CN104098995A - 一种阻燃与防水性水性聚氨酯涂料的制备方法 - Google Patents
一种阻燃与防水性水性聚氨酯涂料的制备方法 Download PDFInfo
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- CN104098995A CN104098995A CN201410346560.2A CN201410346560A CN104098995A CN 104098995 A CN104098995 A CN 104098995A CN 201410346560 A CN201410346560 A CN 201410346560A CN 104098995 A CN104098995 A CN 104098995A
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- aqueous polyurethane
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 14
- 239000004814 polyurethane Substances 0.000 title abstract description 8
- 229920002635 polyurethane Polymers 0.000 title abstract description 8
- 239000003973 paint Substances 0.000 title abstract description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 13
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- XRADHEAKQRNYQQ-UHFFFAOYSA-K trifluoroneodymium Chemical compound F[Nd](F)F XRADHEAKQRNYQQ-UHFFFAOYSA-K 0.000 claims abstract description 12
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 8
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 8
- 239000004970 Chain extender Substances 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000011527 polyurethane coating Substances 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 10
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 9
- 239000012747 synergistic agent Substances 0.000 claims description 9
- 238000004945 emulsification Methods 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 5
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 5
- WIHIUTUAHOZVLE-UHFFFAOYSA-N 1,3-diethoxypropan-2-ol Chemical compound CCOCC(O)COCC WIHIUTUAHOZVLE-UHFFFAOYSA-N 0.000 claims description 4
- PSCXEUSWZWRCMQ-UHFFFAOYSA-N F[S](F)F Chemical compound F[S](F)F PSCXEUSWZWRCMQ-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 4
- GZCGUPFRVQAUEE-KVTDHHQDSA-N aldehydo-D-mannose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-KVTDHHQDSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- ULUJSLFWDQSXRS-UHFFFAOYSA-N ethenyl diethyl phosphate Chemical compound CCOP(=O)(OCC)OC=C ULUJSLFWDQSXRS-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- YYUUJIWMNXYSDW-UHFFFAOYSA-N COCC[S](N)(F)(F)F Chemical compound COCC[S](N)(F)(F)F YYUUJIWMNXYSDW-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- HGCRMXNQSAARKC-UHFFFAOYSA-N ethyl 2-methyl-4-propylpyrimidine-5-carboxylate Chemical group CCCC1=NC(C)=NC=C1C(=O)OCC HGCRMXNQSAARKC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 8
- 239000004753 textile Substances 0.000 abstract description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- YBNBOGKRCOCJHH-UHFFFAOYSA-N hydroxy-[4-[hydroxy(dimethyl)silyl]phenyl]-dimethylsilane Chemical compound C[Si](C)(O)C1=CC=C([Si](C)(C)O)C=C1 YBNBOGKRCOCJHH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- GEPJPYNDFSOARB-UHFFFAOYSA-N tris(4-fluorophenyl)phosphane Chemical compound C1=CC(F)=CC=C1P(C=1C=CC(F)=CC=1)C1=CC=C(F)C=C1 GEPJPYNDFSOARB-UHFFFAOYSA-N 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 10
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000000779 smoke Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实验组 | 实例一 | 实例二 | 实例三 | 实例四 | 实例五 |
膜外观(耐水性48h) | 透明 | 透明 | 透明 | 透明 | 透明 |
硬度 | B | B | B | B | B |
附着力/ 级 | 2 | 2 | 2 | 3 | 3 |
柔韧性/mm | 2 | 2 | 2 | 2 | 3 |
实验组 | 实例一 | 实例二 | 实例三 | 实例四 | 实例五 |
断裂伸长率(%) | 151 | 146 | 155 | 167 | 169 |
抗张强度(MPa) | 5.7 | 5.6 | 5.7 | 5.9 | 5.8 |
抗磨耗(级) | 3.5 | 4 | 4 | 4.5 | 4.5 |
实例一 | 实例二 | 实例三 | 实例四 | 实例五 | 市场PU-1 | |
最大烟密度 | 23 | 26 | 28 | 11 | 6 | 43 |
达到最大烟密度时间/s | 160 | 160 | 185 | 180 | 180 | 120 |
氧指数 | 25.5 | 24.7 | 25.8 | 26.8 | 26.7 | 23 |
有焰燃烧时间/s | 21.4 | 21.4 | 13.2 | 10.7 | 10.0 | 24 |
无焰燃烧时间/s | 0 | 0 | 0 | 0 | 0 | 0 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410346560.2A CN104098995B (zh) | 2014-07-21 | 2014-07-21 | 一种阻燃与防水性水性聚氨酯涂料的制备方法 |
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CN201410346560.2A CN104098995B (zh) | 2014-07-21 | 2014-07-21 | 一种阻燃与防水性水性聚氨酯涂料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104098995A true CN104098995A (zh) | 2014-10-15 |
CN104098995B CN104098995B (zh) | 2016-05-04 |
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CN201410346560.2A Active CN104098995B (zh) | 2014-07-21 | 2014-07-21 | 一种阻燃与防水性水性聚氨酯涂料的制备方法 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040230010A1 (en) * | 2003-05-15 | 2004-11-18 | Korea Kumho Petrochemical Co., Ltd. | High 1,4-cis polybutadiene-polyurethane copolymer and preparation method thereof |
CN1884335A (zh) * | 2006-05-23 | 2006-12-27 | 山东圣光化工集团有限公司 | 聚硅氧烷-聚醚共聚物改性水性聚氨酯的制造方法 |
CN102361888A (zh) * | 2009-01-23 | 2012-02-22 | 株式会社普利司通 | 用多氰基化合物官能化的聚合物 |
CN102898936A (zh) * | 2012-10-13 | 2013-01-30 | 段宝荣 | 一种阻燃型水性聚氨酯的制备方法 |
CN103436155A (zh) * | 2013-09-09 | 2013-12-11 | 段宝荣 | 一种耐光性水性聚氨酯涂料的制备方法 |
CN103865027A (zh) * | 2014-02-27 | 2014-06-18 | 西安理工大学 | 一种水性聚氨酯及其制备方法 |
-
2014
- 2014-07-21 CN CN201410346560.2A patent/CN104098995B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040230010A1 (en) * | 2003-05-15 | 2004-11-18 | Korea Kumho Petrochemical Co., Ltd. | High 1,4-cis polybutadiene-polyurethane copolymer and preparation method thereof |
CN1884335A (zh) * | 2006-05-23 | 2006-12-27 | 山东圣光化工集团有限公司 | 聚硅氧烷-聚醚共聚物改性水性聚氨酯的制造方法 |
CN102361888A (zh) * | 2009-01-23 | 2012-02-22 | 株式会社普利司通 | 用多氰基化合物官能化的聚合物 |
CN102898936A (zh) * | 2012-10-13 | 2013-01-30 | 段宝荣 | 一种阻燃型水性聚氨酯的制备方法 |
CN103436155A (zh) * | 2013-09-09 | 2013-12-11 | 段宝荣 | 一种耐光性水性聚氨酯涂料的制备方法 |
CN103865027A (zh) * | 2014-02-27 | 2014-06-18 | 西安理工大学 | 一种水性聚氨酯及其制备方法 |
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Inventor after: Luo Congdian Inventor after: Tan Yonggan Inventor before: Zhu Lei Inventor before: Gao Xiaolin Inventor before: Zhang Jianguo |
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Effective date of registration: 20160411 Address after: Huadu District, Guangdong city of Guangzhou province 510880 Flower Town Huacheng Road No. 13 four Xinzhuang self Applicant after: Sports field material Co., Ltd of nation is contained in Guangzhou Address before: 264000 16-2, Fu Qing Street, Zhifu District, Shandong, Yantai Applicant before: Zhu Lei |