CN104114278A - 基于非贵金属的氢化硅烷化催化剂 - Google Patents

基于非贵金属的氢化硅烷化催化剂 Download PDF

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Publication number
CN104114278A
CN104114278A CN201280069318.4A CN201280069318A CN104114278A CN 104114278 A CN104114278 A CN 104114278A CN 201280069318 A CN201280069318 A CN 201280069318A CN 104114278 A CN104114278 A CN 104114278A
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CN
China
Prior art keywords
alkyl
formula
aryl
unsaturated
hydrosilylation
Prior art date
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Pending
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CN201280069318.4A
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English (en)
Chinese (zh)
Inventor
K.J.维勒
C.C.H.阿迪恩扎
J.博耶
P.西里科
J.G.P.得利斯
K.刘易斯
S.A.奈
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General Electric Co
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General Electric Co
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Publication of CN104114278A publication Critical patent/CN104114278A/zh
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/323Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/847Nickel

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201280069318.4A 2011-12-14 2012-12-13 基于非贵金属的氢化硅烷化催化剂 Pending CN104114278A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/325,250 2011-12-14
US13/325,250 US9782763B2 (en) 2011-12-14 2011-12-14 Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
PCT/US2012/069469 WO2013090548A1 (en) 2011-12-14 2012-12-13 Non- precious metal -based hydrosilylation catalysts

Publications (1)

Publication Number Publication Date
CN104114278A true CN104114278A (zh) 2014-10-22

Family

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Family Applications (1)

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CN201280069318.4A Pending CN104114278A (zh) 2011-12-14 2012-12-13 基于非贵金属的氢化硅烷化催化剂

Country Status (8)

Country Link
US (2) US9782763B2 (enExample)
EP (1) EP2790829B1 (enExample)
JP (1) JP6211531B2 (enExample)
KR (1) KR20140116100A (enExample)
CN (1) CN104114278A (enExample)
BR (1) BR112014014517A2 (enExample)
TW (1) TWI614063B (enExample)
WO (1) WO2013090548A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107511176A (zh) * 2017-08-15 2017-12-26 常州大学 一种铁基吡咯烷酮离子液体催化不饱和烷基酯硅氢加成反应的方法
CN108200762A (zh) * 2015-10-26 2018-06-22 国际壳牌研究有限公司 强催化剂及催化剂载体、其制备和其用途
CN110343128A (zh) * 2018-04-04 2019-10-18 中国科学院化学研究所 一种通过硅氢化反应制备硅烷的方法
US11319265B2 (en) 2018-11-02 2022-05-03 Shell Usa, Inc. Separation of ethane oxidative dehydrogenation effluent

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US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
US9890182B2 (en) * 2013-05-06 2018-02-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
CN105228744B (zh) 2013-05-15 2021-04-06 莫门蒂夫性能材料股份有限公司 用甲硅烷基氢化物活化金属盐及其在氢化硅烷化反应中的应用
EP3071584B1 (en) 2013-11-19 2017-11-08 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
WO2015077304A1 (en) 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2016540753A (ja) 2013-11-19 2016-12-28 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのそれらの使用
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ES2880788T3 (es) 2017-03-08 2021-11-25 Evonik Operations Gmbh Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos
ES2881271T3 (es) 2017-03-08 2021-11-29 Evonik Operations Gmbh Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos
US10377776B2 (en) 2017-03-08 2019-08-13 Evonik Degussa Gmbh Process for preparing tris[3-(alkoxysilyl)propyl]isocyanurates
EP3473631B1 (de) 2017-10-19 2020-01-08 Evonik Operations GmbH Neue epoxy-funktionelle alkoxysilane, verfahren zu deren herstellung und deren verwendung
DE102018210886A1 (de) 2018-07-03 2020-01-09 Evonik Degussa Gmbh Verfahren zur Herstellung von Alkylalkoxysilanen
CN112739787B (zh) 2018-09-13 2023-07-25 迈图高新材料有限责任公司 官能聚硅氧烷
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108200762A (zh) * 2015-10-26 2018-06-22 国际壳牌研究有限公司 强催化剂及催化剂载体、其制备和其用途
CN107511176A (zh) * 2017-08-15 2017-12-26 常州大学 一种铁基吡咯烷酮离子液体催化不饱和烷基酯硅氢加成反应的方法
CN107511176B (zh) * 2017-08-15 2020-02-14 常州大学 一种铁基吡咯烷酮离子液体催化不饱和烷基酯硅氢加成反应的方法
CN110343128A (zh) * 2018-04-04 2019-10-18 中国科学院化学研究所 一种通过硅氢化反应制备硅烷的方法
CN110343128B (zh) * 2018-04-04 2021-02-19 中国科学院化学研究所 一种通过硅氢化反应制备硅烷的方法
US11319265B2 (en) 2018-11-02 2022-05-03 Shell Usa, Inc. Separation of ethane oxidative dehydrogenation effluent

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US20130158281A1 (en) 2013-06-20
TW201330930A (zh) 2013-08-01
KR20140116100A (ko) 2014-10-01
BR112014014517A2 (pt) 2017-06-13
JP6211531B2 (ja) 2017-10-11
TWI614063B (zh) 2018-02-11
EP2790829B1 (en) 2022-12-07
US9782763B2 (en) 2017-10-10
JP2015501842A (ja) 2015-01-19
US20180015449A1 (en) 2018-01-18
US11052383B2 (en) 2021-07-06
WO2013090548A1 (en) 2013-06-20
EP2790829A1 (en) 2014-10-22

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Application publication date: 20141022