CN104119821A - Special hot melt adhesive containing graphite powder and having outstanding wear resistance for notebook gluing - Google Patents
Special hot melt adhesive containing graphite powder and having outstanding wear resistance for notebook gluing Download PDFInfo
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- CN104119821A CN104119821A CN201410291646.XA CN201410291646A CN104119821A CN 104119821 A CN104119821 A CN 104119821A CN 201410291646 A CN201410291646 A CN 201410291646A CN 104119821 A CN104119821 A CN 104119821A
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Abstract
The invention discloses a special hot melt adhesive containing graphite powder and having outstanding wear resistance for notebook gluing. The special hot melt adhesive is prepared from the raw materials in parts by weight: 1-2 parts of graphite powder, 2-4 parts of carbon fiber, 0.2-0.4 part of propylene oxide, 4-6 parts of fly ash, 1-2 parts of calcium formate, 0.2-0.4 part of sulfamic acid, 0.1-0.2 part of zinc chloride, 1-2 parts of bauxite, 1-2 parts of styrene, 30-35 parts of waterborne acrylic resin, 30-35 parts of organic fluorine, 0.2-0.3 part of dicyclohexyl phthalate, 0.3-0.7 part of barium petroleum sulfonate, 1-2 parts of antioxidant 1135 and 10-15 parts of tackifying resin. The special hot melt adhesive is reasonable in recipe, is good in the working effect, is low in the production cost and is particularly suitable for paper products to use; after being added with the graphite powder and the carbon fiber, the special hot melt adhesive is outstanding in the wear resistance and has small possibility of cracking.
Description
Technical field
The invention belongs to binding agent field, relate in particular to the gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that a kind of wear resistance is outstanding.
Background technology
Hot melt adhesive is bonding is to utilize hot melt adhesive machine by heating power, hot melt adhesive to be melted, and the glue after melten gel becomes a kind of liquid, by hot melt pipe and the thermosol gelgun of hot melt adhesive machine, delivers to adherend surface, has completed bonding after hot melt adhesive is cooling.
In our daily life, run into sometimes this situation: paper has just fallen notebook while turning over.Making the hot melt adhesive of making good use of is the quality-guarantee that glue is ordered sheet paper products.
Summary of the invention
The object of this invention is to provide the gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that a kind of wear resistance is outstanding.
The present invention adopts following technical scheme to achieve these goals:
The gluing hot melt adhesive special of notebook that what wear resistance was outstanding contain Graphite Powder 99, is characterized in that, it is to be made by the raw material of following weight parts:
Graphite Powder 99 1-2, carbon fiber 2-4, the bright alkane 0.2-0.4 of epoxy, flyash 4-6, calcium formiate 1-2, thionamic acid 0.2-0.4, zinc chloride 0.1-0.2, bauxitic clay 1-2, vinylbenzene 1-2, water-borne acrylic resin 30-35, organic fluorine 30-35, dicyclohexyl phthalate 0.2-0.3, barium mahogany sulfonate 0.3-0.7, oxidation inhibitor 1135 1-2, tackifying resin 10-15;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, silicone based defoamer 1-2;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 10-15min in 140-150 DEG C, add clay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 130-150 DEG C, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
The gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that described a kind of wear resistance is outstanding, is characterized in that: preparation method comprises the following steps:
(1) after zinc chloride, bauxitic clay, vinylbenzene, water-borne acrylic resin are mixed, 200-250 rev/min is stirred 8-12 minute, then puts into kneader, in 155-162 DEG C of kneading 10-15 minute, must mediate resin for subsequent use;
(2) after organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, oxidation inhibitor 1135, tackifying resin are mixed, the suitable quantity of water that adds water,, dries after 15-20 minute in 30-35 DEG C of stirring, and ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 20-30 minute in 155-160 DEG C, to obtain final product.
Beneficial effect of the present invention: the present invention fills a prescription rationally, good working effect, production cost is low, is particularly suitable for paper product and uses, and has added Graphite Powder 99, carbon fiber, wear resistance outstanding, not easy to crack.
Embodiment
The gluing hot melt adhesive special of notebook that what wear resistance was outstanding contain Graphite Powder 99, it is to be made by the raw material of following weight (kg):
Graphite Powder 99 2, carbon fiber 4, the bright alkane 0.4 of epoxy, flyash 6, calcium formiate 1, thionamic acid 0.4, zinc chloride 0.2, bauxitic clay 2, vinylbenzene 2, water-borne acrylic resin 35, organic fluorine 35, dicyclohexyl phthalate 0.3, barium mahogany sulfonate 0.3, oxidation inhibitor 1,135 1, tackifying resin 15;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.3, clay 6, porcelain powder 6, polyvinylpyrrolidone 2, Vaseline 3, oxidized polyethlene wax 1.5, antioxidant 1010 1, silane coupling agent kh530 2, rosin 9, diacetone-acryloamide(DAA) 0.4, acrylic resin 5, poly(lactic acid) 0.4, water glass 0.2, dioctyl sebacate 1, silicone based defoamer 2;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 15min in 144 DEG C, add clay, porcelain powder, ball milling 4 minutes, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 150 DEG C, stir 20min, add again all the other raw materials, 760 revs/min are stirred 20min, and ball milling 4min, to obtain final product.
The gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that described a kind of wear resistance is outstanding, preparation method comprises the following steps:
(1) after zinc chloride, bauxitic clay, vinylbenzene, water-borne acrylic resin are mixed, 250 revs/min are stirred 12 minutes, then put into kneader, in 162 DEG C of kneadings 12 minutes, must mediate resin for subsequent use;
(2) after organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, oxidation inhibitor 1135, tackifying resin are mixed, the suitable quantity of water that adds water,, dries after 20 minutes in 33 DEG C of stirrings, and ball milling 12 minutes, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 30 minutes in 157 DEG C, to obtain final product.
Hot melt adhesive the key technical indexes of the present invention detects as follows:
88 ± 5 DEG C of the softening temperatures of the hot melt adhesive of the present embodiment, stripping strength 66N/2.5cm, initial bonding strength reaches steel ball No. 5, open hour 39s, within 24 hours, thermally-stabilised proterties is stable.
Claims (2)
1. the gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that wear resistance is outstanding, is characterized in that, it is to be made by the raw material of following weight parts:
Graphite Powder 99 1-2, carbon fiber 2-4, the bright alkane 0.2-0.4 of epoxy, flyash 4-6, calcium formiate 1-2, thionamic acid 0.2-0.4, zinc chloride 0.1-0.2, bauxitic clay 1-2, vinylbenzene 1-2, water-borne acrylic resin 30-35, organic fluorine 30-35, dicyclohexyl phthalate 0.2-0.3, barium mahogany sulfonate 0.3-0.7, oxidation inhibitor 1135 1-2, tackifying resin 10-15;
Described tackifying resin is made by the raw material of following weight parts:
Nano-sized carbon 0.1-0.3, clay 4-6, porcelain powder 4-6, polyvinylpyrrolidone 1-2, Vaseline 2-4, oxidized polyethlene wax 1-2, antioxidant 1010 1-2, silane coupling agent kh530 1-2, rosin 8-14, diacetone-acryloamide(DAA) 0.3-0.4, acrylic resin 5-8, poly(lactic acid) 0.2-0.4, water glass 0.1-0.2, dioctyl sebacate 1-2, silicone based defoamer 1-2;
Described tackifying resin preparation method is:
After rosin, clay, diacetone-acryloamide(DAA), nano-sized carbon are mixed, stir 10-15min in 140-150 DEG C, add clay, porcelain powder, ball milling 3-5 minute, then add acrylic resin, polyvinylpyrrolidone, Vaseline, at 130-150 DEG C, stir 10-20min, add again all the other raw materials, 700-800 rev/min is stirred 15-20min, and ball milling 4-6min, to obtain final product.
2. the gluing hot melt adhesive special of the notebook that contains Graphite Powder 99 that a kind of wear resistance according to claim 1 is outstanding, is characterized in that: preparation method comprises the following steps:
(1) after zinc chloride, bauxitic clay, vinylbenzene, water-borne acrylic resin are mixed, 200-250 rev/min is stirred 8-12 minute, then puts into kneader, in 155-162 DEG C of kneading 10-15 minute, must mediate resin for subsequent use;
(2) after organic fluorine, dicyclohexyl phthalate, barium mahogany sulfonate, oxidation inhibitor 1135, tackifying resin are mixed, the suitable quantity of water that adds water,, dries after 15-20 minute in 30-35 DEG C of stirring, and ball milling 8-12 minute, obtains modified resin powder, for subsequent use;
(3) will mediate resin, modified resin powder, with and raw material blending after, mediate 20-30 minute in 155-160 DEG C, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291646.XA CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410291646.XA CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119821A true CN104119821A (en) | 2014-10-29 |
| CN104119821B CN104119821B (en) | 2016-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410291646.XA Expired - Fee Related CN104119821B (en) | 2014-06-26 | 2014-06-26 | The gluing hot melt adhesive special of notebook that what a kind of wearability was outstanding contain graphite powder |
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| Country | Link |
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| CN (1) | CN104119821B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500472A (en) * | 1995-02-17 | 1996-03-19 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| CN101684400A (en) * | 2009-08-26 | 2010-03-31 | 安徽邦宁节能建材有限公司 | macromolecular multifunctional binder |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
-
2014
- 2014-06-26 CN CN201410291646.XA patent/CN104119821B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500472A (en) * | 1995-02-17 | 1996-03-19 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| CN101684400A (en) * | 2009-08-26 | 2010-03-31 | 安徽邦宁节能建材有限公司 | macromolecular multifunctional binder |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
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| Publication number | Publication date |
|---|---|
| CN104119821B (en) | 2016-05-18 |
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Granted publication date: 20160518 Termination date: 20180626 |
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| CF01 | Termination of patent right due to non-payment of annual fee |