, and can directly arrive focus.It contains a large amount of cellulosics, treatment bone and joint diseases medicine and antibiotic synergist, again sweetener, the antioxidant of food, can stimulate the growth of Bifidobacterium in baby intestinal, participate in liver, kidney removing toxic substances, human body is had to important physiological effect, also there is anti-inflammatory, the multiple pharmacological effect such as anti-oxidant, anticorrosion, antibacterial, antitumor.To staphylococcus aureus, Escherichia coli, bacillus subtilis, 21 kinds of bacteriums such as aspergillus flavus, mould, saccharomycete all have obvious antibacterial action [Chen Xin etc., " the anti-corrosive antibacterial effect of aminoglucose hydrochloride " 02 phase of " fine chemistry industry " calendar year 2001].

Cayropteris incana in above-mentioned raw materials is a kind of important medicinal plant that Verenaceae common bluebeard belongs to, and is distributed in Zhejiang, Anhui, Jiangsu and southern each provinces and regions.Herb is containing glycosides displayed, alkaloid, phenols, steroidal, amino acid, organic acid, tannin and volatile oil component.Its ethereal oil main component has [Sun Lingfeng etc., " research of cayropteris incana chemical composition of volatile oil " " fragrance flavor and cosmetic " 06 phases in 2004] such as linalool, perilla alcohol, carvol, shepherd's purse alkene, 4-methyl-6-teracrylic acid-one, oxalene, verbenone, left-handed pinocarvone, 2-nonene-4-alkynes.There is very strong fragrance, can expelling wind to resolve the exterior, expelling phlegm and arresting coughing, blood stasis removing analgesic, staphylococcus aureus, typhoid bacillus, bacillus, Escherichia coli, Pseudomonas aeruginosa are all had to inhibitory action.

Smallflower galinsoga herb in above-mentioned raw materials is composite family Achyranthes herbaceous plant, is distributed in the ground such as Zhejiang, Jiangxi, Sichuan, Guizhou, Yunnan and Tibet, has higher nutritive value.Bibliographical information herb is containing trace element and volatile oil such as cyanidenon-7-O-β-glucopyanoside, apiolin 7-O-β-D-glucopyanoside, stigmasterol, cupreol, ascorbic acid, dehydroascorbic acid, vitamin C, anthocyanidin, iron, manganese, zinc, manganese, nickel, chromium.Its volatile oil main component is β-carypohyllene, α-bergamotene, β-farnesene, β-selinene, 1-15 carbenes and β-bisabolence.There is effect of anti-inflammatory, clearing liver, improving eyesight.

From the document of retrieval, though both at home and abroad to the existing many reports of the research of cayropteris incana, smallflower galinsoga herb, but the bioactive ingredients about cayropteris incana and smallflower galinsoga herb is composite, is added into biscuit by its formula rate of appropriate variable and goes flavor and enhancing flavor, report antibacterial and preservation very few.

The present inventor gropes to sum up in a large number, find to exist between cayropteris incana and smallflower galinsoga herb the synergistic function of antibiotic property, in significantly improving biscuit healthy nutritive value, make anti-oxidant, antibacterial, fresh-keeping, decomposition and absorption there is synergistic function, to removing flavor and enhancing flavor, antibacterial, the fresh-keeping action effect that shows addition, both sloughed the bitter off-flavors in mantis shrimp enzymolysis protein powder, there is again natural flavor, the health care that has additional nutrients again in stimulating appetite, has more unique local flavor and increases fresh effect.Can also make in flour protein-SH radical oxidation of the compositions such as its contained glycosides displayed, ascorbic acid, vitamin C becomes cystine linkage-S-S-structure, branched structure in protein structure changes into network structure, improve dough rheological property and structure of dough, strengthen pulling force and the viscous force of dough, improve adherence, the retentiveness of dough and hold gas, promoting bulkiness and the organoleptic quality of biscuit.

Cape gooseberry in above-mentioned raw materials, another name gooseberry etc., nutritious, contain the trace elements such as polysaccharide, organic acid, pectin, vitamin C, vitamin B1, vitamin B2 and iron, phosphorus, potassium, calcium, zinc, simultaneously the content of biological flavone is very high, effects such as having softening blood vessel, reduce blood fat and blood pressure, replenish the calcium and strengthen body immunity, be anticancer.

Fiery sour jujube fruit in above-mentioned raw materials, have another name called torch fruit etc., it is a kind of medicine-food two-purpose, the wild plant resource that reserves are abundant, be rich in protein, amino acid, fat, starch, polysaccharide, pectin, cellulose, carotene, Cobastab, vitamin C, vitamin E, rutin, Quercetin, phosphatide, flavones, sitosterol, anthocyanidin, former cyanine, superoxide dismutase (SOD), chlorogenic acid and selenium, phosphorus, potassium, the trace elements such as calcium, there is enhancing body immunity, anti-oxidant, anticancer, reducing blood lipid, delay senility, improve artery sclerosis and promote the effects such as digestion.

Cape gooseberry, fiery sour jujube fruit have done more research at home and abroad as the exploitation of functional pectin.But the present inventor is surprised to find, by compound cape gooseberry, fiery sour jujube fruit make pectin and squash polyoses, aminoglucose hydrochloride compound after through intermolecular interaction, except good alimentary health-care function, present extremely significant synergistic tackifying, gelation and film forming, its hydroxyl can with starch chain on hydroxyl and moisture around form a large amount of hydrogen bonds, play the effect of starch retrogradation of stoping.Simultaneously, jelly powder of the present invention has very strong water absorption and swelling, flour is had to fibrous connective effect, colloidal complex form with stickiness forms gluten, making dough cohere complexing power strengthens, in dough, gluten network is more careful and flexible, improves stability, extensibility, toughness, elasticity and the machining property of dough.Effectively improve the fracture strength of biscuit, biscuit hardness increases, and is difficult for breaking.

Stachyose in above-mentioned raw materials is a kind of functional oligose that can significantly promote Bifidobacterium propagation.Safety has no side effect, solubility is high, good stability in food, sugariness is only 22% of sucrose, effectively prevents decayed tooth, significantly promotes the synthetic of vitamin B1, vitamin B2, promote the absorption of intestines and stomach to the mineral matter element such as calcium, magnesium, adsorbable intestines and stomach noxious material and pathogen, be of value to nutrition digestion and absorb and intestinal health, and then promote bone density and improve bone structure.

The present inventor shows through the result of research in many ways, stachyose and aminoglucose hydrochloride add in dough by its formula rate of appropriate variable, effect complementation, make gluten particulate be difficult for bonding and form gluten network, the viscosity of dough and elasticity reduce, reduce biscuit distortion, the biscuit hardness, brittleness and the chewiness that toast out are good, and moisture-sensitive not.

Herpetospermum pedunculosum seed oil in above-mentioned raw materials, is to extract from the seed of cucurbitaceous plant herpetospermum pedunculosum, has unique fragrance.Result of study shows both at home and abroad; Semen Herpetospermi contains the human essential elementses such as protein, polypeptide, amino acid, fat oil, cumarin, lignanoid, alkaloid, phenols and copper, iron, zinc, manganese, cobalt, nickel, chromium, selenium; oil content is up to more than 50%; it forms taking alpha-linolenic acid, linoleic acid, oleic acid as main; alpha-linolenic acid and linoleic acid belong to respectively n-3 type and n-6 type polyunsaturated fatty acid, have anti-oxidant, anti-inflammatory, antitumor, hypoglycemic, reducing blood lipid, atherosclerosis, protection cardiovascular system, suppress the effects such as ulcer and gastrorrhagia.Mono-kind of Chinese patent CN102000136A extracts the method with antibacterial activity component from herpetospermum pedunculosum, confirms that Semen Herpetospermi reads the bacterium such as coccus, bacillus subtilis, salmonella and have inhibitory action in various degree to gold-coloured staphylococci, white.

Pigeon egg in above-mentioned raw materials is rich in the nutritional labelings such as good protein, phosphatide, iron, calcium, vitamin A, vitamin B1, vitamin B2, vitamin D, the traditional Chinese medical science is thought: pigeon egg is sweet, salty, flat, has the effects such as the blood circulation of improvement, clearing heat and detoxicating, invigorating kidney qi, robustness function.

The present inventor conducts in-depth research discovery, in biscuit, be added into herpetospermum pedunculosum seed oil, there is the peculiar flavour that natural salted cake fried in sesame oil taste brings, can remove flavor and enhancing flavor, easily cause people's appetite, have stronger emulsibility when having given bacteriostatic activity again, the adhesion to starch granules and gelatinization have certain restriction, weaken gluten, thereby make biscuit there is loose structure.And the compositions such as the phosphatide in pigeon egg can make herpetospermum pedunculosum seed oil be dispersed in dough with emulsified state, prevent that herpetospermum pedunculosum seed oil from oozing out from biscuit, encouraging has loosened sends out, and has improved loose property, non-oxidizability and the ageing resistace of biscuit, not moisture-sensitive, extends the shelf life.

The present invention extracts mantis shrimp enzymolysis protein powder, aminoglucose hydrochloride by the manufacturing process of number of ways from mantis shrimp head, Squilla Oratoria Shell, slough bitter off-flavors, make it not only can be used as the basic foodstuff of people's life but also have the good nutrition health-care functions of human body, realize the comprehensive utilization to waste material, the added value that further improves mantis shrimp head, Squilla Oratoria Shell, is containing huge society, ecology, environment and economy benefit.

After the present invention passes through the raw materials such as mantis shrimp head, Squilla Oratoria Shell, cayropteris incana, smallflower galinsoga herb, fiery sour jujube fruit, cape gooseberry, Semen Herpetospermi to process, with the compound biscuit of producing in flour that is added into of stachyose, pigeon egg, dry ferment, squash polyoses, citric acid and glycine, each composition plays a role and brings out the best in each other, Synergistic, nutritional labeling is abundant more comprehensively, health care is more outstanding and reasonable, and without any artificial synthetic food additives, edible safety is higher.Its aromatic flavour, good taste, mouthfeel is crisp, long shelf-life.And when mantis shrimp enzymolysis protein pruinescence human body absorbs in time, also active material that biscuit of the present invention has and the quick absorption of nutritive and health protection components have been promoted, improve to greatest extent gastrointestinal absorption and bioavilability, often edible adjustable function of human body, build up health, improve body resistance against diseases, anti-ageing prolonging life.To prevention diabetes, cardiovascular and cerebrovascular diseases, joint disease, disease of digestive tract, increase bone density, improve bone structure, obesity controlling, antitumor etc. all play an important role.

Detailed description of the invention

Below in conjunction with specific embodiment, further set forth the present invention.Be not used in and limit the scope of the invention but these embodiment only limit to the present invention is described.

Embodiment mono-

1. raw material is prepared:

1. prepare mantis shrimp enzymolysis protein powder, gather fresh mantis shrimp head, clean, pour in pot for solvent extraction, and add the water of 3 times of the nose heave amounts of mantis shrimp, boil 15 minutes, filter, filter residue carries out defibrination with colloid mill, limit edging adds the water of 3.5 times of filter residue weight, pH is adjusted to 8.5, add again the trypsase of filter residue weight 0.3%, enzymolysis 3 hours under 55 DEG C of conditions, enzyme 20 minutes goes out under 90 DEG C of conditions, centrifugal, get supernatant, add the squash polyoses of supernatant weight 3%, the de-raw meat of 0.15% citric acid and 0.3% glycine debitterize, reduced pressure concentration, spraying is dry, obtain mantis shrimp enzymolysis protein powder,

2. prepare aminoglucose hydrochloride: gather fresh Squilla Oratoria Shell, clean, dry, being ground into 15 order shell sheets pours in pot for solvent extraction, and to add concentration by 5 times of heavy amounts of shell sheet be the HCI solution of 3～7wt%, under room temperature, soak 12 hours, be washed to neutrality, drain, adding concentration by 3 times of heavy amounts of shell sheet is again 3% NaOH solution, 95 DEG C of Water Under solutions 3 hours, filter, filter residue is washed to neutrality, dry, the HCI solution that the concentration that adds 5 times of filter residue weight is 25wt%, 50 DEG C of ultrasonic water bath 35 minutes, then add the active carbon of filter residue weight 3% to decolour, filter while hot, when filtrate is concentrated into 1/3 volume, the ethanol that the concentration that adds 4 times of volumes of concentrate is 90wt%, stir after 5 minutes, leave standstill and be cooled to 3 DEG C, crystallization, slough ethanol, get crystallizing and drying, pulverized 100 mesh sieves, obtain aminoglucose hydrochloride,

3. prepare pectin: the cape gooseberry that takes fresh state by formula, fire sour jujube fruit, remove respectively foreign material and the fruit of rotting, clean, drain, mix, sterilizing, be ground into 30 mesh sieve fragments and put into pot for solvent extraction, and add the water of 3 times of fragment weight to stir, add salt acid for adjusting pH value to 1.5, in 90 DEG C of Water Under solutions 2 hours, filter, collect filtrate, in filtrate, add the activated carbon decolorizing of filtrate weight 0.5%, liquid vacuum after decolouring is concentrated into 2/3 of original volume, in concentrate, adding isopyknic absolute ethyl alcohol to carry out alcohol analyses, the ethanol washing that to leach precipitate be 65wt% by concentration again 2 times, slough ethanol, dry, obtain pectin,

4. prepare herpetospermum pedunculosum seed oil: gather without the Semen Herpetospermi that goes mouldy, dry to water content and be less than 5%, be ground into 50 order fine powders, pass through supercritical CO ₂the method of extracting makes herpetospermum pedunculosum seed oil.

2. composition of raw materials:

Flour 59.5kg, mantis shrimp enzymolysis protein powder 9kg, aminoglucose hydrochloride 5kg, pectin 0.3kg, herpetospermum pedunculosum seed oil 3kg, cayropteris incana 5kg, smallflower galinsoga herb 2kg, stachyose 7kg, pigeon egg 8kg, dry ferment 1.2kg.

3. preparation process:

1. take cayropteris incana 5kg, the smallflower galinsoga herb 2kg of fresh state, impurity elimination respectively, clean, mixes, and is ground into 35 order meal and puts into beater, add the water of 21kg, making beating, squeezing, obtain pressed liquor and press residue, 50 DEG C of hot water lixiviates 2 hours for press residue, filter, obtain squeezing juice, squeezing juice and pressed liquor merge, and filtrate is crossed D101 large pore resin absorption column, first water, the ethanol elution that is then 45wt% by concentration, collects eluent, reduced pressure concentration, spraying is dry, obtains mixed powder;

2. take pigeon egg 8kg, shell, put into eggbeater, and add pectin 0.3kg, stachyose 7kg to beat evenly, form egg sugar material, in egg sugar material, add the water of 3.06kg, continue to beat 5 minutes, obtain egg liquid glucose;

3. take dry ferment 1.2kg, activate into yeast juice with the water of 15～20 DEG C;

4. take flour 59.5kg, mantis shrimp enzymolysis protein powder 9kg, aminoglucose hydrochloride 5kg, step mixed powder 1. and put into dough mixing machine, stir, add herpetospermum pedunculosum seed oil 3kg, step egg liquid glucose, step yeast juice 3. 2., water regulates humidity while stirring, and becomes dough;

The dough of 5. 4. step being become reconciled is placed in 35 DEG C of environment and ferments 50 minutes, then send into roller and prick machine central roll and be bundled into and wear, then will wear roller and cut and be molded into cake embryo, put into 230 DEG C of baking ovens and toast 5 minutes, come out of the stove, cooling, obtain the health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell.

Embodiment bis-

1. raw material is prepared:

1. prepare mantis shrimp enzymolysis protein powder, gather fresh mantis shrimp head, clean, pour in pot for solvent extraction, and add the water of 5 times of the nose heave amounts of mantis shrimp, boil 20 minutes, filter, filter residue carries out defibrination with colloid mill, limit edging adds the water of 3 times of filter residue weight, pH is adjusted to 9, add again the trypsase of filter residue weight 0.5%, enzymolysis 2 hours under 75 DEG C of conditions, enzyme 20 minutes goes out under 95 DEG C of conditions, centrifugal, get supernatant, add the squash polyoses of supernatant weight 5%, the de-raw meat of 0.1% citric acid and 0.5% glycine debitterize, reduced pressure concentration, spraying is dry, obtain mantis shrimp enzymolysis protein powder,

2. prepare aminoglucose hydrochloride: gather fresh Squilla Oratoria Shell, clean, dry, being ground into 20 order shell sheets pours in pot for solvent extraction, and to add concentration by 3 times of heavy amounts of shell sheet be the HCI solution of 5wt%, under room temperature, soak 15 hours, be washed to neutrality, drain, adding concentration by 5 times of heavy amounts of shell sheet is again the NaOH solution of 5wt%, 90 DEG C of Water Under solutions 3 hours, filter, filter residue is washed to neutrality, dry, the HCI solution that the concentration that adds 3 times of filter residue weight is 30wt%, 60 DEG C of ultrasonic water bath 35 minutes, then add the active carbon of filter residue weight 3% to decolour, filter while hot, when filtrate is concentrated into 1/3 volume, the ethanol that the concentration that adds 4 times of volumes of concentrate is 95wt%, stir after 5 minutes, leave standstill and be cooled to 5 DEG C, crystallization, slough ethanol, get crystallizing and drying, pulverized 100 mesh sieves, obtain aminoglucose hydrochloride,

3. prepare pectin: the cape gooseberry that takes fresh state by formula, fire sour jujube fruit, remove respectively foreign material and the fruit of rotting, clean, drain, mix, sterilizing, being ground into 20 mesh sieve fragments pours in pot for solvent extraction, and add the water of 3 times of fragment weight to stir, add salt acid for adjusting pH value to 2, in 85 DEG C of Water Under solutions 2 hours, filter, collect filtrate, in filtrate, add the activated carbon decolorizing of filtrate weight 0.3%, liquid vacuum after decolouring is concentrated into 2/3 of original volume, in concentrate, adding isopyknic absolute ethyl alcohol to carry out alcohol analyses, the ethanol washing that to leach precipitate be 50wt% by concentration again 2 times, slough ethanol, dry, obtain pectin,

4. prepare herpetospermum pedunculosum seed oil: gather without the Semen Herpetospermi that goes mouldy, dry to water content and be less than 5%, be ground into 50 order fine powders, pass through supercritical CO ₂the method of extracting makes herpetospermum pedunculosum seed oil.

2. composition of raw materials:

Flour 54.5kg, mantis shrimp enzymolysis protein powder 10kg, aminoglucose hydrochloride 4kg, pectin 0.5kg, herpetospermum pedunculosum seed oil 2kg, cayropteris incana 6kg, smallflower galinsoga herb 3kg, stachyose 9kg, pigeon egg 10kg, dry ferment 1.0kg.

3. preparation process:

1. take cayropteris incana 6kg, the smallflower galinsoga herb 3kg of fresh state, impurity elimination respectively, clean, mixes, and is ground into 30 order meal and puts into beater, add the water of 27kg, making beating, squeezing, obtain pressed liquor and press residue, 35 DEG C of hot water lixiviates 3 hours for press residue, filter, obtain squeezing juice, squeezing juice and pressed liquor merge, and filtrate is crossed D101 large pore resin absorption column, first water, the ethanol elution that is then 50wt% by concentration, collects eluent, reduced pressure concentration, spraying is dry, obtains mixed powder;

2. take pigeon egg 10kg, shell, put into eggbeater, and add pectin 0.5kg, stachyose 9kg to beat evenly, form egg sugar material, add the water of 3.9kg at egg sugar material, continue to beat 5 minutes, obtain egg liquid glucose;

3. take dry ferment 1.0kg, activate into yeast juice with the water of 15～20 DEG C;

4. take flour 54.5kg, mantis shrimp enzymolysis protein powder 10kg, aminoglucose hydrochloride 4kg, step mixed powder 1. and put into dough mixing machine, stir, add herpetospermum pedunculosum seed oil 2kg, step egg liquid glucose, step yeast juice 3. 2., water regulates humidity while stirring, and becomes dough;

The dough of 5. 4. step being become reconciled is placed in 40 DEG C of environment and ferments 30 minutes, then send into roller and prick machine central roll and be bundled into and wear, then will wear roller and cut and be molded into cake embryo, put into 250 DEG C of baking ovens and toast 3 minutes, come out of the stove, cooling, obtain the health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell.

Claims (1)

1. the health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell, it is characterized in that, the composition of raw materials of this biscuit is by weight percentage: flour 45～70%, mantis shrimp enzymolysis protein powder 7～11%, aminoglucose hydrochloride 3～6%, pectin 0.2～0.7%, herpetospermum pedunculosum seed oil 2～5%, cayropteris incana 3～6%, smallflower galinsoga herb 2～5%, stachyose 6～10%, pigeon egg 6～10%, dry ferment 0.8～1.3%; Described pectin is to be made by the fiery sour jujube fruit of the cape gooseberry 25～75% and 25～75% of weight percentage 25～75%; Its preparation method comprises following processing step:

1. prepare mantis shrimp enzymolysis protein powder, gather fresh mantis shrimp head, clean, pour in pot for solvent extraction, and add the water of 2～5 times of the nose heave amounts of mantis shrimp, boil 10～20 minutes, filter, filter residue carries out defibrination with colloid mill, limit edging adds the water of 3～6 times of filter residue weight, pH is adjusted to 7.5～9, add again the trypsase of filter residue weight 0.2～1.1%, enzymolysis 2～5 hours under 40～75 DEG C of conditions, enzyme 20 minutes goes out under 80～95 DEG C of conditions, centrifugal, get supernatant, add the squash polyoses of supernatant weight 3～7%, the de-raw meat of 0.1～0.3% citric acid and 0.3～0.6% glycine debitterize, reduced pressure concentration, spraying is dry, obtain mantis shrimp enzymolysis protein powder,

2. prepare aminoglucose hydrochloride: gather fresh Squilla Oratoria Shell, clean, dry, being ground into 15～25 order shell sheets pours in pot for solvent extraction, and to add concentration by 3～6 times of heavy amounts of shell sheet be 3～7wt%HCI solution, under room temperature, soak 12～16 hours, be washed to neutrality, drain, adding concentration by 2～5 times of heavy amounts of shell sheet is again the NaOH solution of 3～7wt%, 85～95 DEG C of Water Under solutions 3 hours, filter, filter residue is washed to neutrality, dry, the HCI solution that the concentration that adds 3～6 times of filter residue weight is 25～37wt%, 50～65 DEG C of ultrasonic water bath 35 minutes, then add the active carbon of filter residue weight 3% to decolour, filter while hot, when filtrate is concentrated into 1/3 volume, the ethanol that the concentration that adds 4 times of volumes of concentrate is 80～95wt%, stir after 5 minutes, leave standstill and be cooled to 3～6 DEG C, crystallization, slough ethanol, get crystallizing and drying, pulverized 100 mesh sieves, obtain aminoglucose hydrochloride,

3. prepare pectin: take cape gooseberry by formula, fire sour jujube fruit, remove respectively foreign material and the fruit of rotting, clean, drain, mix, sterilizing, being ground into 20～30 mesh sieve fragments pours in pot for solvent extraction, add the water of 3 times of fragment weight to stir, add salt acid for adjusting pH value to 1.5～3, in 75～90 DEG C of Water Under solutions 2 hours, filter, collect filtrate, in filtrate, add the activated carbon decolorizing of filtrate weight 0.3～0.7%, liquid vacuum after decolouring is concentrated into 2/3 of original volume, in concentrate, adding isopyknic absolute ethyl alcohol to carry out alcohol analyses, the ethanol washing that to leach precipitate be 35～85wt% by concentration again 2 times, slough ethanol, dry, obtain pectin,

4. prepare herpetospermum pedunculosum seed oil: gather without the Semen Herpetospermi that goes mouldy, dry to water content and be less than 5%, be ground into 50～80 order fine powders, pass through supercritical CO ₂the method of extracting makes herpetospermum pedunculosum seed oil;

5. take cayropteris incana, the smallflower galinsoga herb of fresh state by formula, impurity elimination respectively, clean, mix, be ground into 30～50 order meal and put into beater, and add the water of 2～9 times of meal weight, making beating, squeezing, obtains pressed liquor and press residue, 35～65 DEG C of hot water lixiviates 1～3 hour for press residue, filter, obtain squeezing juice, squeezing juice and pressed liquor merge, and filtrate is crossed D101 large pore resin absorption column, first water, then the ethanol Shen that is 35～75wt% by concentration is de-, collects eluent, reduced pressure concentration, spraying is dry, obtains mixed powder;

6. take pigeon egg by formula, shell, put into eggbeater, and add pectin, the stachyose of formula ratio to beat evenly, form egg sugar material, in egg sugar material, add the water of 0.2 times of amount of egg sugar material, continue to beat 5～10 minutes, obtain egg liquid glucose;

7. take dry ferment by formula, activate into yeast juice with the water of 15～20 DEG C;

8. take flour, mantis shrimp enzymolysis protein powder, aminoglucose hydrochloride, step mixed powder 5. by formula and put into dough mixing machine, stir, add herpetospermum pedunculosum seed oil, step egg liquid glucose, the step yeast juice 7. 6. of formula ratio, water regulates humidity while stirring, and becomes dough;

The dough of 9. 8. step being become reconciled is placed in 35～40 DEG C of environment and ferments 30～50 minutes, then sending into roller pricks machine central roll and is bundled into and wears, to wear roller cuts and is molded into cake embryo again, put into 220～250 DEG C of baking oven bakings 3～5 minutes, come out of the stove, cooling, obtain the health-caring biscuit containing mantis shrimp head, Squilla Oratoria Shell.