CN104119818A - Vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding - Google Patents

Vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding Download PDF

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Publication number
CN104119818A
CN104119818A CN201410291282.5A CN201410291282A CN104119818A CN 104119818 A CN104119818 A CN 104119818A CN 201410291282 A CN201410291282 A CN 201410291282A CN 104119818 A CN104119818 A CN 104119818A
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CN
China
Prior art keywords
parts
hot melt
melt adhesive
resin
minute
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Pending
Application number
CN201410291282.5A
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Chinese (zh)
Inventor
赵强
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ANHUI TUQIANG STATIONERY MANUFACTURING Co Ltd
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ANHUI TUQIANG STATIONERY MANUFACTURING Co Ltd
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Priority to CN201410291282.5A priority Critical patent/CN104119818A/en
Publication of CN104119818A publication Critical patent/CN104119818A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding. The hot melt adhesive is prepared from the following raw materials in parts by weight: 1-2 parts of polyvinyl alcohol, 0.2-0.4 part of stearic acid, 1-2 parts of oxidized starch, 1-2 parts of cashew nut shell oil, 2-4 parts of ammonium persulfate, 0.2-0.4 part of humic acid, 1-2 parts of chitosan, 3-5 parts of guar gum, 1-2 parts of sodium oleate, 1-2 parts of nonylphenol polyoxyethylene ether, 1-2 parts of sodium carbonate, 3-5 parts of vermiculite powder, 1-2 parts of sodium carbonate, 1-2 parts of vinyl acetate, 10-20 parts of polyester resin, 40-50 parts of chloroprene rubber, 1-2 parts of an antioxidant 168, 0.2-0.4 part of chlorinated paraffin and 3-5 parts of tackifying resin. The hot melt adhesive provided by the invention is convenient, sanitary and good in adhesiveness; the phenomena of drip leakage, diffusion and permeation cannot be caused when the hot melt adhesive is used.

Description

A kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power
Technical field
The invention belongs to binding agent field, relate in particular to a kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power.
Background technology
Hot melt adhesive is bonding is to utilize hot melt adhesive machine by heating power, hot melt adhesive to be melted, and the glue after melten gel becomes a kind of liquid, by hot melt pipe and the thermosol gelgun of hot melt adhesive machine, delivers to adherend surface, has completed bonding after hot melt adhesive is cooling.
In our daily life, run into sometimes this situation: paper has just fallen notebook while turning over.Making the hot melt adhesive of making good use of is the quality-guarantee that glue is ordered sheet paper products.
Summary of the invention
The object of this invention is to provide a kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power.
The present invention adopts following technical scheme to achieve these goals:
A kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power, it is characterized in that, it is to be made by the raw material of following weight parts: polyvinyl alcohol 1-2, stearic acid 0.2-0.4, Sumstar 190 1-2, cashew nut shell oil 1-2, ammonium persulphate 2-4, humic acid 0.2-0.4, chitosan 1-2, guar gum 3-5, sodium oleate 1-2, polyoxyethylene nonylphenol ether 1-2, sodium carbonate 1-2, vermiculite power 3-5, sodium carbonate 1-2, vinyl-acetic ester 1-2, vibrin 10-20, chloroprene rubber 40-50, irgasfos 168 1-2, clorafin 0.2-0.4, tackifying resin 3-5;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, coumarone indene resin 1-2;
Tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 10-15min in 140-150 DEG C, add clay, porcelain powder, ball milling 3-5 minute, then add water glass, polyvinylpyrrolidone, Vaseline, at 130-150 DEG C, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
Described a kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power, is characterized in that: preparation method comprises the following steps:
(1) after polyvinyl alcohol, stearic acid, Sumstar 190, cashew nut shell oil, chloroprene rubber, irgasfos 168 are mixed, 400-500 rev/min is stirred 8-12 minute, then puts into kneader, in 160-165 DEG C of kneading 18-22 minute, must mediate resin for subsequent use;
(2) by after vermiculite power, sodium carbonate, vinyl-acetic ester, vibrin, humic acid, chitosan, guar gum, the suitable quantity of water that adds water,, dries after 15-20 minute in 35-39 DEG C of stirring, and ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 20-30 minute in 150-155 DEG C, to obtain final product.
Beneficial effect of the present invention:
Hot melt adhesive provided by the invention is convenient and healthy, cohesiveness good, and water clock, diffusion and phenomenon of osmosis can not occur when use.
Embodiment
A quick-drying notebook bonding hot melt adhesive that contains vermiculite power, it is to be made by the raw material of following weight (kg): polyvinyl alcohol 1, stearic acid 0.4, Sumstar 190 1, cashew nut shell oil 1, ammonium persulphate 4, humic acid 0.4, chitosan 2, guar gum 5, sodium oleate 1, polyoxyethylene nonylphenol ether 1, sodium carbonate 1, vermiculite power 5, sodium carbonate 2, vinyl-acetic ester 1, vibrin 20, chloroprene rubber 40, irgasfos 168 2, clorafin 0.4, tackifying resin 4;
Described tackifying resin is made by the raw material of following weight (kg):
Nano-sized carbon 0.3, clay 6, porcelain powder 4, polyvinylpyrrolidone 1, Vaseline 2, oxidized polyethlene wax 2, antioxidant 1010 1, silane coupling agent kh530 1, rosin 14, diacetone-acryloamide(DAA) 0.4, acrylic resin 8, poly(lactic acid) 0.4, water glass 0.1, dioctyl sebacate 2, coumarone indene resin 1;
Tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 15min in 150 DEG C, add clay, porcelain powder, ball milling 5 minutes, then add water glass, polyvinylpyrrolidone, Vaseline, at 150 DEG C, stir 20min, add again all the other raw materials, 800 revs/min are stirred 20min, and ball milling 4min, to obtain final product.
Described a kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power, preparation method comprises the following steps:
(1) after polyvinyl alcohol, stearic acid, Sumstar 190, cashew nut shell oil, chloroprene rubber, irgasfos 168 are mixed, 500 revs/min are stirred 12 minutes, then put into kneader, in 160 DEG C of kneadings 20 minutes, must mediate resin for subsequent use;
(2) by after vermiculite power, sodium carbonate, vinyl-acetic ester, vibrin, humic acid, chitosan, guar gum, the suitable quantity of water that adds water,, dries after 20 minutes in 35 DEG C of stirrings, and ball milling 12 minutes, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 25 minutes in 155 DEG C, to obtain final product.
Hot melt adhesive the key technical indexes of the present invention detects as follows:
80 ± 5 DEG C of the softening temperatures of the hot melt adhesive of the present embodiment, stripping strength 63N/2.5cm, initial bonding strength reaches steel ball No. 5, open hour 37s, within 24 hours, thermally-stabilised proterties is stable.

Claims (2)

1. a quick-drying notebook bonding hot melt adhesive that contains vermiculite power, it is characterized in that, it is to be made by the raw material of following weight parts: polyvinyl alcohol 1-2, stearic acid 0.2-0.4, Sumstar 190 1-2, cashew nut shell oil 1-2, ammonium persulphate 2-4, humic acid 0.2-0.4, chitosan 1-2, guar gum 3-5, sodium oleate 1-2, polyoxyethylene nonylphenol ether 1-2, sodium carbonate 1-2, vermiculite power 3-5, sodium carbonate 1-2, vinyl-acetic ester 1-2, vibrin 10-20, chloroprene rubber 40-50, irgasfos 168 1-2, clorafin 0.2-0.4, tackifying resin 3-5;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, coumarone indene resin 1-2;
Tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 10-15min in 140-150 DEG C, add clay, porcelain powder, ball milling 3-5 minute, then add water glass, polyvinylpyrrolidone, Vaseline, at 130-150 DEG C, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
2. a kind of quick-drying notebook bonding hot melt adhesive that contains vermiculite power according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) after polyvinyl alcohol, stearic acid, Sumstar 190, cashew nut shell oil, chloroprene rubber, irgasfos 168 are mixed, 400-500 rev/min is stirred 8-12 minute, then puts into kneader, in 160-165 DEG C of kneading 18-22 minute, must mediate resin for subsequent use;
(2) by after vermiculite power, sodium carbonate, vinyl-acetic ester, vibrin, humic acid, chitosan, guar gum, the suitable quantity of water that adds water,, dries after 15-20 minute in 35-39 DEG C of stirring, and ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 20-30 minute in 150-155 DEG C, to obtain final product.
CN201410291282.5A 2014-06-26 2014-06-26 Vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding Pending CN104119818A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410291282.5A CN104119818A (en) 2014-06-26 2014-06-26 Vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410291282.5A CN104119818A (en) 2014-06-26 2014-06-26 Vermiculite powder-containing quick-drying hot melt adhesive for notebook bonding

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CN104119818A true CN104119818A (en) 2014-10-29

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286864A (en) * 2017-06-26 2017-10-24 佛山市绿葵环保科技有限公司 A kind of industrial modified starch binder of environmentally friendly green non-pollution and its manufacturing process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280162A (en) * 2008-05-29 2008-10-08 同济大学 Preparation of low-cost hot-melt adhesive
CN102925080A (en) * 2012-11-29 2013-02-13 无锡市万力粘合材料有限公司 Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof
CN103468171A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Hot melt adhesive used for automobile interior decoration parts
CN103509474A (en) * 2013-09-18 2014-01-15 滁州市光威化工有限公司 Book and periodical side glue

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280162A (en) * 2008-05-29 2008-10-08 同济大学 Preparation of low-cost hot-melt adhesive
CN102925080A (en) * 2012-11-29 2013-02-13 无锡市万力粘合材料有限公司 Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof
CN103468171A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Hot melt adhesive used for automobile interior decoration parts
CN103509474A (en) * 2013-09-18 2014-01-15 滁州市光威化工有限公司 Book and periodical side glue

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286864A (en) * 2017-06-26 2017-10-24 佛山市绿葵环保科技有限公司 A kind of industrial modified starch binder of environmentally friendly green non-pollution and its manufacturing process

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Application publication date: 20141029