CN104119822B - The gluing hot melt adhesive special of a kind of low smell notebook - Google Patents
The gluing hot melt adhesive special of a kind of low smell notebook Download PDFInfo
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- CN104119822B CN104119822B CN201410291676.0A CN201410291676A CN104119822B CN 104119822 B CN104119822 B CN 104119822B CN 201410291676 A CN201410291676 A CN 201410291676A CN 104119822 B CN104119822 B CN 104119822B
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- resin
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- antioxidant
- notebook
- hot melt
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Abstract
The invention discloses the gluing hot melt adhesive special of a kind of low smell notebook, it is to be made by the raw material of following weight parts: AEO 1.2-2.3, polyacrylamide 1-2, hide glue 2-4, isomerous tridecanol polyoxyethylene ether 0.2-0.4, butanedioic acid monoglyceride 0.5-0.8, butyl acrylate 0.1-0.3, cupric oxide 0.1-0.2, zinc chloride 1-2, eucalyptus oil 2-4, starch 1-2, tackifying resin 10-15, hexamethylenetetramine 1-2, acrylic resin 60-70, EVA10-20, IPDI 1-2, Tripolyglycerol monostearates 0.1-0.2, di-n-octyl sebacate 0.1-0.2, antioxidant 264? 0.2-0.4, antioxidant T501? 0.2-0.5, environment protection health of the present invention, not chafe, does not have penetrating odor, in production process, uses, safe ready, viscosity is strong simultaneously.
Description
Technical field
The invention belongs to binding agent field, relate in particular to the gluing hot melt adhesive special of a kind of low smell notebook.
Background technology
PUR is bonding is to utilize hot melt adhesive machine by heating power, PUR to be melted, and the glue after melten gel becomes a kind of liquid,By hot melt pipe and the thermosol gelgun of hot melt adhesive machine, deliver to adherend surface, after PUR is cooling, complete bonding.
In our daily life, run into sometimes this situation: paper has just fallen notebook while turning over. Make to make good use ofPUR is the quality assurance that glue is ordered sheet paper products.
Summary of the invention
The object of this invention is to provide the gluing hot melt adhesive special of a kind of low smell notebook.
The present invention adopts following technical scheme to achieve these goals:
The gluing hot melt adhesive special of a kind of low smell notebook, is characterized in that, it is to be made by the raw material of following weight parts:AEO 1.2-2.3, polyacrylamide 1-2, hide glue 2-4, isomerous tridecanol polyoxyethylene ether 0.2-0.4, amberAmber acid monoglyceride 0.5-0.8, butyl acrylate 0.1-0.3, cupric oxide 0.1-0.2, zinc chloride 1-2, eucalyptus oil 2-4, starch 1-2, tackifying resin 10-15, hexamethylenetetramine 1-2, acrylic resin 60-70, EVA10-20, IPDI 1-2, Tripolyglycerol monostearates 0.1-0.2, di-n-octyl sebacate 0.1-0.2, antioxidant 264 0.2-0.4, antioxidant T5010.2-0.5；
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, vaseline 2-4, oxidic polyethyleneWax 1-2, antioxidant 1010 1-2, silane coupler kh5301-2, rosin 8-14, DAAM 0.3-0.4, propyleneAcid resin 5-8, PLA 0.2-0.4, sodium metasilicate 0.1-0.2, di-n-octyl sebacate 1-2, silicone based defoamer 1-2;
Described tackifying resin preparation method is:
After rosin, clay, DAAM, nano-sized carbon are mixed, in 140-150 DEG C of stirring 10-15min, addClay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, vaseline, at 130-150 DEG C, stirMix 10-20min, then add all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
The gluing hot melt adhesive special of the low smell notebook of described one, is characterized in that: preparation method comprises the following steps:
(1) butanedioic acid monoglyceride, butyl acrylate, cupric oxide, zinc chloride, eucalyptus oil, starch, tackifying resin are mixedAfter, 800-900 rev/min is stirred 20-28 minute, then puts into kneader, in 150-162 DEG C of kneading 10-20 minute, must mediate treeFat is for subsequent use;
(2) acrylic resin, EVA, IPDI, Tripolyglycerol monostearates, decanedioic acid two is pungentAfter ester, antioxidant 264 mix, the suitable quantity of water that adds water,, dries after 10-20 minute in 30-35 DEG C of stirring, ball milling 15-17 minute,Modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 12-17 minute in 150-160 DEG C,.
Beneficial effect of the present invention:
Environment protection health of the present invention, not chafe, does not have penetrating odor, in production process, uses, safe ready, simultaneouslyViscosity is strong.
Detailed description of the invention
The gluing hot melt adhesive special of a kind of low smell notebook, it is to be made by the raw material of following weight (kg): poly alkyl alcoholOxygen vinethene 1.3, polyacrylamide 1.2, hide glue 4, isomerous tridecanol polyoxyethylene ether 0.4, butanedioic acid monoglyceride 0.5, propyleneAcid butyl ester 0.3, cupric oxide 0.2, zinc chloride 1, eucalyptus oil 4, starch 2, tackifying resin 15, hexamethylenetetramine 2, acrylic resin70, EVA20, IPDI 2, Tripolyglycerol monostearates 0.2, di-n-octyl sebacate 0.2, antioxidant 2640.2, antioxidant T5010.2;
Described tackifying resin is made by the raw material of following weight (kg):
Nano-sized carbon 0.1, clay 6, porcelain powder 6, polyvinylpyrrolidone 1, vaseline 2, OPE 2, antioxidant10101, silane coupler kh5301, rosin 10, DAAM 0.3, acrylic resin 5, PLA 0.4, silicic acidSodium 0.2, di-n-octyl sebacate 1.8, silicone based defoamer 2;
Described tackifying resin preparation method is:
After rosin, clay, DAAM, nano-sized carbon are mixed, in 140 DEG C of stirring 15min, add clay, porcelainPowder, ball milling 3 minutes, then add acrylic resin, polyvinylpyrrolidone, vaseline, at 150 DEG C, stir 20min, then addAll the other raw materials, 800 revs/min are stirred 20min, and ball milling 6min, to obtain final product.
The gluing hot melt adhesive special of the low smell notebook of described one, preparation method comprises the following steps:
(1) butanedioic acid monoglyceride, butyl acrylate, cupric oxide, zinc chloride, eucalyptus oil, starch, tackifying resin are mixedAfter, 900 revs/min are stirred 28 minutes, then put into kneader, in 162 DEG C of kneadings 20 minutes, must mediate resin for subsequent use;
(2) acrylic resin, EVA, IPDI, Tripolyglycerol monostearates, decanedioic acid two is pungentAfter ester, antioxidant 264 mix, the suitable quantity of water that adds water,, dries after 20 minutes in 35 DEG C of stirrings, and ball milling 15 minutes, obtains modified resinPowder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 15 minutes in 160 DEG C, to obtain final product.
PUR the key technical indexes of the present invention detects as follows:
84 ± 5 DEG C of the softening points of the PUR of the present embodiment, peel strength 64N/2.5cm, initial bonding strength reaches steel ball No. 5,Open hour 39s, within 24 hours, thermally-stabilised proterties is stable.
Claims (2)
1. the gluing hot melt adhesive special of low smell notebook, is characterized in that, it is to be made by the raw material of following weight parts: fatFat alcohol APEO 1.2-2.3, polyacrylamide 1-2, hide glue 2-4, isomerous tridecanol polyoxyethylene ether 0.2-0.4, amberAcid monoglyceride 0.5-0.8, butyl acrylate 0.1-0.3, cupric oxide 0.1-0.2, zinc chloride 1-2, eucalyptus oil 2-4, starch 1-2,Tackifying resin 10-15, hexamethylenetetramine 1-2, acrylic resin 60-70, EVA10-20, IPDI 1-2,Tripolyglycerol monostearates 0.1-0.2, di-n-octyl sebacate 0.1-0.2, antioxidant 264 0.2-0.4, antioxidant T5010.2-0.5; Described tackifying resin is made by the raw material of following weight parts: nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6,Polyvinylpyrrolidone 1-2, vaseline 2-4, OPE 1-2, antioxidant 1010 1-2, silane coupler kh5301-2, rosin 8-14, DAAM 0.3-0.4, acrylic resin 5-8, PLA 0.2-0.4, sodium metasilicate 0.1-0.2, the last of the ten Heavenly stemsTwo dioctyl phthalate 1-2, silicone based defoamer 1-2; Described tackifying resin preparation method is: by rosin, clay, diacetoneAfter acrylamide, nano-sized carbon mix, in 140-150 DEG C of stirring 10-15min, add porcelain powder, ball milling 3-5 minute, then add propyleneAcid resin, polyvinylpyrrolidone, vaseline stir 10-20min at 130-150 DEG C, then add all the other raw materials, 700-800Rev/min stir 15-20min, ball milling 4-6min, to obtain final product.
2. the gluing hot melt adhesive special of the low smell notebook of one according to claim 1, is characterized in that: preparation method's bagDraw together following steps:
(1) after butanedioic acid monoglyceride, butyl acrylate, cupric oxide, zinc chloride, eucalyptus oil, starch, tackifying resin are mixed,800-900 rev/min is stirred 20-28 minute, then puts into kneader, in 150-162 DEG C of kneading 10-20 minute, obtains kneading resinFor subsequent use;
(2) by acrylic resin, EVA, IPDI, Tripolyglycerol monostearates, di-n-octyl sebacate, anti-After oxygen agent 264 mixes, add water appropriate,, after 10-20 minute, dry in 30-35 DEG C of stirring, ball milling 15-17 minute, obtains modification treeCosmetics, for subsequent use;
(3) after kneading resin, modified resin powder and other surplus stocks are mixed, in 150-160 DEG C of kneading 12-17 minute,Obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291676.0A CN104119822B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of a kind of low smell notebook |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291676.0A CN104119822B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of a kind of low smell notebook |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119822A CN104119822A (en) | 2014-10-29 |
| CN104119822B true CN104119822B (en) | 2016-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410291676.0A Expired - Fee Related CN104119822B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of a kind of low smell notebook |
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| Country | Link |
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| CN (1) | CN104119822B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0301867A2 (en) * | 1987-07-31 | 1989-02-01 | Shell Oil Company | Hot melt adhesives |
| CN102433087A (en) * | 2011-08-29 | 2012-05-02 | 华南理工大学 | High-temperature-resistant paper-plastic laminating adhesive and preparation method thereof |
| CN103571380A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Hot melt adhesive with low odor |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120176A (en) * | 1991-07-29 | 1992-06-09 | Dennison Manufacturing Company | Fabrication of bound documents |
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2014
- 2014-06-26 CN CN201410291676.0A patent/CN104119822B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0301867A2 (en) * | 1987-07-31 | 1989-02-01 | Shell Oil Company | Hot melt adhesives |
| CN102433087A (en) * | 2011-08-29 | 2012-05-02 | 华南理工大学 | High-temperature-resistant paper-plastic laminating adhesive and preparation method thereof |
| CN103571380A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Hot melt adhesive with low odor |
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| Publication number | Publication date |
|---|---|
| CN104119822A (en) | 2014-10-29 |
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