CN104042507B - High printing opacity state pure amino acid is from thick soft gel of type face cleaning and preparation method thereof - Google Patents

High printing opacity state pure amino acid is from thick soft gel of type face cleaning and preparation method thereof Download PDF

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CN104042507B
CN104042507B CN201410270157.6A CN201410270157A CN104042507B CN 104042507 B CN104042507 B CN 104042507B CN 201410270157 A CN201410270157 A CN 201410270157A CN 104042507 B CN104042507 B CN 104042507B
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amino acid
lauroyl
parts
sodium
product
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CN104042507A (en
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贾福怀
马云龙
宁丛江
胡建锋
许璐云
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NINGBO YUFANGTANG BIOTECHNOLOGY CO Ltd
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NINGBO YUFANGTANG BIOTECHNOLOGY CO Ltd
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Abstract

The invention discloses a kind of high printing opacity state pure amino acid from the thick soft gel of type face cleaning; it is characterized in that being made up of following component raw material: cocounut oil acyl glycine potassium, lauroyl glycine potassium, sodium lauroyl sarcosine, lauroyl taurine potassium, cocounut oil acyl apple amino acid sodium, lauroyl oat amino acid sodium, palmityl hydrolyzed wheat protein, dipotassium glycyrrhizinate, trimethylglycine, glycerine, sodium citrate, sodium chloride, plants essential oil and purified water, utilize conventional equipment cold process high efficiency to prepare high-consistency product.Instant invention overcomes the deficiencies in the prior art, provide a kind of produce convenient, good stability, foam are fine and closely woven, skinfeel is pleasant, preservative free adds and the brilliant glimmering bright pure amino acid of outward appearance is from the thick soft gel of type face cleaning, product is strayed into human body once in a while also because of in the middle of its body metabolism and end product belongs to food scope and lossless health.

Description

High printing opacity state pure amino acid is from thick soft gel of type face cleaning and preparation method thereof
Technical field
The present invention relates to technical field of skin care, especially relate to a kind of high printing opacity state pure amino acid from thick type The soft gel of face cleaning.The invention still further relates to the preparation from the thick soft gel of type face cleaning of a kind of high printing opacity state pure amino acid Method.
Background technology
Along with the acceleration of modernization, skin care trilogy classics theory (cleans, clears up cortex and moisten) Spread to the popular common people from modern woman.That is, people focus more on air-borne dirt, it is intended to by using Face cleaning product reduces the contaminated air injury to facial skin.So, due to step pair based on clean skin In beauty treatment, there is most important effect, therefore come from the series of the face cleaning with mildy wash as representative of petrochemical material Appearing on the market in a large number of product.
But the fact that severe it is that people are while being widely used chemical synthesis type face cleaning product, in raw material The microchemical pollutions such as the side reaction product being mixed into just are penetrated into internal from pore, the most absorbed synthetic Matter being unfavorable for, the catabolite of health is hidden assembly, waits to accumulate and can cause various health to a certain extent Problem occurs.Therefore, it is derived from that natural material, self green health be harmless and in the middle of its body metabolism and End-product belongs to again the face cleaning product of food scope and is the most progressively pursued by consumer.Wherein, with natural grease Fat acid and the pure amino acid surfactant face cleaning product that amino acid is raw material, just comply with development trend, Become industry and fall over each other the focus of research and development.
The soft gel products of face cleaning with amino acid surfactant as major ingredient, detergency is moderate, foam is soft, Skinfeel is pleasant, to allergic and excitatory low, gain great popularity.But because of amino acid surfactant self Some features, cause the amino acid on existing market to be washed one's face clean skin product, on formula and preparation technology All deposit many drawbacks, more do not reach decomposition or body metabolism intermediate product belongs to this requirement of food scope.Tool Being summarized as follows of body:
1. amino acid surfactant thickening is extremely because of difficulty, the most still without fruitful special thickener, Although some fatty acyl dilactic acid sodium and fatty alcohol lactate can help to amino acid surfactant system Thickening, but effect is limited, it is extremely difficult to prepare soft gel；The most popular amino acid mildy wash Series is still by traditional fatty alcohol polyoxyethylene ether sulfate (or fatty alcohol phosphate)+aliphatic acid second The thickening of alkylolamides (or amine oxide and glycine betaine) system, the even support oleic series macromolecule having Thickener, amino acid surfactant is only supporting role, numerous synthesis compounds negative effect nothing to skin Method is avoided；
2. Japanese patent application JP Laid-Open 6-264092A discloses a kind of transparent solid washing agent, can make For the soap washed one's face, its raw material composition includes: with potassium, sodium and three ethanol of 55 weight portion 1.8 equivalents In amine with the palmityl becoming salt-Pidolidone salt and stearyl-Pidolidone salt, 15 parts by weight of glycerin, 1.0 parts by weight of urea and ion exchange water 29 weight portion, its preparation method includes: mixed by each composition, It is heated to 70～80 DEG C, uniform dissolution, it is then injected in mould, cooling and solidifying shapes, and is dried aging. Commercially available DHC amino acid transparent moisturizing crystal soap is the representative products of this technology.But this amino acid is transparent Moisturizing crystal soap, for forming regid gel, too much depends on the alcamines petrochemical materials such as triethanolamine, reaches not To being derived from natural and decomposing or body metabolism intermediate product belongs to the requirement of food scope.And the water of this gellike Solution has the turning point that obvious denseness falls sharply, and can not get pure amino acid table in the aqueous solution and lives content less than 35% Still in the soft gel that height is thick.Could not it addition, these glutamic acid series of products store a color and luster variation difficult problem for a long time always Overcome.Undesirable to Oily cleaning power, in process, the trace solvent of residual is still idiosyncrasy The sensitization hidden danger of person；
3. the Chinese invention patent of application number CN201310339096.X relates to one not containing sulfate and two The conditioning shampoo composition of oxane, it is characterised in that: include the amino acid pattern anionic surface of 4.5%-15% Activating agent and thickening composition, described amino acid pattern anion surfactant is cocoyl alanine Salt, lauroyl glutamate, cocounut oil acyl glycinate, Hamposyl L salt, methyl cocoyl ox One of sulfonate or their mixture, salt therein is sylvite or sodium salt or triethanolamine salt；Described increasing Thick composition be the glyceryl cocoate of 0.2%-4.0%, the trihydroxy stearin of 0.05%-1.00%, The poly-hydroxy stearic acid of 0.05-1.50% and acrylic acid (ester) analog copolymer of 0.2-3.0%, described percentage It is mass percent.It is an advantage of the current invention that range of viscosities, at 3000-30000cps, presents long rheology, Being prone to from container pour out, be easily spread on hair, uniform in foaming is comfortable, and not containing sulfate with Dioxanes, has safety, bland beneficial effect.But this technical scheme still relies on, and to be derived from petrochemical industry former Acrylic acid (ester) analog copolymer of material makees thickener leading role, and methyl cocoyl taurate and three ethanol Amine salt is also relevant with petrochemical, do not reach decomposition or body metabolism intermediate product belong to food scope this Requirement.It addition, the existence of trihydroxy stearin and poly-hydroxy stearic acid causes product low-temperature transparent the best, The defects such as easy layering.
The amino acid tables such as cocounut oil acyl glycinate that 4. accurate purification processes is crossed or lauroyl glycinate are lived, though The high thick system of electrolyte furnishing of available sodium chloride etc, but this high thick system transparency is poor, the easily analysis of storage for a long time Going out particulate, during low temperature, water solubility is deteriorated and returns turbid, and denseness reduces, and this system washes rear skin in puckery, very Difficult commercialization.
In sum, up to now, industry not yet develop good stability, foam is fine and closely woven, skinfeel is pleasant, The pure amino acid of high printing opacity state is from the thick soft gel of type face cleaning.
Summary of the invention
It is an object of the invention to provide a kind of high printing opacity state pure amino acid from the thick soft gel of type face cleaning, it has Good stability, foam are fine and closely woven, skinfeel is pleasant, high printing opacity state, and side effect is little, completely from thick feature. The invention also discloses a kind of high printing opacity state pure amino acid preparation method from the thick soft gel of type face cleaning.
3) the technical solution adopted in the present invention is: high printing opacity state pure amino acid is soft solidifying from thick type face cleaning Glue, by weight percentage, its raw material includes:
Cocounut oil acyl glycine potassium 8～12 parts；
Lauroyl glycine potassium 6～10 parts；
Sodium lauroyl sarcosine 6.2～9 parts；
Lauroyl taurine potassium 0.5～1.5 parts；
Cocounut oil acyl apple amino acid sodium 0.5～1.0 parts；
Lauroyl oat amino acid sodium 0.5～1.0 parts；
Palmityl hydrolyzed wheat protein 0.1～0.5 part；
Dipotassium glycyrrhizinate 0.1～0.15 part；
Trimethylglycine 0.5～1.0 parts；
Glycerine 1～3 parts；
Sodium citrate 2.8～3.2 parts；
Sodium chloride 3.2～3.8 parts；
Plants essential oil 0.1～0.15 part；
Purified water 62.7～72.8 parts；
Wherein, described cocounut oil acyl glycine potassium is commercially available to be derived from natural cosmetics-stage cocounut oil acyl glycine potassium powder End 30～35% aqueous solution dosage be 20～30ppm food grade xanthans and dosage be 30～50ppm solvable Property chitin in 38～42 DEG C of mix and blends 8 hours, then add 0.1～0.5% pharmaceutical grade decolouring special-purpose activated charcoal Press filtration after 35～37 DEG C of mix and blends at least 1 hour and obtain；Lauroyl glycine potassium system pharmaceutical grade is high-purity pale blue Osmanthus acyl glycine potassium powder 30～35% aqueous solution dosage be 20～30ppm food grade xanthans and dosage It is 30～50ppm soluble chitins in 38～42 DEG C of mix and blends 8 hours, then adds 0.1～0.5% medicinal Level decolouring special-purpose activated charcoal after 35～37 DEG C of mix and blends at least 1 hour press filtration and obtain.
By weight percentage, its raw material includes:
Cocounut oil acyl glycine potassium 10～11 parts；
Lauroyl glycine potassium 7～9 parts；
Sodium lauroyl sarcosine 7.6～8.4 parts；
Lauroyl taurine potassium 0.8～1.2 parts；
Cocounut oil acyl apple amino acid sodium 0.75～0.88 part；
Lauroyl oat amino acid sodium 0.75～0.88 part；
Palmityl hydrolyzed wheat protein 0.25～0.4 part；
Dipotassium glycyrrhizinate 0.12～0.14 part；
Trimethylglycine 0.65～0.85 part；
Glycerine 1.8～2.6 parts；
Sodium citrate 2.9～3 parts；
Sodium chloride 3.4～3.6 parts；
Plants essential oil 0.12～0.13 part；
Purified water 58～65 parts.
Described cocounut oil acyl glycine potassium, lauroyl glycine potassium, sodium lauroyl sarcosine, cocounut oil acyl apple Amino acid sodium, lauroyl oat amino acid sodium, palmityl hydrolyzed wheat protein, lauroyl taurine potassium, Dipotassium glycyrrhizinate, trimethylglycine are and are derived from natural cosmetics-stage or pharmaceutical grade high sterling.
Described glycerine, sodium citrate, sodium chloride are and are derived from natural food-grade, cosmetics-stage or medicine Level.
Described plants essential oil is India essential oil in the last of the ten Heavenly stems, refined jasmine oil, flores aurantii essential oil, white orchid essential oil or Buddha's hand Mandarin orange essential oil.
Described purified water is pure water, distilled water or deionized water.
High printing opacity state pure amino acid, from the preparation method of the thick soft gel of type face cleaning, comprises the steps:
1) under the stirring of 80～100rpm, cocounut oil acyl glycine potassium or lauroyl glycine potassium are divided many Criticize and put in purified water, be made into 35% aqueous solution, with sprayer by 0.1% food grade xanthan glue under stirring Solution sprayed in 10 minutes, made food grade xanthans concentration in system reach 20～30ppm, after stirring, With sprayer, the 0.5% soluble chitin aqueous solution was sprayed in 10 minutes, make solubility first in system Shell element concentration reaches 30～50ppm, controls temperature 38～42 DEG C of mix and blends at least 8 hours, then adds to system Add up material weigh 0.1～0.5% pharmaceutical grade decolouring special-purpose activated charcoal in 35～37 DEG C of mix and blends at least 1 hour, Enter plate and frame filter press press filtration by infusion and obtain colourless transparent liquid, with filter cake washing lotion degree of thickening to 30%, obtain product Thing A, this product A separate out without floccule when 0 DEG C of low temperature；
The lauroyl taurine potassium aqueous solution of purified water furnishing 30% content, adds dipotassium glycyrrhizinate, trimethyl Glycine and glycerine, control temperature 30～35 DEG C of mix and blends at least 1 hour, add plants essential oil, control Temperature 25～30 DEG C of mix and blends at least 1 hour, making system is fully transparent state, obtains product B；
Sodium citrate and sodium chloride mixing, be crushed to 80 mesh particle diameters with pulverizer, obtain product C；
2) under the stirring of 80～100rpm, by sodium lauroyl sarcosine, cocounut oil acyl apple amino acid sodium And palmityl hydrolyzed wheat protein is separately added in product A, at least stirring 30 minutes to uniform state, then Add product B, control temperature 30～35 DEG C of mixing at least stir 1 hour to uniform state；
4) under the stirring of 300～500rpm, in 30 minutes, product C is divided in many batches of uniform inputs Stating in material, temperature control 25～35 DEG C dissolve at least 1 hour, and then rate controlling degree 80～100rpm stirs at least 2 hours, obtain the thick soft gel of transparent height, then stand at least 24 hours to automatic froth breaking, fill after denseness is stable Expect to obtain finished product.
Advantage for present invention is: good stability, foam are fine and closely woven, skinfeel is pleasant, high printing opacity state, And side effect is little, completely from thick.The high printing opacity state pure amino acid of the present invention is ingenious from the thick soft gel of type face cleaning Avoid the strong power harsh conditions such as fast homogeneous and high-temperature heating, utilize conventional equipment cold process high efficiency to prepare High-consistency product, ultralow stimulation has the pure amino acid surfactant of antibacterial effect concurrently, is completely free of and is derived from The macromolecule thickener of petrochemical industry, complete independently thickening, it is derived from the compound pure of natural each tool advantage Amino acid surfactant, by the comprehensively regulating function of many effects of protein hydrolysate class surfactant, Avoid adding compatibility and the complex process sex chromosome mosaicism that numerous synthesis component causes, more make product toward edibleization, Naturalization and safe step bigger step, in the middle of and its body metabolism harmless from self green health and From the point of view of end-product belongs to again food scope, this technique still belongs to pioneering.
Meanwhile, the high printing opacity state pure amino acid of the present invention also has the following characteristics that from the thick soft gel of type face cleaning
1. store transparency for a long time for cocounut oil acyl glycine potassium or lauroyl glycine potassium aqua to decline, its chlorination Sodium thickening finished product low temperature is easily in cotton-shaped precipitation and the defect such as denseness is unstable, originally in food grade materials In the range of filter out efficient xanthans-soluble chitin removal of impurities system, coordinate activated carbon and conventional equipment, It is secondary that quickness and high efficiency ground removes the trace that in this type of amino acid surfactant product, extremely difficult conventional method is removed Product and other non-active ingredients, even if making the glycine table soft gel for major ingredient alive remain at low temperature Presenting high light transmittance as crystal, and denseness is stable, anti-interference ability is strong.
2. make can be by open-and-shut mode at low electrolyte conditions for sodium citrate-sodium chloride collaboration system The denseness of the pure base acid table complex liquid alive of each tool characteristic is adjusted to whippy gel state, avoids conventional gel Clean skin product are derived from, because adding, the such as blocking pore that the synthesising macromolecule copolymer thickener of petrochemical industry brings, sliding Greasy, it is difficult to the drawbacks such as flushing, finished product bath sense is pleasant, to face skin without irritating.
3. it is derived from the optimal compatibility of natural pure base acid table complex liquid surfactant alive, makes finished product disposable Complete washing foaming nursing and compose fat moisturizing and tender skin operating process.
4. it is derived from natural pure base acid surfaces activating agent and the optimal compatibility of food grade auxiliary agent, both stops synthesis The importing of chemical composition sensitizing agent, makes again product be strayed into human body once in a while also because of in the middle of its body metabolism and End-product belongs to food scope and lossless health；
Filter out amino acid surfactant compound system the most originally, in addition to routine effect, and this Other material Synergistic in invention formula, the creative antiseptic effect having embodied excellence, make this The pot-life of application can reach 2～3 years.The soft gel of face cleaning provided herein effectively prevent and causes The risk that health is constituted by allergic arch-criminal's chemical synthesis preservative.
Construct lauroyl taurine potassium dipotassium glycyrrhizinate green solubilizing systems solubilising plant essence the most originally Oil, makes the finished product of interpolation natural essential oil remain to keep high light transmittance under low-temperature condition, avoids and be derived from stone Change the raw material polyoxyethylene series easy sensitization of essential oil solubilizer and dioxanes remains the equivalent risk that exceeds standard.
7. the technique of the application belongs to cold process technique, it is not necessary to the strong power condition such as fast homogeneous and high-temperature heating, Safety, energy-saving and environmental protection.
In sum, the high printing opacity state pure amino acid of the present invention overcomes existing skill from the thick soft gel of type face cleaning The deficiency of art, it is provided that a kind of production is convenient, good stability, foam are fine and closely woven, skinfeel is pleasant, without anticorrosion Agent interpolation and the brilliant glimmering bright pure amino acid of outward appearance are from the thick soft gel of type face cleaning, and product is strayed into human body also once in a while Because of in the middle of its body metabolism and end product belongs to food scope and lossless health.
Meanwhile, the high printing opacity state pure amino acid of the present invention uses work from the preparation method of the thick soft gel of type face cleaning Skill is ripe, it is not necessary to uses custom-designed equipment, thus is not only beneficial to prepare high-quality product, and easily In control, it is simple to operation, production batch wise differences is more made to reduce, it is simple to modernize big production operation.
Detailed description of the invention
Embodiment 1
Charge ratio:
Cosmetics-stage cocounut oil acyl glycine potassium powder double centner；
80 kilograms of cosmetics-stage lauroyl glycine potassium powder；
30% cosmetics-stage sodium lauroyl sarcosine 250 kilograms；
50% 15 kilograms of cosmetics-stage lauroyl taurine potassium；
30% cosmetics-stage cocounut oil acyl apple amino acid sodium 18 kilograms；
30% cosmetics-stage lauroyl oat amino acid sodium 18 kilograms；
30% cosmetics-stage palmityl hydrolyzed wheat protein 5 kilograms；
Pharmaceutical grade high sterling dipotassium glycyrrhizinate 1.2 kilograms；
Pharmaceutical grade trimethylglycine 10 kilograms；
Cosmetics-stage glycerine 6 kilograms；
Pharmaceutical grade sodium citrate 28 kilograms；
35 kilograms of pharmaceutical grade sodium chloride；
Plants essential oil uses natural India essential oil in the last of the ten Heavenly stems 1.5 kilograms；
Purified water uses deionized water 412.3 kilograms.
Concrete preparation process:
1) by putting into deionized water 334.29 kilograms in 1000 liter enamel reaction pots, 80rpm's Under stirring, by commercially available cosmetics-stage cocounut oil acyl glycine potassium powder double centner and cosmetics within half an hour Level lauroyl 3 batches of inputs of glycine potassium powder 80 kg.p.m., stir at least 1 hour, are made into 35% water-soluble Liquid, sprayed 0.1% food grade xanthan gum solution 15.42 kilograms with sprayer under stirring in 10 minutes Enter, make food grade xanthans concentration in system reach 30ppm, after stirring, can by 0.5% with sprayer Dissolubility chitin water soluble liquid 5.14 kilograms sprayed in 10 minutes, made soluble chitin concentration in system Reach 50ppm, control 38 DEG C of mix and blends of temperature at least 8 hours, then weigh 0.5% to the total material of system interpolation Pharmaceutical grade decolouring special-purpose activated charcoal meter 10.28 kilograms, in 35 DEG C of mix and blends at least 1 hour, enters by infusion Plate and frame filter press press filtration i.e. obtains colourless transparent liquid, adjusts production concentration by filter cake deionized water washing lotion in three times To 30%, obtain product A, 600 kilograms altogether.
2) deionized water 10 kilograms and 50% cosmetics-stage lauroyl will be put in 50 liter enamel reaction pots Taurine aqueous solutions of potassium 15 kilograms, the aqueous solution of furnishing 30% content, add pharmaceutical grade high sterling glycyrrhizic acid 1.2 kilograms of potassium, pharmaceutical grade trimethylglycine 10 kilograms and cosmetics-stage glycerine 2.6 kilograms, control 30 DEG C of mix and blends of temperature at least 1 hour, add natural India essential oil in the last of the ten Heavenly stems 15 kilograms, control temperature 25 DEG C Mix and blend at least 1 hour, making system is fully transparent state, obtains product B.
3) by pharmaceutical grade sodium citrate 28 kilograms and the mixing of 35 kilograms of pharmaceutical grade sodium chloride, pulverizer powder is used It is broken to 80 mesh particle diameters, obtains product C.
4) product A is counted 600 kilograms and put into 1000 liter enamel reaction pots, under the stirring of 80rpm, By 30% cosmetics-stage sodium lauroyl sarcosine 250 kilograms, cosmetics-stage 30% cocounut oil acyl apple amino acid sodium 18 kilograms, 30% cosmetics-stage lauroyl oat amino acid sodium 18 kilograms and 30% cosmetics-stage palmityl water Solve wheat gluten 5 kilograms to be separately added in product A, stir at least 30 minutes to uniform state.Add Product B, controls 30 DEG C of mix and blends of temperature at least 1 hour to uniform state.
5) under the stirring of 300～500rpm, product C is counted 63 kg.p.m. 6 batches equal in 30 minutes In the above-mentioned material of even input, temperature control 25 DEG C dissolves 1 hour, and then rate controlling degree 80rpm stirring at least 2 is little Time, obtain the thick soft gel of transparent height, then stand at least 24 hours, wait automatic froth breaking, after denseness is stable i.e. Can be fed to obtain finished product.
Embodiment 2
Charge ratio is shown in Table 1.
Concrete preparation process:
1) by putting into distilled water 334.29 kilograms in 1000 liter enamel reaction pots, in the stirring of 90rpm Under, within half an hour, it is derived from 82 kilograms natural of cosmetics-stage cocounut oil acyl glycine potassium powder and source by commercially available From natural cosmetics-stage lauroyl 6 batches of inputs of glycine potassium powder 98 kg.p.m., stir at least 1 hour, It is made into 35% aqueous solution, with sprayer by 0.1% food grade xanthan gum solution 15.42 kilograms under stirring Sprayed in 10 minutes, make food grade xanthans concentration in system reach 30ppm, after stirring, with spray The 0.5% soluble chitin aqueous solution 5.14 kilograms was sprayed in 10 minutes by day with fog, and making can in system Dissolubility chitin concentration reaches 50ppm, controls 40 DEG C of mix and blends of temperature at least 8 hours, then adds to system Add up material and weigh 0.5% pharmaceutical grade decolouring special-purpose activated charcoal meter 10.28 kilograms in 36 DEG C of mix and blends at least 1 Hour, enter plate and frame filter press press filtration by infusion and i.e. obtain colourless transparent liquid, in three times with filter cake distillation washing Liquid adjusts production concentration to 30%, obtains product A, 600 kilograms altogether.
2) distilled water 12.83 kilograms will be put in 50 liter enamel reaction pots and be derived from natural cosmetics-stage 5.5 kilograms of lauroyl taurine potassium, the aqueous solution of furnishing 30% content, add and be derived from natural cosmetics-stage Dipotassium glycyrrhizinate 1 kilogram, it is derived from natural cosmetics-stage trimethylglycine 6 kilograms and is derived from natural food Grade glycerine 10 kilograms, controls 32 DEG C of mix and blends of temperature at least 1 hour, adds natural India essential oil in the last of the ten Heavenly stems 12 kilograms, controlling 28 DEG C of mix and blends of temperature at least 1 hour, making system is fully transparent state, obtains product B。
3) natural food-grade sodium citrate 29 kilograms will be derived from and be derived from natural food-grade sodium chloride 35 Kilogram mixing, be crushed to 80 mesh particle diameters with pulverizer, obtain product C.
4) product A is counted 600 kilograms and put into 1000 liter enamel reaction pots, under the stirring of 90rpm, Natural cosmetics-stage sodium lauroyl sarcosine 88 kilograms will be derived from, be derived from natural cosmetics-stage cocounut oil acyl Apple amino acid sodium 9.8 kilograms, it is derived from natural cosmetics-stage lauroyl oat amino acid sodium 5.2 kilograms And be derived from natural cosmetics-stage palmityl hydrolyzed wheat protein 1.2 kilograms and be separately added in product A, stir Mix at least 30 minutes to uniform state.Add product B and distilled water 197.17 kilograms, control temperature 33 DEG C of mix and blends at least 1 hour are to uniform state.
5) under the stirring of 400rpm, product C is counted the 3 batches of uniform throwings of 64 kg.p.m. in 30 minutes Entering in above-mentioned material, temperature control 30 DEG C dissolves at least 1 hour, and then rate controlling degree 90rpm stirring at least 2 is little Time, obtain the thick soft gel of transparent height, then stand at least 24 hours, wait automatic froth breaking, after denseness is stable i.e. The finished product that can feed.
Embodiment 3
Charge ratio is shown in Table 1.
Concrete preparation process:
1) by putting into distilled water 334.29 kilograms in 1000 liter enamel reaction pots, under the stirring of 90rpm, By 95 kilograms of commercially available pharmaceutical grade high sterling cocounut oil acyl glycine potassium powder and pharmaceutical grade high sterling within half an hour Lauroyl 6 batches of inputs of glycine potassium powder 85 kg.p.m., stir at least 1 hour, are made into 35% aqueous solution, With sprayer, 0.1% food grade xanthan gum solution 15.42 kilograms was sprayed in 10 minutes under stirring, Food grade xanthans concentration in system is made to reach 30ppm, after stirring, with sprayer by 0.5% solubility Chitin water soluble liquid 5.14 kilograms sprayed in 10 minutes, made soluble chitin concentration in system reach 50ppm, controls 40 DEG C of mix and blends of temperature at least 8 hours, then weighs 0.5% medicine to the total material of system interpolation With level decolouring special-purpose activated charcoal meter 10.28 kilograms in 36 DEG C of mix and blends at least 1 hour, use pump injection plate Frame filter press press filtration i.e. obtains colourless transparent liquid, adjusts production concentration extremely by filter cake distilled water washing lotion in three times 30%, obtain product A, 600 kilograms altogether.
2) distilled water 10.6 kilograms and pharmaceutical grade high-purity product lauroyl will be put in 50 liter enamel reaction pots 8.4 kilograms of taurine potassium, the aqueous solution of furnishing 30% content, add pharmaceutical grade high sterling dipotassium glycyrrhizinate 1.2 Kilogram, pharmaceutical grade high sterling trimethylglycine 7 kilograms and cosmetics-stage glycerine 14 kilograms, control temperature 32 DEG C of mix and blends at least 1 hour, add natural refined jasmine oil 1.3 kilograms, control temperature 28 DEG C mixing Stirring at least 1 hour, making system is fully transparent state, obtains product B.
3) by cosmetics-stage sodium citrate 28 kilograms and the mixing of 37.5 kilograms of cosmetics-stage sodium chloride, powder is used Broken machine is crushed to 80 mesh particle diameters, obtains product C.
4) product A is counted 600 kilograms and put into 1000 liter enamel reaction pots, under the stirring of 90rpm, By high-purity for pharmaceutical grade product sodium lauroyl sarcosine 76 kilograms, pharmaceutical grade high sterling cocounut oil acyl apple amino acid sodium 8.2 kilograms, pharmaceutical grade high-purity product lauroyl oat amino acid sodium 7.8 kilograms and pharmaceutical grade high sterling palmityl Hydrolyzed wheat protein 2.6 kilograms is separately added in product A, stirs at least 30 minutes to uniform state.Again Add product B and distilled water 269.4 kilograms, control 33 DEG C of mix and blends of temperature at least 1 hour to uniformly State.
5) under the stirring of 400rpm, product C is counted the 3 batches of uniform throwings of 65.5 kg.p.m. in 30 minutes Entering in above-mentioned material, temperature control 30 DEG C dissolves at least 1 hour, and then rate controlling degree 90rpm stirring at least 2 is little Time, obtain the thick soft gel of transparent height, then stand at least 24 hours, wait automatic froth breaking, after denseness is stable i.e. Can be fed to obtain finished product.
Embodiment 4
Charge ratio is shown in Table 1.
Concrete preparation process:
1) by putting into deionized water 330.57 kilograms in 1000 liter enamel reaction pots, under the stirring of 90rpm, It is derived from 106 kilograms natural of cosmetics-stage cocounut oil acyl glycine potassium powder and medicine by commercially available within half an hour The high-purity product lauroyl 6 batches of inputs of glycine potassium powder 72 kg.p.m. of level, stir at least 1 hour, are made into 35% The aqueous solution, under stirring with sprayer by 0.1% food grade xanthan gum solution 15.28 kilograms in 10 minutes Inside spray into, make food grade xanthans concentration in system reach 30ppm, after stirring, with sprayer by 0.5% The soluble chitin aqueous solution 5.09 kilograms sprayed in 10 minutes, made soluble chitin in system dense Degree reaches 50ppm, controls 40 DEG C of mix and blends of temperature at least 8 hours, then weighs 0.5% to the total material of system interpolation Pharmaceutical grade decolouring special-purpose activated charcoal meter 2.54 kilograms, in 36 DEG C of mix and blends at least 1 hour, uses pump injection plate Frame filter press press filtration i.e. obtains colourless transparent liquid, adjusts production concentration extremely by filter cake deionized water washing lotion in three times 30%, obtain product A, 593 kilograms altogether.
2) high-purity pale blue with pharmaceutical grade by putting into deionized water 29.87 kilograms in 50 liter enamel reaction pots 12.8 kilograms of osmanthus acyl taurine potassium, the aqueous solution of furnishing 30% content, add pharmaceutical grade high sterling glycyrrhizic acid 1.3 kilograms of potassium, it is derived from natural cosmetics-stage trimethylglycine 8 kilograms and pharmaceutical grade glycerine 18 kilograms, Control 32 DEG C of mix and blends of temperature at least 1 hour, add natural orange flower essential oil 1.2 kilograms, control temperature 28 DEG C of mix and blends at least 1 hour, making system is fully transparent state, obtains product B.
3) by pharmaceutical grade sodium citrate 30 kilograms and the mixing of 36 kilograms of pharmaceutical grade sodium chloride, pulverizer powder is used It is broken to 80 mesh particle diameters, obtains product C.
4) product A is counted 593 kilograms and put into 1000 liter enamel reaction pots, under the stirring of 90rpm, Natural cosmetics-stage sodium lauroyl sarcosine 70 kilograms will be derived from, be derived from natural cosmetics-stage cocounut oil acyl Apple amino acid sodium 6.9 kilograms, pharmaceutical grade high-purity product lauroyl oat amino acid sodium 9.1 kilograms and be derived from sky Right cosmetics-stage palmityl hydrolyzed wheat protein 3.7 kilograms is separately added in product A, stirs at least 30 Minute to uniform state.Add product B and deionized water 224.8 kilograms, control temperature 33 DEG C mixing Stir at least 1 hour to uniform state.
5) under the stirring of 400rpm, product C is counted the 3 batches of uniform throwings of 66 kg.p.m. in 30 minutes Entering in above-mentioned material, temperature control 30 DEG C dissolves at least 1 hour, and then rate controlling degree 90rpm stirring at least 2 is little Time, obtain the thick soft gel of transparent height, then stand at least 24 hours, wait automatic froth breaking, after denseness is stable i.e. Can be fed to obtain finished product.
Embodiment 5
Charge ratio is shown in Table 1.
Concrete preparation process:
1) by putting into distilled water 332.43 kilograms in 1000 liter enamel reaction pots, in the stirring of 90rpm Under, by 118 kilograms of commercially available pharmaceutical grade high sterling cocounut oil acyl glycine potassium powder and be derived from sky within half an hour Right cosmetics-stage lauroyl 6 batches of inputs of glycine potassium powder 61 kg.p.m., stir at least 1 hour, join Become 35% aqueous solution, under stirring with sprayer by 0.1% food grade xanthan gum solution 15.34 kilograms in 10 Spray in minute, make food grade xanthans concentration in system reach 30ppm, after stirring, will with sprayer The 0.5% soluble chitin aqueous solution 5.11 kilograms sprayed in 10 minutes, made solubility crust in system Element concentration reaches 50ppm, controls 40 DEG C of mix and blends of temperature at least 8 hours, more always expects weight to system interpolation 0.5% pharmaceutical grade decolouring special-purpose activated charcoal meter 2.56 kilograms, in 36 DEG C of mix and blends at least 1 hour, uses pump Inject plate and frame filter press press filtration and i.e. obtain colourless transparent liquid, adjust product dense by filter cake distilled water washing lotion in three times Degree, to 30%, obtains product A, 596 kilograms altogether.
2) distilled water 30.07 kilograms will be put in 50 liter enamel reaction pots and be derived from natural cosmetics-stage 14.6 kilograms of lauroyl taurine potassium, the aqueous solution of furnishing 30% content, add and be derived from natural cosmetics Level dipotassium glycyrrhizinate 1.4 kilograms, pharmaceutical grade high sterling trimethylglycine 9 kilograms and be derived from natural food Level glycerine 25 kilograms, controls 32 DEG C of mix and blends of temperature at least 1 hour, adds natural white orchid essential oil 1.4 kilograms, controlling 28 DEG C of mix and blends of temperature at least 1 hour, making system is fully transparent state, obtains product Thing B.
3) by cosmetics-stage sodium citrate 31 kilograms and the mixing of 37.5 kilograms of pharmaceutical grade sodium chloride, with pulverizing Machine is crushed to 80 mesh particle diameters, obtains product C.
4) product A is counted 596 kilograms and put into 1000 liter enamel reaction pots, under the stirring of 90rpm, By high-purity for pharmaceutical grade product sodium lauroyl sarcosine 62 kilograms, pharmaceutical grade high sterling cocounut oil acyl apple amino acid sodium 5.4 kilograms, be derived from natural cosmetics-stage lauroyl oat amino acid sodium 10 kilograms and pharmaceutical grade high sterling Palmityl hydrolyzed wheat protein 4.8 kilograms is separately added in product A, stirs at least 30 minutes to uniform shape State.Add product B and 277.3 kilograms of water, control 33 DEG C of mix and blends of temperature at least 1 hour to all Even state.
5) under the stirring of 400rpm, product C is counted the 3 batches of uniform throwings of 66 kg.p.m. in 30 minutes Entering in above-mentioned material, temperature control 30 DEG C dissolves at least 1 hour, and then rate controlling degree 90rpm stirring at least 2 is little Time, obtain the thick soft gel of transparent height, then stand at least 24 hours, wait automatic froth breaking, after denseness is stable i.e. Can be fed to obtain finished product.
Table 1: embodiment charge ratio table
The pure amino acid that previous embodiment 1～5 prepares from the brilliant glimmering printing opacity of the thick soft gel of type face cleaning, stable performance, Decontamination is preferable with skin-moisturizing, skin effect, and Xi Hou face is pleasant moist, without tight sense, popular with current market Outward appearance similar face cleaning product compare, product of the present invention belongs to pure amino acid type, and product is strayed into human body once in a while Also because of in the middle of its body metabolism and end product belongs to food scope and lossless health.
With reference to the countries concerned's standard and professional standard, to the pure amino acid of the present invention from the thick soft gel of type face cleaning With the intimate transparent height selected from the amino acid surfactant content the highest (12%) that circulates in the market The key property of denseness facial cleaner comparative sample is measured that (testing result is polymerized by department of chemistry of Zhejiang University Thered is provided), refer to table 2.
Following artificial digestion liquid can to the putative metabolites toxicity detection of the soft gel of pure amino acid face cleaning of the present invention Verify its nontoxic characteristic.
The preparation (with reference to Chinese Pharmacopoeia 2005 editions second) of simulated gastric fluid: taking concentration is 1mol/L's Hydrochloric acid, adds deionized water dilution, makes pH respectively reach 1.5, add 1g stomach egg with every 100mL liquid The ratio of white enzyme is prepared, after fully dissolving, with miillpore filter (aperture 0.2 μm) filtration sterilization, Stand-by.
The preparation (with reference to Chinese Pharmacopoeia 2005 editions second) of simulated intestinal fluid: take potassium dihydrogen phosphate 6.8g, Add deionized water dissolving, adjust pH to 6.8, be settled to 1000mL, add 10g trypsase, fill Divide after dissolving, with miillpore filter (aperture 0.2 μm) filtration sterilization, stand-by.
By the soft gel of pure amino acid face cleaning of the present invention 50 grams, adjust all with above-mentioned simulated gastric fluid 1000mL, permanent Incubator is put 24 hours for 37 DEG C, adjusts pH to 6.8, add above-mentioned simulated intestinal fluid 1000mL and adjust all, constant temperature Case puts 24 hours for 37 DEG C.The dehydration of mixed liquor normal freeze-drying method is in powdered form, (water content is less than 0.5%), name face cleaning soft gel metabolism powder.
Acute with reference to GBZ/T240.2-2011 chemicals toxicological evaluation program and test method part 2 The correlation step of Oral toxicity test, records the above-mentioned face cleaning soft gel metabolism powder acute oral to big white mouse Toxicity LD50 is 35000mg/kg, and this face cleaning soft gel metabolism powder has belonged to nontoxic level scope, thus indirectly demonstrate,proves The bright soft gel products of pure amino acid face cleaning of the present invention is strayed into human body once in a while also because of in the middle of its body metabolism and final Product belongs to food scope and lossless health.
The foregoing is only the preferred embodiments of the present invention, not thereby limit the scope of the claims of the present invention, Every equivalent structure utilizing description of the invention to be made or equivalence flow process conversion, or directly or indirectly use In the technical field that other are relevant, the most in like manner it is included in the scope of patent protection of the present invention.

Claims (7)

  1. The highest printing opacity state pure amino acid is from the thick soft gel of type face cleaning, and by weight percentage, its raw material includes:
    Cocounut oil acyl glycine potassium 8～12 parts；
    Lauroyl glycine potassium 6～10 parts；
    Sodium lauroyl sarcosine 6.2～9 parts；
    Lauroyl taurine potassium 0.5～1.5 parts；
    Cocounut oil acyl apple amino acid sodium 0.5～1.0 parts；
    Lauroyl oat amino acid sodium 0.5～1.0 parts；
    Palmityl hydrolyzed wheat protein 0.1～0.5 part；
    Dipotassium glycyrrhizinate 0.1～0.15 part；
    Trimethylglycine 0.5～1.0 parts；
    Glycerine 1～3 parts；
    Sodium citrate 2.8～3.2 parts；
    Sodium chloride 3.2～3.8 parts；
    Plants essential oil 0.1～0.15 part；
    Purified water 62.7～72.8 parts；
    Wherein, described cocounut oil acyl glycine potassium is commercially available to be derived from natural cosmetics-stage cocounut oil acyl glycine potassium powder End 30～35% aqueous solution dosage be 20～30ppm food grade xanthans and dosage be 30～50ppm solvable Property chitin in 38～42 DEG C of mix and blends 8 hours, then add 0.1～0.5% pharmaceutical grade decolouring special-purpose activated charcoal Press filtration after 35～37 DEG C of mix and blends at least 1 hour and obtain；Lauroyl glycine potassium system pharmaceutical grade is high-purity pale blue Osmanthus acyl glycine potassium powder 30～35% aqueous solution dosage be 20～30ppm food grade xanthans and dosage It is 30～50ppm soluble chitins in 38～42 DEG C of mix and blends 8 hours, then adds 0.1～0.5% medicinal Level decolouring special-purpose activated charcoal after 35～37 DEG C of mix and blends at least 1 hour press filtration and obtain.
  2. High printing opacity state pure amino acid the most according to claim 1 from the thick soft gel of type face cleaning, by weight hundred Proportion by subtraction meter, its raw material includes:
    Cocounut oil acyl glycine potassium 10～11 parts；
    Lauroyl glycine potassium 7～9 parts；
    Sodium lauroyl sarcosine 7.6～8.4 parts；
    Lauroyl taurine potassium 0.8～1.2 parts；
    Cocounut oil acyl apple amino acid sodium 0.75～0.88 part；
    Lauroyl oat amino acid sodium 0.75～0.88 part；
    Palmityl hydrolyzed wheat protein 0.25～0.4 part；
    Dipotassium glycyrrhizinate 0.12～0.14 part；
    Trimethylglycine 0.65～0.85 part；
    Glycerine 1.8～2.6 parts；
    Sodium citrate 2.9～3 parts；
    Sodium chloride 3.4～3.6 parts；
    Plants essential oil 0.12～0.13 part；
    Purified water 58～65 parts.
  3. High printing opacity state pure amino acid the most according to claim 1 is from the thick soft gel of type face cleaning, and its feature exists In: described cocounut oil acyl glycine potassium, lauroyl glycine potassium, sodium lauroyl sarcosine, cocounut oil acyl apple amino Acid sodium, lauroyl oat amino acid sodium, palmityl hydrolyzed wheat protein, lauroyl taurine potassium, dipotassium glycyrrhizinate, Trimethylglycine is and is derived from natural cosmetics-stage or pharmaceutical grade high sterling.
  4. High printing opacity state pure amino acid the most according to claim 1 is from the thick soft gel of type face cleaning, and its feature exists In: described glycerine, sodium citrate, sodium chloride are and are derived from natural food-grade, cosmetics-stage or pharmaceutical grade.
  5. High printing opacity state pure amino acid the most according to claim 1 is from the thick soft gel of type face cleaning, and its feature exists In: described plants essential oil is India essential oil in the last of the ten Heavenly stems, refined jasmine oil, flores aurantii essential oil, white orchid essential oil or bergamot essence Oil.
  6. High printing opacity state pure amino acid the most according to claim 1 is from the thick soft gel of type face cleaning, and its feature exists In: described purified water is pure water, distilled water or deionized water.
  7. High printing opacity state pure amino acid the most according to any one of claim 1 to 6 is soft solidifying from thick type face cleaning The preparation method of glue, comprises the steps:
    1) content of component according to any one of claim 1 to 6 is got the raw materials ready:
    2) under the stirring of 80～100rpm, many batches of throwings are divided by cocounut oil acyl glycine potassium or lauroyl glycine potassium Enter in purified water, be made into 35% aqueous solution, under stirring with sprayer by 0.1% food grade xanthan gum solution in Spray in 10 minutes, make food grade xanthans concentration in system reach 20～30ppm, after stirring, with spraying The 0.5% soluble chitin aqueous solution was sprayed in 10 minutes by device, made soluble chitin concentration in system Reach 30～50ppm, control temperature 38～42 DEG C of mix and blends at least 8 hours, then add total material to system and weigh 0. 1～0.5% pharmaceutical grade decolouring special-purpose activated charcoal in 35～37 DEG C of mix and blends at least 1 hour, enter sheet frame by infusion Filter press press filtration and colourless transparent liquid, with filter cake washing lotion degree of thickening to 30%, obtain product A, this product A in Separate out without floccule during 0 DEG C of low temperature；
    The lauroyl taurine potassium aqueous solution of purified water furnishing 30% content, addition dipotassium glycyrrhizinate, trimethyl are sweet Propylhomoserin and glycerine, control temperature 30～35 DEG C of mix and blends at least 1 hour, add plants essential oil, control temperature 25～30 DEG C of mix and blends at least 1 hour, making system is fully transparent state, obtains product B；
    Sodium citrate and sodium chloride mixing, be crushed to 80 mesh particle diameters with pulverizer, obtain product C；
    3) under the stirring of 80～100rpm, by sodium lauroyl sarcosine, cocounut oil acyl apple amino acid sodium and palm fibre Palmitic acid acyl hydrolyzed wheat protein is separately added in product A, and at least stirring adds product to uniform state in 30 minutes Thing B, controls temperature 30～35 DEG C of mixing at least stir 1 hour to uniform state；
    4) under the stirring of 300～500rpm, product C is divided the many batches of above-mentioned things of uniform input in 30 minutes In material, temperature control 25～35 DEG C dissolve at least 1 hour, and then rate controlling degree 80～100rpm stirs at least 2 hours, Obtain the thick soft gel of transparent height, then stand at least 24 hours to automatic froth breaking, feed after denseness is stable Product.
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CN105997572B (en) * 2016-05-19 2021-02-02 广州靓美莲美容科技有限公司 Facial cleanser containing nano graphene and preparation method thereof
CN106667782B (en) * 2017-03-01 2018-02-06 广州市花安堂生物科技有限公司 A kind of face cleaning gel and preparation method thereof
CN109984953B (en) * 2019-05-22 2022-08-19 宁波御坊堂生物科技有限公司 Protein peptide gel for bath and skin cleaning and preparation method thereof
CN110327243A (en) * 2019-08-15 2019-10-15 武汉洛园生物科技有限公司 A kind of clean mousse composition of the amino acid of plant origin and preparation method
CN110680759A (en) * 2019-11-18 2020-01-14 浙江绿岛科技有限公司 Aerosol type amino acid face-cleaning gel and preparation method thereof
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