CN104206456A - Environmental-protective household fragrant water-based pesticide - Google Patents
Environmental-protective household fragrant water-based pesticide Download PDFInfo
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- CN104206456A CN104206456A CN201410341236.1A CN201410341236A CN104206456A CN 104206456 A CN104206456 A CN 104206456A CN 201410341236 A CN201410341236 A CN 201410341236A CN 104206456 A CN104206456 A CN 104206456A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses an environmental-protective household fragrant water-based pesticide and a preparation method thereof. The environmental-protective household fragrant water-based pesticide is employed as an organic component of a ceramic furnace and an electronic constant-temperature heater and can kill mosquitoes, flies, cockroaches, ants, termites, mites, louses, bugs, ticks, fleas and the like. An active compound of the pesticide is compounded from natural plant fragrant oil with a mass ratio being 0.2-0.58%. The pesticide also comprises 1-1.8% of a surfactant, 0.1-0.32% of a permeating agent, 3-20% of a solubilizer, a proper amount of a chelating agent, a proper amount of a moistening agent and a proper amount of a fragrance solubilizer. An excipient is pure water or deionized water. A total mass percentage of above raw materials and auxiliary materials is 100%. The environmental-protective household fragrant water-based pesticide is formed into a homogeneous-phase transparent solution, has multiple functional characteristics of expelling and killing insects and being long in lasting time, is a green product having a high performance-price ratio and does not exist on domestic and foreign markets.
Description
Technical field
The invention belongs to PCO (PCO) field, especially relate to champignon aqua type domestic insecticide agent series products and preparation method thereof.In application patent of invention---the basis of the water base insecticide of environment-friendly type champignon family expenses is carried out the innovation such as the feature of environmental protection, systematic function and improve.Be applied to and kill mosquito, fly, blattaria, the insects such as ant, lice, flea, tick, mite.
Background technology
Vector pest damage people life and health, has listed the measurement index of urban civilization degree or even the very important index of measurement-safe and comfortable level of the individual national people in its level of preventing and treating.At present, the domestic pesticide on domestic and international market is generally oil base, alcohol radical, " shaking water base " type aerosol, electric mosquito repellent tablet, mosquito liquid, is also using traditional coiled mosquito-repellent incense etc.Aerosol directly hits the type of killing, electric mosquito repellent tablet has residue, and mosquito liquid has kerosene etc., and electric mat, except discharging the chemical substances such as sub-Lenin, toluene, still has many unknowns, and tool is containing the compound of harmfulness.As used in confined chamber, the phenomenon of severe allergy may be produced, as having a sore throat, having a stuffy nose, headache etc.Liquid mosquito-repellent incense apparatus easily leaks electricity.If electric mat and electric mosquito repellent liquid liquid medicine quality do not pass a test, be very easily detrimental to health.Coiled mosquito-repellent incense fine particle severe contamination room air also endangers health of human body; Production wood powders etc. destroy mountain forest protection, use initiation fire, should limit as early as possible and eliminate!
the agent of environment-friendly household champignon water-base pesticideovercome the defect of above-mentioned series pesticide agent product, belong to environment-friendly and green product.For this reason, water is told in the market meeting worldwide ecological requirements and green consumption, urgently Application and Development." this product comes into the market early; still do not offset a Gospel of expense person, and should be evaluated from higher angle, and this is the historical Important Change of China's desinsection formulation; an important milestone, and Ye Shishi China insecticide is in the mark crossing over world standard ".Application and Development "
environment-friendly household champignon water-base pesticide agent series products", avoid secondary pollution etc., not only reduce potential hazard that health is brought and produce indirect loss difficult to the appraisal etc., and meeting national environmental protection industrial policy.Create the Chinese products of independent intellectual property right, thus promote create global brand and improve competitiveness in the international market and improve social and economic effects.
Summary of the invention
The object of this invention is to provide series of products, under being to protect the principle of human health and living environment, reaching repellent or kill the optimum efficiency of vector insect.
From patent retrieval, application
champignon aqua type domestic pesticideseries of products are blank, market also do not have the product of this formulation at home and abroad.The present invention, through multiple ambient scene experiment for many years, achieves the application excellent specific property of this technology and product, obtains the index of positive effect.1.
the agent of environment-friendly household champignon water-base pesticideseries of products use water as excipient; 2. toxicological parameters LD
50> 18000 ~ 21800mg/kg, environmental toxicity standard and WHO standard are: micro-(nothing) malicious level.3. biological effect: kill mosquito, fly, cockroach, ant, coptotermes formosanus, mite, lice, bedbug, tick, flea etc., and the multifunctional characteristics with repellent and lasting period length, exceed GB A level (excellent) evaluation criterion.3. water vapour (certainly the comprising expelling worm composition) form of volatilization, there is not avoiding of PM2.5, because being with " gas " form, fills the air space, all-pervasive, kills the insect aobvious " particularity " in dark narrow corners; 4. without pessimal stimulation peculiar smell; 5. physicochemical property and quality are very stable, this product not yet can worked it out both at home and abroad so far; 6. the environmental applications of opening wide is effective, easy to use, durable, reliably; 7. without hidden danger; 8. cost performance is good; 9. adopt pure
natural plant sesame oil is as expelling worm active component.Without any
plant insecticidewith the toxic and side effect of chemical insecticide; 10. auxiliary material, all adopts the material of nuisanceless, environmental friendliness, the easily biological-degradable of WHO and the pertinent regulations such as the Ministry of Agriculture and national environmental protection portion and standard recommendation, avoids secondary pollution, improve consumption safety reliability etc.
Adopt pure
natural plant sesame oil is as expelling worm active component, avoid the chemical insecticide using high malicious high residue, structural, feature of environmental protection innovation carried out to insecticide formulation, the efficient environment-friendly insecticide products of genuine a new generation.
As the efficient environment-friendly insecticide products of a new generation, advantage: active component complexity can act on multiple organ and the system of insect, 1. easily decomposes; 2. pair pest controling effect is good, nontoxic to person poultry safety, free from environmental pollution, noresidue; 3. pair insect kills and wounds high specificity, does not injure natural enemy and beneficial organism; 4. many factors and composition play a role, and insect and pathogen are difficult to develop immunity to drugs.
In order to realize above-mentioned high-quality characteristic, technical solution of the present invention is mainly made up of following raw and auxiliary material:
Composition: 1. active insecticidal components: pure
natural plants sesame oilcomposite; 2. surfactant: alkynol class Gemini surface active, fatty alcohol ethers, MOA series, fatty acid ester T series; 3. bleeding agent: JFC series; (wetting agent: Tao Shi TRITON X-405, TRITON CF-10, GSK-588/GSK-565); (intercalating agent: organic phosphonate, hydroxycarboxylate, citrate); 4. excipient: pure water or deionized water; 5. solubilizer: alcohol, ether, acetate type; 6. essence, Fragrance Solubilizers is appropriate.
Foundation of the present invention
plant sesame oildevelopment repellent that pest is carried out and the efficiency test of killing effect mechanism and environmental friendly principle thereof, screen with pure
natural plants sesame oilcomposite, sesame oil, citronella oil, lemongrass oil, peppermint oil, wintergreen, distillation citrus seed oil, perilla leaf oil, rosemary oil, oil of badian, camphor oil white, shiu oil, litsea cubeba oil, turpentine oil, eucalyptus oil, Michelia alba leaf oil, Blumea oil, petit grain oil, lemon oil, spearmint oil, lavender oil, anistree leaf oil, fragrant camphor oil, garlic oil, eucalyptus citriodora oil, Java Cananga Oil, eucalyptus oil, thyme linaloe oil, peppermint oil, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS, Aztec marigold wet goods product is many, does not enumerate.
Perform according to the related standards of WHO and the Ministry of Agriculture and Chinese Ministry of Environmental Protection etc., scientific and reasonable configuration mass ratio.Pure
natural plants sesame oilbetween composite mass ratio 0.01 ~ 0.52%.Sesame oil 0.006 ~ 0.01%, or citronella oil 0.01 ~ 0.12%, or lemongrass oil 0.01 ~ 0.1%, or peppermint oil 0.01 ~ 0.2%, or wintergreen 0.001 ~ 0.01%, perilla leaf oil 0.01 ~ 0.1%, rosemary oil 0.01 ~ 0.16%, oil of badian 0.01 ~ 0.1%, camphor oil white 0.01 ~ 0.17%, shiu oil 0.01 ~ 0.1%, litsea cubeba oil 0.01 ~ 0.1%, turpentine oil 0.01 ~ 0.1%, eucalyptus oil 0.01 ~ 0.1%, Michelia alba leaf oil 0.01 ~ 0.16%, Blumea oil 0.01 ~ 0.13%, petit grain oil 0.01 ~ 0.1%, spearmint oil 0.01 ~ 0.2%, lavender oil 0.01 ~ 0.1%, garlic oil 0.01 ~ 0.1%, eucalyptus citriodora oil 0.01 ~ 0.21%, Java Cananga Oil 0.01 ~ 0.1%, thyme linaloe oil 0.01 ~ 0.19%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.01 ~ 0.2%, tagetes oil 0.01 ~ 0.23% grade composite.
Other surfactant, auxiliary agent, selecting of the compositions such as solubilizer and mass ratio: alkynol class Gemini surface active 0.01 ~ 0.12%, or fatty alcohol ethers 0.1 ~ 0.6%, or MOA series 0.1 ~ 0.9%, or fatty acid ester T series 0.1 ~ 1.8%; Or JFC class 0.1 ~ 0.5%; Or alcohols 1 ~ 20%, Tao Shi TRITON X-405,0.001 ~ 0.006%, GSK-588/GSK-565,0.001 ~ 0.006%, or acetate type 1 ~ 10%, or ethers 0.8 ~ 4.2%, organic phosphonate or hydroxycarboxylate or citrate appropriate, or Fragrance Solubilizers is appropriate etc., pure water or deionized water+to 100%.
Be preferably: 1. citronella oil 0.01 ~ 0.12%, or lemongrass oil 0.01 ~ 0.1%, or peppermint oil 0.01 ~ 0.2%, or wintergreen 0.001 ~ 0.01%, perilla leaf oil 0.01 ~ 0.1%, rosemary oil 0.01 ~ 0.16%, spearmint oil 0.01 ~ 0.2%, lavender oil 0.01 ~ 0.1%, garlic oil 0.01 ~ 0.1%, eucalyptus citriodora oil 0.01 ~ 0.21%, Java Cananga Oil 0.01 ~ 0.1%, thyme linaloe oil 0.01 ~ 0.19%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.01 ~ 0.2%, tagetes oil 0.01 ~ 0.23%, alkynol class Gemini surface active 0.01 ~ 0.12%, fatty acid ester T series 0.1 ~ 1.8%, JFC class 0.1 ~ 0.5%, or Silwet 408,0.001 ~ 0.006%, alcohols (comprising edible alcohol) 1 ~ 13%, ethers 0.8 ~ 4.2%, , organic phosphonate is appropriate, and Fragrance Solubilizers is appropriate, pure water or deionized water+and to 100%.
2. each composition and consumption can also be: spearmint oil 0.01 ~ 0.2%, eucalyptus citriodora oil 0.01 ~ 0.21%, peppermint oil 0.01 ~ 0.2%, thyme linaloe oil 0.01 ~ 0.19%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.01 ~ 0.2%, tagetes oil 0.01 ~ 0.23%, alkynol class Gemini surface active 0.01 ~ 0.12%, MOA series 0.1 ~ 0.9%, alcohols 1 ~ 13%, JFC class 0.1 ~ 0.3%, Tao Shi TRITON X-4050.001 ~ 0.004%, hydroxycarboxylate is appropriate, and Fragrance Solubilizers is appropriate, pure water or deionized water+and to 100%.
3. also can select: pyrethrum crude oil 0.01 ~ 026%, thyme linaloe oil 0.01 ~ 0.19%, rosemary oil 0.01 ~ 0.16%, lemongrass oil 0.01 ~ 0.1%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.01 ~ 0.2%, alkynol class Gemini surface active 0.01 ~ 0.12%, fatty alcohol ethers 0.1 ~ 0.6%, JFC class 0.1 ~ 0.3%, alcohols 1 ~ 16%, acetate type 1 ~ 6%, GSK-588/GSK-5650.001 ~ 0.0048%, citrate is appropriate, Fragrance Solubilizers is appropriate, pure water or deionized water+and to 100%.
In strict accordance with the requirement of the World Health Organization and Ministry of Agriculture's Information for pesticide Product Registration, filter out synergy to combine significantly and optimum proportioning, and to its surfactant, the multiple auxiliary agent such as solubilizer carries out screening test, a series of synergy of developing remarkable, stable, have good quick-acting and longer duration and broad spectrum type plant sesame oil that is environmentally friendly, ecological safety composite kill vector insect and corresponding matching tooling.
The applicable conventional plants of composition of the present invention, method are made
the agent of environment-friendly household champignon water-base pesticideseries of products.Described raw and auxiliary material is that plant sesame oil is composite, surfactant, bleeding agent, wetting agent, intercalating agent, excipient, solubilizer, Fragrance Solubilizers are appropriate.
Usage: ceramics furnace and " electronic thermostatic heater " organically combine.Window can be open during use.After electronic thermostatic heater energising, 10 ~ 20min water vapour just to volatilize, about 1h can be distributed equably in room, so it should be at dusk time-division or 1h before sleeping that the best kills the mosquito time, liquid can be vaporized evenly from start to finish completely, keeps stable effect, without remaining waste.
Consumption: ceramic aroma burner adds water, adds
the agent of environment-friendly household champignon water-base pesticide, as guidance: each 5 ~ 20ml, depending on the interior space, residing environment, expelling worm kind and strain are added.
Ceramics furnace and " electronic thermostatic heater " organically combine, and are novel household sanitary insecticide article.
Embodiment
Come by the following examples to illustrate beneficial effect of the present invention further, it should be understood that these embodiments only for the object of illustration, never limit the scope of the invention.
Embodiment one:
1. raw and auxiliary material: spearmint oil 0.16%, eucalyptus citriodora oil 0.1%, peppermint oil 0.2%, thyme linaloe oil 0.12%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.16%, tagetes oil 0.2%, alkynol class Gemini surface active 0.12%, fatty acid ester T series 0.13%, JFC class 0.08%, TRITON CF-100.001%, alcohols (comprising edible alcohol) 10.8%, ethers 0.8%, citrate is appropriate, Fragrance Solubilizers is appropriate, and pure water or deionized water, the percentage summation of above-mentioned raw and auxiliary material is 100%.
2. preparation method: according to Principles of Chemical Engineering and conventional production process, take each plant sesame oil composition by proportioning, first dissolve, auxiliary agent and excipient stir, and total synthesis stirs again, leave standstill, observe it and fully dissolve, and after forming homogeneous phase liquid, can obtain of the present invention
the agent of environment-friendly household champignon water-base pesticideseries of products.
Embodiment two:
A. thyme linaloe oil 0.12% is selected, rosemary oil 0.015%, lemongrass oil 0.1%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.13%, pyrethrum crude oil 0.16%, spices synergist 0.1%, alkynol class Gemini surface active 0.07%, MOA series 0.8%, Tao Shi TRITONX-4050.001%, JFC class 0.18%, alcohols 12%, hydroxycarboxylate is appropriate, Fragrance Solubilizers is appropriate, pure water or deionized water+and to 100%.
B. preparation method: as embodiment one, conventional method and facility, obtained of the present invention
the agent of environment-friendly household champignon water-base pesticideseries of products.
Embodiment three:
A. citronella oil 0.12%, lemongrass oil 0.012%, peppermint oil 0.2%, wintergreen 0.001%, perilla leaf oil 0.1%, rosemary oil 0.014%, spearmint oil 0.18%, lavender oil 0.01%, garlic oil 0.01%, eucalyptus citriodora oil 0.01%, Java Cananga Oil 0.012%, thyme linaloe oil 0.013%, ACTIVITY OF THE RUE OIL AND ANALYSIS OF ITS COMPONENTS 0.015%, tagetes oil 0.2%, fatty acid ester T series 0.1%, MOA series 0.14%, GSK-588/GSK-565, 0.002%, JFC class 0.2%, acetate type 3%, alcohols 9.5%, essence 0.02%, in right amount, organic phosphonate, Fragrance Solubilizers is appropriate, pure water or deionized water+to 100%.
B. preparation method: as product of the present invention obtained described in embodiment one, two.Cylinder method:
the water base pesticide product experiment effect of environment-friendly type champignon family expenses table 1
Evaluate: belong to A level by agriculture chemical registration hygienic insecticide drug effect.
environment-friendly type champignon family expenses water base insecticide series of products experiment effect
table 2
Conclusion: according to the acute toxicity grading criteria of China's agriculture chemical registration toxicology test method, all belongs to micro-(nothing) poison.
Field experiment: select 3rd floors, 10th floors, town and country local-style dwelling houses indoor as mosquito test respectively, area is m more than 20
2, m more than 50
2time-division at dusk, get environment-friendly household champignon water-base pesticide agent 10ml and add the ceramic aroma burner that 360ml water is housed, aroma burner is placed on limit, corner, 12min steam volatilization after energising, door and window opens wide, have wind flow, in 45min ~ 2h, mosquito space fly etc., fallen down successively, All Through The Night does not have mosquito.There is dead 3 of Groton bug for 3rd floors.Dead mosquito is without inspection.
Second night, gets environment-friendly type champignon family expenses water base insecticide 5ml and adds the ceramic aroma burner that 200ml water is housed, aroma burner is placed on limit, corner, 9min steam volatilization after energising, door and window opens wide, and has wind flow, after 45min ~ 1:30h, mosquito has been lacked, and has not had, and All Through The Night does not have mosquito.In 3rd day evening, as the way of second night, All Through The Night does not have mosquito.Find that 1 dead has been done Groton bug for 3rd floors again.
In 4th day evening, do not see mosquito, stop using for 10th floors.3rd floors ways as second night, but the rare mosquito in indoor, the time-division at midnight is stopped using.Fall asleep safely.……
Experimental result shows, in the environment opened wide, environment-friendly household champignon water-base pesticide agent series products of the present invention can kill mosquito, fly, cockroach effectively.
The foregoing is only embodiments of the invention and preparation, explanation that using method is done, be not limited to the present invention, this is to those skilled in the art on basis of the present invention, and it is apparent for making some modifications or improvements it.Therefore, all on the basis of the present invention's spirit and principle and framework, any amendment made, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. environment-friendly household champignon water-base pesticide agent, is characterized in that: the environment-friendly household champignon water-base pesticide agent of obtained homogeneous phase transparent liquid, is supporting application in the organic composition of ceramics furnace and electronic thermostatic heater.Adopt the composite of pure natural plant sesame oil, mass ratio is 0.2 ~ 0.58%; Also has surfactant 1 ~ 1.8%; Bleeding agent 0.1 ~ 0.32%; Solubilizer 3 ~ 20%; Intercalating agent, wetting agent, Fragrance Solubilizers are appropriate; Excipient is pure water or deionized water; The mass percent summation of above-mentioned raw and auxiliary material is 100%.
2. environment-friendly household champignon water-base pesticide according to claim 1 agent, is characterized in that: described insecticide is the composite of pure natural plant source sesame oil.
3. environment-friendly household champignon water-base pesticide according to claim 1 agent, is characterized in that: described surfactant by alkynol class Gemini, nonionic surface active agent composite.
4. environment-friendly household champignon water-base pesticide according to claim 1 agent, is characterized in that: described ceramics furnace and the organic composition of electronic thermostatic heater support the use.
5. the fragrant family expenses of environment-friendly type according to claim 1 smoke water-base pesticide agent, and it is characterized in that: described bleeding agent is JFC series of products, wetting agent is Silwet 408, Tao Shi TRITON X-405, TRITON CF-10.
6. the fragrant family expenses of environment-friendly type according to claim 1 smoke water-base pesticide agent, it is characterized in that: described auxiliary material are intercalating agent is citrate, organic phosphonate, hydroxycarboxylate.
7. the fragrant family expenses of environment-friendly type according to claim 1 smoke water-base pesticide agent, it is characterized in that: described excipient is pure water or deionized water; Solubilizer is alcohols (comprising edible alcohol), ether, acetate type, Fragrance Solubilizers.
8. environment-friendly household champignon water-base pesticide according to claim 1 agent, is characterized in that: the configuration of necessary power line adapter in described application.
9. a method for producing insecticide according to claim 1, is characterized in that it comprises the following steps:
1.. get composite 0.2 ~ 0.58% of pure natural plant sesame oil, solubilizer 3 ~ 20%, Fragrance Solubilizers is appropriate,
2.. water intaking adds surfactant 1 ~ 1.8%, bleeding agent 0.1 ~ 0.32%; Wetting agent, fully to stir, dissolve.
3.. 1. 2. step is added step while stirring, records pH value, take the circumstances into consideration to add intercalating agent, fully stir until obtain the aqueous solution of clear, leave standstill, filter, bottling.The finished product of obtained environment-friendly household champignon water-base pesticide agent.
10. be named and be called: the agent of environment-friendly household champignon water-base pesticide.
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| CN201410341236.1A CN104206456A (en) | 2014-07-18 | 2014-07-18 | Environmental-protective household fragrant water-based pesticide |
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| CN110477002A (en) * | 2019-08-30 | 2019-11-22 | 泉州中翰龙生物科技有限公司 | A kind of environmentally-friendly water-based domestic insecticide aerosol |
| CN112205397A (en) * | 2020-10-13 | 2021-01-12 | 中国烟草总公司海南省公司 | Ant food attractant and application thereof |
| CN113696299A (en) * | 2021-08-31 | 2021-11-26 | 江苏美标家居科技有限公司 | Plant fiber insect-expelling density board |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113696299A (en) * | 2021-08-31 | 2021-11-26 | 江苏美标家居科技有限公司 | Plant fiber insect-expelling density board |
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Application publication date: 20141217 |