CN104145952A - Environment-friendly fragrant water-based household insecticide - Google Patents
Environment-friendly fragrant water-based household insecticide Download PDFInfo
- Publication number
- CN104145952A CN104145952A CN201410341212.6A CN201410341212A CN104145952A CN 104145952 A CN104145952 A CN 104145952A CN 201410341212 A CN201410341212 A CN 201410341212A CN 104145952 A CN104145952 A CN 104145952A
- Authority
- CN
- China
- Prior art keywords
- insecticide
- environment
- family expenses
- friendly type
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an environment-friendly fragrant water-based household insecticide and a preparation method thereof. The prepared environment-friendly fragrant water-based household insecticide is applied to organic composition of ceramic burners and electronic constant temperature heaters. The insecticide is used for safely killing mosquitoes, flies, cockroaches, ants, termites, mites, lice, bugs, ticks, fleas and the like. The insecticide is characterized in that raw insecticides are compounds of botanical insecticides and the mass ratio is 0.2-0.58%; the insecticide also comprises 1-2.8% of surfactants, 0.1-0.2% of penetrants, 3-10.8% of solubilizers, a proper amount of chelating agents, wetting agents and perfume solubilizers, an excipient and less than 0.026% of essence; the excipient is purified water or deionized water; the total mass percent of the raw and auxiliary materials is 100%. Homogenous phase transparent liquid is formed by the environment-friendly fragrant water-based household insecticide. The green product has the multifunction characteristics of repelling, killing and long duration, has high cost performance and is not yet available on the domestic and foreign markets.
Description
Technical field
The invention belongs to PCO (PCO) field, especially relate to champignon aqua type domestic pesticide series of products and preparation method thereof.In (family expenses champignon water-base pesticide agent
and preparation method thereof) and the basis of the application patent of invention of (champignon aqua type domestic pesticide and preparation method thereof) on carry out that the innovations such as the feature of environmental protection, systematic function improve.Be applied to insects such as killing mosquito, fly, blattaria, ant, lice, flea, tick, mite.
Background technology
Vector pest damage people life and health, the very important index of a safe and comfortable level of the national people of the measurement index that its level of preventing and treating has been listed in to urban civilization degree or even measurement.At present, the domestic pesticide on domestic and international market is generally oil base, alcohol radical, " shaking water base " type aerosol, electric mosquito repellent tablet, and mosquito liquid, is also using traditional coiled mosquito-repellent incense etc.Aerosol is the type of killing that directly hits, and electric mosquito repellent tablet has residue, and mosquito liquid has kerosene etc., and electric mat is except discharging the chemical substances such as sub-Lenin, toluene, still has many unknowns, and tool is containing the compound of harmfulness.As used in confined chamber, may produce the phenomenon of severe allergy, as have a sore throat, nasal obstruction, headache etc.Liquid mosquito-repellent incense apparatus easily leaks electricity.If electric mat and electric mosquito repellent liquid liquid medicine quality do not pass a test, be very easily detrimental to health.Coiled mosquito-repellent incense fine particle severe contamination room air also endangers health of human body; Produce with destruction mountain forest protections such as wood powders, initiation fire in use, should limit as early as possible and eliminate!
the water base insecticide of environment-friendly type scent family expensesovercome the defect of above-mentioned series pesticide agent product, belong to environment-friendly and green product.For this reason, meet the Market Demand of worldwide environmental protection demand and green consumption, urgently Application and Development." this product comes into the market early; still do not offset expense person's a Gospel, and should be evaluated from higher angle, the historical Important Change of Zhe Shi China desinsection formulation; an important milestone, Ye Shishi China insecticide is in crossing over a mark of world standard ".Application and Development "
the water base insecticide series of products of environment-friendly type scent family expenses", avoid secondary pollution etc., not only reduce the potential hazard that health is brought and produce indirect loss difficult to the appraisal etc., and meeting national environmental protection industrial policy.Create the Chinese products of independent intellectual property right, thereby promotion is created global brand and is improved competitiveness in the international market and improve social and economic effects.
Summary of the invention
The object of this invention is to provide series of products, be under the principle of the healthy and living environment of to protect mankind, reach repellent or kill the optimum efficiency of vector insect.
From patent retrieval, application
champignon aqua type domestic pesticideseries of products are blank, also there is no the product of this formulation at home and abroad on market.The present invention, through multiple environment field experiment for many years, has realized the application excellent specific property of this technology and product, obtains the index of positive effect.1.
the water base insecticide of environment-friendly type champignon family expensesseries of products be water as excipient, except minute quantity is used for dissolving the former medicine of desinsection, there is no VOCs; 2. toxicity index LD
50> 16000～18800mg/kg, environmental toxicity standard and WHO standard are: micro-(nothing) poison level.3. biological effect: kill mosquito, fly, cockroach, ant, coptotermes formosanus, mite, lice, bedbug, tick, flea etc., and there is repellent and long multifunctional characteristics of lasting period, exceed GB A level (excellent) evaluation criterion.3. water vapour (certainly the comprising expelling worm composition) form of volatilization, there is not avoiding of PM2.5, because being with " gas " form, fills the air space, all-pervasive, kills the insect aobvious " particularity " in dark narrow corners; 4. without pessimal stimulation peculiar smell; 5. physicochemical property and quality are very stable, the product that this not yet can work it out so far both at home and abroad; 6. unlimited environmental applications produces effect, easy to use, durable, reliable; 7. without hidden danger; 8. cost performance is good; 9. adopt green pesticide---
plant insecticide, avoid the toxic and side effect of chemical insecticide; 10. auxiliary material, all adopts nuisanceless, the environmental friendliness of the pertinent regulations such as WHO and the Ministry of Agriculture and national environmental protection portion and standard recommendation, the material of easily biological-degradable, avoids secondary pollution, improves consumption safety reliability etc.
According to insecticide mixture principle, chemical insecticide, in production and use procedure, can be served negative effect to Human and nature environment band.1. pest resistance to insecticide sustainable growth, effect of chemical control declines; Medicament residual life in environment long, be difficult for degraded and pollute; 3. the abuse of chemical insecticide is dangerous to people and animals, and killed natural enemies and non-target organism, cause Pest rampancy etc.Should avoid using the chemical insecticide of high malicious high residue as far as possible, just must carry out structural reform to insecticide formulation, produce a new generation's safety-type green pesticide efficiently.
Adopt composite between plant insecticide.Plant insecticide Botanical insecticides is called green pesticide.Active component complexity can act on multiple organs and the system of insect, is conducive to overcome the pesticide resistance of insect.Chemical pesticide relatively, advantage: 1. easily decompose; 2. pair pest controling effect is good, nontoxic to person poultry safety, free from environmental pollution, noresidue; 3. pair insect is killed and wounded high specificity, does not injure natural enemy and beneficial organism; 4. many factors and composition play a role, and insect and pathogen are difficult to develop immunity to drugs.
In order to realize above-mentioned high-quality characteristic, technical solution of the present invention is mainly made up of following raw and auxiliary material:
Composition: the 1. former medicine of desinsection: plant insecticide composite; 2. surfactant: fluorine-containing surfactant, fatty alcohol ethers, MOA series, fatty acid ester T series; 3. auxiliary agent: (bleeding agent: JFC series; (wetting agent: Tao Shi TRITON X-405, TRITON CF-10, GSK-588/GSK-565); (intercalating agent: organic phosphonate, hydroxycarboxylate, citrate); 4. excipient: pure water or deionized water; 5. solubilizer: alcohol, ether, acetate type; 6. essence, spices solubilizer is appropriate.
The present invention carries out repellent or killing effect mechanism and the environmental friendly principle thereof of efficiency test to the characteristic of pest according to the development of the former medicine of desinsection, screening is composite with plant insecticide Botanical insecticides and pyrethroid insecticides Pyrethroid insectici des's; .Plant insecticide is wherein: pyrethrum crude oil, and spices synergist, pyrethrin, nimbin (China tree, melia toosendan print chinaberry), Celastrus angulatus, rotenone etc., product is many, does not enumerate.
Selecting according to WHO and Ministry of Agriculture's related standards of insecticide carried out, scientific and reasonable configuration mass ratio.Composite mass ratio 0.2～0.62% between plant insecticide.Or pyrethrum crude oil 0.01～026%, or spices synergist 0.01～0.1%, or pyrethrin 0.02～0.2%, or nimbin 0.05～0.23%, or Celastrus angulatus 0.1～0.25%, or rotenone 0.02～0.18%, that waits is composite.
Other surfactant, auxiliary agent, the selecting of the compositions such as solubilizer and mass ratio: fluorine-containing surfactant 0.01～0.12%, or fatty alcohol ethers 0.1～0.6%, or MOA series 0.1～0.9%, or fatty acid ester T series 0.1～1.8%; Or JFC class 0.1～0.5%; Or alcohols 1～13%, Tao Shi TRITON X-405,0.001～0.006%, GSK-588/GSK-565,0.001～0.006%, or acetate type 1～6%, or ethers 0.8～4.2%, essence 0.01～0.026%, or organic phosphonate or hydroxycarboxylate or citrate appropriate, or spices solubilizer is appropriate etc., pure water or deionized water+to 100%.
Be preferably: 1. pyrethrin 0.02～0.2%, nimbin 0.05～0.23%, fluorine-containing surfactant 0.01～0.12%, fatty acid ester T series 0.1～1.8%; JFC class 0.1～0.5%; Or Silwet 408,0.001～0.006%, alcohols (comprising edible alcohol) 1～13%; Ethers 0.8～4.2%; Essence 0.01～0.026%, organic phosphonate is appropriate, pure water or deionized water+to 100%.
2. each composition and consumption can also be: nimbin 0.05～0.23%, Celastrus angulatus 0.1～0.25%, pyrethrin 0.02～0.2%, fluorine-containing surfactant 0.01～0.12%, MOA series 0.1～0.9%, alcohols 1～13%, JFC class 0.1～0.3%, Tao Shi TRITON X-4050.001～0.004%, essence 0.01～0.026%, hydroxycarboxylate is appropriate, and spices solubilizer is appropriate, pure water or deionized water+and to 100%.
3. also can select: pyrethrum crude oil 0.01～026%, Celastrus angulatus 0.1～0.25%, fluorine-containing surfactant 0.01～0.12%, fatty alcohol ethers 0.1～0.6%, JFC class 0.1～0.3%, acetate type 1～6%, GSK-588/GSK-5650.001～0.0048%, alcohols 1～13%, essence 0.01～0.026%, citrate is appropriate, pure water or deionized water+and to 100%.
Plant insecticide principle of compound, in strict accordance with the requirement of Ministry of Agriculture's Information for pesticide Product Registration, filter out the significant combination of synergy and best proportioning thereof, and to its surfactant, the multiple auxiliary agent such as solubilizer carries out screening test, a series of synergy of developing remarkable, stable, there is good quick-acting and longer duration and broad spectrum type compounded pesticides and corresponding matching tooling environmentally friendly, ecological safety.
The applicable conventional facility of composition of the present invention, method are made
the water base insecticide of environment-friendly type scent family expensesseries of products.Described raw and auxiliary material is that plant insecticide, surfactant, bleeding agent, wetting agent, intercalating agent, excipient, solubilizer, essence, spices solubilizer are appropriate.
Usage: ceramics furnace and " electronic thermostatic heater " organically combine.When use, can open wide window.After electronic thermostatic heater energising, 10～20min water vapour just to volatilize, 1h can be distributed equably in room, so the best kill the mosquito time should be at dusk the time-division or sleep before 1h, liquid can be waved evenly loose from start to finish completely, keeps stable effect, without remaining waste.
Consumption: ceramic aroma burner adds water, adds
the water base insecticide of environment-friendly type scent family expenses, as guidance: each 8～15ml, depending on the interior space, environment of living in, expelling worm kind and strain are added.
Ceramics furnace and " electronic thermostatic heater " organically combine, and are novel household sanitary insecticide article.
Embodiment
Come by the following examples further to illustrate beneficial effect of the present invention, it should be understood that these embodiment, only for the object of illustration, never limit the scope of the invention.
Embodiment mono-:
1. raw and auxiliary material: pyrethrin 0.2%, nimbin 0.23%, fluorine-containing surfactant 0.12%, fatty acid ester T series 0.13%, JFC class 0.08%, TRITON CF-100.001%, alcohols (comprising edible alcohol) 10.8%, ethers 0.8%, essence 0.026%, citrate is appropriate, pure water or deionized water, and the percentage summation of above-mentioned raw and auxiliary material is 100%.
2. preparation method: according to Principles of Chemical Engineering and conventional production method, take each composition according to proportioning, first dissolve the former medicine of desinsection etc., separately get various auxiliary materials successively with excipient, stir, leave standstill, observing it fully dissolves, and forms after homogeneous phase liquid, can make of the present invention
the water base insecticide of environment-friendly type scent family expensesseries of products.
Embodiment bis-:
A. select pyrethrum crude oil 0.16%, nimbin 0.2%, spices synergist 0.1%, fluorine-containing surfactant 0.07%, MOA series 0.8%, Tao Shi TRITON X-4050.001%, JFC class 0.18%, alcohols 12%, essence 0.026%, hydroxycarboxylate is appropriate, and solubilizer is appropriate, pure water or deionized water+and to 100%.
B. preparation method: as embodiment mono-, conventional method and facility, make of the present invention
the water base insecticide of environment-friendly type champignon family expensesseries of products.
Embodiment tri-:
A. pyrethrin 0.15%, Celastrus angulatus 0.1%, nimbin 0.18%, fatty acid ester T series 1.4%, MOA series 0.6%, GSK-588/GSK-565,0.002%, JFC class 0.2%, acetate type 2.3%, alcohols 8.2%, essence 0.02%, in right amount, organic phosphonate, spices solubilizer are appropriate, pure water or deionized water+and to 100%.
B. preparation method: make product of the present invention described in embodiment mono-, two.
Cylinder method:
the water base pesticide product experiment effect of environment-friendly type champignon family expenses table 1
Evaluate: belong to A level by agriculture chemical registration hygienic insecticide drug effect.
the water base insecticide series of products of environment-friendly type champignon family expenses experiment effect
table 2
Conclusion: according to the acute toxicity grading criteria of China's agriculture chemical registration toxicology test method, all belong to micro-(nothing) poison.
Field experiment: select city local-style dwelling houses indoor as mosquito test, at dusk the time-division, area is m more than 20
2get the water base insecticide 10ml of environment-friendly type champignon family expenses and add the ceramic aroma burner that 360ml water is housed, aroma burner is placed on to wall limit, 12min steam volatilization after energising, door and window opens wide, have wind flow, in 45min～2h, mosquito space flies, fall down successively, All Through The Night does not have mosquito, is checked through 12 dead mosquitoes tomorrow morning, also has 4 of Groton bugs.
Second night, get the water base insecticide 5ml of environment-friendly type champignon family expenses and add the ceramic aroma burner that 200ml water is housed, aroma burner is placed on to wall limit, 9min steam volatilization after energising, door and window opens wide, have wind flow, after 45min～1:30h, mosquito has been lacked, not, All Through The Night does not have mosquito, is checked through 7 dead mosquitoes tomorrow morning, also has 3 of Groton bugs.、
In the 3rd day evening, as the way of second night, All Through The Night does not have mosquito, is checked through 3 dead mosquitoes tomorrow morning, also has 1 of Groton bug.
In the 4th day evening, as the way of second night, All Through The Night does not have mosquito, is checked through 3 dead mosquitoes tomorrow morning, there is no Groton bug.
In the 5th day evening, do not used intentionally, has once in a while 1,2 mosquito flying, and soon also do not had, and All Through The Night is fallen asleep safely.……
Experimental result shows, in unlimited environment, the water base insecticide series of products of environment-friendly type champignon family expenses of the present invention can be killed mosquito, fly, cockroach effectively.
The foregoing is only the explanation of embodiments of the invention and preparation, using method work, be not limited to the present invention, this is to those skilled in the art on basis of the present invention, and it is made some modifications or improvements is apparent.Therefore, all on the basis of the present invention spirit and principle and framework, any amendment of making, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. the water base insecticide of environment-friendly type champignon family expenses, is characterized in that: make the water base insecticide of environment-friendly type champignon family expenses of homogeneous phase transparent liquid, be supporting application in the organic composition of ceramics furnace and electronic thermostatic heater.Adopt the composite of plant insecticide, mass ratio is 0.2～0.58%; Also has surfactant 1～2.8%; Bleeding agent 0.1～0.2%; Solubilizer 3～10.8%; Intercalating agent, wetting agent, spices solubilizer are appropriate; Excipient is pure water or deionized water; Essence is below 0.026%, and the mass percent summation of above-mentioned raw and auxiliary material is 100%.
2. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: what described insecticide was plant insecticide is composite.
3. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: described surfactant by fluorine-containing, nonionic surface active agent is composite.
4. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: described ceramics furnace and the organic composition of electronic thermostatic heater support the use.
5. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: described bleeding agent is JFC series of products, wetting agent is Silwet 408, Tao Shi TRITON X-405, TRITON CF-10.
6. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: described auxiliary material are that intercalating agent is citrate, organic phosphonate.
7. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: described excipient is pure water or deionized water; Solubilizer is alcohols (comprising edible alcohol), ether, acetate type, spices solubilizer.
8. the water base insecticide of environment-friendly type champignon family expenses according to claim 1, is characterized in that: the configuration of necessary power line adapter in described application.
9. a method for producing insecticide claimed in claim 1, is characterized in that it comprises the following steps:
1.. get the composite 0.2～0.58% of plant insecticide, solubilizer 3～10.8%; Essence is below 0.026%.
2.. water intaking adds surfactant 1～2.8%, bleeding agent 0.1～0.26%; Wetting agent, spices solubilizer are appropriate, fully stir, and dissolve.
3.. 1. 2. step added to step while stirring, record pH value, take the circumstances into consideration to add intercalating agent, fully stir until obtain the aqueous solution of clear, leave standstill, filter, bottling.Make the finished product of the water base insecticide of environment-friendly type champignon family expenses.
10. be named and be called: the water base insecticide of environment-friendly type champignon family expenses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410341212.6A CN104145952A (en) | 2014-07-18 | 2014-07-18 | Environment-friendly fragrant water-based household insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410341212.6A CN104145952A (en) | 2014-07-18 | 2014-07-18 | Environment-friendly fragrant water-based household insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104145952A true CN104145952A (en) | 2014-11-19 |
Family
ID=51871760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410341212.6A Pending CN104145952A (en) | 2014-07-18 | 2014-07-18 | Environment-friendly fragrant water-based household insecticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104145952A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110477002A (en) * | 2019-08-30 | 2019-11-22 | 泉州中翰龙生物科技有限公司 | A kind of environmentally-friendly water-based domestic insecticide aerosol |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6063392A (en) * | 1996-01-17 | 2000-05-16 | Lts Lohmann Therapie-System Gmbh | Method of applying an active substance to plants and a suitable preparation |
| CN1836522A (en) * | 2006-04-18 | 2006-09-27 | 红河森菊生物有限责任公司 | Pyrethrin missible oil formulation using neem oil as synergistic agent |
| CN102450252A (en) * | 2010-10-20 | 2012-05-16 | 周端午 | Green, long-lasting antibacterial, mildew-resistant and insecticidal water-based micro-emulsifier |
| CN103315006A (en) * | 2013-04-22 | 2013-09-25 | 河南省科高植物天然产物开发工程技术有限公司 | Insecticidal composition containing natural celastrus angulatus and natural vitex negundo and application thereof |
| CN103329943A (en) * | 2013-04-22 | 2013-10-02 | 河南省科高植物天然产物开发工程技术有限公司 | Insecticide composition containing natural celastrus angulatus and natural pyrethrin |
-
2014
- 2014-07-18 CN CN201410341212.6A patent/CN104145952A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6063392A (en) * | 1996-01-17 | 2000-05-16 | Lts Lohmann Therapie-System Gmbh | Method of applying an active substance to plants and a suitable preparation |
| CN1836522A (en) * | 2006-04-18 | 2006-09-27 | 红河森菊生物有限责任公司 | Pyrethrin missible oil formulation using neem oil as synergistic agent |
| CN102450252A (en) * | 2010-10-20 | 2012-05-16 | 周端午 | Green, long-lasting antibacterial, mildew-resistant and insecticidal water-based micro-emulsifier |
| CN103315006A (en) * | 2013-04-22 | 2013-09-25 | 河南省科高植物天然产物开发工程技术有限公司 | Insecticidal composition containing natural celastrus angulatus and natural vitex negundo and application thereof |
| CN103329943A (en) * | 2013-04-22 | 2013-10-02 | 河南省科高植物天然产物开发工程技术有限公司 | Insecticide composition containing natural celastrus angulatus and natural pyrethrin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110477002A (en) * | 2019-08-30 | 2019-11-22 | 泉州中翰龙生物科技有限公司 | A kind of environmentally-friendly water-based domestic insecticide aerosol |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5818860B2 (en) | 匍匐 Pest repellent and repellant method | |
| KR20160079371A (en) | Wild animal Repellent Composition and preparation thereof | |
| US20090169655A1 (en) | Insect repellent formulation | |
| JP5637737B2 (en) | Spray for controlling fly flies | |
| CN105454329B (en) | Oil of Cymbopogon winterianus vaporizer mosquito liquid and preparation method thereof | |
| JP2018530602A (en) | Pyrethrin-rich insecticide | |
| CN104206456A (en) | Environmental-protective household fragrant water-based pesticide | |
| CN108419810A (en) | A kind of natural plant composition compound bio insect aerosol | |
| CN105519587A (en) | Liquid mosquito repellent incense containing tea tree essential oil and preparation method of liquid mosquito repellent incense | |
| CN107047554A (en) | With natural plant essential oils attractant that function is trapped for Bemisia tabaci and preparation method thereof | |
| CN104145952A (en) | Environment-friendly fragrant water-based household insecticide | |
| CN105994438A (en) | Environment-friendly and nontoxic mosquito-repelling product and preparation method thereof | |
| JP6651436B2 (en) | Combustible pest control agent | |
| CN104542729A (en) | Azadirachtin-containing botanical insect aerosol and preparation method thereof | |
| KR101692667B1 (en) | Mosquito repelling composition and manufacturing method thereof, and method of manufacturing water paint using the said composition and water paint produced by thereof method | |
| JP2005520842A (en) | A herbal synergistic formulation effective against mosquito larvae and its use in controlling malaria vectors | |
| KR101090052B1 (en) | Natural mosquito repellent composition containing the turmeric-leaf and method for manufacturing the same | |
| CN105724445A (en) | Rosemary essential oil mosquito-repellent incense liquid and preparation method thereof | |
| CN102334511A (en) | Cockroach plant-source pesticide bait | |
| CN104938530A (en) | Botanical electric warming mosquito incense mat synergist and electric warming mosquito incense mat | |
| CN106614561A (en) | Biomass fuel mosquito-repellent incense and preparation method thereof | |
| CN105994445A (en) | Mosquito-repellent incense | |
| CN104126577A (en) | Scented water-based household insecticide | |
| CN104126572A (en) | Household scented water-based insecticide | |
| CN105475372A (en) | Peppermint essential oil mosquito liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141119 |
|
| RJ01 | Rejection of invention patent application after publication |