CN104119821B - The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder - Google Patents
The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder Download PDFInfo
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- CN104119821B CN104119821B CN201410291646.XA CN201410291646A CN104119821B CN 104119821 B CN104119821 B CN 104119821B CN 201410291646 A CN201410291646 A CN 201410291646A CN 104119821 B CN104119821 B CN 104119821B
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Abstract
Does is the invention discloses the gluing hot melt adhesive special of the notebook that contains graphite powder that a kind of wearability is outstanding, it to be made by the raw material of following weight parts: graphite powder 1-2, carbon fiber 2-4, the bright alkane 0.2-0.4 of epoxy, flyash 4-6, calcium formate 1-2, sulfamic acid 0.2-0.4, zinc chloride 0.1-0.2, bauxite 1-2, styrene 1-2, water-borne acrylic resin 30-35, organic fluorine 30-35, dicyclohexyl phthalate 0.2-0.3, barium mahogany sulfonate 0.3-0.7, antioxidant 1135? 1-2, tackifying resin 10-15; The present invention fills a prescription rationally, good working effect, and production cost is low, is particularly suitable for paper products and uses, and has added graphite powder, carbon fiber, wearability outstanding, not easy to crack.
Description
Technical field
The invention belongs to binding agent field, relate in particular to the notebook that contains graphite powder that a kind of wearability is outstanding gluing specialPUR.
Background technology
PUR is bonding is to utilize hot melt adhesive machine by heating power, PUR to be melted, and the glue after melten gel becomes a kind of liquid,By hot melt pipe and the thermosol gelgun of hot melt adhesive machine, deliver to adherend surface, after PUR is cooling, complete bonding.
In our daily life, run into sometimes this situation: paper has just fallen notebook while turning over. Make to make good use ofPUR is the quality assurance that glue is ordered sheet paper products.
Summary of the invention
The object of this invention is to provide the gluing hot melt adhesive special of the notebook that contains graphite powder that a kind of wearability is outstanding.
The present invention adopts following technical scheme to achieve these goals:
The gluing hot melt adhesive special of notebook that what wearability was outstanding contain graphite powder, is characterized in that, its be by underThe raw material of stating weight portion makes:
Graphite powder 1-2, carbon fiber 2-4, the bright alkane 0.2-0.4 of epoxy, flyash 4-6, calcium formate 1-2, sulfamic acid 0.2-0.4, zinc chloride 0.1-0.2, bauxite 1-2, styrene 1-2, water-borne acrylic resin 30-35, organic fluorine 30-35, neighbourDicyclo-hexyl phthlate 0.2-0.3, barium mahogany sulfonate 0.3-0.7, antioxidant 11351-2, tackifying resin 10-15;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, vaseline 2-4, oxidic polyethyleneWax 1-2, antioxidant 1010 1-2, silane coupler kh5301-2, rosin 8-14, DAAM 0.3-0.4, propyleneAcid resin 5-8, PLA 0.2-0.4, sodium metasilicate 0.1-0.2, di-n-octyl sebacate 1-2, silicone based defoamer 1-2;
Described tackifying resin preparation method is:
After rosin, clay, DAAM, nano-sized carbon are mixed, in 140-150 DEG C of stirring 10-15min, addClay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, vaseline, at 130-150 DEG C, stirMix 10-20min, then add all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
The gluing hot melt adhesive special of the notebook that contains graphite powder that described a kind of wearability is outstanding, is characterized in that: systemPreparation Method comprises the following steps:
(1), after zinc chloride, bauxite, styrene, water-borne acrylic resin are mixed, 200-250 rev/min is stirred 8-12 and dividesClock, then put into kneader, in 155-162 DEG C of kneading 10-15 minute, must mediate resin for subsequent use;
(2) organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, antioxidant 1135, tackifying resin are mixedAfter even, the suitable quantity of water that adds water,, dries after 15-20 minute in 30-35 DEG C of stirring, and ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 20-30 minute in 155-160 DEG C,.
Beneficial effect of the present invention: the present invention fills a prescription rationally, good working effect, production cost is low, is particularly suitable for paper productsUse, added graphite powder, carbon fiber, wearability outstanding, not easy to crack.
Detailed description of the invention
The gluing hot melt adhesive special of notebook that what wearability was outstanding contain graphite powder, it is by following weight (kg)Raw material makes:
Graphite powder 2, carbon fiber 4, the bright alkane 0.4 of epoxy, flyash 6, calcium formate 1, sulfamic acid 0.4, zinc chloride 0.2, aluminiumAlumina 2, styrene 2, water-borne acrylic resin 35, organic fluorine 35, dicyclohexyl phthalate 0.3, barium mahogany sulfonate0.3, antioxidant 11351, tackifying resin 15;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.3, clay 6, porcelain powder 6, polyvinylpyrrolidone 2, vaseline 3, OPE 1.5, antioxidant10101, silane coupler kh5302, rosin 9, DAAM 0.4, acrylic resin 5, PLA 0.4, sodium metasilicate0.2, di-n-octyl sebacate 1, silicone based defoamer 2;
Described tackifying resin preparation method is:
After rosin, clay, DAAM, nano-sized carbon are mixed, in 144 DEG C of stirring 15min, add clay, porcelainPowder, ball milling 4 minutes, then add acrylic resin, polyvinylpyrrolidone, vaseline, at 150 DEG C, stir 20min, then addAll the other raw materials, 760 revs/min are stirred 20min, and ball milling 4min, to obtain final product.
The gluing hot melt adhesive special of the notebook that contains graphite powder that described a kind of wearability is outstanding, preparation method comprise withLower step:
(1), after zinc chloride, bauxite, styrene, water-borne acrylic resin are mixed, 250 revs/min are stirred 12 minutes, thenPut into kneader, in 162 DEG C of kneadings 12 minutes, must mediate resin for subsequent use;
(2) organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, antioxidant 1135, tackifying resin are mixedAfter even, the suitable quantity of water that adds water,, dries after 20 minutes in 33 DEG C of stirrings, and ball milling 12 minutes, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 30 minutes in 157 DEG C, to obtain final product.
PUR the key technical indexes of the present invention detects as follows:
88 ± 5 DEG C of the softening points of the PUR of the present embodiment, peel strength 66N/2.5cm, initial bonding strength reaches steel ball No. 5,Open hour 39s, within 24 hours, thermally-stabilised proterties is stable.
Claims (2)
1. the gluing hot melt adhesive special of the notebook that contains graphite powder that wearability is outstanding, is characterized in that, it is by followingThe raw material of weight portion makes: graphite powder 1-2, carbon fiber 2-4, expoxy propane 0.2-0.4, flyash 4-6, calcium formate 1-2, aminoSulfonic acid 0.2-0.4, zinc chloride 0.1-0.2, bauxite 1-2, styrene 1-2, water-borne acrylic resin 30-35, organic fluorine30-35, dicyclohexyl phthalate 0.2-0.3, barium mahogany sulfonate 0.3-0.7, antioxidant 11351-2, tackifying resin 10-15；
Described tackifying resin is made by the raw material of following weight parts: nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, poly-secondAlkene pyrrolidone 1-2, vaseline 2-4, OPE 1-2, antioxidant 1010 1-2, silane coupler kh5301-2, pineFragrant 8-14, DAAM 0.3-0.4, acrylic resin 5-8, PLA 0.2-0.4, sodium metasilicate 0.1-0.2, decanedioic acidDioctyl ester 1-2, silicone based defoamer 1-2; Described tackifying resin preparation method is: by rosin, clay, diacetone propyleneAfter acid amides, nano-sized carbon mix, in 140-150 DEG C of stirring 10-15min, add porcelain powder, ball milling 3-5 minute, then add acrylic acid treeFat, polyvinylpyrrolidone, vaseline stir 10-20min at 130-150 DEG C, then add all the other raw materials, 700-800 turn/Divide and stir 15-20min, ball milling 4-6min, to obtain final product.
2. the gluing hot melt adhesive special of the notebook that contains graphite powder that a kind of wearability according to claim 1 is outstanding, itsBe characterised in that: preparation method comprises the following steps:
(1), after zinc chloride, bauxite, styrene, water-borne acrylic resin are mixed, 200-250 rev/min is stirred 8-12 minute,Put into again kneader, in 155-162 DEG C of kneading 10-15 minute, must mediate resin for subsequent use;
(2) organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, antioxidant 1135, tackifying resin are mixedAfter, add water appropriate,, after 15-20 minute, to dry in 30-35 DEG C of stirring, ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) after kneading resin, modified resin powder and other surplus stocks are mixed, in 155-160 DEG C of kneading 20-30 minute,Obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291646.XA CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291646.XA CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119821A CN104119821A (en) | 2014-10-29 |
| CN104119821B true CN104119821B (en) | 2016-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410291646.XA Expired - Fee Related CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
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| CN (1) | CN104119821B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500472A (en) * | 1995-02-17 | 1996-03-19 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| CN101684400A (en) * | 2009-08-26 | 2010-03-31 | 安徽邦宁节能建材有限公司 | macromolecular multifunctional binder |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
-
2014
- 2014-06-26 CN CN201410291646.XA patent/CN104119821B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500472A (en) * | 1995-02-17 | 1996-03-19 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| CN101684400A (en) * | 2009-08-26 | 2010-03-31 | 安徽邦宁节能建材有限公司 | macromolecular multifunctional binder |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
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| Publication number | Publication date |
|---|---|
| CN104119821A (en) | 2014-10-29 |
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Granted publication date: 20160518 Termination date: 20180626 |