CN104163719A - Method for preparing water soluble fertilizer containing amino acid - Google Patents

Method for preparing water soluble fertilizer containing amino acid Download PDF

Info

Publication number
CN104163719A
CN104163719A CN201410394736.1A CN201410394736A CN104163719A CN 104163719 A CN104163719 A CN 104163719A CN 201410394736 A CN201410394736 A CN 201410394736A CN 104163719 A CN104163719 A CN 104163719A
Authority
CN
China
Prior art keywords
amino acid
acetate solution
organic acid
solution
soluble fertilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410394736.1A
Other languages
Chinese (zh)
Other versions
CN104163719B (en
Inventor
冯思慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201410394736.1A priority Critical patent/CN104163719B/en
Publication of CN104163719A publication Critical patent/CN104163719A/en
Application granted granted Critical
Publication of CN104163719B publication Critical patent/CN104163719B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Fertilizers (AREA)

Abstract

The invention relates to a method for producing a water soluble fertilizer containing an amino acid employing pyrolysis of an organic acid solution by using biomass and mixed fermentation of urea, and belongs to the technical field of a fertilizer production process. According to the method, the amino acid water soluble fertilizer is produced by biomass pyrolysis and organic acid fermentation, so that the product has stable amino acid content, the biological activity of the organic acid solution pyrolyzed by the biomass is preserved, a stable product application effect is ensured, meanwhile, the yield of the crop can be significantly increased and the quality is obviously improved after the product is applied to the crop. The product disclosed by the invention is also capable of disinfecting and sterilizing besides of promoting plant growth, and has a certain inhibiting effect on higher fungous diseases such as downy mildew, powdery mildew, gray mold, leaf spot disease, anthracnose and red rust disease of a plant, the pH value of the soil can be regulated, fungal spore growth in the soil is inhibited, and a preventive effect on ceitocybe bescens is also achieved.

Description

A kind of preparation method containing the water-soluble fertilizer of amino acid
Technical field
The invention belongs to production technique for fertilizer technical field, be specifically related to a kind of method of utilizing biomass pyrolytic organic acid soln and urea mixed fermentation production to contain the water-soluble fertilizer of amino acid.
Background technology
In recent years, amino acid pattern foliar nutrient is used widely, and fertilizer efficiency is comparatively sure, can not only increase production, and can also improve agricultural product quality.China market sell containing amino acid foliage fertilizer, mainly contain the Water Soluble Compound amino acid obtaining through hydrochloric acid or sulphuric acid hydrolysis containing proteinaceous substances, also have the amino acid that adopts biological fermentation process to produce.Generally have good trophism, but biological activity is poor.
The liquid that biomass pyrolytic organic acid produces while being biomass pyrolytic, it contains the multiple compounds such as water, acetic acid, ketone, phenols, lipid, aldehydes, alcohols, biological activity is stronger, can promote the growth of the plants such as vegetables, fruit tree, flowers, paddy rice, lawn.Some wood vinegar, bamboo vinegar liquid have had a small amount of application in agricultural as folk prescription, but because the nutritive element of product is uncontrollable, cause agriculture practical function unstable, cannot mass-producing application.
Biomass mainly refer to stalk, husk, shell fruit stone, fastgrowing trees and forestry, agricultural machining waste etc., and china natural resources total amount is not less than 1,000,000,000 tons/year according to estimates, and wherein the annual production of all kinds of stalks and husk is not less than 700,000,000 tons, is roughly equal to 2~300,000,000 tons of Petroleum Equivalents.Biomass are through high temperature pyrolysis, can output carbon, wood tar oil, wood gas and organic acid soln.
Fertilizer is that the important substance of development high yield and high quality agricultural ensures, the in the situation that of especially having a large population in a small area in China, fertilizer improves the determinative of agriculture per unit area yield especially.So a lot of agriculturals all will use chemical fertilizer or fertilizer increases soil fertility, though chemical fertilizer has production-increasing function, but contain the multiple Chemical Composition that is unfavorable for human body and environment, cause the quality of farm crop to decline, make the hardening soil, soil fertility declines, and makes human survival and health be subject to great threat.If can adopt the resourceful stale garbage of landfill to be used as the organic fertilizer of raw material production agricultural use, will there is unrivaled superiority in economic benefit and environmental benefit.
Amino acid, as the smallest molecule that forms protein, supplements plant essential amino acid, stimulates and regulating plant Fast Growth, impels plant-growth stalwartness, promotes the absorption to nutritive substance.Strengthen the metabolic function of plant, improve photosynthesis, promote root system of plant prosperity, accelerate plant-growth breeding, in current existing amino acid fertilizer, can not carry out good inhibition to higher fungi venereal disease evil and root rot, therefore how overcoming the deficiencies in the prior art, is the problem that current production technique for fertilizer technical field is needed solution badly.
Summary of the invention
The object of the invention is the biological activity in order to make full use of biomass pyrolytic organic acid soln, ensure the stable of product application effect, provide one to utilize the water-soluble fertile method of biomass pyrolytic organic acid soln compatibility urea fermentative production amino acid.
The technical solution used in the present invention is as follows:
A kind of preparation method containing the water-soluble fertilizer of amino acid is, first, made containing amino acid solution by biomass pyrolytic organic acid and urea mixed fermentation, then add respectively calcium oxide, iron powder, copper powder, zinc powder, manganese powder generation chemistry and react by another part of biomass pyrolytic organic acid soln to make calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution; Second step, will, containing amino acid solution and calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution, after being uniformly mixed, obtain of the present invention containing the water-soluble fertilizer of amino acid.
The above-mentioned preparation method containing the water-soluble fertilizer of amino acid, comprises the steps:
Step (1), get stalk, fruit tree branch, shell, wood chip, the starting material of any one or a few in bagasse and Chinese herb residues carry out low temperature pyrogenation processing, the smog producing is after reclaiming condensation, in storage tank, leave standstill and purifying 120-180 days, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%, pH value 2.3-4,
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described urea is the 40-60% of the weight of acetic acid, be heated to 30-70 DEG C, then be incubated 12-48 hour, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain of the present invention containing the water-soluble fertilizer of amino acid.
When low temperature pyrogenation in step described in technical solution of the present invention (1) is processed, temperature is 300-600 DEG C.
In step in technical solution of the present invention (1), the method for separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate pH value to 4.0~4.5 of distillate.
In technical solution of the present invention, further preferably described urea is agricultural urea.
The principle of described use biomass pyrolytic organic acid, the water-soluble fertilizer of urea fermentative production amino acid is as follows:
Amino acid forms by containing amino carboxyl: R-H-C-COOH-NH 2
Acetic acid is simply made up of a methyl and a carboxyl: CH 3cOOH
Urea has two amino: CO (NH 2) 2
Urea and biomass pyrolytic organic acid soln merge secondary fermentation, the amino of urea is combined with the carboxyl of acetic acid, be that urea provides nitrogenous source, biomass pyrolytic organic acid soln that carbon source is provided, there is again the amino acid that biomass pyrolytic organic acid soln contained originally that wild-type strain is provided, contain amino acid 3-6% through the biomass pyrolytic organic acid soln leaving standstill after purifying, these wild amino acid bacterial classifications ferment and produce amino acid (mostly being methyl) in the time of 30 DEG C-70 DEG C, and have neutralized pH value.
The inventive method provides a kind of method of utilizing biomass pyrolytic organic acid soln and the water-soluble fertilizer of urea fermentative production amino acid, by utilizing biomass pyrolytic organic acid soln cost of development lower and be rich in the water-soluble fertilizer of bioactive amino acid, can effectively reduce environmental pollution, reduce agricultural cost, improve quality of agricultural product.
Product of the present invention is containing amino acid >=10%, and middle amount or trace element reach the ministerial standard of the Ministry of Agriculture's " water-soluble fertilizer of amino acid ".
The present invention compared with prior art, its beneficial effect is: (1) the present invention utilizes biomass pyrolytic organic acid fermentation to produce the water-soluble fertilizer of amino acid, make product possess stable aminoacids content, retain again the biological activity of biomass pyrolytic organic acid soln, ensured the stable of product application effect; (2) farm crop are used after this product, can significantly improve crop yield, and quality is obviously improved, and can increase production 10%-50%; Fruit pol 2-5% can be provided, can improve potato starch content 5-10%; (3) except Promoting plant growth, product of the present invention can also the present invention except Promoting plant growth, product of the present invention can also sterilization, and oidium to plant, Powdery Mildew, gray mold, leaf spot, anthrax, red rust disease etc. have certain restraining effect to higher fungi venereal disease evil; (4) can regulate soil acidity or alkalinity, suppress the fungal spore growth in soil, root rot is also had to prophylactic effect.
Brief description of the drawings
Fig. 1 different concns biomass pyrolytic organic acid pH value changing trend diagram.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
The biomass pyrolytic organic acid soln of indication of the present invention, that the organic substance plant that utilization can be grown is raw material, by produce the liquid of smog through condensation recovery in pyrolysis or distillation process process, through the techniques such as separation of purifying, obtain containing amino acid 3-6%, containing the solution of acetic acid 10-50%.
The material that the inventive method is used: adopting the pyrolysis charring still that the patent No. is 201120186765.0, denomination of invention is " a kind of self-supplying heat product reclaims pyrolysis charring still entirely " is production unit.
The agricultural urea nitrogen content of the present invention is 46%.
Embodiment 1
Containing a preparation method for the water-soluble fertilizer of amino acid, comprise the steps:
Step (1), getting Chinese herb residues is at 300 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 120 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.0 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 40%, be heated to 30 DEG C, then be incubated 48 hours, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
Embodiment 2
Containing a preparation method for the water-soluble fertilizer of amino acid, comprise the steps:
Step (1), getting stalk, fruit tree branch and shell is starting material, be at 600 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 180 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.5 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 60%, be heated to 70 DEG C, then be incubated 12 hours, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
Embodiment 3
Containing a preparation method for the water-soluble fertilizer of amino acid, comprise the steps:
Step (1), getting stalk, fruit tree branch, shell, wood chip, bagasse and Chinese herb residues is starting material, be at 500 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 150 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.3 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 50%, be heated to 50 DEG C, then be incubated 35 hours, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
Comparative example 1
Comparative example 1 is with the difference of embodiment 3: low temperature pyrogenation treatment temp is 700 DEG C.Concrete steps are as follows:
Step (1), getting stalk, fruit tree branch, shell, wood chip, bagasse and Chinese herb residues is starting material, be at 700 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 150 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.3 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 50%, be heated to 50 DEG C, then be incubated 35 hours, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
Comparative example 2
Comparative example 2 is with the difference of embodiment 3: in elementary refined raw material pyrolysis organic acid soln, add agricultural urea without fermentative processing.Concrete steps are as follows:
Step (1), getting stalk, fruit tree branch, shell, wood chip, bagasse and Chinese herb residues is starting material, be at 500 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 150 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.3 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 50%, be stirred to and mix, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
Comparative example 3
Comparative example 3 is with the difference of embodiment 3: do not add calcium oxide and iron powder.Concrete steps are as follows:
Step (1), getting stalk, fruit tree branch, shell, wood chip, bagasse and Chinese herb residues is starting material, be at 500 DEG C, to carry out low temperature pyrogenation processing in temperature, the smog producing is after reclaiming condensation, standing also purifying 150 days in storage tank, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4; The method of described separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate the pH value to 4.3 of distillate;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add agricultural urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described agricultural urea be acetic acid weight 50%, be stirred to and mix, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of copper powder, zinc powder and manganese powder, make respectively neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain the present embodiment containing the water-soluble fertilizer of amino acid.
The elementary refined raw material pyrolysis organic acid soln that embodiment 1 is obtained detects, and does not detect that objectionable impurities arsenic, lead, cadmium, mercury exceed standard, and aminoacids content is as shown in table 1:
Aminoacids content in the elementary refined raw material of table 1 pyrolysis organic acid soln
Amino acid kind Biomass pyrolytic organic acid soln/(mg/g)
Aspartic acid 1
Serine 2.2
L-glutamic acid 2.1
Glycine 1.3
L-Ala 1.7
α-amino-isovaleric acid 2.5
Leucine 2.3
Isoleucine 2.1
Total amino acid content 15.2
, product of the present invention is detected, detected result is as shown in table 2 meanwhile.
Table 2
Investigate the embodiment of the present invention 1~3, comparative example 1~3 and the clear water control group restraining effect to Sanchi Leaf pinta and soybean Powdery Mildew, on pseudo-ginseng diseased plant, spray 300 times of embodiment of the present invention 1~3 and comparative example 1~3 and clear water control group after 15 days, check its sickness rate; On soybean diseased plant, spray 300 times of embodiment of the present invention 1~3 and comparative example 1~3 and clear water control group after 15 days, check its sickness rate; The results are shown in Table 3.
Table 3
? Sanchi Leaf pinta sickness rate Soybean Powdery Mildew sickness rate
Embodiment 1 20 15
Embodiment 2 18 13
Embodiment 3 16 14
Comparative example 1 35 26
Comparative example 2 32 32
Comparative example 3 33 30
Clear water control group 40 42
Investigate the impact of the embodiment of the present invention 1~3, comparative example 1~3 and the aspect of clear water control group on output, on pseudo-ginseng, spray 300 times of embodiment of the present invention 1~3 and comparative example 1~3 and commercially available common fertilizer, taking the output of clear water control group as benchmark, its impact on output the results are shown in Table 4.
Table 4
? Pseudo-ginseng
Embodiment 1 1.3
Embodiment 2 1.5
Embodiment 3 1.45
Comparative example 1 1.2
Comparative example 2 1.18
Comparative example 3 1.25
Commercially available common fertilizer 1
The Powdery Mildew control effect of test example 1 to soybean
Adopt this EXPERIMENTAL EXAMPLE 3 products at soybean foliar spray, investigate its effect to Powdery Mildew control.
One test objective
For verifying the Powdery Mildew control effect of this EXPERIMENTAL EXAMPLE 3 products to soybean, make good use of this fertilizer for popularization scientific basis is provided, test and demonstrate.
Test site: farmland, Yang Guan villagers' committee river sand dam, Bin Ju town, Dali Prefecture, Yunnan Province Binchuan County
Report time: 2014-7-19
Two testing programs
Experimental field select
Select representational typical soybean plot in farmland, Yang Guan villagers' committee river sand dam, Bin Ju town, Dali Prefecture, Yunnan Province Binchuan County on May 13rd, 2014, test physical features is smooth, fertility is even; Select medium fertility plot, test plot is around without building the things that shade such as thing, the woods; 0.9 mu of testing ground area.
Process numbering: (1)
Demonstration medicament: embodiment 3 products, 100g
Treatment dosage: 100g
Demonstration area: 0.4 mu
Process numbering: (3)
Demonstration medicament: clear water (contrast)
Treatment dosage: 0g
Demonstration area: 0.4 mu
Three test design and processing
1, for examination crop varieties: fresh No. 2 soybean of the Liao Dynasty
2, for examination fertilizer: embodiment 3 products
Four field investigation projects
1, test point fundamental state survey:
The farmland, Yang Guan villagers' committee river sand dam, Bin Ju town, specific address Dali Prefecture, Yunnan Province Binchuan County of test point, husky earth, test physical features is smooth, fertility is even, medium fertility, and test plot is around without building the things that shade such as thing, the woods; 0.9 mu of testing ground area, outdoor planting.Soybean is in flower bud differentiation period.
2, pilot survey project:
1. crop at different growth and development stages the demand percentage to nutritive ingredient and demand be distinguishing general seedling stage fertilizer requirement few, the phase fertilizer requirement of yielding positive results is large, therefore, now imposes fertilizer fine period, supply the short seedling of nutrient strong, the middle and late growth stage sprays the short high yield of anti-early ageing more.
2. economical character investigation
Outdoor plant growth is subject to the effect of natural conditions such as light, temperature, gas, heat larger, want to improve embodiment 3 product effects, temperature, humidity and wind direction must grasp spray fertilizer time, generally spray fertile optimal temperature and be 20-30 DEG C, and atmospheric moisture is 60-70%, at this moment crop leaf pore all opens, it is many and fast that blade absorbs nutrient, if temperature is high, humidity is little, solution is become dry by evaporation rapidly on blade, not only assimilation effect is poor, and the bright leaf of fertilizer damage easily occurs.So, this time foliage application the calm fine day of 2014-5-13 morning 7-10 time sprayed.
3. environment and the crop situation drug level feature of investigating in detail sample plot, every mu sprays with solution 400g, and I am 60kg for the amount of being watered, and crop cauline leaf (comprising pros and cons) is evenly stained with liquid.
Five field test implementation and operations
1, prepare before dispenser: before dispenser machinery (atomizer), mu water consumption (60kg), insecticide-applying way (foliage-spray) dispenser, do not pour water, spraying time (2014-5-13), control time (the observed and recorded crop growth conditions of the 15 day).
2, using method: atomizer, conical nozzle, 15 liters of capacity, when foliage-spray, mu water consumption is 15 liters, and when dispenser, field temperature is less than 30 degrees Celsius, and humidity is greater than 65%, and wind speed is less than 4m/s.Spray: dilute 300 times,
3, dispenser process:
On May 13rd, 2014 is fine, bright and sunny, and more suitable spraying medicine instructs peasant household's dispenser in the growing area of sampling.
Crop dispenser
Fine day sprays the morning, to increase blade absorbed dose, anti-damage blade.Ratio by embodiment 3 products with mono-barrel of water of 100g, even spraying is to crop, and it is thin that even spray is sprayed in spray when medicine, and the pros and cons of leaf is all sprayed onto, and has strictly grasped spraying concentration.
The soybean Powdery Mildew that sprays embodiment 3 products after 15 days obviously reduces, and samples and draws mean value three times by five-spot, refers to shown in following table 5 and table 6.Wherein table 5 is for using embodiment 3 products, and table 6 is clear water control group.
Table 5
Note: mean value is percentage ratio
Table 6
Note: mean value is percentage ratio
Six statistics and conclusions
Crop, using after embodiment 3 products soybean Powdery Mildew restraining effect, has reduced soybean Powdery Mildew onset state, has strengthened crop disease-resistant, antibacterial ability, has increased crop photosynthesis, and has optimized soybean fresh kidney beans quality, brings the raising in output.
Embodiment 3 products are " gold partner " in plant growth, and it can suppress crop pest generation, play the effect increasing income of producing of protecting.
To sum up, this product experiment effect is very outstanding, and crop is come along fine after dispenser, has good bacteriostatic action, and greenery fast, supplement the nutrients, robust plant, and flower-retention fruit-setting, effect is remarkable especially.Be conducive to can take in output significantly in the later stage equally and improve.
Test example 2 paddy rice, corn seed germination experiment
1 materials and methods
For examination material
Be No. 23, day purple for examination corn variety, by Chinese Academy of Agricultural Sciences Beijing, Zhong Pin Katyuan seed company limited provides.Be embodiment 2 products for examination seed soaking material, pH is 3.
Test design and method
8 processing are established in test, repeat for three times, 100 seeds of every repetition, 8 processing are respectively the embodiment of the present invention 2 product stostes, the 25 times of embodiment of the present invention 2 products of dilution, the 50 times of embodiment of the present invention 2 products of dilution, the 100 times of embodiment of the present invention 2 products of dilution, the 200 times of embodiment of the present invention 2 products of dilution, the 400 times of embodiment of the present invention 2 products of dilution, the 600 times of embodiment of the present invention 2 products of dilution, the 800 times of embodiment of the present invention 2 products of dilution, and tap water compares.
Select healthy full seed, with the embodiment of the present invention 2 product seed soaking 24h of different extension rates, after seed soaking finishes, clean and dry with clear water, carry out vernalization with the culture dish that is lined with 5 metafiltration paper, test is carried out in illumination box, and temperature is 28 DEG C, humidity is 80%~85%, and the photoperiod is 10h/14h (light/secretly than).
Project is measured
Carry out according to GB/T3543.4-1995 Seed Inspection code.
The calculating of germinating energy: observation can germinable seed amount afterwards in 3 days;
The calculating of percentage of germination: in percentage of germination (%)=8 day, subnumber × 100% is planted experimentally in normal seed number/confession of germinateing
Height of seedling is measured: representational 20 strains are chosen in each processing, measures seedling length, and unit is cm;
Radical flow measurement: representational 20 strains are chosen in each processing, measures radical amount, and unit is bar;
Germination index: Gi=∑ (Gt/Dt) (in formula, Gi is germination index, the germination grain number that Gt is t days, Dt is corresponding number of days);
Vitality index: Vi=Gi × L (Vi is vitality index, and Gi is germination index, and L is height of seedling).
Data processing
Adopt Excel2010 and DPS7.0 software to carry out data analysis and drawing.
2 results and analysis
2.1 impacts of the different concns embodiment of the present invention 2 products on rice seed germination and growth of seedling
As can be drawn from Table 7, from processing A1 to processing the increase of A8 along with the each processing embodiment of the present invention 2 product extension rates, process A1 all dead, compare to contrast A0, increase gradually to A8 seedling length from processing A2, wherein best to process A7, A8.Dry weight and fresh weight of plant seedlings is than aspect, and except processing A2, other are processed all lower than control treatment A0, and this is relevant with method of calculation with observing time.In the quantity of root, each processing with contrast compared there was no significant difference, and difference is little.Aspect germination index, compare to contrast, except processing A2, A3 significantly lower than control treatment A0, other are processed to contrast and compare there was no significant difference.
The impact of the table 7 different concns embodiment of the present invention 2 products on rice seed germination and growth of seedling
Process Germinating energy Percentage of germination (%) Radical amount (root) Seedling length (cm) Dry weight and fresh weight of plant seedlings ratio Germination index Vitality index
A0 93.67±1.5a 97.33±0.9a 4.23±0.3ab 3.20±0.4c 0.37±0.02b 12.17±0.1ab 39.00±0.1bc
A1 0.00±0.0d 0.00±0.0c 0.00±0.0c 0.00±0.0e 0.00±0.00f 0.00±0.0d 0.00±0.0e
A2 32.00±1.0c 70.33±3.8b 4.17±0.3ab 2.13±0.1d 0.41±0.04a 8.79±0.5c 18.70±0.5d
A3 87.00±2.0b 94.33±0.7a 4.03±0.6ab 3.33±0.1bc 0.31±0.01c 11.79±0.1b 39.31±0.1bc
A4 95.00±0.6a 98.00±0.6a 4.68±0.1a 3.60±0.2abc 0.24±0.01d 12.25±0.1a 44.12±0.1ab
A5 95.00±0.6a 97.67±0.3a 3.77±0.6ab 3.67±0.4ab 0.23±0.01de 12.13±0.1ab 44.48±0.1ab
A6 94.00±1.2a 97.00±1.5a 3.95±0.3ab 3.67±0.1ab 0.21±0.01de 12.13±0.2ab 44.43±0.2ab
A7 94.33±2.3a 96.33±1.7a 3.90±0.3ab 3.97±0.1a 0.19±0.02e 12.04±0.2ab 47.74±0.2a
A8 97.67±0.3a 98.00±0.1a 4.17±0.3ab 3.70±0.2ab 0.20±0.03de 12.25±0.1a 45.33±0.1a
The dependency of the 2.2 different concns embodiment of the present invention 2 products and rice seed germination and growth of seedling
As can be drawn from Table 8, from processing A1 to processing the increase of A8 along with the each processing embodiment of the present invention 2 product extension rates, process A1, A2 all dead, compare to contrast A0, increase gradually to A8 seedling length from processing A3, wherein best to process A6, A7, A8.Dry weight and fresh weight of plant seedlings, than aspect, is significantly higher than contrast A0 except processing A3, and other are processed with control treatment A0 there was no significant difference.In the quantity of root, except processing A3 significantly lower than contrast A0, other each processing with contrast are compared there was no significant difference, but processing A5, A6, A7, A8 are best.Aspect germination index, compare to contrast, except processing A3, A4 significantly lower than control treatment A0, other are processed all higher than contrast, and processing A7, A8 have significant difference.
The impact of the table 8 different concns embodiment of the present invention 2 products on Course of Corn Seed Germination and growth of seedling
Process Germinating energy Percentage of germination (%) Radical (root) Seedling long (cm) Dry weight and fresh weight of plant seedlings ratio Germination index Vitality index
A0 69.67±0.2c 60.67±2.7c 8±0.3a 13.50±0.4a 0.18±0.01bc 7.58±0.3b 102.3±5.4c
A1 0.00±0.0f 0.00±0.0f 0±0.0c 0.00±0.0e 0.00±0.00d 0.00±0.0e 0.00±0.0e
A2 0.00±0.0f 0.00±0.0f 0±0.0c 0.00±0.0e 0.00±0.00d 0.00±0.0e 0.00±0.0e
A3 5.67±2.3f 16.67±2.4e 5±0.3b 6.00±0.9d 0.33±0.04a 2.08±0.3d 12.96±3.5e
A4 29.00±1.7e 46.67±1.9d 8±0.3a 10.27±0.3c 0.23±0.01b 5.83±0.2c 59.78±1.4d
A5 63.00±2.6d 65.33±7.1c 9±0.6a 12.00±0.4b 0.19±0.01bc 8.17±0.9b 97.51±8.6c
A6 75.00±3.5bc 68.00±4.2bc 9±0.7a 13.07±0.1ab 0.16±0.01c 8.50±0.5b 111.07±6.8bc
A7 78.33±1.2ab 77.33±3.2ab 9±1.0a 12.47±0.4ab 0.17±0.01bc 9.67±0.4a 120.69±8.1ab
A8 84.00±2.4a 79.67±3.7a 9±0.3a 13.50±0.5a 0.18±0.01bc 9.96±0.5a 134.58±9.0a
As can be seen from Figure 1, compare with the clear water that contrasts A0, other each increases of processing along with extension rate, each pH value of processing all increases gradually, and the too low sprouting that is unfavorable for plantation of pH value, even causes plantation dead.Slightly high pH value, if pH value is the sprouting that 4 left and right contribute to seed.
3 conclusions
The embodiment of the present invention 2 products by these different extension rates are tested the seed soaking of paddy rice, corn seed, we can find out, the too low processing of extension rate is unfavorable for the sprouting of seed, and the paddy rice of processing A1 all causes death with the corn of processing A1, A2, so data are zero.Processing A7, the A8 multilist in every germination index that extension rate is very high is now better, especially on corn, behaves oneself best.Too low pH value has affected the germination of seed greatly, and the higher pH value of processing A7, A8 can promote the germination of seed.Comprehensive every data target, on paddy rice and corn, the embodiment of the present invention 2 products soak seed to dilute 600 to 800 times best at indices such as germinating energy, radical amount (root), seedling length (cm), dry weight and fresh weight of plant seedlings ratio, germination index, vitality indexs to seed.
From this experiment, can find out, 1, the embodiment of the present invention 2 products of high density are disadvantageous to seed germination, it can hurt the physiological structure of seed most probably, thereby destroy the germination of seed, and the embodiment of the present invention 2 products of lower concentration are in providing nutritive substance for seed, also because the sterilization and disinfection effect played of lower pH value, thereby promote the germination of seed.2, adopting the embodiment of the present invention 2 products different seeds of when seed soaking dilution because the difference of its structure, because taking different extension rates and the duration of soaking seed.
Test example 3 potato field experiments
1 materials and methods
For examination material
Experiment is cooperation 88 potatos with seed.Be embodiment 2 products for examination fertilizer, pH is 3.
Test design and method
8 processing are established in test, repeat for three times, 8 processing are respectively the 100 times of embodiment of the present invention 2 products of dilution, the 200 times of embodiment of the present invention 2 products of dilution, the 300 times of embodiment of the present invention 2 products of dilution, the 400 times of embodiment of the present invention 2 products of dilution, the 500 times of embodiment of the present invention 2 products of dilution, the 600 times of embodiment of the present invention 2 products of dilution, the 700 times of embodiment of the present invention 2 products of dilution, and tap water compares.
After potato sprouts one month, start to spray, every 15 days once, sprays altogether 3 times.
Project is measured
After potato harvest, carry out classification determination of yield, it is large size that single potato weighs more than 300, and 125-300 is medium size, is small size below 125.
2 results and analysis
As can be seen from Table 9, compared with the control, the per mu yield of processing 1,2,3,4,5 is improved, to process 2,4,5 for the highest.The large size potato yield of processing 1,2,3,4,5,6, all higher than contrast, has been created favourable condition for improving the economic output value.
The each biological yield of processing of table 9
Process Large size Medium size Small size Ultimate production Per mu yield Output increases (Kg)
1 61 47 52 160 2227 94
2 68 51 38 157 2277 144
3 70 41 38 149 2172 39
4 72 46 47 165 2329 196
5 68 54 46 167 2306 173
6 60 51 40 151 2129 -4
7 54 47 43 144 2070 -63
CK 57 50 39 146 2133 0
Process as can be seen from Table 10 1,2,3,4,5,6 the output value all higher than contrast, and to process 2,3,4,5 as best.
The economic output value of the each processing of table 10
3 conclusions
By using 100-500 times of embodiment 2 products to spray on potato leaf, can effectively increase potato per unit area yield, improve the ratio of large size potato, thereby effectively raise the economic worth of potato, wherein the highest to spray 200-500 processing output value increase doubly, reach 7.8-11.8%.Show by this test, spraying 200-500 times of embodiment 2 products can effectively increase potato biological yield, can significantly improve the economic output value simultaneously.
The leaf spot control effect of test example 4 to pseudo-ginseng
One test objective
For the leaf spot control effect of checking product of the present invention to pseudo-ginseng, make good use of this fertilizer for popularization scientific basis is provided, test and demonstrate.
Test fertilizer is the embodiment of the present invention 3 products.
Test site: farmland, Ming Hu village, De Hou town, Wenshan Prefecture of Yunnan Province Wenshan County
Report time: 2014-7-29
Two testing programs
Experimental field select
On May 23rd, 2014 is selected representational typical pseudo-ginseng plot in farmland, Ming Hu village, De Hou town, Wenshan Prefecture of Yunnan Province Wenshan County, and test physical features is smooth, fertility is even; Select medium fertility plot, test plot is around without building the things that shade such as thing, the woods; 4 mu of testing ground areas.
Process numbering: (1)
Demonstration medicament: embodiment 3 products (100g)
Treatment dosage: 100g
Demonstration area: 0.4 mu
Process numbering: (3)
Demonstration medicament: clear water (contrast)
Treatment dosage: 0g
Demonstration area: 4 Kong
Three test design and processing
1, for examination crop varieties: pseudo-ginseng
2, for examination fertilizer: embodiment 3 products
Four field investigation projects
1, test point fundamental state survey:
Farmland, Ming Hu village, De Hou town, Wenshan Prefecture of specific address Yunnan Province Wenshan County, the loam of test point, test physical features is smooth, fertility is even; Medium fertility plot, test plot is around without building the things that shade such as thing, the woods; 4 mu of testing ground areas, shade covers and plants.Pseudo-ginseng is in flower bud differentiation period.
2, pilot survey project:
1. crop at different growth and development stages the demand percentage to nutritive ingredient and demand be distinguishing general seedling stage fertilizer requirement few, the phase fertilizer requirement of yielding positive results is large, therefore, now imposes foliage fertilizer fine period, supply the short seedling of nutrient strong, the middle and late growth stage sprays the short high yield of anti-early ageing more.
2. economical character investigation
Panax notoginseng Growth is subject to the effect of natural conditions such as light, temperature, gas, heat larger, want to improve foliage application effect, temperature, humidity and wind direction must grasp spray fertilizer time, generally spraying fertile optimal temperature is 20-30 DEG C, atmospheric moisture is 60-70%, at this moment crop leaf pore all opens, it is many and fast that blade absorbs nutrient, if temperature is high, humidity is little, solution is become dry by evaporation rapidly on blade, not only assimilation effect is poor, and the bright leaf of fertilizer damage easily occurs.So this time foliage application has sprayed in the time of the 7-10 in the calm fine day of 2014-5-23 morning.
3. environment and the crop situation drug level feature of investigating in detail sample plot, every mu sprays with solution 400g, and I am 60kg for the amount of being watered, and crop cauline leaf (comprising pros and cons) is evenly stained with liquid.
Five field test implementation and operations
1, prepare before dispenser: before dispenser machinery (atomizer), the dispenser of mu water consumption (45kg), insecticide-applying way (filling root), do not pour water, spraying time (2014-5-23), control time (the observed and recorded crop growth conditions of the 15 day).
2, using method: lotus spray-head, capacity 200 premium on currency buckets, while filling with root, mu water consumption is 5t, and when dispenser, field temperature is less than 30 degrees Celsius, and humidity is greater than 45%.Spray: dilute 500 times.
3, dispenser process:
1. on May 23rd, 2014 fine, bright and sunny, plot is in lack of water period, more suitable watering,
In the growing area of sampling, instruct peasant household's dispenser.
2. crop dispenser
Fine day morning, prevent that the soil moisture is too high to pseudo-ginseng injury blade.Ratio by medicine with mono-barrel of water of 400g, evenly waters pseudo-ginseng on the ground, waters even watering carefully, and spraying concentration has strictly been grasped in this time test.
The Sanchi Leaf pinta that sprays the embodiment of the present invention 3 products after 15 days reduces to some extent, draws for three times and refers to table 11 and table 12. by mean value with the sampling of S shape method
Table 11 uses the plot of the embodiment of the present invention 3 products
Note: mean value is percentage ratio
Table 12 does not use the plot of the embodiment of the present invention 3 products
Note: mean value is percentage ratio
Six statistics and conclusions
Crop is being used after the embodiment of the present invention 3 product foliage fertilizers Sanchi Leaf pinta restraining effect, reduce Sanchi Leaf pinta onset state, strengthened crop disease-resistant, antibacterial ability, increased crop photosynthesis, and optimize blade face quality, can bring the raising in output.
Product of the present invention---" foliage fertilizer product " is " gold partner " in plant growth, and it can suppress crop pest generation, plays the effect increasing income of producing of protecting.Being appropriate to beans uses
To sum up, this product experiment effect is very outstanding, and crop is come along fine after dispenser, has good bacteriostatic action, and greenery fast, supplement the nutrients, robust plant, and flower-retention fruit-setting, effect is remarkable especially.Be conducive to can take in output significantly in the later stage equally and improve.

Claims (5)

1. the preparation method containing the water-soluble fertilizer of amino acid, it is characterized in that: first, made containing amino acid solution by biomass pyrolytic organic acid and urea mixed fermentation, then add respectively calcium oxide, iron powder, copper powder, zinc powder, manganese powder generation chemistry and react by another part of biomass pyrolytic organic acid soln to make calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution; Second step, will, containing amino acid solution and calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution, after being uniformly mixed, obtain of the present invention containing the water-soluble fertilizer of amino acid.
2. according to the preparation method containing the water-soluble fertilizer of amino acid described in claim 1, it is characterized in that: comprise the steps:
Step (1), any one or a few the starting material of getting in stalk, fruit tree branch, shell, wood chip, bagasse and Chinese herb residues carry out low temperature pyrogenation processing, the smog producing is after reclaiming condensation, in storage tank, leave standstill and purifying 120-180 days, make organic acid soln, then by organic acid soln through separating-purifying, obtain elementary refined raw material pyrolysis organic acid soln, in described primary solution, contain the material of following weight percent content: acetic acid 10%-50%, amino acid 3-6%, arsenic element≤0.0011%, cadmium element≤0.001%, lead element≤0.008%; PH value 2.3-4;
Step (2), in above-mentioned elementary refined raw material pyrolysis organic acid soln, add urea, the weight of getting the acetic acid in elementary refined raw material pyrolysis organic acid soln is benchmark, the add-on of described urea is the 40-60% of the weight of acetic acid, be heated to 30-70 DEG C, then be incubated 12-48 hour, make containing amino acid solution;
Step (3), meter by weight, get biomass pyrolytic organic acid soln that step (1) obtains with acetometer each 100 parts, add respectively each 20 parts of calcium oxide, iron powder, copper powder, zinc powder and manganese powder, make respectively calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and manganese acetate solution;
Step (4), meter by weight, that gets respectively that step (2) obtains adds containing 90 parts of amino acid solutions each 10 parts of calcium acetate solution, iron acetate solution, neutralized verdigris solution, zinc acetate solution and the manganese acetate solution that step (3) obtains successively, after being uniformly mixed, obtain of the present invention containing the water-soluble fertilizer of amino acid.
3. according to the preparation method containing the water-soluble fertilizer of amino acid described in claim 2, it is characterized in that: when the low temperature pyrogenation in described step (1) is processed, temperature is 300-600 DEG C.
4. the preparation method containing the water-soluble fertilizer of amino acid according to claim 2, it is characterized in that: in step (1), the method for separating-purifying is: organic acid soln is distilled, obtain distillate, then distillate is filtered, and regulate pH value to 4.0 ~ 4.5 of distillate.
5. the preparation method containing the water-soluble fertilizer of amino acid according to claim 1 and 2, is characterized in that: described urea is agricultural urea.
CN201410394736.1A 2014-08-12 2014-08-12 A kind of preparation method containing aminoacid Water soluble fertilizer Active CN104163719B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410394736.1A CN104163719B (en) 2014-08-12 2014-08-12 A kind of preparation method containing aminoacid Water soluble fertilizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410394736.1A CN104163719B (en) 2014-08-12 2014-08-12 A kind of preparation method containing aminoacid Water soluble fertilizer

Publications (2)

Publication Number Publication Date
CN104163719A true CN104163719A (en) 2014-11-26
CN104163719B CN104163719B (en) 2016-09-28

Family

ID=51907724

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410394736.1A Active CN104163719B (en) 2014-08-12 2014-08-12 A kind of preparation method containing aminoacid Water soluble fertilizer

Country Status (1)

Country Link
CN (1) CN104163719B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104591813A (en) * 2015-02-10 2015-05-06 湛社铭 Organic amino acid fertilizer for rice yield increase and application method thereof
CN105272599A (en) * 2015-10-26 2016-01-27 淮阴师范学院 Ca fertilizer for leaf surface
CN105461388A (en) * 2015-12-08 2016-04-06 石河子大学 Amino acid foliar fertilizer prepared from cottonseed meal and preparation method of amino acid foliar fertilizer
WO2019172277A1 (en) * 2018-03-05 2019-09-12 味の素株式会社 Composition for inducing plant disease damage resistance or preventing plant disease damage
JP2022510530A (en) * 2019-11-18 2022-01-27 中国水▲稲▼研究所 New organic fertilizer that suppresses heavy metal cadmium contamination or accumulation of paddy rice, its manufacturing method and application method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1778773A (en) * 2005-10-17 2006-05-31 浙江林学院 Liquid fertilizer with pyroligneous liquor and oxalacetic liquor and production thereof
CN102617219A (en) * 2012-04-08 2012-08-01 冯思慧 Production method of amino acid foliar-fertilizer
KR20120099873A (en) * 2011-03-02 2012-09-12 김정환 Eco-friendly custom crop rhizodegradation enzyme complexes
CN103864539A (en) * 2014-03-28 2014-06-18 山东绿林生物质材料科技有限公司 Preparation method of wood vinegar water-soluble fertilizer
CN103964924A (en) * 2014-05-14 2014-08-06 张铭强 Biological carbon energy water-soluble fertilizer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1778773A (en) * 2005-10-17 2006-05-31 浙江林学院 Liquid fertilizer with pyroligneous liquor and oxalacetic liquor and production thereof
KR20120099873A (en) * 2011-03-02 2012-09-12 김정환 Eco-friendly custom crop rhizodegradation enzyme complexes
CN102617219A (en) * 2012-04-08 2012-08-01 冯思慧 Production method of amino acid foliar-fertilizer
CN103864539A (en) * 2014-03-28 2014-06-18 山东绿林生物质材料科技有限公司 Preparation method of wood vinegar water-soluble fertilizer
CN103964924A (en) * 2014-05-14 2014-08-06 张铭强 Biological carbon energy water-soluble fertilizer

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104591813A (en) * 2015-02-10 2015-05-06 湛社铭 Organic amino acid fertilizer for rice yield increase and application method thereof
CN105272599A (en) * 2015-10-26 2016-01-27 淮阴师范学院 Ca fertilizer for leaf surface
CN105461388A (en) * 2015-12-08 2016-04-06 石河子大学 Amino acid foliar fertilizer prepared from cottonseed meal and preparation method of amino acid foliar fertilizer
WO2019172277A1 (en) * 2018-03-05 2019-09-12 味の素株式会社 Composition for inducing plant disease damage resistance or preventing plant disease damage
JPWO2019172277A1 (en) * 2018-03-05 2021-03-11 味の素株式会社 Composition for inducing disease resistance of plants or controlling disease of plants
JP7375743B2 (en) 2018-03-05 2023-11-08 味の素株式会社 Composition for inducing plant disease resistance or controlling plant diseases
JP2022510530A (en) * 2019-11-18 2022-01-27 中国水▲稲▼研究所 New organic fertilizer that suppresses heavy metal cadmium contamination or accumulation of paddy rice, its manufacturing method and application method

Also Published As

Publication number Publication date
CN104163719B (en) 2016-09-28

Similar Documents

Publication Publication Date Title
CN105123759B (en) Saline alkali tolerant plant growth promoter
US9150461B2 (en) Bioorganic agent for treating plants (variants)
CN109496734A (en) Method and a kind of ferment rice using ferment rice cultivation
CN105104044A (en) Planting method for organic rice in mountainous area
CN109315247B (en) Method for producing selenium-rich rice by using astragalus sinicus and rape activated soil
CN104163719B (en) A kind of preparation method containing aminoacid Water soluble fertilizer
CN102960226A (en) Dendrobium officinale Kimura et Migo tissue culture seedling acclimatization method
CN107231903A (en) A kind of implantation methods of good quality wheat
CN103444385A (en) Agricultural planting method
CN111320507A (en) Functional liquid fertilizer, preparation method thereof and cotton fertilization method
Das et al. Response of soil covers on guava cv. L-49
CN111052997B (en) Preparation and application method of biological stimulin for improving strawberry continuous cropping obstacle resistance
CN108840752A (en) A kind of biological organic fertilizer containing complex micro organism fungicide
CN114904900A (en) Method for promoting sweet sorghum to repair heavy metal contaminated soil by using fungi and biochar
CN111592405B (en) Organic water-soluble fertilizer capable of resisting wheat dry hot air and powdery mildew as well as preparation and application thereof
CN114751776A (en) Mixed fungal fertilizer suitable for reduced fertilizer application of low-fertility farmland and application method
CN107278580A (en) A kind of underwood planting method of roxburgh anoectochilus terminal bud
CN108192628A (en) A kind of carried titanium dioxide even ploughs the preparation method of soil-repairing agent
Sabeti et al. Investigation of effective microorganisms application method on alleviation of salt stress effects on root morphology of sweet corn
CN107484453A (en) A kind of agricultural non-point source pollution Sources controlling method
CN109197896B (en) Plant-source organic-inorganic compound molluscicidal fertilizer preparation and preparation method and application thereof
Prakash et al. Cumulative effect of botanical seed pelleting and foliar spray on morpho physiological, leaf chlorophyll, gas exchange and yield parameters in black gram
Antonov et al. Application of a vermicomposter containing biostimulant for pine tapping
CN111226724A (en) Cultivation method for green prevention and control efficient cost-saving production of scutellaria baicalensis
CN101565334B (en) Novel multi-vitamin crop nutrient cold resistant agent and preparation process thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Feng Sihui

Inventor after: Zhang Guoyun

Inventor after: Bi Shengbin

Inventor after: Zhou Xinwei

Inventor after: Zheng Yufeng

Inventor before: Feng Sihui

COR Change of bibliographic data
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20141126

Assignee: Yunnan one hundred Yue Biological Technology Co., Ltd.

Assignor: Feng Sihui

Contract record no.: 2017530000001

Denomination of invention: Method for preparing water soluble fertilizer containing amino acid

Granted publication date: 20160928

License type: Exclusive License

Record date: 20170510