CN104119835A - Non-toxic hot-melt adhesive containing bone glue and for bookbinding of notebook - Google Patents
Non-toxic hot-melt adhesive containing bone glue and for bookbinding of notebook Download PDFInfo
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- CN104119835A CN104119835A CN201410291711.9A CN201410291711A CN104119835A CN 104119835 A CN104119835 A CN 104119835A CN 201410291711 A CN201410291711 A CN 201410291711A CN 104119835 A CN104119835 A CN 104119835A
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Abstract
The invention discloses a non-toxic hot-melt adhesive containing bone glue and for bookbinding of a notebook. The hot-melt adhesive is prepared by the following raw materials in parts by weight: 2-4 parts of viscose fibers, 30-40 parts of rosin resin, 1-2 parts of calcium formate, 2-4 parts of dibutyl phthalate, 1-2 parts of carbon nano-tube, 3-5 parts of attapulgite, 3-5 parts of antimonous oxide, 2-4 parts of bone glue, 1-3 parts of tributyl phosphate, 2-4 parts of sisal fibers, 1-2 parts of antioxidant 2246, 1-2 parts of silane coupling agent KH550, 20-30 parts of tackifying resin, and 1-2 parts of dimethicone. The hot-melt adhesive is simple to prepare and excellent in usage effect; by adopting a method for compounding purely plant raw material sisal fibers with chemical components, the damage to a human body can be reduced while the bonding effect is guaranteed.
Description
Technical field
The invention belongs to binding agent field, relate in particular to a kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine.
Background technology
Hot melt adhesive is bonding is to utilize hot melt adhesive machine by heating power, hot melt adhesive to be melted, and the glue after melten gel becomes a kind of liquid, by hot melt pipe and the thermosol gelgun of hot melt adhesive machine, delivers to adherend surface, has completed bonding after hot melt adhesive is cooling.
In our daily life, run into sometimes this situation: paper has just fallen notebook while turning over.Making the hot melt adhesive of making good use of is the quality-guarantee that glue is ordered sheet paper products.
Summary of the invention
The object of this invention is to provide a kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine.
The present invention adopts following technical scheme to achieve these goals:
A kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine, it is characterized in that, it is that raw material by following weight parts makes: viscose fiber 2-4, Gum Rosin 30-40, calcium formiate 1-2, dibutyl phthalate 2-4, carbon nanotube 1-2, attapulgite 3-5, antimonous oxide 3-5, gelatine 2-4, tributyl phosphate 1-3, sisal fibers 2-4, antioxidant 2246 1-2, Silane coupling agent KH550 1-2, tackifying resin 20-30, dimethyl silicone oil 1-2;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, cashew nut shell oil 1-2;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, in 140-150 ℃, stir 10-15min, add clay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 130-150 ℃, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, obtains.
Described a kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine, is characterized in that: preparation method comprises the following steps:
(1) after Gum Rosin, calcium formiate, dibutyl phthalate, carbon nanotube, attapulgite are mixed, 80-90 rev/min is stirred 14-18 minute, then puts into kneader, in 120-135 ℃ of kneading 10-20 minute, must mediate resin standby;
(2) after attapulgite, antimonous oxide, gelatine, tributyl phosphate, sisal fibers, antioxidant 2246 are mixed, add water suitable quantity of water, in 35-42 ℃ of stirring, after 12-19 minute, dry, ball milling 18-27 minute, obtains attapulgite modified, standby;
(3) will mediate resin, attapulgite modified, with and raw material blending after, mediate 10-20 minute in 120-125 ℃, obtain.
Beneficial effect of the present invention: the present invention makes simply, and result of use is good, adopts the composite synthetic method of pure plant material sisal fibers and chemical composition, when guaranteeing bond effect, has reduced the harm to human body.
Embodiment
A nontoxic notebook bookbinding hot melt adhesive that contains gelatine, it is that raw material by following weight (kg) makes: viscose fiber 4, Gum Rosin 40, calcium formiate 1, dibutyl phthalate 4, carbon nanotube 2, attapulgite 5, antimonous oxide 3, gelatine 4, tributyl phosphate 3, sisal fibers 4, antioxidant 2246 1, Silane coupling agent KH550 2, tackifying resin 30, dimethyl silicone oil 2;
Described tackifying resin is made by the raw material of following weight (kg):
Nano-sized carbon 0.3, clay 4, porcelain powder 6, polyvinylpyrrolidone 1, Vaseline 4, oxidized polyethlene wax 1, antioxidant 1010 1, silane coupling agent kh530 1, rosin 8, diacetone-acryloamide(DAA) 0.4, acrylic resin 8, poly(lactic acid) 0.4, water glass 0.2, dioctyl sebacate 1, cashew nut shell oil 1;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, in 150 ℃, stir 15min, add clay, porcelain powder, ball milling 5 minutes, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 150 ℃, stir 20min, add again all the other raw materials, 770 revs/min are stirred 18min, and ball milling 4min, obtains.
Described a kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine, preparation method comprises the following steps:
(1) after Gum Rosin, calcium formiate, dibutyl phthalate, carbon nanotube, attapulgite are mixed, 90 revs/min are stirred 18 minutes, then put into kneader, in 128 ℃ of kneadings 20 minutes, must mediate resin standby;
(2) after attapulgite, antimonous oxide, gelatine, tributyl phosphate, sisal fibers, antioxidant 2246 are mixed, add water suitable quantity of water, in 35 ℃ of stirrings, after 19 minutes, dry, ball milling 18 minutes, obtains attapulgite modified, standby;
(3) will mediate resin, attapulgite modified, with and raw material blending after, mediate 20 minutes in 125 ℃, obtain.
Hot melt adhesive the key technical indexes of the present invention detects as follows:
87 ± 5 ℃ of the softening temperatures of the hot melt adhesive of the present embodiment, stripping strength 66N/2.5cm, initial bonding strength reaches steel ball No. 5, open hour 37s, within 24 hours, thermally-stabilised proterties is stable.
Claims (2)
1. a nontoxic notebook bookbinding hot melt adhesive that contains gelatine, it is characterized in that, it is that raw material by following weight parts makes: viscose fiber 2-4, Gum Rosin 30-40, calcium formiate 1-2, dibutyl phthalate 2-4, carbon nanotube 1-2, attapulgite 3-5, antimonous oxide 3-5, gelatine 2-4, tributyl phosphate 1-3, sisal fibers 2-4, antioxidant 2246 1-2, Silane coupling agent KH550 1-2, tackifying resin 20-30, dimethyl silicone oil 1-2;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, cashew nut shell oil 1-2;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, in 140-150 ℃, stir 10-15min, add clay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 130-150 ℃, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, obtains.
2. a kind of nontoxic notebook bookbinding hot melt adhesive that contains gelatine according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) after Gum Rosin, calcium formiate, dibutyl phthalate, carbon nanotube, attapulgite are mixed, 80-90 rev/min is stirred 14-18 minute, then puts into kneader, in 120-135 ℃ of kneading 10-20 minute, must mediate resin standby;
(2) after attapulgite, antimonous oxide, gelatine, tributyl phosphate, sisal fibers, antioxidant 2246 are mixed, add water suitable quantity of water, in 35-42 ℃ of stirring, after 12-19 minute, dry, ball milling 18-27 minute, obtains attapulgite modified, standby;
(3) will mediate resin, attapulgite modified, with and raw material blending after, mediate 10-20 minute in 120-125 ℃, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291711.9A CN104119835A (en) | 2014-06-26 | 2014-06-26 | Non-toxic hot-melt adhesive containing bone glue and for bookbinding of notebook |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291711.9A CN104119835A (en) | 2014-06-26 | 2014-06-26 | Non-toxic hot-melt adhesive containing bone glue and for bookbinding of notebook |
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| Publication Number | Publication Date |
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| CN104119835A true CN104119835A (en) | 2014-10-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410291711.9A Pending CN104119835A (en) | 2014-06-26 | 2014-06-26 | Non-toxic hot-melt adhesive containing bone glue and for bookbinding of notebook |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104777725A (en) * | 2015-04-17 | 2015-07-15 | 广西藤县通轩立信化学有限公司 | Method for preparing adhesive resin composition for toner |
| CN105176488A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Adhesives for assembling plastic toy |
| CN117050716A (en) * | 2023-09-26 | 2023-11-14 | 上海东睿化学有限公司 | Copolyamide hot melt adhesive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280162A (en) * | 2008-05-29 | 2008-10-08 | 同济大学 | Preparation of low-cost hot-melt adhesive |
| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
| CN103509474A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Book and periodical side glue |
-
2014
- 2014-06-26 CN CN201410291711.9A patent/CN104119835A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280162A (en) * | 2008-05-29 | 2008-10-08 | 同济大学 | Preparation of low-cost hot-melt adhesive |
| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
| CN103509474A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Book and periodical side glue |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104777725A (en) * | 2015-04-17 | 2015-07-15 | 广西藤县通轩立信化学有限公司 | Method for preparing adhesive resin composition for toner |
| CN105176488A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Adhesives for assembling plastic toy |
| CN117050716A (en) * | 2023-09-26 | 2023-11-14 | 上海东睿化学有限公司 | Copolyamide hot melt adhesive and preparation method thereof |
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Application publication date: 20141029 |